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MSDS Material Safety Data Sheet
CAS

8042-47-5

File Name: whitakeroil_com---Duoprime_200.asp
                                                      DUOprime庐 Oil 200
Material Safety Data Sheet
Lyondell Lubricants
669350003
MSDS No.
12000 Lawndale Avenue
Hazard Rankings
P.O. Box 2451
Revision Date 07/31/2000
Houston, TX 77252-2451
HMIS NFPA
IMPORTANT: Read this MSDS before handling or disposing of this product and pass this information on to 0 0
Health Hazard
employees, customers and users of this product.
1 1
Fire Hazard
Emergency Overview 0
Reactivity 0
Liquid.
Physical State
* = Chronic Health Hazard
Colorless. Odorless.
Color Odor
This product can cause mild eye and skin irritation. Protective Equipment
Protect eyes from misting or spraying material.
Minimum Requirements
Protect exposed skin from repeated or prolonged exposure.
See Section 8 for Details
This product can burn when preheated but will not ignite readily.
Do not store material in open or unmarked containers.
Spills can cause slipping hazard.




SECTION 1: IDENTIFICATION
DUOprime庐 Oil 200 (918) 495-5933
Trade Name Technical Contact

(918) 495-4700
Product Number 669350003 Medical Emergency

8042-47-5 (800) 424-9300
CAS Number CHEMTREC Emergency

White Mineral Oil
Product Family

White Mineral Oil;
Synonyms
ARCOprime庐 Oil (former name);
Lyondell Product Code: 16428;
SAP Product Code No.: 669350003


SECTION 2: COMPOSITION
Concentration (%)
Component Name(s) CAS Registry No.
1) White Mineral Oil 8042-47-5 100



SECTION 3: HAZARDS IDENTIFICATION
Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS.

Major Route(s) of Entry Skin contact.
Signs and Symptoms of Acute Exposure

No significant adverse health effects are expected to occur upon short-term exposure to this product.
Inhalation
Aspiration of liquid into the lungs can cause severe lung damage or death.
Minimal eye irritation may result from short-term contact with liquid, mist, and/or vapor.
Eye Contact

This product can cause mild, transient skin irritation with short-term exposure.
Skin Contact
If swallowed in quantities greater than one teaspoon, this material can cause a laxative effect.
Ingestion


MSDS No. Revision Date
669350003 Page Number: 1
07/31/2000 Continued on Next Page
DUOprime庐 Oil 200

Contains a petroleum-based mineral oil. Prolonged or repeated skin contact can cause mild irritation and
Chronic Health Effects
Summary inflammation characterized by drying, cracking, (dermatitis) or oil acne. Inhalation of petroleum-based
mineral oils can cause respiratory irritation or other pulmonary effects after repeated or prolonged
inhalation of oil mists at concentrations above applicable workplace exposure levels.
None known.
Conditions Aggravated
by Exposure

None
Target Organs

This product does not contain any components at concentrations above 0.1% which are considered
Carcinogenic Potential
carcinogenic by OSHA, IARC, or NTP.
OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present, the product does not exhibit the
hazard as defined in the OSHA Hazard Communication Standard (29 CFR 1910.1200).

OSHA Health Hazard Classification OSHA Physical Hazard Classification

Explosive Pyrophoric
Irritant Toxic Combustible

Oxidizer Water-reactive
Sensitizer Highly Toxic Flammable

Carcinogenic Organic Peroxide Unstable
Corrosive Compressed Gas




SECTION 4: FIRST AID MEASURES
Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific
information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS.
Vaporization is not expected at ambient temperatures. This material is not expected to cause
Inhalation
inhalation-related disorders under anticipated conditions of use. In case of overexposure, move the
person to fresh air.
Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water while
Eye Contact
occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing, redness, or pain
persists.
Remove contaminated shoes and clothing. Wipe off excess material. Wash exposed skin with soap
Skin Contact
and water. Seek medical attention if tissue appears damaged or if irritation persists. Thoroughly clean
contaminated clothing before reuse. Discard contaminated leather goods. If material is injected under
the skin, into muscle, or into the bloodstream, seek medical attention immediately.
Do not induce vomiting unless directed to by a physician. Do not give anything to drink unless directed
Ingestion
to by a physician. Never give anything by mouth to a person who is not fully conscious. If large
amounts are swallowed or irritation or discomfort occurs, seek medical attention immediately.
The viscosity range of the product(s) represented by this MSDS is 100 to 400 SUS at 100掳 F.
Notes to Physician
Accordingly, upon ingestion there is a low to moderate risk of aspiration. Careful gastric lavage may be
considered to evacuate large quantities of material. Subcutaneous or intramuscular injection requires
prompt surgical debridement.


SECTION 5: FIRE FIGHTING MEASURES
OSHA/NFPA Class-IIIB combustible liquid. Slightly combustible!
NFPA Flammability
Classification
OPEN CUP: >207掳C (405掳F) (Cleveland.).
Flash Point Method

No data. No data.
Lower Flammable Limit Upper Flammable Limit

Not available.
Autoignition Temperature

Carbon dioxide, carbon monoxide, smoke, fumes, and unburned hydrocarbons.
Hazardous
Combustion Products




MSDS No. Revision Date
669350003 Page Number: 2
07/31/2000 Continued on Next Page
DUOprime庐 Oil 200

This material can burn but will not readily ignite. This material will release vapors when heated above
Special Properties
the flash point temperature that can ignite when exposed to a source of ignition. In enclosed spaces,
heated vapor can ignite with explosive force. Mists or sprays may burn at temperatures below the flash
point.
Use dry chemical, foam, Carbon Dioxide or water fog.
Extinguishing Media

Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained
Fire Fighting Protective
Clothing breathing apparatus to protect against potential hazardous combustion or decomposition products and
oxygen deficiencies.


SECTION 6: ACCIDENTAL RELEASE MEASURES
Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific
information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection in Section 8 and Disposal
Considerations in Section 13 of this MSDS.
Do not touch damaged containers or spilled material unless wearing appropriate protective equipment.
Slipping hazard; do not walk through spilled material. Stop leak if you can do so without risk. For small
spills, absorb or cover with dry earth, sand, or other inert non-combustible absorbent material and place
into waste containers for later disposal. Contain large spills to maximize product recovery or disposal.
Prevent entry into waterways or sewers. In urban area, cleanup spill as soon as possible. In natural
environments, seek cleanup advice from specialists to minimize physical habitat damage. This material
will float on water. Absorbent pads and similar materials can be used. Comply with all laws and
regulations.


SECTION 7: HANDLING AND STORAGE
Avoid water contamination and extreme temperatures to minimize product degradation. Empty
Handling
containers may contain product residues that can ignite with explosive force. Do not pressurize, cut,
weld, braze solder, drill, grind or expose containers to flames, sparks, heat or other potential ignition
sources. Consult appropriate federal, state and local authorities before reusing, reconditioning,
reclaiming, recycling or disposing of empty containers and/or waste residues of this product.
Keep container closed. Do not store with strong oxidizing agents. Do not store at temperatures above
Storage
120掳 F or in direct sunlight for extended periods of time. Consult appropriate federal, state and local
authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers or waste
residues of this product.


SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists
and/or vapors below the recommended exposure limits (see below). An eye wash station and safety
shower should be located near the work-station.
Personal Protective Personal protective equipment should be selected based upon the conditions under which this material is
Equipment used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified
professional pursuant to OSHA regulations. The following pictograms represent the minimum
requirements for personal protective equipment. For certain operations, additional PPE may be required.




Safety glasses equipped with side shields should be adequate protection under most conditions of use.
Eye Protection
Wear goggles and/or face shield if splashing or spraying is anticipated. Wear goggles and face shield if
material is heated above 125掳F (51掳C). Have suitable eye wash water available.
Use gloves constructed of chemical resistant materials such as neoprene or heavy nitrile rubber if
Hand Protection
frequent or prolonged contact is expected. Use heat-protective gloves when handling product at
elevated temperatures.
Use clean and impervious protective clothing (e.g., neoprene or Tyvek庐) if splashing or spraying
Body Protection
conditions are present. Protective clothing may include long-sleeve outer garment, apron, or lab coat.
If significant contact occurs, remove oil-contaminated clothing as soon as possible and promptly
shower. Launder contaminated before reuse or discard. Wear heat protective boots and protective
clothing when handling material at elevated temperatures.

MSDS No. Revision Date
669350003 Page Number: 3
07/31/2000 Continued on Next Page
DUOprime庐 Oil 200

Vaporization or misting is not expected at ambient temperatures. Therefore, the need for respiratory
Respiratory Protection
protection is not anticipated under normal use conditions and with adequate ventilation. If elevated
airborne concentrations above applicable workplace exposure levels are anticipated, a
NIOSH-approved organic vapor respirator equipped with a dust/mist prefilter should be used.
Protection factors vary depending upon the type of respirator used. Respirators should be used in
accordance with OSHA requirements (29 CFR 1910.134).
Use good personal hygiene practices. Wash hands and other exposed skin areas with plenty of mild
General Comments
soap and water before eating, drinking, smoking, use of toilet facilities, or leaving work. DO NOT use
gasoline, kerosene, solvents or harsh abrasives as skin cleaners. Since specific exposure
standards/control limits have not been established for this product, the "Oil Mist, Mineral" exposure
limits shown below are suggested as minimum control guidelines.
Occupational Exposure Guidelines

Substance Applicable Workplace Exposure Levels

TWA: 5 STEL: 10 (mg/M3) from ACGIH (TLV)
1) White Mineral Oil
TWA: 5 (mg/M3) from OSHA (PEL)
TWA: 5 STEL: 10 (mg/M3) from NIOSH


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Colorless. Odorless.
Odor
Color
Liquid.
Physical State
GT 1 (Air = 1)
Vapor Density
Not Applicable.
Not available. pH
Specific Gravity
Not available. Not available.
Melting/Freezing Point
Boiling Point/Range
LT 0.1 mm of Hg (@ 20掳C) 41
Vapor Pressure Viscosity (cSt @ 40掳C)

Insoluble in cold water. Negligible volatility
Solubility in Water Volatile Characteristics
Additional Properties This oil meets FDA and U.S.P. standards for solid paraffins, sulfur compounds, taste, odor and neutrality.



SECTION 10: STABILITY AND REACTIVITY
Hazardous Polymerization Not expected to occur.
Stable.
Chemical Stability

Keep away from extreme heat, sparks, open flame, and strongly oxidizing conditions.
Conditions to Avoid

Strong oxidizers.
Materials Incompatibility

No additional hazardous decomposition products were identified other than the combustion products
Hazardous
Decomposition Products identified in Section 5 of this MSDS.


SECTION 11: TOXICOLOGICAL INFORMATION
For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification in Section 3 of this
MSDS.
Toxicity Data Low-viscosity and High-viscosity White Mineral Oils:
ORAL (LD50): Acute: >5000 mg/kg [Rat].
DERMAL (LD50): Acute: >2000 mg/kg [Rabbit].
DRAIZE EYE: Acute: Non-irritating [Rabbit].
DRAIZE DERMAL: Acute: Non-irritating [Rabbit].
BUEHLER: Acute: Non-sensitizing [Guinea Pig].
28-Day DERMAL: Sub-Chronic: Non-irritating [Rabbit].
104-Week DERMAL: Chronic: No skin tumors at site of application [Mouse].
MUTAGENICITY:
Modified Ames Assay: Negative [Salmonella typhimurium].
in-vitro Lymphoma Assay: Negative or no toxicity [Mouse].

Lifetime mouse skin painting studies indicated that this product is NOT mutagenic or carcinogenic.




MSDS No. Revision Date
669350003 Page Number: 4
07/31/2000 Continued on Next Page
DUOprime庐 Oil 200

White Mineral Oil:
Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities
in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil
mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid
granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to
lower concentrations of mineral oil mists at or near current work place exposure levels produced no
significant toxicological effects. In long term studies (up to two years) no carcinogenic effects have
been reported in any animal species tested.


SECTION 12: ECOLOGICAL INFORMATION
Analysis for ecological effects has not been conducted on this product. However, if spilled, this product
Ecotoxicity
and any contaminated soil or water may be harmful to human, animal, and aquatic life. Also, the
coating action associated with petroleum and petroleum products can be harmful or fatal to aquatic life
and waterfowl.
An environmental fate analysis has not been conducted on this specific product. However, plants and
Environmental Fate
animals may experience harmful or fatal effects when coated with petroleum-based products.
Petroleum-based (mineral) lube oils will normally float on water. In stagnant or slow-flowing waterways,
an oil layer can cover a large surface area. As a result, this oil layer might limit or eliminate natural
atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the
waterway might be enough to cause a fish kill or create an anaerobic environment.




SECTION 13: DISPOSAL CONSIDERATIONS
Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility
of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and
residues at the time of disposition.
Conditions of use may cause this material to become a hazardous waste, as defined by Federal or
State regulations. It is the responsibility of the user to determine if the material is a hazardous waste
at the time of disposal. Transportation, treatment, storage and disposal of waste material must be
conducted in accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State and/or
local regulations may be more restrictive. Contact the RCRA/Superfund Hotline at (800) 424-9346 or
your regional US EPA office for guidance concerning case specific disposal issues.


SECTION 14: TRANSPORT INFORMATION
Not a U.S. Department of Transportation regulated material.
DOT Status
Petroleum Oil, N.O.I.B.N.
Proper Shipping Name
Not a DOT controlled material (United States).
Hazard Class Not applicable.
Packing Group(s)
Not applicable.
UN/NA ID

Reportable Quantity A Reportable Quantity (RQ) has not been established for any components of this material.
Not applicable.
Emergency Response Guide
Placards No.
Not available.
HAZMAT STCC No.

Not a DOT "Marine Pollutant"
MARPOL III Status
per 49 CFR 171.8.




MSDS No. Revision Date
669350003 Page Number: 5
07/31/2000 Continued on Next Page
DUOprime庐 Oil 200



SECTION 15: REGULATORY INFORMATION
This product and/or its components are listed on the Toxic Substance Control Act (TSCA) inventory.
TSCA Inventory

The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject
SARA 302/304
to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold
Planning Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely Hazardous Substances"
listed in 40 CFR 302.4 and 40 CFR 355. No components were identified.
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject
SARA 311/312
to this subpart to submit aggregate information on chemicals by "Hazard Category" as defined in 40
CFR 370.2. This material would be classified under the following hazard categories:
No SARA 311/312 hazard categories identified.
This product contains the following components in concentrations above de minimis levels that are
SARA 313
listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA: No
components were identified.
The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
CERCLA
requires notification of the National Response Center concerning release of quantities of "hazardous
substances" equal to or greater than the reportable quantities (RQ's) listed in 40 CFR 302.4. As defined
by CERCLA, the term "hazardous substance" does not include petroleum, including crude oil or any
fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. This product or refinery
stream is not known to contain chemical substances subject to this statute. However, it is
recommended that you contact state and local authorities to determine if there are any other reporting
requirements in the event of a spill.
This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil
CWA
Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United
States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the
EPA's National Response Center at (800) 424-8802.
This product is not known to contain the any components for which the State of California has found to
California
Proposition 65 cause cancer, birth defects or other reproductive harm.
Petroleum Oil
New Jersey
Right-to-Know Label

No additional regulatory remarks.
Additional Regulatory
Remarks




SECTION 16: OTHER INFORMATION
Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product.
REVISION INFORMATION
1.1
Version Number
07/31/2000
Revision Date
Printed on 07/31/2000.
Print Date
ABBREVIATIONS

AP = Approximately EQ = Equal GT = Greater Than LT = Less Than NA = Not Applicable ND = No Data NE = Not
Established
ACGIH = American Conference of Governmental Industrial Hygienists AIHA = American Industrial Hygiene Association
IARC = International Agency for Research on Cancer NTP = National Toxicology Program
NIOSH = National Institute of Occupational Safety and Health OSHA = Occupational Safety and Health Administration
NPCA = National Paint and Coating Manufacturers Association HMIS = Hazardous Materials Information System
NFPA = National Fire Protection Association EPA = Environmental Protection Agency
DISCLAIMER OF LIABILITY




MSDS No. Revision Date
669350003 Page Number: 6
07/31/2000 Continued on Next Page
DUOprime庐 Oil 200

THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE
INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS. SOME
INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE
SUBSTANCE ITSELF. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS
A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR
OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR
PURPOSE.

THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL
AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND
EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH
HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.

***** END OF MSDS *****

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