MATERIAL SAFETY DATA SHEET
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT
PRODUCT CODE AND NAME DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
:
ISSUE DATE : 04/14/1998
7/1/2000
MSDS CD DATE :
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MATERIAL IDENTITY
PRODUCT CODE AND NAME
DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
Chemical Name and/or Family or Description:
Alkanolamine
COMPANY INFORMATION
Huntsman Petrochemical Corporation
P.O. Box 27707
Houston, TX 77227-7707
TELEPHONE NUMBERS
Transportation Emergency
Company: (409) 727-0831
CHEMTREC: (800) 424-9300
Medical Emergency: (409) 722-9673 (24 Hour)
General MSDS Assistance: (713) 235-6432
Technical Information: (512) 459-6543
2. COMPOSITION AND INFORMATION ON INGREDIENTS
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION ARE AS FOLLOWS: CARCINOGENS ARE LISTED WHEN
PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN
PRESENT AT 1.0 % OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT INTENDED
TO BE COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND
OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
NONE X
OSHA IARC NTP OTHER
Composition:
Chemical Name CAS Number Exposure Limits Range in %
Ethanol, 2- (dimethylamino)- 108-01-0 100
THIS PRODUCT IS CONSIDERED HAZARDOUS ACCORDING TO OSHA (1910.1200).
1
PRODUCT CODE AND NAME DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
:
ISSUE DATE : 04/14/1998
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance:
Colorless liquid
Odor:
Ammonia-like odor
WARNING STATEMENT
DANGER ! CORROSIVE - CAUSES EYE AND SKIN BURNS
HARMFUL OR FATAL IF SWALLOWED
CAUSES RESPIRATORY TRACT IRRITATION AND CAN CAUSE DAMAGE
ASPIRATION HAZARD IF SWALLOWED -
CAN ENTER LUNGS AND CAUSE DAMAGE
MAY CAUSE ALLERGIC SKIN AND RESPIRATORY -
(ASTHMA-LIKE) - REACTION
COMBUSTIBLE LIQUID AND VAPOR
Hazardous Material National Fire Protection
3
Health Flammability
2
Information System Association NFPA
2
Fire
3 0 Reactivity
(United States) (United States) Health
0
Reactivity
Personal protection Specific danger
POTENTIAL HEALTH EFFECTS
Primary Route of Exposure
Eye X Skin X Inhalation X Ingestion
Effects of Overexposure
Acute:
Causes irritation, experienced as pain, with excess blinking and tear production, and seen as
Eyes:
extreme redness and swelling of the eye and chemical burns of the eye. Severe eye damage
may cause blindness.
Causes severe irritation with pain, severe excess redness and swelling with chemical burns,
Skin:
blister formation, and possible tissue destruction. Other than the potential skin irritation
effects noted above, acute (short term) adverse effects are not expected from brief skin
contact; see other effects, below, and Section 11 for information regarding potential long
term effects.
Vapors, mists, or dusts are irritating and cause burning of the nose, throat, and eyes,
Inhalation:
coughing, tightness of the chest, and difficulty breathing. Prolonged or severe overexposure
may result in cyanosis (blue discoloration of the skin or lips), pulmonary edema, lung
damage, or death. Inhalation may result in the absorption of potentially harmful amounts of
material.
Causes burning of mouth, throat, and stomach with abdominal and chest pain, nausea,
Ingestion:
vomiting, diarrhea, thirst, weakness, and collapse. Aspiration may occur during swallowing
or vomiting, resulting in lung damage.
This product or a component of this product is a potential skin and respiratory sensitizer.
Sensitization Properties:
Therefore, inhalation of this product may cause an allergic or asthma-like reaction,
experienced as wheezing, coughing, increased mucous production, tightness in the chest, or
difficulty breathing, in sensitive, exposed persons. Prolonged and repeated contact with this
product may cause an allergic skin reaction in sensitive, exposed persons.
Chronic:
2
PRODUCT CODE AND NAME DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
:
ISSUE DATE : 04/14/1998
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
Repeated skin contact may cause a persistent irritation or dermatitis. Repeated inhalation may cause lung damage.
Medical Conditions Aggravated by Exposure:
Skin contact may aggravate an existing dermatitis (skin condition). Overexposure to vapor, dust or mist may aggravate
existing respiratory conditions, such as asthma, bronchitis, and inflammatory or fibrotic respiratory disease.
Other Remarks:
This product contains one or more amines which may produce temporary and reversible hazy or blurred vision. Symptoms
disappear when exposure is terminated.
4. FIRST AID MEASURES
Eyes:
Immediately flush eyes with large amounts of running water for at least 15 minutes. Hold eyelids apart while flushing to rinse entire
surface of eye and lids with water. Do not attempt to neutralize with chemical agents. Obtain medical attention immediately. Continue
flushing for an additional 15 minutes if medical attention is not immediately available.
Skin:
Immediately remove contaminated clothing and shoes. Under a safety shower, flush skin thoroughly with large amounts of running
water for at least 15 minutes. Do not attempt to neutralize with chemical agents. Get medical attention immediately. Discard or
decontaminate clothing and shoes before reuse.
Ingestion:
If person is conscious and can swallow, immediately give two glasses of water (16 oz.) but do not induce vomiting. This material is
corrosive. If vomiting occurs, give fluids again. Have a physician determine if condition of patient will permit induction of vomiting or
evacuation of stomach. Do not give anything by mouth to an unconscious or convulsing person.
Inhalation:
If inhaled, remove to fresh air. If not breathing or in respiratory distress, clear person's airway and start artificial respiration. With a
physician's advice, give supplemental oxygen using a bag-valve mask or manually triggered oxygen supply.
Other Instructions:
Swallowing of this corrosive material may result in severe ulceration, inflammation, and possible perforation of the upper
alimentary tract, with hemorrhage and fluid loss. Aspiration of this product during induced emesis can result in severe lung
injury. If evacuation of stomach is necessary, use method least likely to cause aspiration, such as gastric lavage after
endotracheal intubation. Contact a Poison Control Center for additional treatment information.
5. FIRE-FIGHTING MEASURES
Ignition Temperature - AIT (degrees C):
235 (455 F)
Flash Point (degrees C):
40.5 ( 105 F ) (PMCC)
Flammable Limits % (Lower-Upper):
Lower: Not Determined
Upper: Not Determined
Recommended Fire Extinguishing Agents And Special Procedures:
Use water spray, dry chemical, foam or carbon dioxide to extinguish flames. Use water spray to cool fire-exposed containers.
Unusual or Explosive Hazards:
None
Special Protective Equipment for Firefighters:
3
PRODUCT CODE AND NAME DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
:
ISSUE DATE : 04/14/1998
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
Wear special chemical protective clothing and positive pressure self-contained breathing apparatus. Approach fire from upwind to
avoid hazardous vapors and toxic decomposition products. Decontaminate or discard any clothing that may contain chemical residues.
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
Procedures in Case of Accidental Release, Breakage or Leakage:
Ventilate area. Avoid breathing vapor. Wear appropriate personal protective equipment, including appropriate respiratory protection.
Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Prevent entry into sewers and waterways. Avoid
contact with skin, eyes or clothing.
7. HANDLING AND STORAGE
Precautions to be Taken in
Handling:
Minimum feasible handling temperatures should be maintained. Eye wash and safety shower should be available nearby when this
product is handled or used.
Storage:
Store away from heat and open flame. Periods of exposure to high temperatures should be minimized. Water contamination should be
avoided.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective Equipment (Type)
Eye/Face Protection:
Avoid eye contact. Chemical type goggles with face shield must be worn. Do not wear contact lenses.
Skin Protection:
Protective clothing such as coveralls or lab coats must be worn. Launder or dry-clean when soiled. Gloves resistant to chemicals and
petroleum distillates required. When handling large quantities, impervious suits, gloves, and rubber boots must be worn.
Remove and dry-clean or launder clothing soaked or soiled with this material before reuse. Dry cleaning of contaminated clothing may
be more effective than normal laundering. Inform individuals responsible for cleaning of potential hazards associated with handling
contaminated clothing.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated and the occupational
exposure limit of the product, or any component of the product, is exceeded, use appropriate NIOSH or MSHA approved air
purifying or air supplied respirator after determining the airborne concentration of the contaminant. Air supplied respirators
should always be worn when airborne concentration of the contaminant or oxygen content is unknown.
Ventilation:
Local exhaust ventilation recommended if generating vapor, dust, or mist. If exhaust ventilation is not available or inadequate, use
MSHA or NIOSH approved respirator as appropriate.
Exposure Limit for the Total Product:
None established for product.
4
PRODUCT CODE AND NAME DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
:
ISSUE DATE : 04/14/1998
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Colorless liquid
Odor:
Ammonia-like odor
Boiling Point (degrees C):
134.4 ( 274 F )
Melting/Freezing Point (degrees C):
-58.7 ( -74 F )
Specific Gravity (water=1):
.888
pH:
12.1
Vapor Pressure:
3.8 mmHg at 17.8 C ( 64 F )
Viscosity:
2.7 cSt at 37.8 C ( 100 F )
VOC Content:
Not Determined
Vapor Density (Air=1):
3.2
Solubility in Water (%):
>10
Other:
None
10. STABILITY AND REACTIVITY
This Material Reacts Violently With:
Heat X Strong Oxidizers X Others X
Air Water None of these
Comments:
This material reacts violently with acids.
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of ammonia, combustion products of nitrogen, carbon monoxide, carbon dioxide, irritating aldehydes and ketones may be
formed on burning in a limited air supply.
Hazardous Polymerizations:
5
PRODUCT CODE AND NAME DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
:
ISSUE DATE : 04/14/1998
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION (ANIMAL TOXICITY DATA)
Oral:
LD50 1.18 g/kg (rat) moderately toxic
Inhalation:
4 hr. LC50 Believed to be > 1000.00 - 2500.00 ppm (gas, vapor) (rat) moderately toxic
Dermal:
LD50 > 2.00 g/kg (rabbit) practically non-toxic
IRRITATION INDEX, ESTIMATION OF IRRITATION (SPECIES)
Skin:
(Draize) 8.00 /8.0 (rabbit) corrosive
Eyes:
(Draize) Believed to be 80.00 - 110.00 /110 (rabbit) extremely irritating
Sensitization:
Not determined
Other:
None
12. DISPOSAL CONSIDERATIONS:
Waste Disposal Methods:
This product (as presently constituted) has the RCRA characteristics of ignitability, and, if discarded in its present form, would have
the hazardous waste number of D001. Under RCRA, it is the responsibility of the user of the product to determine, at the time of
disposal, whether the product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures,
processes, etc. may change the classification to non-hazardous, or hazardous for reasons other than, or in addition to ignitability.
Remarks:
None
13. TRANSPORT INFORMATION
Transportation
DOT:
Proper Shipping Name:
2-dimethylaminoethanol
Hazard Class:
8/3
Identification Number:
UN 2051
Packing Group:
II
Label Required:
Corrosive, Flammable liquid
IMDG
Proper Shipping Name:
Not evaluated
ICAO
Proper Shipping Name:
Not evaluated
6
PRODUCT CODE AND NAME DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
:
ISSUE DATE : 04/14/1998
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
TDG
Proper Shipping Name:
2-dimethylaminoethanol
Hazard Class:
3.3
Identification Number:
UN 2051
Label Required:
Flammable
14. REGULATORY INFORMATION
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
Chemical Name CAS Number Range in % TPQ RQ
None.
Section 311 Hazardous Categorization:
Acute X Chronic X Fire X Pressure Reactive N/A
Section 313 Toxic Chemical
Chemical Name CAS Number Concentration
None.
CERCLA 102(a)/DOT Hazardous Substances:
Chemical Name CAS Number Range in % RQ
None.
States Right-to-Know Regulations:
Chemical Name State Right-to-know
Ethanol, 2- (dimethylamino)- FL, MA, NJ, PA
State list: CT (Connecticut), FL (Florida), IL (Illinois), MI (Michigan), LA (Louisiana), MA
(Massachusetts), NJ (New Jersey), PA (Pennsylvania), RI (Rhode Island)
California Prop. 65:
The following detectable components of this product are substances, or belong to classes of substances, known to the State of
California to cause cancer and/or reproductive toxicity.
Chemical Name CAS Number
None.
INTERNATIONAL REGULATIONS:
TSCA Inventory Status:
This product, or its components, are listed on or are exempt from the the Toxic Substance Control Act (TSCA) Chemical
Substance Inventory.
WHMIS Classification:
Class D, Div 2, Subdiv A: Respiratory sensitizer Class E: Corrosive Class B, Div 3: Combustible liquid
Canadian Inventory Status:
This product, or its components, are listed on or are exempt from the Canadian Domestic Substance List (DSL).
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PRODUCT CODE AND NAME DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
:
ISSUE DATE : 04/14/1998
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
EINECS Inventory Status:
This product, or its components, are listed on or are exempt from the European Inventory of Existing Chemical Substances (EINECS) or
the European List of Notified Chemical Substances (ELINCS).
Australian Inventory Status:
This product, or its components, are listed on or are exempt from the Australian Inventory of Chemical Substances (AICS).
Japan Inventory Status:
This product, or its components, are listed on or are exempt from the Japan Ministry of International Trade and Industry (MITI)
inventory.
15. ENVIRONMENTAL INFORMATION
Aquatic Toxicity:
Mobility:
Not determined.
Persistence and Biodegradability:
Not determined.
Potential to Bioaccumulate:
Not determined.
Remarks:
None
16. OTHER INFORMATION 04/14/1998
Huntsman recommends that all exposures to this product be minimized by strictly adhering to recommended occupational controls
procedures to avoid any potential adverse health effects.
Supercedes: 5/1/96 The following sections have been revised: 4, 8
Print Date: 06/09/2000
THE INFORMATION IN THIS DATA SHEET IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT. IT IS PROVIDED
FOR THE PURPOSE OF HAZARD COMMUNICATION AS PART OF HUNTSMAN鈥橲 PRODUCT SAFETY PROGRAM. IT IS INTENDED
ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE PRODUCT BY A PROPERLY TRAINED PERSON.
YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE
INFORMATION CONTAINED HEREIN. THE DATA RELATES ONLY TO THE SPECIFIC PRODUCT DESIGNATED, AND DOES NOT
RELATE TO USE OF THE PRODUCT IN COMBINATION WITH ANY OTHER MATERIAL OR USE OF THE PRODUCT IN ANY
PROCESS. THE DATA IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO
EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY FOR FITNESS FOR A PARTICULAR PURPOSE IS MADE
WITH RESPECT TO THE PRODUCT, ITS COMPOSITION, ITS SAFETY OR THE INFORMATION CONTAINED IN THIS DATA SHEET.
TO DETERMINE THE APPLICABILITY OR THE EFFECTS OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT,
THE USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. HUNTSMAN DOES NOT
UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.
CURRENT DATA SHEETS ARE AVAILABLE FOR ALL HUNTSMAN PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR
ALL HUNTSMAN PRODUCTS YOU BUY, USE OR DISTRIBUTE BY CALLING (713) 235-6432 OR DIRECTING YOUR INQUIRIES TO:
HUNTSMAN
COORDINATOR, PRODUCT SAFETY
P.O. Box 27707
HOUSTON, TX 77227-7707
8
PRODUCT CODE AND NAME DMEA N,N-DIMETHYLETHANOLAMINE, DMEA
:
ISSUE DATE : 04/14/1998
MSDS CD DATE : 7/1/2000
COMPANY : HUNTSMAN
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR
MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY
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COPYRIGHT 漏 1999 BY HUNTSMAN CORPORATION. ALL RIGHTS RESERVED.
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