Annihilator鈩? Insecticide Premise Spray (EPA Reg. No. 4691-164)
Material Safety Data Sheet
DOT HCS Risk Phrases Protective Clothing
This material not hazardous under OSHA
Not a controlled material.
regulations.
Section 1: Product Identification and Uses
Common/Trade
Annihilator鈩? Insecticide Premise Spray (EPA
name
CI# Not available
Reg. No. 4691-164)
Synonyms Not available TSCA TSCA inventory: No products were
found.
Chemical name (s)-cyano-3-phenoxybenzyl-(1R,3R)-3(2,2- CAS# Not applicable
dibromovinyl)-2,2-dimethyl-cyclopropane
carboxylate
Chemical formula Not available Code MSDS ID#: E00DE164
Chemical family Not available Molecular Not available
weight
Manufacturer Boehringer Ingelheim Vetmedica, Inc.
Supplier Boehringer Ingelheim Vetmedica, Inc. 2621 North Belt Hwy
2621 North Belt Hwy St. Joseph MO 64506-2002
St. Joseph MO 64506-2002 816-233-2571
Material uses Annihilator Insecticide Premise Spray is a ready-to-use insecticide for various indoor and outdoor pests.
Section 2: Hazardous Ingredients
Name CAS# % by Weight TLV/PEL LC50 / LD 50
1)Deltamethrin 52918-63-5 0.02 OSHA/ACGIH Limits: None established
None established
Manufacturer鈥檚
Recommended Limits:
TWA-TLV: 45 ug/m3
STEL (15 minutes): 100
ug/m3
Section 3: First Aid Measures
Eye contact Causes moderate eye irritation. Immediately flush eyes with plenty of 1% physiological saline for 5 minutes
while holding eyelids open. I no saline is easily available, flush eyes with plenty of water. Call a physician if
irritation persists.
Note: Product may be difficult to remove using only water.
Skin contact May cause skin irritation. Wash with plenty of soap and water. Seek medical attention if irritation occurs.
Hazardous skin
No additional information.
contact
Slight inhalation Remove person from contaminated area to fresh air. Apply artificial respiration if needed.
Hazardous inhalation No additional information.
Slight ingestion Call a physician or poison control center. Drink 1 or 2 glasses of water and induce vomiting by touching back
of throat with finger. If person is unconscious, do not give anything by mouth and do not induce vomiting.
Hazardous ingestion Not available
Section 4: Physical Data
Annihilator鈩? Insecticide Premise Spray (EPA Reg. No. 4691-164)
Clear liquid
Physical state and
appearance Odor Odorless
PH (1% soln/water) Not available Taste Not available
Odor threshold Odorless Color Clear
Volatility Not available
Melting/Sublimation point 32掳F or 0掳C
Boiling/Condensation point 212掳 F or 100掳C
Specific gravity (Water=1) >1.00
Vapor density Not available
Vapor pressure Not available
Water/oil dist. Coeff. Not available
Ionicity (surface active Not available
agent)
Critical temperature Not available
Instability temperature Not available
Conditions of instability Not available
Dispersion properties Not available
Solubility Not available
Section 5: Fire and Explosion Data
The product is: Not available
Auto-ignition Not available
temperature
Fire degradation Not available
products
Flash points >200掳F or >93掳C
Flammable limits Not available
Fire extinguishing Carbon dioxide, dry chemical, foam, water.
procedures
SPECIAL FIRE FIGHTING PROCEDURES: Recommend pressure-demand, self-contained breathing
apparatus (SCBA). Wear full protective equipment and isolate hazard area. Keep upwind. Avoid inhalation of
smoke and fumes. Use water or foam to reduce fumes. Do not touch spilled material. If possible, move
containers from area. Extinguish only if flow can be stopped. Use flooding amounts of water as a fog. Cool
containers with flooding amounts of water from as far as distance as possible. Avoid breathing vapors.
Flammability NFPA/OSHA Class: IIIB
NFPA Rating (Fire): 1
Risks of explosion Do not use this product on electrical equipment due to the possibility of shock hazard.
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Annihilator鈩? Insecticide Premise Spray (EPA Reg. No. 4691-164)
Section 6: Reactivity Data
Stability The product is stable.
Hazardous decomp. Not available
products
Degradability Not available
Product of Not available
degradation
Corrosivity Not available
Reactivity Not available
Section 7: Toxicological Properties
Routes of entry Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
TLV Not available
Acute Studies
Toxicity for animals
The following Data were developed with: deltamethrin, the active ingredient.
CHRONIC TOXICITY AND CARCINOGENICITY
General neurological symptoms were exhibited in studies with rats, mice and dogs. These symptoms
included unsteadiness, abnormal gait, tremors and liquid feces. No histopathologic findings were
observed except some sings of slight hepatotoxicity in mice. No Observable Effect Levels (NOEL鈥檚) were
1 mg/kg/day in the 2-year rat and dog studies. The NOEL for the 2-year mouse study was approximately
12 mg/kg/day. Deltamethrin was not carcinogenic in rats or mice.
REPRODUCTIVE AND DEVELOPMENTAL TOXICITY
No developmental effects were observed in studies with rabbits in the absence of maternal toxicity. The
development NOEL for the rat study was 11mg/kg/day (highest dose tested). The developmental NOEL
in rabbits was 25 mg/kg/day. A 2/generation reproductive study with rats produced clinical signs of
toxicity, reduced body weight gain and mortality in both parents and offspring. The parental and
reproductive (offspring) NOEL鈥檚 were 80 ppm which is equivalent to approximately 4 mg/kg/day for adults
and 18 mg/kg/day for the offspring.
NEUROTOXICITY
Deltamethrin does not inhibit acetylcholinesterase. Neurobehavioral effects including unsteadiness,
excessive salivation, vomiting, liquid feces, uncoordinated movement, tremors, spasmodic convulsions
which are typically related to Central Nervous System (CNS) stimulation, were observed in some studies.
The NOEL for these studies was 1 mg/kg/day or higher.
MUTAGENICITY (GENETIC EFFECTS)
No evidence of genotoxicity was observed in a battery of in vitro and in vivo studies.
Environmental hazards Not available
Chronic effects on humans Not available
Acute effects on humans Not available
Page 3 of 5
Annihilator鈩? Insecticide Premise Spray (EPA Reg. No. 4691-164)
Section 8: Preventive Measures
Waste information Do not reuse empty container. Wrap container in several layers of newspaper and discard in trash.
Ensure that the disposal is in compliance with all Federal, State/Provincial, and local regulations.
Waste stream This product is extremely toxic to fish and aquatic invertebrates. Do not apply directly to water, to
areas where surface water is present or to intertidal areas below the mean high water mark. Use with
care when applying in areas adjacent to any body of water. Do not contaminate water when disposing
of equipment washwater.
Storage Keep only in the original container in a cool, dry, locked place away from reach of children. Protect
from freezing.
Precautions Avoid skin contact. This product is extremely toxic to fish and aquatic invertebrates. Do not apply
directly to water. Do not contaminate water when disposing of washwater or rinsate. This product is
highly toxic to bees exposed to direct treatment or residues on blooming crops or weeds. Do not apply
this product or allow it to drift to blooming crops or weeds if bees are visiting the treatment area.
Do not apply this product in or on electrical equipment due to possibility of shock hazard.
Small spill and leak Absorb with an inert absorbent material such as granular clay, saw dust, or pet litter. Sweep up
carefully while avoiding the formation of a dust cloud. Place in an approved chemical waste container
for disposal. Rinse spill area with small amount of soapy water. Contain and absorb the rinsate with
inert absorbents and place into the same disposal container. Area can be washed with water to
remove the last trace residue. Do not allow water to contaminate water supplies or sewers.
Eliminate all sources of ignition. Stop leak if you can do so without coming into contact with spilled
Large spill and leak
material. Dike far ahead of liquid spill for later disposal. All equipment used to clean up spill should be
grounded. Prevent entry into waterways, sewers, basements or confined areas. Inform appropriate
authorities immediately if contamination occurs.
Protective Clothing Eye protection and chemically resistant gloves, a long-sleeved shirt and long-legged pants or coveralls
are recommended. To avoid breathing spray mist during application in confined areas, wear a mask or
respirator of a type recommended by NIOSH for filtering spray mists.
Section 9: Classification
DOT Not a DOT controlled material (United States).
Maritime
No additional information.
transportation
Not an HCS controlled material in USA
HCS
Federal and
Not applicable
State
Regulations
HMIS (U.S.A.)
National Fire Protection
Health Hazard 1
Fire Hazard
1
Association (U.S.A.)
Fire Hazard 1
1 0
Reactivity 0
Reactivity
B
Personal Protection
Specific hazard
Section 10: Protective Measures
Protective Eye protection and chemically resistant gloves, a long-sleeved shirt and long-legged pants or coveralls
clothing are recommended. To avoid breathing spray mist during application in confined areas, wear a mask or
respirator of a type recommended by NIOSH for filtering spray mists.
Engineering Ensure that eyewash stations and safety showers are proximal to the work-station location. Control
controls airborne concentrations below the appropriate exposure guideline. Local exhaust ventilation may be
necessary.
Page 4 of 5
Annihilator鈩? Insecticide Premise Spray (EPA Reg. No. 4691-164)
Section 11: Other Information
References Not available
Validated by Company: 3/21/05
CALL 1(800) 821-7467
Emergency Medical: (800)530-5432
Chemtrec: (800)424-9300
The information provided herein is offered by Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) in good faith as accurate as of the date hereof, but
without guarantee. This information includes information which has been generated by other parties and provided to BIV, and which BIV has
not independently verified. The information provided herein relates only to the specific product designated, and may not be valid where such
product is used in combination with any other materials or in any process. The information provided herein is offered solely for your
consideration, investigation and verification, and Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) expressly disclaims all liability for reliance
thereon. BIV EXPRESSLY DISCLAIMS ALL WARRANTIES OF EVERY KIND AND NATURE (INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE) WITH RESPECT TO THE USE OR SUITABILITY OF THE
PRODUCT. In addition, since the conditions of use and suitability of the product for particular uses are beyond BIV鈥檚 control, ALL RISKS OF
USE OF THE PRODUCT ARE THEREFORE ASSUMED BY THE USER, AND BIV EXPRESSLY
DISCLAIMS ANY AND ALL LIABILITY AS TO ANY RESULTS OBTAINED OR ARISING FROM ANY USE OF THE PRODUCT. Use or
retransmission of the information contained herein in any other format than the format as presented is strictly prohibited. Nothing herein shall
be construed as a permission or recommendation for the use of the product in a manner that might infringe an existing patent. BIV neither
represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any other country
except the United States of America.
漏 Copyright 2001 Boehringer Ingelheim Vetmedica, Inc. All rights reserved.
Page 5 of 5
Annihilator鈩? Insecticide Premise Spray (EPA Reg. No. 4691-164)
The information provided herein is offered by Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) in
good faith as accurate as of the date hereof, but without guarantee. This information includes
information which has been generated by other parties and provided to BIV, and which BIV has
not independently verified. The information provided herein relates only to the specific product
designated, and may not be valid where such product is used in combination with any other
materials or in any process. The information provided herein is offered solely for your
consideration, investigation and verification, and Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?)
expressly disclaims all liability for reliance thereon. BIV EXPRESSLY DISCLAIMS ALL
WARRANTIES OF EVERY KIND AND NATURE (INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE) WITH RESPECT
TO THE USE OR SUITABILITY OF THE PRODUCT. In addition, since the conditions of use
and suitability of the product for particular uses are beyond BIV鈥檚 control, ALL RISKS OF USE
OF THE PRODUCT ARE THEREFORE ASSUMED BY THE USER, AND BIV EXPRESSLY
DISCLAIMS ANY AND ALL LIABILITY AS TO ANY RESULTS OBTAINED OR
ARISING FROM ANY USE OF THE PRODUCT.
Use or re-transmission of the information contained herein in any other format than the format as
presented is strictly prohibited. Nothing herein shall be construed as a permission or
recommendation for the use of the product in a manner that might infringe an existing patent.
BIV neither represents nor warrants that the format, content or product formulas contained in this
document comply with the laws of any other country except the United States of America.
漏 Copyright 2001 Boehringer Ingelheim Vetmedica, Inc. All rights reserved.
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