MSDS No.: 3383
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER EE
SECTION 1: IDENTIFICATION
Product Name: GLYCOL ETHER EE
Product Number: 000000000000005045
Chemical Family: Glycol Ethers
CAS Number: 110-80-5
Chemical Name: 2-ethoxyethanol
Synonyms: Ethylene Glycol Monoethyl Ether, Cellosolve, Ethylene glycol ethyl ether
Manufacturer Business Contact
Equistar Chemicals, LP Customer Service
One Houston Center, Suite 700 888 777-0232
1221 McKinney St. Product Safety
P.O. Box 2583 800 700-0946
Houston Texas 77252-2583
24 Hour Emergency Contact
CHEMTREC 800 424-9300
EQUISTAR 800-245-4532
SECTION 2 : COMPOSITION/INFORMATION ON INGREDIENTS
Component Name CAS # EU Inventory Concentration Wt.%* Risk Symbol
2-Ethoxyethanol 110-80-5 203-804-1 99.0 <= 99.9 R60, R61, T
Rep2, R10,
R20/21/22
1,2-Ethanediol 107-21-1 203-473-3 <= 0.5 R22 Xn
Diethylene Glycol Monoethyl 111-90-0 203-919-7 <= 0.5 None None
Ether
Water 7732-18-5 231-791-2 <= 0.2 None None
* Concentration of gaseous products or materials is given in Mole %
Compositions given are typical values not specifications.
SECTION 3: HAZARD IDENTIFICATION
Emergency Overview
This material is HAZARDOUS by OSHA Hazard Communication definition.
Signal Word
WARNING!
Hazards
Flammable liquid. Eye irritant. Mucous membrane irritant. Respiratory tract irritant. CNS depressant. May cause liver
and/or kidney damage.
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MSDS No.: 3383
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER EE
HMIS庐
NFPA庐
2
Health * 2
Flammability 2
2 0
Reactivity 0
Physical State
Liquid.
Color
Clear
Odor
Mild Sweetish Odor
Odor Threshold
2.7 ppm / (detectable) 6.5 ppm / (recognizable)
Potential Health Effects
Routes of Exposure
Inhalation Skin. Ingestion
Signs and Symptoms of Acute Exposure
See component summary.
鈥? 2-Ethoxyethanol 110-80-5
May be irritating to the eyes. Exposure to this material may cause respiratory irritation. This substance may cause effects
on the central nervous system, liver and kidneys. This material may be absorbed through the skin. Not a skin irritant. Not
expected to be a sensitizer.
鈥? 1,2-Ethanediol 107-21-1
Ingestion hazard. Ingestion may include inebriation, nausea and vomiting, metabolic acidosis, and CNS depression.
Cardiopulmonary effects including tachycardia, hypertension, severe metabolic acidosis with hyperventilation, hypoxia,
congestive heart failure and adult respiratory distress syndrome, as well as, renal failure are also possible. May also
produce a local irritation effect on the digestive system, and cause pain and bleeding. Irritation of the eyes and respiratory
system. Effects of eye irritation are reversible. High aerosol concentrations may cause respiratory irritation. Mildly irritating
to the skin but not a skin sensitizer. Not a skin absorption hazard.
鈥? Diethylene Glycol Monoethyl Ether 111-90-0
May be irritating to the eyes. Slight skin irritant.
Skin
May be absorbed in toxic amounts through the skin.
Inhalation
Vapor or mist is irritating to the respiratory tract.
Eye
May be irritating to the eyes.
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MSDS No.: 3383
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Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER EE
Ingestion
May cause headache, dizziness, nausea, vomiting, gastrointestinal distress, liver and kidney injury.
Chronic Health Effects
See component summary.
鈥? 2-Ethoxyethanol 110-80-5
Prolonged or repeated exposure may result in CNS and gastrointestinal system disturbance, and possible adverse
reproductive effects. Excessive oral exposure may result in changes to the liver and testes. Repeated, prolonged,
excessive exposure may result in kidney damage.
鈥? 1,2-Ethanediol 107-21-1
Repeated or prolonged exposure may result in kidney damage. May produce symptoms of central nervous system
depression including headache, dizziness, nausea, euphoria, loss of equilibrium, drowsiness, visual disturbances, fatigue,
unconsciousness and respiratory arrest.
鈥? Diethylene Glycol Monoethyl Ether 111-90-0
Repeated or prolonged skin contact may cause slight transient irritation. Skin absorption may add significantly to the overall
toxic effect.
Conditions Aggravated by Exposure
Any pre-existing conditions affecting target organs:
SECTION 4: FIRST AID MEASURES
General
Take proper precautions to ensure your own health and safety before attempting rescue and providing first aid. For specific
information refer to the Emergency Overview in Section 3 of this MSDS.
Skin
Immediately remove excess chemical and contaminated clothing; thoroughly wash contaminated skin with mild soap and
water. If irritation persists after washing, seek medical attention. Thoroughly clean contaminated clothing before reuse;
discard contaminated leather goods (gloves, shoes, belts, wallets, etc.).
Inhalation
Move the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. When breathing is
difficult, properly trained personnel may assist the affected person by administering oxygen. Keep the affected person
warm and at rest. Get medical attention immediately.
Eye
Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Ingestion
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Have patient drink several glasses of water then
induce vomiting by having patient tickle back of throat with finger.
SECTION 5: FIRE FIGHTING MEASURES
Flammable Properties
Classification
OSHA/NFPA Class II combustible liquid.
Flash Point:
43 掳C (109.4 掳F) closed cup
Auto-Ignition Temperature
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MSDS No.: 3383
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER EE
235 掳C (455 掳F)
Lower Flammable Limit
1.8 vol%
Upper Flammable Limit
14 vol%
Extinguishing Media
Suitable: SMALL FIRE: Use dry chemicals, CO2, water spray or alcohol-resistant foam. LARGE FIRE: Use water spray,
water fog or alcohol-resistant foam.
Unsuitable: Do not use solid water stream.
Protection of Firefighters
Protective Equipment/Clothing: Wear an approved positive pressure self-contained breathing apparatus and firefighter
turnout gear.
Fire Fighting Guidance: Avoid sparks, heat, and open flame. Fight fire from maximum distance or use unmanned hose
holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw
immediately in case of rising sound from venting safety devices or discoloration of tank. Always stay away from tanks
engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area
and let fire burn.
Hazardous Combustion Products: Carbon oxides (CO, CO2)
SECTION 6: ACCIDENTAL RELEASE MEASURES
Release Response
Contain spill with dike to prevent entry into sewers or waterways. For large spills, dike and pump into properly labeled
containers for reclamation or disposal. For small spills, soak up with absorbent material and place in properly labeled
containers for disposal. All recovered material should be packaged, labeled, transported and disposed of or reclaimed in
conformance with applicable laws and regulations and in conformance with good engineering practices. Reclaim where
possible.
SECTION 7: HANDLING AND STORAGE
Handling
Containers, even those that have been emptied, will retain product residue and vapor and should be handled as if they were
full. Do not eat, drink or smoke in areas where this material is used. After handling, always wash hands thoroughly with
soap and water. Do not handle near heat, sparks, or flame. Avoid contact with incompatible agents. Use only with
adequate ventilation/personal protection. Avoid contact with eyes, skin and clothing. Do not enter storage area unless
adequately ventilated. Metal containers involved in the transfer of this material should be grounded and bonded.
Storage
Store containers in a cool, dry, ventilated, fire resistant area away from sources of ignition and incompatible materials. Keep
container tightly closed and properly labeled.
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. Emergency shower and eyewash facility should be in close proximity (ANSI Z358.1)
Personal Protection
Inhalation A respiratory protection program that meets OSHA's 29 CFR 1910.134 or ANSI Z88.2 requirements must be
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MSDS No.: 3383
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER EE
followed whenever workplace conditions warrant respirator use.
Skin Wear chemical resistant gloves such as: Butyl rubber. When skin contact is possible, protective clothing including
gloves, apron, sleeves, boots, head and face protection should be worn. The equipment must be cleaned thoroughly after
each use.
Eye Wear chemical safety goggles plus full face shield to protect against splashing when appropriate (ANSI Z87.1).
Additional Remarks
Selection of appropriate personal protective equipment should be based on an evaluation of the performance
characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and
the hazards and/or potential hazards that may be encountered during use. Emergency eye wash fountains and safety
showers should be available in the immediate vicinity of any potential exposure. Use good personal hygiene practices.
Wash hands before eating, drinking, smoking, or using toilet facilities. Promptly remove soiled clothing/wash thoroughly
before reuse. Use care in walking on spilled material.
Occupational Exposure Limits
Component Name Source / Date Value Type Notation
2-Ethoxyethanol US (ACGIH) 18 mg/m3 8 HRS/TWA
US (OSHA) 740 mg/m3 8 HRS/TWA
1,2-Ethanediol US (ACGIH) 100 mg/m3 CEILING
Aerosol
US (OSHA) N/L
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Liquid. Clear
Odor: Mild Sweetish Odor
Odor Threshold: 2.7 ppm (detectable) 6.5 ppm (recognizable)
pH: Not applicable.
Boiling Point/Boiling Range: 135 掳C (275 掳F)
Freezing Point/Melting Point: -90 掳C (-130 掳F)
Flash Point: 43 掳C (109.4 掳F) closed cup
Auto-ignition: 235 掳C (455 掳F)
Flammability: OSHA/NFPA Class II combustible liquid.
Lower Flammable Limit: 1.8 vol%
Upper Flammable Limit: 14 vol%
Explosive Properties: No Data Available.
Oxidizing Properties: No Data Available.
Vapor Pressure: 3.7 mm Hg @ 20 掳C (68 掳F)
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MSDS No.: 3383
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER EE
Evaporation Rate: 0.41
Relative Density: 0.931 @ 20 掳C (68 掳F) (Water = 1)
Relative Vapor Density: 3.10 (Air = 1.0)
Viscosity: Not applicable.
Solubility (Water): @ 20 掳C (68 掳F) 100%
Partition Coefficient (Kow): Not applicable.
Additional Physical and Chemical Properties: No additional information available.
SECTION 10: STABILITY AND REACTIVITY
Chemical Stability
The product is stable.
Conditions to Avoid
All sources of ignition.
Substances to Avoid
Oxidizers, Alkalis, Other
Decomposition Products
Carbon oxides (CO, CO2)
Hazardous Polymerization
May form peroxides in the presence of air.
Reactions with Air and Water
Does not react with air or water.
SECTION 11: TOXICOLOGICAL INFORMATION
PRODUCT INFORMATION
Product Summary
Repeated, prolonged, excessive exposure may result in kidney damage.
COMPONENT INFORMATION
鈥? 2-Ethoxyethanol 110-80-5
Acute Toxicity - Lethal Doses
LC50 (Inhl) Guinea Pig 2000 PPM 7 HOURS
LD50 (Oral) Rat 2125 MG/KG
Rabbit 3300 MG/KG
LD50 (Skin) Rat 3.35 G/KG
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Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER EE
鈥? 1,2-Ethanediol 107-21-1
Acute Toxicity - Lethal Doses
LD50 (Oral) Rat 5890 - 13,400 MG/KG BWT
NOAEL Rabbit > 3549 MG/KG BWT (SKIN)
Irritation
Skin May be irritating to the skin. Not expected to be a sensitizer. No significant signs or symptoms indicative of any health
hazard are expected to occur as a result of skin absorption exposure.
Eye May cause minor eye irritation. Effects of eye irritation are reversible.
Sensitization
Not expected to be a sensitizer.
Target Organ Effects
Central nervous system effects. Blood (metabolic acidosis). Respiratory system. Cardiovascular system. Kidneys.
Repeated Dose Toxicity
If exposures are sufficiently high to cause accumulation of calcium oxalate crystals, kidney pathology may occur. In male
rats, crystal nephropathy has been seen after dietary administration of 500 mg/kg/day bwt for 16 weeks, whereas no effects
were seen in rats that ingested 200 mg/kg/day bwt for 2 years or in several animal species that inhaled 12 mg/m3 for 3
months . Human exposures at occupational relevant concentrations are unlikely to cause crystal nephropathy.
Reproductive Effects
No evidence of adverse effects on reproductive organs or fertility in rats and rabbits have occurred from ethylene glycol
exposure. Mice exposed to doses considerably higher than those associated with developmental effects or kidney effects in
rats exhibited reduced number of litters and smaller litters. No reproductive effects expected from human exposures.
Developmental Effects
Doses of ethylene glycol that result in high levels of the metabolite glycolic acid induce developmental/teratogenic effects in
rats and mice, although at doses greater than those associated with kidney effects in rats. Human exposure is not expected
to generate sufficient levels of glycolic acid; therefore, no developmental effects are expected in humans.
Genetic Toxicity
Negative for genotoxicity both in vitro and in vivo tests.
Carcinogenicity
Ethylene glycol was not carcinogenic in two year studies in rats and mice. This material is not classified as a carcinogen.
Not listed by IARC, NTP, or OSHA.
Other Information
Human acute toxicity has three recognized stages: Stage 1. (0.5 to 12 hours post ingestion) may include inebriation, nausea
and vomiting, metabolic acidosis, and CNS depression. Stage 2. (12-24 hours) cardiopulmonary effects include
tachycardia, hypertension, severe metabolic acidosis with hyperventilation, hypoxia, congestive heart failure and adult
respiratory distress syndrome. Stage 3. (24-72 hours) renal failure. Ethylene glycol may also produce a local irritation effect
on the digestive system, and cause pain and bleeding.
鈥? Diethylene Glycol Monoethyl Ether 111-90-0
Acute Toxicity - Lethal Doses
LD50 (Oral) Rat 5.5 G/KG
Mouse 6.6 G/KG
LD50 (Skin) Rabbit 9.0 G/KG
Acute Toxicity - Effects
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MSDS No.: 3383
Variant: U.S.A.-EN
Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER EE
Ingestion Rat toxicity data (5.0 g/kg/day) indicates oxalate crystals in urine, degeneration of the liver and renal tubules, and
transient dermititis.
Repeated Dose Toxicity
In a two year drinking water study with rats and mice, no adverse effects were observed at 1% and 5%, respectively.
Carcinogenicity
Not listed by IARC, NTP, or OSHA.
鈥? Water 7732-18-5
Repeated Dose Toxicity
No known chronic health effects.
SECTION 12: ECOLOGICAL INFORMATION
PRODUCT INFORMATION
Ecotoxicity
This material is highly soluble in water. Limited toxicity tests and models indicate this material should exhibit low toxicity to
aquatic organisms. The odor and flavor of this material may attract some wildlife and cause them to consume spilled
material.
Environmental Fate and Pathway
This material should biodegrade after an acclimation period, and it is is not expected to be environmentally persistant. Due
care should be taken to avoid accidental releases to aquatic or terrestrial systems.
Persistance and Degradability
Bioaccumulation: This material is highly soluble in water and should not bioaccumulate in aquatic or terrestrial organisms.
COMPONENT INFORMATION
鈥? 2-Ethoxyethanol 110-80-5
Ecotoxicity
This material is not classified as harmful or toxic to fish.
Acute toxicity to fish
LC50 / 24 HOUR goldfish > 5,000 mg/l
LC50 / 96 HOUR bluegill. > 10,000 mg/l
Environmental Fate and Pathway
Expected to have high mobility in soils. Volatilization from dry soil surfaces is expected. Not likely to adsorb to suspended
solids and sediment in water. This material is expected to exist solely as a vapor in the ambient atmosphere. Vapor-phase
is degraded in the atmosphere by reaction with photochemically produced hydroxyl radicals.
Persistance and Degradability
Biodegradation: This material is expected to be readily biodegradable.
Bioaccumulation: This material is not expected to bioaccumulate.
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GLYCOL ETHER EE
鈥? 1,2-Ethanediol 107-21-1
Ecotoxicity
Terrestrial plant and avian NOEC (No Observed Effect Concentration) data are available upon request.
Acute toxicity to fish
LC50 / 96 HOUR rainbow trout. 22,810 mg/l
LC50 / 96 HOUR fathead minnow 49,000 mg/l
Summary: This material is not classified as harmful or toxic to fish.
Acute toxicity to aquatic invertebrates
EC50 / 48 HOUR Daphnia magna. 41,000 mg/l
EC50 / 48 HOUR daphnia 10,000 mg/l
Summary: This material is not classified as harmful or toxic to invertebrates.
Toxicity to aquatic plants
Toxicity Threshold / 7 DAY blue green algae. 2,000 mg/l
Summary: This material is not classified as harmful or toxic to algae or higher aquatic plants.
Toxicity to microorganisms
Toxicity Threshold / 16 HOUR bacteria. > 10,000 mg/l
Chronic toxicity to fish
LC50 / 12 DAY rainbow trout. 20,403 mg/l
Chronic toxicity to aquatic invertebrates
LC50 / 7 DAY daphnia 30,461 mg/l
Environmental Fate and Pathway
Mobile in soil. Not expected to volatilize from surface waters or soils. Not likely to adsorb to suspended solids and sediment
in water. Environmental half-life of 0.35 to 24 days in soil, air, surface and ground water. Not expected to undergo
hydrolysis. Undergoes photooxidation with hydroxyl radicals in air with a half-life of 8.3 to 83 hours.
Persistance and Degradability
Biodegradation: Reported biodegradation studies show ethylene glycol with 97% biodegradation after 20 days, and 96%
biodegradation after 28 days. Biodegradable under aerobic conditions.
Bioaccumulation: BCF = 0.21 - 0.61 (crawfish) BCF = 10.0 (fish) This material is not expected to bioaccumulate.
鈥? Diethylene Glycol Monoethyl Ether 111-90-0
Ecotoxicity
This material is expected to have low toxicity to aquatic species. However, due caution should be exercised to prevent the
accidental release of this material to the environment.
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GLYCOL ETHER EE
Acute toxicity to fish
LC50 / 24 HOUR goldfish > 5,000 mg/l
LC50 / 96 HOUR fathead minnow 26,500 mg/l
Environmental Fate and Pathway
Expected to have high mobility in soils. Volatilization from dry soil surfaces is expected. While this material may evaporate
into the air from dry soil, it is unlikely to evaporate from moist soil or water. This material is expected to exist solely as a
vapor in the ambient atmosphere. The vapor-phase of this material is degraded in the atmosphere by reaction with
photochemically-produced hydroxyl radicals and ozone.
Persistance and Degradability
Biodegradation: Incubation of diethylene glycol monoethyl ether for 5, 10, and 20 days without an acclimation period
resulted in theorectical BOD values or 5, 31, and 48%, respecitively. This material is expected to be readily biodegradable.
Bioaccumulation: BCF = 0.2 This material is not expected to bioaccumulate.
鈥? Water 7732-18-5
Ecotoxicity
Not Applicable.
Environmental Fate and Pathway
Not Applicable.
SECTION 13: DISPOSAL CONSIDERATIONS
Recycle if possible. Use only licensed transporters and permitted facilities for waste disposal. Contaminated
product/soil/water may be U.S. Resource Conservation and Recovery Act (RCRA)/U.S. Occupational Safety and Health
Administration (OSHA) hazardous waste. Comply with federal, state, or local regulations for disposal.
SECTION 14: TRANSPORT INFORMATION
Special Requirements
If you reformulate or further process this material, you should consider re-evaluation of the regulatory status of the
components listed in the composition section of this sheet, based on final composition of your product.
Proper Shipping Name Ethylene glycol monoethyl ether
RQ ETHYLENE GLYCOL MONOETHYL ETHER
ID No. UN1171
Hazard Class 3
PG III
SECTION 15: REGULATORY INFORMATION
Regulatory Status
Country Inventory X = All components are included or are otherwise
exempt from inclusion on this inventory.
Australia AICS X
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Material Safety Data Sheet Version No: 1.1
Validation Date: 03/16/2005
GLYCOL ETHER EE
Canada DSL X
Canada NDSL
China IECS X
European Union EINECS X
European Union ELINCS
European Union NLP C = Contact Lyondell/Equistar by e-mail at
product.safety@lyondell.com or
Japan ENCS X
product.safety@equistarchem.com for additional
Korea ECL X
information.
Philippines PICCS X
United States TSCA X
If identified components of this product are listed under the TSCA 12(b) Export Notification rule, they will be listed below.
Export notification required.
Ethylene glycol ethyl ether - CASRN 110-80-5 TSCA section 5
SARA 302/304
This material contains a component(s) with known CAS numbers classified as hazardous substances subject to the
reporting of CERCLA (40 CFR 302) and/or to the release reporting requirements of SARA (Section 302) based on
reportable quantities (RQs).
Component RQ
Ethylene Glycol Monoethyl Ether / CAS# 110-80-5 1,000 lbs
Ethylene glycol / CAS# 107-21-1 5,000 lbs
SARA 311/312
Based upon available information, this material is classified as the following health and/or physical hazards according to
Section 311 & 312:
Immediate (Acute) Health Hazard.
Delayed (Chronic) Health Hazard.
Fire Hazard.
SARA 313
This material contains the following chemicals with known CAS numbers subject to the reporting requirements of SARA Title
III, Section 313 and 40 CFR 372:
Component Reporting Threshold
Ethylene Glycol Monoethyl Ether / CAS# 110-80-5 1.0%
State Reporting
This product contains the following ingredients for which the state of California has found to cause cancer, birth defects or
other reproductive harm, which would require a warning under the statute:
鈥? Ethylene glycol monoethyl ether, Reproductive and Developmental Toxin
SECTION 16: OTHER INFORMATION
Latest Revision(s)
Conversion to SAP template. Date of Revision: April 1 2004
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DISCLAIMER OF RESPONSIBILITY
The information on this MSDS was obtained from sources which we believe are reliable. However, the information is
provided without any warranty, expressed or implied, regarding its correctness. Some information presented and
conclusions drawn herein are from sources other than direct test data on the substance itself. The conditions or methods
of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this
and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense arising
out of or in any way connected with handling, storage, use, or disposal of this product. If the product is used as a
component in another product, this MSDS information may not be applicable.
Numerical Data Presentation
The presentation of numerical data, such as that used for physical and chemical properties and toxicological values, is
expressed using a comma (,) to separate digits into groups of three and a period (.) as the decimal marker. For example,
1,234.56 mg/kg = 1 234,56 mg/kg
Language Translations
The information presented in this document has been translated from English by a vendor Lyondell believes to be reliable.
Lyondell and its vendor have made a good-faith effort to verify the accuracy of the translation, but assume no responsibility
for any errors that may have occurred. Please refer to our web sites (www.lyondell.com and www.equistarchem.com) for
the original document written in English.
< end of document >
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