Commando Insecticide Cattle Ear Tag EPA Reg. No.: 4691-157
Material Safety Data Sheet
DOT HCS Risk Phrases Protective Clothing
This material contains organophosphates.
Shipping Name: Insecticide dry
Section 1: Product Identification and Uses
Common/Trade
COMMANDO INSECTICIDE CATTLE EAR TAG
name
CI# Not available
EPA Reg. No.: 4691-157
Synonyms Not available TSCA No products found.
Chemical name Not available CAS# Not applicable
Chemical formula Not available Code MSDS ID#: E97ET157A
Chemical family Organophosphate Insecticide Molecular Not available
weight
Manufacturer Boehringer Ingelheim Vetmedica, Inc.
Supplier Boehringer Ingelheim Vetmedica, Inc. 2621 North Belt Hwy
2621 North Belt Hwy St. Joseph MO 64506-2002
St. Joseph MO 64506-2002 816-233-2571
Material uses Insecticidal ear tag for use in the control of various flies and ticks common to beef and dairy cattle.
Section 2: Hazardous Ingredients
Name CAS# % by Weight TLV/PEL LC50 / LD 50
LD50: Oral = 47 mg/kg
1) Ethion [O,O,O鈥?,O鈥?- 563122 36.0 0.4 mg/m3 (skin).
(rat)
tetraethyl S,S鈥?-
methylene Dermal = 1084 mg/kg
bisphosphorodithioate] (rabbit)
Section 3: First Aid Measures
Eye contact IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek medical
attention.
Skin contact Wash contaminated skin with soap and water. Remove contaminated clothing and gloves. Seek medical
attention if symptoms occur.
Hazardous skin No additional information.
contact
Slight inhalation Generally not likely to occur, however if breathing is difficult, allow the victim to rest in a well ventilated area.
Seek immediate medical attention.
Hazardous inhalation No additional information.
Slight ingestion Not likely to occur. Harmful if swallowed, get immediate medical attention. Give large quantities of water. Can
cause symptoms typical of cholinesterase depression (e.g. constricted pupils, increased perspiration,
shortness of breath, nausea stomach cramps, muscle twitching, etc.) Seek medical attention.
Hazardous ingestion Not available
Commando Insecticide Cattle Ear Tag EPA Reg. No.: 4691-157
Section 4: Physical Data
Solid (plastic mass solid)
Physical state and
appearance
Odor Acrid, sulfur-like
PH (1% soln/water) Not available Taste Not available
Odor threshold Not available Color red
Volatility <1% (w/v).
Melting/Sublimation point Not available
Boiling/Condensation point Not available
Specific gravity (Water=1) 1.2 (Water=1)
Vapor density Heavier
Vapor pressure Not available
Water/oil dist. Coeff. Not available
Ionicity (surface active Not available
agent)
Critical temperature Not available
Instability temperature Not available
Conditions of instability No additional remark.
Dispersion properties Not available
Solubility Basically insoluble
Section 5: Fire and Explosion Data
The product is: Not available
Auto-ignition Not available
temperature
Fire degradation
When heated to decomposition, acrid smoke and irritating fumes can occur i.e., oxides of sulfur and
products phosphorus, mercaptans, carbon monoxide, carbon dioxide, hydrogen chloride and hydrogen cyanide.
Flash points Not available
Flammable limits Not available
Fire extinguishing SMALL FIRE: Use DRY chemicals, CO2, water spray or foam.
procedures
LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
SPECIAL FIRE FIGHTING PROCEDURES: Recommend pressure-demand, self-contained breathing
apparatus (SCBA). Wear full protective equipment and isolate area. Contain all water runoff and do not allow
water to contaminate water supplies.
Flammability Not available
Risks of explosion Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the
product in presence of static discharge: Not available.
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Commando Insecticide Cattle Ear Tag EPA Reg. No.: 4691-157
Section 6: Reactivity Data
Stability The product is stable.
Hazardous decomp. When heated to decomposition, acrid smoke and irritating toxic fumes can occur, i.e., oxides of sulfur and
Products phosphorus, mercaptans, carbon monoxide, carbon dioxide, hydrogen chloride and hydrogen cyanide.
Degradability Not available
Product of Possibly hazardous short term degradation products are not likely. However, long term degradation products
degradation may arise. Not available.
Corrosivity No specific information is available in our database regarding the corrosivity of this product in the presence
of various materials.
Reactivity Strong bases will decompose the active ingredient (ETHION).
Section 7: Toxicological Properties
Routes of entry Eye contact, skin contact
TLV Not available
Toxicity for animals Not available
Environmental hazards Marine pollutant
Chronic effects on humans Unlikely from ear tag device. Physician: This product contains a cholinesterase inhibitor. If symptoms of
cholinesterase inhibition are present, atropine sulphate by injection is antidotal. 2/PAM is also antidotal
and may be administered, but only in conjunction with atropine. Morphine, reserpine, phenothiazines,
and theophzylline are contraindicated.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Pre-existing conditions which
lower cholinesterase levels or hemolytic anemia increase vulnerability to cholinesterase depressions.
Acute effects on humans No specific information is available in our database regarding the other toxic effects of this material for
humans.
Section 8: Preventive Measures
Waste information Product is not a RCRA defined waste. Because acceptable methods of disposal may vary by location
and regulatory requirements may change, dispose of product and containers in accordance with Local,
State and Federal regulations. Observe label precautions regarding disposal.
Waste stream Not available
Storage Use according to label directions. Keep out of reach of children. Store in a cool, dry place in original
container. Do not contaminate water, food or feed by improper storage or disposal.
Precautions For use on animals only. Active ingredient is toxic to fish. Do not apply directly to water. Do not
contaminate water by disposal of waste (spent tags).
Small spill and leak Care should be taken to avoid contamination of the aquatic environment. Notify Local, State and
Federal Agencies in the event of a massive spill.
Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by
Large spill and leak
spreading water on the contaminated surface and allow to evacuate through the sanitary system.
Protective Clothing Gloves and safety glasses
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Commando Insecticide Cattle Ear Tag EPA Reg. No.: 4691-157
Section 9: Classification
DOT Shipping Name: Insecticide dry
Maritime Environmentally hazardous substances, N.O.S., (Solid),
transportation
(Ethion), UN3077, PG: III
This material contains organophosphates.
HCS
Federal and
Not available
State
Regulations
HMIS (U.S.A.)
National Fire Protection
Health Hazard 2
Fire Hazard
0
Association (U.S.A.)
Fire Hazard 0
2 0
Reactivity 0
Reactivity
B
Personal Protection
Specific hazard
Page 4 of 5
Commando Insecticide Cattle Ear Tag EPA Reg. No.: 4691-157
Section 10: Protective Measures
Protective Gloves (impervious). Wash hands thoroughly after handling. Safety glasses.
clothing
Engineering Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne
controls levels below recommended exposure limits. If user operations generate dust, fume or mist, use
ventilation to keep exposure to airborne contaminants below the exposure limit.
Section 11: Other Information
References Not available
Validated by Company: 3/22/05
CALL 1(800) 821-7467
Emergency Medical: (800)530-5432
Chemtrec: (800)424-9300
The information provided herein is offered by Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) in good faith as accurate as of the date hereof, but
without guarantee. This information includes information which has been generated by other parties and provided to BIV, and which BIV has
not independently verified. The information provided herein relates only to the specific product designated, and may not be valid where such
product is used in combination with any other materials or in any process. The information provided herein is offered solely for your
consideration, investigation and verification, and Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) expressly disclaims all liability for reliance
thereon. BIV EXPRESSLY DISCLAIMS ALL WARRANTIES OF EVERY KIND AND NATURE (INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE) WITH RESPECT TO THE USE OR SUITABILITY OF THE
PRODUCT. In addition, since the conditions of use and suitability of the product for particular uses are beyond BIV鈥檚 control, ALL RISKS OF
USE OF THE PRODUCT ARE THEREFORE ASSUMED BY THE USER, AND BIV EXPRESSLY
DISCLAIMS ANY AND ALL LIABILITY AS TO ANY RESULTS OBTAINED OR ARISING FROM ANY USE OF THE PRODUCT. Use or
retransmission of the information contained herein in any other format than the format as presented is strictly prohibited. Nothing herein shall
be construed as a permission or recommendation for the use of the product in a manner that might infringe an existing patent. BIV neither
represents nor warrants that the format, content or product formulas contained in this document comply with the laws of any other country
except the United States of America.
漏 Copyright 2001 Boehringer Ingelheim Vetmedica, Inc. All rights reserved.
Page 5 of 5
The information provided herein is offered by Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?) in
good faith as accurate as of the date hereof, but without guarantee. This information includes
information which has been generated by other parties and provided to BIV, and which BIV has
not independently verified. The information provided herein relates only to the specific product
designated, and may not be valid where such product is used in combination with any other
materials or in any process. The information provided herein is offered solely for your
consideration, investigation and verification, and Boehringer Ingelheim Vetmedica, Inc. (鈥淏IV鈥?)
expressly disclaims all liability for reliance thereon. BIV EXPRESSLY DISCLAIMS ALL
WARRANTIES OF EVERY KIND AND NATURE (INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE) WITH RESPECT
TO THE USE OR SUITABILITY OF THE PRODUCT. In addition, since the conditions of use
and suitability of the product for particular uses are beyond BIV鈥檚 control, ALL RISKS OF USE
OF THE PRODUCT ARE THEREFORE ASSUMED BY THE USER, AND BIV EXPRESSLY
DISCLAIMS ANY AND ALL LIABILITY AS TO ANY RESULTS OBTAINED OR
ARISING FROM ANY USE OF THE PRODUCT.
Use or re-transmission of the information contained herein in any other format than the format as
presented is strictly prohibited. Nothing herein shall be construed as a permission or
recommendation for the use of the product in a manner that might infringe an existing patent.
BIV neither represents nor warrants that the format, content or product formulas contained in this
document comply with the laws of any other country except the United States of America.
漏 Copyright 2001 Boehringer Ingelheim Vetmedica, Inc. All rights reserved.
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