Material Safety Data Sheet
Manganese (II) Sulfate Monohydrate
ACC# 13655
Section 1 - Chemical Product and
Company Identification
MSDS Name: Manganese (II) Sulfate Monohydrate
Catalog Numbers: S80061ACS, S80071-2, M113-3,
M113-500, M114-12, M114-212, M114-500, M115-12,
M115-212, M115-500, NC9747671
Synonyms: Manganese(II) sulfate, monohydrate; manganous
sulfate monohydrate
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call:
703-527-3887
Section 2 - Composition, Information on
Ingredients
CAS# Chemical Name Percent EINECS/ELINCS
Manganese sulfate,
10034-96-5 >98 unlisted
monohydrate
Hazard Symbols: XN
Risk Phrases: 68/20/22
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: pink solid. May cause eye and skin
irritation. May cause respiratory and digestive tract irritation.
May cause central nervous system effects. Hygroscopic
(absorbs moisture from the air).
Target Organs: Central nervous system.
Potential Health Effects
Eye: May cause mild eye irritation.
Skin: May cause skin irritation. Low hazard for usual
industrial handling.
Ingestion: May cause gastrointestinal irritation with nausea,
vomiting and diarrhea.
Inhalation: May cause respiratory tract irritation.
Chronic: Chronic inhalation or ingestion of silver salts may
cause argyria characterized by a permanent blue-gray
discoloration of the eyes, skin, mucous membranes, and
internal organs.
Section 4 - First Aid Measures
Eyes: Flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. Get
medical aid.
Skin: Flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical
aid if irritation develops or persists. Remove contaminated
clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls
of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.
Antidote: The use of Calcium disodium EDTA as a chelating
agent should be determined by qualified medical personnel.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained
breathing apparatus in pressure-demand, MSHA/NIOSH
(approved or equivalent), and full protective gear. Material
will not burn.
Extinguishing Media: For small fires, use water spray, dry
chemical, carbon dioxide or chemical foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0;
Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective
equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a
suitable disposal container. Avoid generating dusty conditions.
Section 7 - Handling and Storage
Handling: Wash hands before eating. Use with adequate
ventilation. Avoid contact with skin and eyes. Avoid ingestion
and inhalation.
Storage: Store in a tightly closed container.
Section 8 - Exposure Controls, Personal
Protection
Engineering Controls: Use adequate general or local
exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
Chemical OSHA - Final
ACGIH NIOSH
Name PELs
Manganese
monohydrate
OSHA Vacated PELs: Manganese sulfate, monohydrate: No
OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin: Wear impervious gloves.
Clothing: Wear appropriate protective gloves and clothing to
prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in
29 CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved respirator
when necessary.
Section 9 - Physical and Chemical
Properties
Physical State: Solid
Appearance: pink
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 1562 deg F
Freezing/Melting Point:1292 deg F
Decomposition Temperature:Not available.
Solubility: Completely soluble in water.
Specific Gravity/Density:3.25 (water=1)
Molecular Formula:MnSO4.H2O
Molecular Weight:169.009
Section 10 - Stability and Reactivity
Chemical Stability: Stable.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Can react with
strong acid, strong oxidizing agents, powdered metals; may
react violently with hydrogen peroxide.
Hazardous Decomposition Products: Carbon dioxide,
sulfur oxides (SOx), including sulfur oxide and sulfur dioxide,
oxides of manganese.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
RTECS#:
CAS# 10034-96-5: OP0893500
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 10034-96-5: Not listed by ACGIH, IARC, NIOSH, NTP,
or OSHA.
Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Neurotoxicity: No data available.
Mutagenicity: No data available.
Other Studies: No data available.
Section 12 - Ecological Information
No information available.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a
discarded chemical is classified as a hazardous waste. US EPA
guidelines for the classification determination are listed in 40
CFR Parts 261.3. Additionally, waste generators must consult
state and local hazardous waste regulations to ensure
complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
Canada
US DOT IATA RID/ADR IMO
TDG
No No
Shipping
information information
Name:
available. available.
Hazard
Class:
UN
Number:
Packing
Group:
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 10034-96-5 is not on the TSCA Inventory because it is
a hydrate. It is considered to be listed if the CAS number for
the anhydrous form is on the inventory (40CFR720.3(u)(2)).
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting
List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical
Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under
TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10034-96-5: chronic.
Section 313
This material contains Manganese sulfate, monohydrate
(listed as Manganese), 98%, (CAS# 10034-96-5) which is
subject to the reporting requirements of Section 313 of SARA
Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA. None of the chemicals in this
product are listed as Priority Pollutants under the CWA. None
of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered highly
hazardous by OSHA.
STATE
CAS# 10034-96-5 is not present on state lists from CA, PA,
MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in
this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 68/20/22 Harmful : possible risk of irreversible
effects through inhalation and if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 10034-96-5: 1
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or
NDSL list. Canada - WHMIS
This product has a WHMIS classification of D2B.
Canadian Ingredient Disclosure List
CAS# 10034-96-5 (listed as Manganese) is listed on the
Canadian Ingredient Disclosure List.
Exposure Limits
CAS# 10034-96-5: OEL-AUSTRALIA:TWA 5 mg(Mn)/m3
JANUARY 1993 OEL-BE
LGIUM:TWA 5 mg(Mn)/m3 JANUARY 1993
OEL-CZECHOSLOVAKIA:TWA 2 mg(Mn)/m
3;STEL 6 mg(Mn)/m3 JANUARY 1993 OEL-DENMARK:TWA 2.5
mg(Mn)/m3 JANUA
RY 1993 OEL-FINLAND:TWA 2.5 mg(Mn)/m3 JANUARY 1993
OEL-HUNGARY:TWA
0.3 mg(Mn)/m3;STEL 0.6 mg(Mn)/m3 JANUARY 1993
OEL-JAPAN:TWA 0.3 mg(Mn
)/m3 JANUARY 1993 OEL-THE NETHERLANDS:TWA 1
mg(Mn)/m3 JANUARY 1993
OEL-POLAND:TWA 0.3 mg(Mn)/m3 JANUARY 1993
OEL-SWEDEN:TWA 1 mg(Mn)/m
3;STEL 2.5 mg(Mn)/m3 (resp. dust) OEL-SWEDEN:TWA 2.5
mg(Mn)/m3;STEL 5
mg(Mn)/m3 (total dust) OEL-UNITED KINGDOM:TWA 5
mg(Mn)/m3 JANUARY 1
993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check
ACGIH TLV OEL IN
NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
Section 16 - Additional Information
MSDS Creation Date: 9/02/1997
Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect
to such information, and we assume no liability resulting from its use.
Users should make their own investigations to determine the suitability
of the information for their particular purposes. In no event shall Fisher
be liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.
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