Material Safety Data Sheet
Nadone庐 (Cyclohexanone)
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Nadone庐
PRODUCT NAME:
Cyclohexanone
OTHER/GENERIC NAMES:
PRODUCT USE: Solvent and thinner in lacquers, insecticides, herbicides, photography, pharmaceuticals.
Honeywell
MANUFACTURER:
101 Columbia Road
Box 1053
Morristown, New Jersey 07962-1053
FOR MORE INFORMATION CALL: IN CASE OF EMERGENCY CALL:
(Monday-Friday, 8:30am-5:00pm) (24 Hours/Day, 7 Days/Week)
Customer Service 800-707-4555 or
1-877-370-7007 (Toll Free) CHEMTREC 800-424-9300
2. COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENT NAME CAS NUMBER WEIGHT %
Cyclohexanone 108-94-1 100
Trace impurities and additional material names not listed above may also appear in Section 15 towards the end of the
MSDS. These materials may be listed for local "Right-To-Know" compliance and for other reasons.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: A clear, colorless to pale yellow liquid with a peppermint-like odor.
Causes irritation to the skin, eyes, mucous membranes and respiratory tract. Can be absorbed
through the skin causing systemic effects. Liquid is flammable.
POTENTIAL HEALTH HAZARDS
SKIN: Can be absorbed through the skin causing systemic effects similar to inhalation. Prolonged or repeated
contact may cause mfld to moderate irritation or dermatitis.
Severe irritant. May produce transient corneal damage.
EYES:
MSDS Number: HPWI-0001 Page 1 of 8
Current Issue Date: April 3, 2003
Material Safety Data Sheet
Nadone庐 (Cyclohexanone)
INHALATION: Irritating to the eyes, mucous membranes and respiratory tract. May cause labored
breathing, central nervous system depression, tremors and decreased heart rate. At high
concentrations, death from respiratory depression may occur. Repeated or prolonged
exposures to high concentrations may cause kidney and liver damage.
Produces systemic effects similar to inhalation.
INGESTION:
DELAYED EFFECTS: Liver and kidney damage, and blood and bone marrow effects have been reported in
animals.
Ingredients found on one of the OSHA designated carcinogen lists are listed below.
INGREDIENT NAME NTP STATUS IARC STATUS OSHA LIST
*No ingredients listed in this section*
4. FIRST AID MEASURES
SKIN: Immediately wash with soap and water. Seek medical assistance for irritation or any other symptoms.
Immediately flush with water for at least 15 minutes. Get medical assistance
EYES:
INHALATION: Remove to fresh air. If not breathing, apply artificial respiration, preferably mouth-to-mouth. Get
medical assistance.
Do not induce vomiting unless advised to do so by a physician.
INGESTION:
Treat according to symptoms present.
ADVICE TO PHYSICIAN:
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
o o
FLASH POINT: 46 C (114.8 F) FLASH POINT METHOD
FLASH POINT:
Closed cup.
FLASH POINT METHOD:
423掳C (793.4掳F)
AUTOIGNITION TEMPERATURE:
12.75
UPPER FLAME LIMIT (volume % in air):
1.1
LOWER FLAME LIMIT (volume % in air):
Not applicable.
FLAME PROPAGATION RATE (solids):
Combustible liquid.
OSHA FLAMMABILITY CLASS:
Health = 1, Flammability = 2, Reactivity = 0
NFPA HAZARD ID
MSDS Number: HPWI-0001 Page 2 of 8
Current Issue Date: April 3, 2003
Material Safety Data Sheet
Nadone庐 (Cyclohexanone)
EXTINGUISHING MEDIA:.
Alcohol foam, carbon dioxide, dry chemical, or water spray. Avoid solid streams of water which may spread
burning liquid.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back. Can
react vigorously with oxidizing materials.
SPECIAL FIRE FIGHTING PRECAUTIONS/INSTRUCTIONS:
Wear self-contained breathing apparatus. Use water spray to keep fire exposed containers cool. Use water
spray to disperse vapors and to protect personnel attempting to stop leak.
6. ACCIDENTAL RELEASE MEASURES
IN CASE OF SPILL OR OTHER RELEASE: (Always wear recommended personal protective equipment.)
Eliminate ignition sources. Use water spray to dilute spills to a nonflammable mixture. Contain liquid with dirt,
sand, vermiculite or other noncombustible solids. Transfer to a metal container for disposal. Do not allow
spills to enter drains, sewers or waterways.
Spills and releases may have to be reported to Federal and/or local authorities. See Section 15 regarding
reporting requirements.
7. HANDLING AND STORAGE
NORMAL HANDLING: (Always wear recommended personal protective equipment.)
Wear adequate personal protective equipment. Avoid breathing vapor. Avoid contact with skin and eyes.
Keep away from heat, sparks and open flame. Ground equipment and comply with the National Electric Code.
STORAGE RECOMMENDATIONS:
Store in a cool, dry, well-ventilated area away from sources of ignition. Keep away from strong oxidants.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS:
Maintain vapor levels below the recommended TLV's and/or PEL's by use of adequate local or general
exhaust system at product transfer/use areas.
PERSONAL PROTECTIVE EQUIPMENT
SKIN PROTECTION:
Neoprene gloves, long sleeve shirt and trousers. Add rubber raincoat and pants if splashing or liquid contact
is anticipated.
MSDS Number: HPWI-0001 Page 3 of 8
Current Issue Date: April 3, 2003
Material Safety Data Sheet
Nadone庐 (Cyclohexanone)
EYE PROTECTION:
Chemical safety goggles or face shield. Do not wear contact lenses.
RESPIRATORY PROTECTION:
None required for adequately ventilated work areas. For large spills, wear self-contained breathing apparatus.
A full face respirator with organic cartridge may be used if vapor concentrations are under 1000 ppm.
ADDITIONAL RECOMMENDATIONS:
Eyewash station and washing facilities are recommended.
EXPOSURE GUIDELINES
INGREDIENT NAME ACGIH TLV OSHA PEL OTHER LIMIT
Cyclohexanone 25 ppm (TWA) 鈥? 25 ppm (TWA) 鈥? None
Skin; A3 (Confirmed Skin
Animal Carcinogen with
Unknown Relevance to
Humans)
* = Limit established by AlliedSignal for internal use.
** = Workplace Environmental Exposure Level (AIHA).
*** = Biological Exposure Index (ACGIH).
OTHER EXPOSURE LIMITS FOR POTENTIAL DECOMPOSITION PRODUCTS: None
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: Clear colorless to pale yellow liquid.
Liquid.
PHYSICAL STATE:
98.14
MOLECULAR WEIGHT
CH2(CH2)4CO
CHEMICAL FORMULA
ODOR: Peppermint-like.
(Water - 1.0) 0.945
SPECIFIC GRAVITY (water = 1.0):
(Weight %) 5% @ 30掳C
SOLUBILITY IN WATER (weight %):
pH: Not applicable.
BOILING POINT: 155.6掳C (312.1掳F)
MELTING POINT: -32.1掳C (-25.8掳F)
VAPOR PRESSURE: 3.95 mm Hg @ 20掳C
VAPOR DENSITY (air = 1.0): (Air - 1.0) 3.4
<1 Ether.
EVAPORATION RATE: COMPARED TO:
% VOLATILES: 100
MSDS Number: HPWI-0001 Page 4 of 8
Current Issue Date: April 3, 2003
Material Safety Data Sheet
Nadone庐 (Cyclohexanone)
46掳C (114.8掳F)
FLASH POINT:
(Flash point method and additional flammability data are found in Section 5.)
10. STABILITY AND REACTIVITY
NORMALLY STABLE? (CONDITIONS TO AVOID):
Stable under normal conditions.
INCOMPATIBILITIES:
Oxidizing agents, including nitric acid and peroxides.
HAZARDOUS DECOMPOSITION PRODUCTS:
None known
HAZARDOUS POLYMERIZATION:
Will not occur.
11. TOXICOLOGICAL INFORMATION
IMMEDIATE (ACUTE) EFFECTS:
LD50 (oral-rat): 1535 mg/kg
LD50 (oral -mouse): 1400 mg/kg
LD50 (skin-rabbit): 948 mg/kg
DELAYED (SUBCHRONIC AND CHRONIC) EFFECTS:
Liver and kidney damage reported in monkeys and rabbits (190 ppm) and rats (105.2 mg/m3). Blood and
bone marrow effects reported in rats, dogs and monkeys injected with 142-284 mg/kg
OTHER DATA:
None.
12. ECOLOGICAL INFORMATION
Breakdown via chemical, photochemical and microbial degradation in natural environment. Generally not
degraded by hydrolysis. 300 ppm is safe for aquatic life. Halogenation may occur in aqueous environment.
Octanol/water partition coefficient - 0.01
MSDS Number: HPWI-0001 Page 5 of 8
Current Issue Date: April 3, 2003
Material Safety Data Sheet
Nadone庐 (Cyclohexanone)
13. DISPOSAL CONSIDERATIONS
RCRA
Yes.
Is the unused product a RCRA hazardous waste if
discarded?
If yes, the RCRA ID number is: U057 and D001
OTHER DISPOSAL CONSIDERATIONS: 40 CFR Section 268 should be consulted for federal regulatory
requirement.
The information offered here is for the product as shipped. Use and/or alterations to the product such as mixing with
other materials may significantly change the characteristics of the material and alter the RCRA classification and the
proper disposal method.
14. TRANSPORT INFORMATION
Cyclohexanone, 3, UN 1915, III
US DOT HAZARD CLASS:
UN 1915 (PIN # in Canada)
US DOT ID NUMBER:
For additional information on shipping regulations affecting this material, contact the information number found in
Section 1.
15. REGULATORY INFORMATION
TOXIC SUBSTANCES CONTROL ACT (TSCA)
Material is on the TSCA Inventory.
TSCA INVENTORY STATUS:
None.
OTHER TSCA ISSUES:
SARA TITLE III/CERCLA
"Reportable Quantities" (RQs) and/or "Threshold Planning Quantities" (TPQs) exist for the following ingredients.
INGREDIENT NAME SARA/CERCLA RQ (lb) SARA EHS TPQ (lb)
Cyclohexanone 5000 None
Spills or releases resulting in the loss of any ingredient at or above its RQ requires immediate notification
to the National Response Center [(800) 424-8802] and to your Local Emergency Planning Committee.
Immediate. Delayed. Fire.
SECTION 311 HAZARD CLASS:
MSDS Number: HPWI-0001 Page 6 of 8
Current Issue Date: April 3, 2003
Material Safety Data Sheet
Nadone庐 (Cyclohexanone)
SARA 313 TOXIC CHEMICALS:
The following ingredients are SARA 313 "Toxic Chemicals". CAS numbers and weight percents are found in
Section 2.
INGREDIENT NAME COMMENT
*No ingredients listed in this section*
STATE RIGHT-TO-KNOW
In addition to the ingredients found in Section 2, the following are listed for state right-to-know purposes.
INGREDIENT NAME WEIGHT % COMMENT
*No ingredients listed in this section*
ADDITIONAL REGULATORY INFORMATION:
None.
WHMIS CLASSIFICATION (CANADA):
Class B, Division 2
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all
the information required by the CPR.
FOREIGN INVENTORY STATUS:
Canadian DSL (Domestic Substance List)
EINECS (European Inventory of Existing Commercial Chemical Substances)
16. OTHER INFORMATION
CURRENT ISSUE DATE: January 17, 2002
PREVIOUS ISSUE DATE: July, 1999
CHANGES TO MSDS FROM PREVIOUS ISSUE DATE ARE DUE TO THE FOLLOWING:
Corrected OSHA Flammability Class.
Added NFPA Hazard Class - 1/02
Included new ACGIH classification (A3) and revised TLV per the 2003 TLV/BEI documentation - 4/03.
MSDS Number: HPWI-0001 Page 7 of 8
Current Issue Date: April 3, 2003
Material Safety Data Sheet
Nadone庐 (Cyclohexanone)
UNITED NATIONS NUMBER:
OTHER INFORMATION:
ADR/RID CLASS:
PACKING GROUP:
IMDG CODE:
ICAO/IATA:
IMO SHIPPING NAME:
IATA SHIPPING NAME:
ADR SHIPPING NAME:
RID SHIPPING NAME:
MSDS Number: HPWI-0001 Page 8 of 8
Current Issue Date: April 3, 2003
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