PRODUCT #: 326755 NAME: COPPER(II) ACETATE, 98%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 11:32AM
Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850
SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: 326755
NAME: COPPER(II) ACETATE, 98%
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 142-71-2
MF: C2H4O2
EC NO: 205-553-3
SYNONYMS
ACETATE DE CUIVRE (FRENCH) * ACETIC ACID, CUPRIC SALT * COPPER(2+)
ACETATE * COPPER(II) ACETATE * COPPER ACETATE (CU(C2H3O2)2) * COPPER
DIACETATE * COPPER(2+) DIACETATE * CRYSTALLIZED VERDIGRIS * CRYSTALS
OF VENUS * CUPRIC ACETATE * CUPRIC DIACETATE * NEUTRAL VERDIGRIS *
OCTAN MEDNATY (CZECH) *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
HARMFUL
HARMFUL IF SWALLOWED.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
DO NOT BREATHE DUST.
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE
RESPIRATORY EQUIPMENT.
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
HYGROSCOPIC
KEEP TIGHTLY CLOSED.
STORE UNDER NITROGEN.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF
WATER FOR AT LEAST 15 MINUTES.
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS
AMOUNTS OF WATER.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
WATER SPRAY.
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY
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PRODUCT #: 326755 NAME: COPPER(II) ACETATE, 98%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 11:32AM
RUBBER GLOVES.
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
SAFETY SHOWER AND EYE BATH.
MECHANICAL EXHAUST REQUIRED.
DO NOT BREATHE DUST.
DO NOT GET IN EYES, ON SKIN, ON CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
IRRITANT.
HARMFUL DUST.
KEEP TIGHTLY CLOSED.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
AQUA POWDER
PHYSICAL PROPERTIES
VAPOR DENSITY: 6.9
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
STRONG ACIDS
PROTECT FROM MOISTURE.
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
TOXIC FUMES OF:
CARBON MONOXIDE, CARBON DIOXIDE
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF SWALLOWED.
MAY BE HARMFUL IF INHALED.
MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
CAUSES EYE AND SKIN IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
ADDITIONAL INFORMATION
CHRONIC COPPER POISONING IS TYPIFIED BY HEPATIC CIRRHOSIS, BRAIN
DAMAGE AND DEMYELINATION, KIDNEY DEFECTS, AND COPPER DEPOSITION IN THE
CORNEA AS EXEMPLIFIED BY HUMANS WITH WILSON'S DISEASE. IT HAS ALSO
BEEN REPORTED THAT COPPER POISONING HAS LEAD TO HEMOLYTIC ANEMIA AND
ACCELERATES ARTERIOSCLEROSIS.
RTECS #: AG3480000
ACETIC ACID, COPPER(2+) SALT
TOXICITY DATA
ORL-RAT LD50:501 MG/KG INJPD2 23,153,1991
IPR-RAT LD50:14700 UG/KG INJPD2 23,153,1991
SCU-RAT LD50:350 MG/KG PMDCAY 15,211,1977
IVN-RAT LD50:17100 UG/KG INJPD2 23,153,1991
ORL-MUS LD50:196 MG/KG INJPD2 23,153,1991
IPR-MUS LD50:2500 UG/KG BCPCA6 30,771,1981
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PRODUCT #: 326755 NAME: COPPER(II) ACETATE, 98%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 11:32AM
IVN-MUS LD50:20 MG/KG INJPD2 23,153,1991
TARGET ORGAN DATA
BEHAVIORAL (SOMNOLENCE)
BEHAVIORAL (CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD)
MUSCULO-SKELETAL (JOINTS)
EFFECTS ON FERTILITY (OTHER MEASURES OF FERTILITY)
TUMORIGENIC (ACTIVE AS ANTI-CANCER AGENT)
BIOCHEMICAL EFFECTS (EFFECT ON INFLAMMATION OR MEDIATION OF INFLAMMATION)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
HARMFUL
R 22
HARMFUL IF SWALLOWED.
R 36/37/38
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
S 22
DO NOT BREATHE DUST.
S 38
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE
RESPIRATORY EQUIPMENT.
S 36/37/39
WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE
PROTECTION.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
OEL-ARAB REPUBLIC OF EGYPT:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-AUSTRALIA:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-AUSTRALIA:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-BELGIUM:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-BELGIUM:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-DENMARK:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-DENMARK:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-FINLAND:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-FINLAND:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-FRANCE:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-FRANCE:TWA 1 MG(CU)/M3;STEL 2 MG(CU)/M3 (DUST) JAN 1993
OEL-GERMANY:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-GERMANY:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-HUNGARY:TWA 0.2 MG(CU)/M3;STEL 0.4 MG(CU)/M3 (DUST) JAN 1993
OEL-INDIA:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-THE NETHERLANDS:TWA 02 MG(CU)/M3 (FUME) JAN 1993
OEL-THE NETHERLANDS:TWA 1 MG(CU)/M3 (DUST) JAN 1993
OEL-THE PHILIPPINES:TWA 1.0 MG(CU)/M3 (FUME) JAN 1993
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PRODUCT #: 326755 NAME: COPPER(II) ACETATE, 98%
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 11, 1903 11:32AM
OEL-POLAND:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-RUSSIA:STEL 0.5 PPM (1 MG(CU)/M3) (DUST) JAN 1993
OEL-SWEDEN:TWA 0.2 MG(CU)/M3 (RESP. DUST) JAN 1993
OEL-SWEDEN:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-SWEDEN:TWA 1 MG(CU)/M3 (TOTAL DUST) JAN 1993
OEL-SWITZERLAND:TWA 0.1 MG(CU)/M3;STEL 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-SWITZERLAND:TWA 1 MG(CU)/M3;STEL 1 MG(CU)/M3 JAN 1993
OEL-THAILAND:TWA 0.1 MG(CU)/M3 (FUME) JAN 1993
OEL-THAILAND:TWA 1 MG(CU)/M3 JAN 1993
OEL-UNITED KINGDOM:TWA 0.2 MG(CU)/M3 (FUME) JAN 1993
OEL-UNITED KINGDOM:TWA 1 MG(CU)/M3 JAN 1993
NOHS 1974: HZD 84332; NIS 4; TNF 139; NOS 5; TNE 565
NOES 1983: HZD 84332; NIS 10; TNF 550; NOS 13; TNE 15459; TFE 10534
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
U.S. INFORMATION
THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY
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