MATERIAL SAFETY DATA SHEET
MSDS DATE:07/30/07
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: TECHNOVIT 9100 HARDENER 2 NEW
SYNONYMS: N/A
PRODUCT CODES: 14655
MANUFACTURER: ELECTRON MICROSCOPY SCIENCES
DIVISION: 1560 INDUSTRY ROAD/P.O. BOX 550
ADDRESS: HATFIELD, PA 19440
EMERGENCY PHONE: 215-412-8400
CHEMTREC PHONE: 800-424 -4300
FAX PHONE: 215-412-8450
CHEMICAL NAME: N/A
CHEMICAL FAMILY: N/A
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT:
N, N, 3, 5-TETRAMETHYLANILINE
CAS NO. % WT % VOL SARA 313 REPORTABLE
4913-13-7 N/A 25-50
mg/m3
ppm
OSHA PEL-TWA: N/A N/A
OSHA PEL STEL : N/A N/A
OSHA PEL CEILING: N/A N/A
ACGIH TLV-TWA: N/A N/A
ACGIH TLV STEL: N/A N/A
ACGIH TLV CEILING: N/A N/A
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: THE PRODUCT HAS TO BE LABELLED DUE TO THE CALCULATION PROCEDURE OF THE 鈥淕ENERAL
CLASSIFICATION GUIDELINE FOR PREPARATIONS OF THE EU鈥? IN THE LATEST VALID VERSION
ROUTES OF ENTRY: INHALATION, SKIN CONTACT, AND INGESTION
POTENTIAL HEALTH EFFECTS
EYES: IRRITATING TO EYES
SKIN: HARMFUL IN CONTACT WITH SKIN. IRRITATING TO SKIN
INGESTION: HARMFULL IF SWALLOWED
INHALATION: HARMFUL IF INHALED. IRRITATING TO RESPIRATORY SYSTEM
ACUTE HEALTH HAZARDS: N/A
CHRONIC HEALTH HAZARDS: N/A
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: N/A
CARCINOGENICITY
OSHA: N/A ACGIH: N/A NTP: N/A IARC: N/A
PAGE 1 OF 6
MATERIAL SAFETY DATA SHEET
MSDS DATE:07/30/07
OTHER: N/A
SECTION 4: FIRST AID MEASURES
EYES: FLUSH WITH WATER FOR 15 MINUTES IF IRRITATION OCCURS. SEEK MEDICAL
ATTENTION
SKIN: RINSE OPENED EYE WITH SOAP AND WATER. IF IRRITATION OCCURS. SEEK MEDICAL ATTENTION.
INGESTION:INSTANTLY CALL FOR DOCTOR
INHALATION: N/A
NOTES TO PHYSICIANS OR FIRST AID PROVIDERS:SYMPTOMS MAY EVEN OCCUR AFTER SEVERAL HOURS; THEREFORE
MEDICAL OBSERVATION FOR AT LEAST 48 HOURS AFTER THE ACCIDENT
SECTION 5: FIRE-FIGHTING MEASURES
FLAMMABLE LIMITS IN AIR, UPPER:N/A
(% BY VOLUME) LOWER:
FLASH POINT: N/A
F: N/A
C: N/A
METHOD USED: N/A
AUTOIGNITION TEMPERATURE:
F: N/A
C: 320 DEG
NFPA HAZARD CLASSIFICATION
HEALTH: N/A FLAMMABILITY: N/A REACTIVITY: N/A
OTHER: N/A
HMIS HAZARD CLASSIFICATION
HEALTH: N/A FLAMMABILITY: N/A REACTIVITY: N/A
PROTECTION: N/A
EXTINGUISHING MEDIA: CO2, EXTINGUISHING POWDER OR WATER JET. FIGHT LARGER FIRES WITH WATER JET OR ALCOHOL-
RESISTANT FOAM
SPECIAL FIRE FIGHTING PROCEDURES: PUT ON BREATHING APPARATUS
UNUSUAL FIRE AND EXPLOSION HAZARDS: FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE
HAZARDOUS DECOMPOSITION PRODUCTS: N/A
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES:
PERSON RELATED SAFETY PRECAUTIONS: NOT REQUIRED
MEASURES FOR ENVIRONMENTAL PROTECTION: NO SPECIAL MEASURES REQUIRED
MEASURES FOR CLEANING/COLLECTING: ABSORB WITH LIQUID-BINDING MATERIAL (DIATOMITE, UNIVERSAL BINDERS, FOR
SMALL AMOUNTS TISSUES). DISPOSE OF CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13
ADDITIONAL INFORMATION: NO DANGEROUS MATERIALS ARE RELEASED.
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MATERIAL SAFETY DATA SHEET
MSDS DATE:07/30/07
SECTION 7: HANDLING AND STORAGE
HANDLING AND STORAGE: INFORMATION FOR SAFE HANDLING: KEEP CONTAINERS TIGHTLY SEALED. ENSURE GOOD
VENTILATION/ EXHAUSTION AT THE WORKPLACE.
OTHER PRECAUTIONS: N/A
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
VENTILATION: N/A
RESPIRATORY PROTECTION: NOT REQUIRED
EYE PROTECTION: PROTECTIVE GOGGLES ARE RECOMMENDED
SKIN PROTECTION: SOLVENT RESSISTANT GLOVES. THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO
THE PRODUCT/ THE SUBSTANCE/ THE PREPARATION. SELECTION OF THE GLOVE MATERIAL ON CONSIDERATION OF THE
PENETRATION TIMES, RATES OF DIFFUSION AND THE DEGRADATION.
MATERIAL OF GLOVES: THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL, BUT ALSO
ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO MANUFACTURER. AS THE PRODUCT IS A
PREPARATION OF SEVERAL SUBSTANCES, THE RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN
ADVANCE AND HAS THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL: THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE
MANUFACTURER OF THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED
FOR THE PERMANENT CONTACT OF A MAXIMUM OF 15 MINUTES GLOVES MADE OF THE FOLLOWING MATERIALS ARE
SUITABLE:
BUTYL RUBBER, BR
FLUOROCARBON RUBBER (VITON)
NITRILE RUBBER, NBR
CHLOROPRENE RUBBER, CR
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: LIGHT WEIGHT PROTECTIVE CLOTHING
WORK HYGIENIC PRACTICES: KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FOOD. INSTANTLY REMOVE ANY SOILD AND
IMPREGNATED GARMENTS. WASH HANDS DURING BREAKS AND AT THE END OF THE WORK. AVOID CONTACT WITH THE EYES
AND SKIN
EXPOSURE GUIDELINES: N/A
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: COLORLESS
ODOR: ODORLESS
PHYSICAL STATE: FLUID
pH AS SUPPLIED: N/A
pH (Other): N/A
BOILING POINT:
F: N/A
C: 227 DEG
MELTING POINT:
F: N/A
C: 38-36 DEG
FREEZING POINT: N/A
F: N/A
C: N/A
VAPOR PRESSURE (mmHg):1 hPa
PAGE 3 OF 6
MATERIAL SAFETY DATA SHEET
MSDS DATE:07/30/07
@
F: N/A
C: 20 DEG
3
VAPOR DENSITY (AIR = 1): 1.090 g/cm
@
F: N/A
C: 20 DEG
@
F: N/A
C: N/A
EVAPORATION RATE: N/A
BASIS (=1): N/A
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (con鈥檛)
SOLUBILITY IN WATER: 500 g/l
PERCENT SOLIDS BY WEIGHT: N/A
PERCENT VOLATILE: N/A
BY WT/ BY VOL @
F: N/A
C: N/A
VOLATILE ORGANIC COMPOUNDS (VOC): O
WITH WATER: 0 LBS/GAL
WITHOUT WATER: 0 LBS/GAL
MOLECULAR WEIGHT: N/A
VISCOSITY: 100 mPas
@
F: N/A
C: 20 DEG
SECTION 10: STABILITY AND REACTIVITY
STABILITY:
CONDITIONS TO AVOID (STABILITY): NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS
INCOMPATIBILITY (MATERIAL TO AVOID): ORGANIC PEROXIDES
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: NO DANGEROUS REACTIONS KNOWN
HAZARDOUS POLYMERIZATION: N/A
CONDITIONS TO AVOID (POLYMERIZATION): N/A
SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION: ACUTE TOXICITY: PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT FOR SKIN AND MUCOUS MEMBRANES
ON THE EYE: IRRITANT EFFECT
SENSITIZATION: NO SENSITIZING EFFECT KNOWN
ADDITIONAL INFORMATION: THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO THE CALCULATION METHOD
OF THE GENERAL EC CLASSIFICATION GUIDELINES FOR PREPARATIONS AS ISSUED IN THE LATEST VERSION: HARMFUL
IRRITANT
PAGE 4 OF 6
MATERIAL SAFETY DATA SHEET
MSDS DATE:07/30/07
SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION: SLIGHTLY HAZARDOUS FOR WATER. DO NOT ALLOW UNDILUTED PRODUCT OR LARGE
QUANTITIES OF IT TO REACH GROUND WATER, WATER BODIES OR SEWAGE SYSTEM.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: COMPLY WITH FEDERAL, STATE, LOCAL REGULATIONS.
RCRA HAZARD CLASS: 1
SECTION 13: DISPOSAL CONSIDERATIONS (con鈥檛)
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM.
SMALL QUANTITIES CAN BE POLYMERIZED WITH THE MATCHING SYSTEM COMPONENTS AND THE CURED SOLID MATERIAL
CAN BE DISPOSED OF WITH THE REGULAR GARBAGE. LARGER QUANTITIES MUST BE DISPOSED OF FOLLOWING THE
REGULATIONS OF THE LOCAL AUTHORITIES
WASTE DISPOSAL KEY NUMBER: 55370
SECTION 14: TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION
PROPER SHIPPING NAME: TOXIC LIQUID, ORGANIC, N.O.S. (N, N, 3, 5-TETRAMETHYLANILINE)
HAZARD CLASS: 1
ID NUMBER: N/A
PACKING GROUP: III
LABEL STATEMENT: 6.1
WATER TRANSPORTATION
PROPER SHIPPING NAME:
HAZARD CLASS: SAME
ID NUMBER:
PACKING GROUP:
LABEL STATEMENTS:
AIR TRANSPORTATION
PROPER SHIPPING NAME:
HAZARD CLASS: SAME
ID NUMBER:
PACKING GROUP:
LABEL STATEMENTS:
OTHER AGENCIES: N/A
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA (TOXIC SUBSTANCE CONTROL ACT): N/A
CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): N/A
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): N/A
311/312 HAZARD CATEGORIES: Xn HARMFUL, WATER HAZARD CLASS 1 ( CALCULATED ACCORDING TO VwVwS): SLIGHTLY
HAZARDOUS FOR WATER
313 REPORTABLE INGREDIENTS: N/A
STATE REGULATIONS: N/A
PAGE 5 OF 6
MATERIAL SAFETY DATA SHEET
MSDS DATE:07/30/07
INTERNATIONAL REGULATIONS: N/A
SECTION 16: OTHER INFORMATION
OTHER INFORMATION: RELAVANT R- PHRASES
20/21/22 HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
33 DANGER OF CUMULATIVE EFFECTS.
36/37/38 IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN
PREPARATION INFORMATION: N/A
DISCLAIMER: IN COMPLIANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD, 2.9 C.F.R
1910. 1200, WE ARE PROVIDING YOU WITH A MSDS FOR THE HAZARDOUS MATERIAL YOU ARE
PURCHASING.
IT IS YOUR RESPONSIBILITY TO EDUCATE YOUR EMPLOYEES ON THE SAFE USE OF THE HAZARDOUS
MATERIAL.
ELECTRON MICROSCOPY SCIENCES MAKES NO PRESENTATION AS TO THE ACCURACY OF THE
INFORMATION IN THE MSDS. THE INFORMATION IS BELIEVED TO BE CORRECT; HOWEVER, YOU
(THE CUSTOMER), SHOULD PERFORM YOUR OWN INVESTIGATION AND INDEPENDENT
VERIFICATION. IF YOU RESELL THE PRODUCT, YOU ARE RESPONSIBLE TO FORWARD THE
INFORMATION IN THE MSDS TO YOUR CUSTOMER.
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