MATERIAL SAFETY DATA SHEET
Page 1
GENAPOL UD 110
Substance key: SXR023977 Revision Date: 11/30/2004
Version : 1 - 2 / USA Date of printing :02/24/2005
Section 01 - Product Information
Identification of the Clariant Corporation
company: 4000 Monroe Road
Charlotte, 28205
Telephone No.: +1 704 331 7000
Information of the substance/preparation:
Product Safety 1-704-331-7710
Emergency tel. number: +1 800-424-9300 CHEMTREC
Trade name: GENAPOL UD 110
CAS number: 127036-24-2
Synonyms: Product Has No Synonyms
Primary product use: Raw material for detergents
Chemical family: fatty alcohol polyglycolether
Section 02 - Composition information on hazardous ingredients
Hazardous ingredients:
Component CAS-no. (Trade secret Concentration
no.)
Ethoxylated Undecyl Alcohol 127036-24-2 100 %
Section 03 - Hazards identification
Expected Route of entry:
Inhalation: no
Skin contact: yes
Eye contact: yes
Ingestion: no
Skin absorption: no
Health effects of exposure:
Poly(oxy-1,2-ethanediyl), a-undecyl-w-hydroxy-, branched and linear ( 127036-24-2 )
Causes severe irritation to the eyes, possibly resulting in eye damage.
Known effects on other illnesses: Pre-existing eye conditions may be aggravated by
exposure to this product.
Listed carcinogen: IARC: No
NTP: No
OSHA: No
Other: No
MATERIAL SAFETY DATA SHEET
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GENAPOL UD 110
Substance key: SXR023977 Revision Date: 11/30/2004
Version : 1 - 2 / USA Date of printing :02/24/2005
HMIS:
Health: 2 Flammability: 1 Reactivity: 0 Personal protection: D
Section 04 - First aid measures
After inhalation:
Get victim to fresh air. Give artificial respiration or oxygen if breathing has stopped. Get prompt
medical attention. Do not give fluids if victim is unconscious.
After contact with skin:
Immediately flush skin with plenty of water while removing contaminated clothing. Wash
contaminated clothing before reuse. If redness or irritation occurs, seek medical attention.
After contact with eyes:
Immediately flush eyes with large amounts of water for at least 15 minutes, holding lids apart to
ensure flushing of the entire surface. Washing eyes within 1 minute is essential to achieve
maximum effectiveness. Seek medical attention immediately.
After ingestion:
If conscious, give the patient 1-2 glasses of water (8-16 oz.) and call a doctor. Never give
anything by mouth to an unconscious person. Induce vomiting only at the instructions of a
doctor or nurse.
Advice to doctor / Treatment:
None known.
Section 05 - Fire fighting measures
Flashpoint: approx. 392 掳F
Method: DIN/ISO 2592 (open cup)
Lower explosion limit: not determined
Upper explosion limit: not determined
Self ignition: not determined
Ignition temperature: not determined
Hazardous combustion products:
In the event of fire the following can be released:
Carbon monoxide (CO)
Carbon dioxide (CO2)
Combustion gases of organic materials must in principle be graded as inhalation poisons.
Extinguishing media: water spray jet
foam
carbon dioxide
dry powder
Special fire fighting procedure:
Apply alcohol-type or all purpose-type foams by manufacturers' recommended techniques for
large fires. Use carbon dioxide or dry chemical media for small fires. Do not direct a solid
stream of water or foam into hot burning pools; this may cause frothing and increase fire
intensity. Use self- contained breathing apparatus and protective equipment.
MATERIAL SAFETY DATA SHEET
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GENAPOL UD 110
Substance key: SXR023977 Revision Date: 11/30/2004
Version : 1 - 2 / USA Date of printing :02/24/2005
Unusual fire and explosion Emits toxic fumes under fire conditions. Product floats on water
hazards: creating a potential floating fire hazard..
Section 06 - Accidental release measures
Steps to be taken in case of spill or leak:
Wearing appropriate personal protective equipment, contain spill, collect into suitable
container. For large spills, contain spills with dikes of soil or commercially available diking
material and collect into suitable containers for disposal. Avoid washing spills into sewers and
waterways. This product is toxic to fish in concentrations of 1 to 10 mg/l.
Section 07 - Handling and storage
Advice on safe handling:
Avoid getting on skin or in eyes when handling product.
Further info on storage conditions:
Keep containers closed.
Section 08 - Exposure controls / personal protection
Respiratory protection: If airborne concentrations pose a health hazard, become irritating
or exceed recommended limits, use a NIOSH approved respirator
in accordance with OSHA respiratory protection requirements
under 29 CFR 1910.134
Hand protection: Butyl Rubber, PVC Or Neoprene.
Eye protection: Chemical splash goggles.
Other protective equipment: Protective clothing to minimize skin contact should be worn.
Chemically resistant safety shoes. Wash contaminated clothing
with soap and water and dry before reuse. Safety showers and
eyewash stations should be provided in all areas where this
material is handled.
Advice on system design: Local ventilation recommended - mechanical ventilation may be
used.
IDLH:
None
Section 09 - Physical and chemical properties
Form: Pasty
Color: white
Odor: slight, original odour
MATERIAL SAFETY DATA SHEET
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GENAPOL UD 110
Substance key: SXR023977 Revision Date: 11/30/2004
Version : 1 - 2 / USA Date of printing :02/24/2005
pH: 6 - 8 (20 掳C, 50 g/l)
Method: DIN 53996
Ethanol/Water 1:1
Solubility in water: (20 掳C)
soluble, clear
Soluble in ... : fat
not determined
Density: 0.99 g/cm3 (50 掳C)
Method: DIN 51757
Pourpoint : approx. 86 掳F
Method: DIN/ISO 3016
Boiling point : not determined
Vapor pressure: not determined
Bulk density: not determined
Relative vapor density: Not applicable
Partitioning coef. Not applicable
octanol/water:
Viscosity / (dynamic): approx. 30 mPa.s (50 掳C)
Method: DIN 53015
Viscosity / (kinematic): not determined
Section 10 - Stability and reactivity
Thermal decomposition: > 300 掳C
Method: DSC
Source: Analogy
No decomposition if used as prescribed.
Chemical stability: Stable.
Hazardous Polymerization: Will not occur.
Conditions to avoid: None known.
Conditions to avoid: Strong acids, oxidizers, and strong bases.
Section 11 - Toxicological information
Product information:
Acute oral toxicity: LD50 500 - 2,000 mg/kg (rat)
Method: OECD 401
Acute inhalation toxicity: not determined
Acute dermal toxicity: not determined
Skin irritation: Non-irritating (rabbit)
Eye irritation: Severe irritant (rabbit)
MATERIAL SAFETY DATA SHEET
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GENAPOL UD 110
Substance key: SXR023977 Revision Date: 11/30/2004
Version : 1 - 2 / USA Date of printing :02/24/2005
Section 12 - Ecological information
Product information:
Biodegradation: > 90 % (15 d)
Method: OECD 302 B
Biodegradation: 91 % (28 d)
readily degradable
Method: OECD 301 E
Fish toxicity: LC50 10 - 100 mg/l (96 h, zebra fish)
Method: OECD 203
Bacteria toxicity: EC50 > 1,000 mg/l (3 h, activated sludge)
Method: OECD 209
Dissolved organic carbon 510 mg/g
(DOC):
Chemical oxygen demand 2,030 mg/g
(COD):
Section 13 - Disposal considerations
Waste disposal information:
Recommended disposal is by incineration in approved facilities.
RCRA hazardous waste:
No -- Not as sold.
RCRA number: NONE
Section 14 - Transport information
DOT not restricted
IATA not restricted
IMDG not restricted
Section 15 - Regulatory information
TSCA Status:
All components of this product are listed on the TSCA Inventory.
SARA (section 311/312):
Reactive hazard: no
Pressure hazard: no
Fire hazard: no
Immediate/acute: yes
Delayed/chronic: no
SARA 313 information:
MATERIAL SAFETY DATA SHEET
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GENAPOL UD 110
Substance key: SXR023977 Revision Date: 11/30/2004
Version : 1 - 2 / USA Date of printing :02/24/2005
This product does not contain any toxic chemical listed under Section 313 of the Emergency
Planning and Community Right-To-Know Act of 1986.
Clean Water Act:
Contains no known priority pollutants at concentrations greater than 0.1%.
Volatile organic compounds VOC:
Remarks: Not Available
FDA:
This product is not registered with the FDA.
Section 16 - Other information
Other precautions:
This product may contain trace amounts of Ethylene Oxide (75-21-8) which may accumulate in
the headspace of shipping and storage containers and in enclosed areas where the product is
handled or used and as such may be regulated by OSHA's Ethylene Oxide standard (29 CFR
1910.1047). Ethylene Oxide is listed as a human carcinogen by OSHA; and a potential human
carcinogen by NTP and IARC. At excess levels, Ethylene Oxide may present reproductive,
mutagenic, genotoxic, neurologic, and sensitization hazards in humans. Users should monitor
personnel to determine levels of exposure and take appropriate action to protect employees
and to comply with the OSHA standard. OSHA Ethylene Oxide exposure limit: OSHA Action
level: 0.5 ppm for 8-hr twa. OSHA Permissible Exposure limit: 1 ppm for 8-hr twa. OSHA
Excursion limit: 5 ppm for 15 minutes. ACGIH Threshold Limit value for Ethylene Oxide: 1 ppm
for 8-hr twa.
Label information:
WARNING!
CAUSES SEVERE EYE IRRITATION MAY CAUSE EYE DAMAGE
Avoid breathing fumes, vapors, mists or spray. Avoid contact with skin and eyes. Use
with adequate ventilation and/or respiratory protection. Wash thoroughly after handling.
Keep container closed when not in use.
Eye contact: immediately flush eyes with large amounts of water for at least 15 minutes,
holding eyelids apart to ensure flushing of the entire surface. Washing eyes within 1
minute is essential to achieve maximum effectiveness. Seek medical attention
immediately. Skin contact: remove contaminated clothing. Wash thoroughly with soap
and water for 15 minutes. If contact has been widespread or prolonged, or if irritation
occurs, seek medical attention. Wash clothing before reuse. Ingestion: do not induce
vomiting. Seek immediate medical assistance. Inhalation: remove to fresh air. If not
breathing, give artificial respiration. If breathing is difficult, give oxygen and seek medical
attention.
This information is supplied under the OSHA Hazard Communication Standard, 29 CFR
1910.1200, and is offered in good faith based on data available to us that we believe to be
true and accurate. The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable to the material. However, each user should review these
MATERIAL SAFETY DATA SHEET
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GENAPOL UD 110
Substance key: SXR023977 Revision Date: 11/30/2004
Version : 1 - 2 / USA Date of printing :02/24/2005
recommendations in the specific context of the intended use and determine whether they are
appropriate for that use. No warranty, express or implied, is made regarding the accuracy of
this data, the hazards connected with the use of the material, or the results to be obtained
from the use thereof. We assume no responsibility for damage or injury from the use of the
product described herein. Data provided here are typical and not intended for use as product
specifications. (R) and TM indicate trademarks of Clariant AG, its business partners or
suppliers.
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