MSDS No.: 3379
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER DM INDUSTRIAL
GRADE
SECTION 1: IDENTIFICATION
Product Name: GLYCOL ETHER DM INDUSTRIAL GRADE
Product Number: 000000000000005122
Chemical Family: Glycol Ethers
CAS Number: 111-77-3
Chemical Name: 2-(2-methoxyethoxy) ethanol
Synonyms: All Grades includes: Industrial and Jet Fuel Grades
Manufacturer Business Contact
Equistar Chemicals, LP Customer Service
One Houston Center, Suite 700 888 777-0232
1221 McKinney St. Product Safety
P.O. Box 2583 800 700-0946
Houston Texas 77252-2583
24 Hour Emergency Contact
CHEMTREC 800 424-9300
EQUISTAR 800-245-4532
SECTION 2 : COMPOSITION/INFORMATION ON INGREDIENTS
Component Name CAS # EU Inventory Concentration Wt.%* Risk Symbol
Diethylene glycol monomethyl 111-77-3 203-906-6 99.0 <= 100.0 R63 Xn
ether
Ethanol, 2-methoxy 109-86-4 203-713-7 <= 0.5 R60, R61, T
R10,
R20/21/22
* Concentration of gaseous products or materials is given in Mole %
Compositions given are typical values not specifications.
SECTION 3: HAZARD IDENTIFICATION
Emergency Overview
This material is HAZARDOUS by OSHA Hazard Communication definition.
Signal Word
WARNING!
Hazards
Combustible liquid. Eye irritant. Skin irritant. Respiratory tract irritant. CNS depressant.
Page 1 of 9
MSDS No.: 3379
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER DM INDUSTRIAL
GRADE
HMIS庐
NFPA庐
2
Health * 1
Flammability 2
1 0
Reactivity 0
Physical State
Liquid.
Color
Clear
Odor
Pleasant. Mild aromatic.
Odor Threshold
No value available.
Potential Health Effects
Routes of Exposure
Eye Skin. Inhalation Ingestion
Signs and Symptoms of Acute Exposure
See component summary.
鈥? Diethylene glycol monomethyl ether 111-77-3
May be irritating to the eyes.
鈥? Ethanol, 2-methoxy 109-86-4
Eye, skin and respiratory tract irritant. May be harmful if inhaled ingested or absorbed through the skin. Overexposure may
cause Central Nervous System depression.
Skin
May be irritating to the skin. Possible systemic toxicity by skin absorption.
Inhalation
Due to low vapor pressure, this mixture is not expected to present an inhalation hazard at ambient temperatures.
Eye
May be irritating to the eyes.
Ingestion
Ingestion not a likely route of exposure.
Chronic Health Effects
See component summary.
Page 2 of 9
MSDS No.: 3379
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER DM INDUSTRIAL
GRADE
鈥? Diethylene glycol monomethyl ether 111-77-3
Extensive/prolonged or repeated exposure to this material can result in significant absorption. Repeated or prolonged
exposure to mists of this material may cause long-term adverse health effects.
鈥? Ethanol, 2-methoxy 109-86-4
Prolonged or repeated exposure to liquid can cause irritation such as redness, burning and cracking of the skin and
dermatitis. Effects caused by chronic exposures include toxic encephalopathy, bone marrow depression without hemolysis,
lung, kidney and liver damage, lethargy, loss of appetite, tremors, fever, bed wetting and marked anemia.
Conditions Aggravated by Exposure
Any pre-existing disorders or diseases of the: skin and/or eyes Special precautions are nessesary for pregnant women
and nursing mothers.
SECTION 4: FIRST AID MEASURES
General
Take proper precautions to ensure your own health and safety before attempting rescue and providing first aid. For specific
information refer to the Emergency Overview in Section 3 of this MSDS.
Skin
Immediately flush affected area with plenty of water while removing contaminated clothing. Wash contaminated clothing
before reuse. If irritation persists, get medical attention.
Inhalation
If symptoms are experienced, move victim to fresh air. Seek medical attention if discomfort persists.
Eye
Thoroughly flush the eyes with large amounts of clean low-pressure water for at least 15 minutes, occasionally lifting the
upper and lower eyelids. If irritation persists, seek medical attention.
Ingestion
DO NOT induce vomiting. If vomiting does occur, have victim lean forward to reduce risk of aspiration. Get medical
attention immediately.
SECTION 5: FIRE FIGHTING MEASURES
Flammable Properties
Classification
Combustible liquid.
Flash Point:
83.9 掳C (183.02 掳F) closed cup
Auto-Ignition Temperature
192.85 掳C (379.13 掳F)
Lower Flammable Limit
1.38 vol%
Upper Flammable Limit
22.7 vol%
Extinguishing Media
Page 3 of 9
MSDS No.: 3379
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER DM INDUSTRIAL
GRADE
Suitable: SMALL FIRE: Use dry chemicals, CO2, water spray or alcohol-resistant foam LARGE FIRE: Use water spray,
water fog or alcohol-resistant foam
Protection of Firefighters
Protective Equipment/Clothing: Wear an approved positive pressure self-contained breathing apparatus and firefighter
turnout gear.
Fire Fighting Guidance: Avoid sparks, heat, and open flame. Fight fire from maximum distance or use unmanned hose
holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well
after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. Always
stay away from tanks engulfed in fire.
Hazardous Combustion Products: Carbon oxides (CO, CO2)
SECTION 6: ACCIDENTAL RELEASE MEASURES
Release Response
Contain spill with dike to prevent entry into sewers or waterways. For large spills, dike and pump into properly labeled
containers for reclamation or disposal. For small spills, soak up with absorbent material and place in properly labeled
containers for disposal. All recovered material should be packaged, labeled, transported and disposed of or reclaimed in
conformance with applicable laws and regulations and in conformance with good engineering practices. Reclaim where
possible.
SECTION 7: HANDLING AND STORAGE
Handling
Do not handle near heat, sparks, or flame. Avoid contact with incompatible agents. Use only with adequate
ventilation/personal protection. Avoid contact with eyes, skin and clothing. Do not enter storage area unless adequately
ventilated. Metal containers involved in the transfer of this material should be grounded and bonded. It is recommended
that any liquid product exposed to air not be highly concentrated by evaporation without first assuring that no peroxide is
present.
Storage
Store containers in a cool, dry, ventilated, fire resistant area away from sources of ignition and incompatible materials. Keep
container tightly closed and properly labeled.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. Emergency shower and eyewash facility should be in close proximity (ANSI Z358.1)
Personal Protection
Inhalation A respiratory protection program that meets OSHA's 29 CFR 1910.134 or ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant respirator use.
Skin Wear chemical resistant gloves such as rubber, neoprene or vinyl. Appropriate protective clothing should be worn to
prevent skin contact.
Eye Wear safety glasses as minimum eye protection. Conditions may warrant the use of chemical goggles and possibly a
face shield. Consult your standard operating procedure or safety professional for advice. Use protective eye and face
devices that comply with ANSI Z87.1-1987.
Occupational Exposure Limits
Component Name Source / Date Value Type Notation
Page 4 of 9
MSDS No.: 3379
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER DM INDUSTRIAL
GRADE
Diethylene glycol monomethyl ether US (ACGIH) / 2003 N/L
US (OSHA) / 2003 N/L
Ethanol, 2-methoxy US (ACGIH) / 2003 5 ppm 8 HRS/TWA Skin.
US (OSHA) / 2003 25 ppm 8 HRS/TWA Skin.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Liquid. Clear
Odor: Pleasant. Mild aromatic.
Odor Threshold: No value available.
pH: Not applicable.
Boiling Point/Boiling Range: 193.6 掳C (380.48 掳F)
Freezing Point/Melting Point: -65 掳C (-85 掳F) Melting point.
Flash Point: 83.9 掳C (183.02 掳F) closed cup
Auto-ignition: 192.85 掳C (379.13 掳F)
Flammability: Combustible liquid.
Lower Flammable Limit: 1.38 vol%
Upper Flammable Limit: 22.7 vol%
Explosive Properties: No Data Available.
Oxidizing Properties: No Data Available.
Vapor Pressure: 0.2 mm Hg @ 20 掳C (68 掳F)
Evaporation Rate: 0.015 (butyl acetate = 1)
Relative Density: 1.025 @ 20 掳C (68 掳F)
Relative Vapor Density: 4.1 (Air = 1.0)
Viscosity: ~ 3.89 mPa.s @ 20 掳C (68 掳F)
Solubility (Water): 100%
Partition Coefficient (Kow): -1.18 (estimated)
Additional Physical and Chemical Properties: No additional information available.
SECTION 10: STABILITY AND REACTIVITY
Chemical Stability
Page 5 of 9
MSDS No.: 3379
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER DM INDUSTRIAL
GRADE
Stable under normal conditions. May form peroxides if in contact with air for long periods of time.
Conditions to Avoid
Heat, sparks, open flames and strong oxidizing conditions.
Substances to Avoid
Oxidizers, Acids, Alkalis
Decomposition Products
Carbon oxides (CO, CO2)
Hazardous Polymerization
Will not occur.
Reactions with Air and Water
May form peroxides in the presence of air.
SECTION 11: TOXICOLOGICAL INFORMATION
PRODUCT INFORMATION
Product Summary
No additional toxicology information is available for this material. (See Component Toxicity Information).
COMPONENT INFORMATION
鈥? Diethylene glycol monomethyl ether 111-77-3
Acute Toxicity - Lethal Doses
Rat > 2 GM/M3 1 HOURS
LD50 (Oral) Rat 9.2 G/KG
Guinea Pig 4.2 G/KG
LD50 (Skin) Rabbit 20.2 G/KG
Reproductive Effects
Laboratory test indicate high doses may cause adverse reproductive effects in rats and mice.
鈥? Ethanol, 2-methoxy 109-86-4
Acute Toxicity - Lethal Doses
LC50 (Inhl) Rat 1480 PPM 7 HOURS
LD50 (Oral) Rat 2370 MG/KG
Mouse 2560 MG/KG
LD50 (Skin) Rabbit 1280 MG/KG
Reproductive Effects
Animal studies indicate the potential for reproductive effects in males.
Page 6 of 9
MSDS No.: 3379
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER DM INDUSTRIAL
GRADE
Carcinogenicity
Not listed by IARC, NTP, or OSHA.
SECTION 12: ECOLOGICAL INFORMATION
PRODUCT INFORMATION
Ecotoxicity
This material is highly soluble in water. Limited toxicity tests and models indicate this material should exhibit low toxicity to
aquatic organisms. The odor and flavor of this material may attract some wildlife and cause them to consume spilled
material.
Environmental Fate and Pathway
This material should biodegrade after an acclimation period, and it is is not expected to be environmentally persistant. Due
care should be taken to avoid accidental releases to aquatic or terrestrial systems. See component summary.
Persistance and Degradability
Bioaccumulation: This material is highly soluble in water and should not bioaccumulate in aquatic or terrestrial organisms.
COMPONENT INFORMATION
鈥? Diethylene glycol monomethyl ether 111-77-3
Ecotoxicity
No Data Available.
Environmental Fate and Pathway
Expected to have high mobility in soils. This material is expected to exist solely as a vapor in the ambient atmosphere.
Vapor-phase is degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals. Volatilization
from dry soil surfaces is expected. While this material may evaporate into the air from dry soil, it is unlikely to evaporate from
moist soil or water.
Persistance and Degradability
Biodegradation: Biodegradable under aerobic conditions.
Bioaccumulation: BCF < 1.0 This material is not expected to bioaccumulate.
鈥? Ethanol, 2-methoxy 109-86-4
Ecotoxicity
No Data Available.
Environmental Fate and Pathway
Expected to exist solely as a vapor in the ambient atmosphere. Vapor-phase is degraded in the atmosphere by reaction
with photochemically produced hydroxyl radicals. It is expected to be poorly adsorbed onto soils or sediments.
Volatilization from dry soil surfaces is expected. It will leach into soil. Hydrolysis is not expected to be an important factor in
the environmental fate process for this material.
Page 7 of 9
MSDS No.: 3379
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER DM INDUSTRIAL
GRADE
Persistance and Degradability
Biodegradation: This material is expected to be biodegradable.
Bioaccumulation: This material is not expected to bioaccumulate.
SECTION 13: DISPOSAL CONSIDERATIONS
Dispose of all waste and contaminated equipment in accordance with all applicable federal, state and local health and
environmental regulations. Recovery and reuse, rather than disposal, should be the ultimate goal of handling efforts. The
materials resulting from clean-up operations may be hazardous wastes and therefore, subject to specific regulations.
SECTION 14: TRANSPORT INFORMATION
Special Requirements
If you reformulate or further process this material, you should consider re-evaluation of the regulatory status of the
components listed in the composition section of this sheet, based on final composition of your product.
Proper Shipping Name Combustible liquid, n.o.s. (DIETHYLENE GLYCOL MONOMETHYL ETHER)
ID No. NA1993
Hazard Class Combustible Liquid
PG III
SECTION 15: REGULATORY INFORMATION
Regulatory Status
Country Inventory
Australia AICS X
X = All components are included or are otherwise
Canada DSL X
exempt from inclusion on this inventory.
Canada NDSL
China IECS X
European Union EINECS X
European Union ELINCS
European Union NLP C = Contact Lyondell/Equistar by e-mail at
product.safety@lyondell.com or
Japan ENCS X
product.safety@equistarchem.com for additional
Korea ECL X
information.
Philippines PICCS X
United States TSCA X
If identified components of this product are listed under the TSCA 12(b) Export Notification rule, they will be listed below.
Export notification required.
2-methoxyethanol (Ethylene glycol methyl ether) - CASRN 1 TSCA section 5
SARA 302/304
No chemicals in this material with known CAS numbers are subject to the reporting requirements of CERCLA.
SARA 311/312
Page 8 of 9
MSDS No.: 3379
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER DM INDUSTRIAL
GRADE
Based upon available information, this material is classified as the following health and/or physical hazards according to
Section 311 & 312:
Immediate (Acute) Health Hazard.
Delayed (Chronic) Health Hazard.
SARA 313
This material contains the following chemicals with known CAS numbers subject to the reporting requirements of SARA Title
III, Section 313 and 40 CFR 372:
Component Reporting Threshold
Diethylene Glycol Monomethyl Ether / CAS # 111-77-3 1.0%
2-Methoxyethanol / CAS# 109-86-4 1.0%
State Reporting
This product contains the following ingredients for which the state of California has found to cause cancer, birth defects or
other reproductive harm, which would require a warning under the statute:
鈥? 2-Methoxyethanol; developmental toxicity, male reproductive toxicity.
SECTION 16: OTHER INFORMATION
Latest Revision(s)
Conversion to SAP template. Revised Section(s): 9 12 15 Date of Revision: March 4 2004
DISCLAIMER OF RESPONSIBILITY
The information on this MSDS was obtained from sources which we believe are reliable. However, the information is
provided without any warranty, expressed or implied, regarding its correctness. Some information presented and
conclusions drawn herein are from sources other than direct test data on the substance itself. The conditions or methods
of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this
and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense arising
out of or in any way connected with handling, storage, use, or disposal of this product. If the product is used as a
component in another product, this MSDS information may not be applicable.
Numerical Data Presentation
The presentation of numerical data, such as that used for physical and chemical properties and toxicological values, is
expressed using a comma (,) to separate digits into groups of three and a period (.) as the decimal marker. For example,
1,234.56 mg/kg = 1 234,56 mg/kg
Language Translations
The information presented in this document has been translated from English by a vendor Lyondell believes to be reliable.
Lyondell and its vendor have made a good-faith effort to verify the accuracy of the translation, but assume no responsibility
for any errors that may have occurred. Please refer to our web sites (www.lyondell.com and www.equistarchem.com) for
the original document written in English.
< end of document >
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