The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification
Product ID: 069.000A902.076
Product Name: A902 GREEN AVIATION PRIMER 6U
Product Use: Paint or Coatings Related Product
Print date: 25/Jun/2007
Revision Date: 23/Jun/2007
Company Identification
The Valspar Corporation - Architectural Coatings Division
1000 Lake Road
Medina, OH 44256
Manufacturer's Phone: 1-330-725-4511
24-Hour Medical Emergency 1-888-345-5732
Phone:
2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name Approx. Chemical name
CAS-No. Weight %
DIMETHYL KETONE 30 - 35 ACETONE
67-64-1
XYLENE (W/ ANTI-STATIC) 15 - 20 Xylenes (o-, m-, p- isomers)
1330-20-7
PROPANE 15 - 20 Propane
74-98-6
MISCELLANEOUS PIGMENT 5 - 10 Ceramic materials and wares, chemicals
66402-68-4
BUTANE 5 - 10 Butane
106-97-8
ETHYLBENZENE 1-5 Ethyl benzene
100-41-4
PROPRIETARY INERT 1-5 PROPRIETARY INERT
If this section is blank there are no hazardous components per OSHA guidelines.
3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Product ID: 069.000A902.076
Page 1 / 7
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or
respiratory irritation. May result in burns of the mucous membranes, bronchospasm, coughing and delayed pulmonary
edema. Causes changes in nasal membranes and metallic taste in mouth. Irritates mucous membranes.
Eye Contact:
Causes eye irritation.
Skin Contact:
May cause moderate skin irritation.
Acute Ingestion:
None known
Other Effects:
May cause kidney damage. May cause liver damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful
or fatal. May cause skin drying with prolonged exposure. Prolonged and/or repeated contact can result in skin irritation.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.
4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention. If inhaled, remove to fresh
air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical
attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing. Flush with plenty of low pressure water for 15 minutes, occasionally lifting
eye lids.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
Rinse mouth with water many times. Get immediate medical attention. If swallowed, contact medical personnel
immediately to determine best course of action.
Medical conditions aggravated by exposure: Any respiratory or skin condition.
5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit): -31潞 F ( -35潞 C) TCC/PM
Lower explosive limit: 1%
Upper explosive limit: 13 %
Autoignition temperature: Not available. 潞 F ( 潞 C)
Sensitivity to impact: No.
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.
Hazardous combustion products: See Section 10.
Product ID: 069.000A902.076
Page 2 / 7
Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire. Firefighters should be equipped with self-
contained breathing apparatus and turn out gear.
6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual
Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with
inert absorbent and non sparking tools. Avoid contact with eyes.
7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F.
(49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA
regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including
flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed
until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint,
an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of
liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly
bonded and grounded at all times.
8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all
exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air
purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to
ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate
ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name Approx. TWA (final) Ceilings limits (final) Skin designations
CAS-No. Weight %
DIMETHYL KETONE 30 - 35 2400 mg/m鲁 1000 ppm
67-64-1
Product ID: 069.000A902.076
Page 3 / 7
Common Name Approx. TWA (final) Ceilings limits (final) Skin designations
CAS-No. Weight %
XYLENE (W/ ANTI-STATIC) 15 - 20 435 mg/m鲁 100 ppm
1330-20-7
PROPANE 15 - 20 1800 mg/m鲁 1000 ppm
74-98-6
ETHYLBENZENE 1-5 435 mg/m鲁 100 ppm
100-41-4
PROPRIETARY INERT 1-5 Respirable. Listed.
Total dust. Listed.
ACGIH Threshold Limit Value (TLV's)
Common Name Approx. TWA STEL Ceiling limits Skin designations
CAS-No. Weight %
DIMETHYL KETONE 30 - 35 500 ppm 750 ppm
67-64-1
XYLENE (W/ ANTI-STATIC) 15 - 20 100 ppm 150 ppm
1330-20-7
PROPANE 15 - 20 1000 ppm
74-98-6
BUTANE 5 - 10 1000 ppm
106-97-8
ETHYLBENZENE 1-5 100 ppm 125 ppm
100-41-4
PROPRIETARY INERT 1-5 2 mg/m鲁
Respirable fraction.
The value is for
particulate matter
containing no
asbestos and <1%
crystalline silica.
If this section is blank, no information is available.
9. PHYSICAL PROPERTIES
Odor: Normal for this product type.
Physical State: Liquid
pH: Not determined.
Vapor pressure: NOT DETERMINED mmHG @ 68潞 F ( 20潞 C)
Vapor density (air = 1.0): 2
Boiling point: -42潞 F ( -41潞 C)
Solubility in water: Not determined.
Coefficient of water/oil distribution: Not determined.
Density (lbs per US gallon): 6.74
Specific Gravity: .81
Evaporation rate (butyl acetate = 1.0): 5.6
10. STABILITY AND REACTIVITY
Stability: Stable
Conditions to Avoid: None known.
Incompatibility: Strong oxidizers.
Hazardous Polymerization: None anticipated.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. Phenolics.
Product ID: 069.000A902.076
Page 4 / 7
10. STABILITY AND REACTIVITY
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.
11. TOXICOLOGICAL INFORMATION
Mutagens:
Teratogens:
Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of
carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name Approx. IARC Group 1 - Human IARC Group 2A - Limited IARC Group 2B -
CAS-No. Weight % Evidence Human Data Sufficient Animal Data
ETHYLBENZENE 1-5 Monograph 77, 2000
100-41-4
Common Name Approx. NTP Known NTP Suspect NTP Evidence of
CAS-No. Weight % Carcinogens Carcinogens Carcinogenicity
ETHYLBENZENE 1-5 male rat-clear evidence;
100-41-4 female rat-some
evidence; male mice-
some evidence; female
mice-some evidence
PROPRIETARY INERT 1-5 YES
Common Name Approx. OSHA Select OSHA Possible Select ACGIH Carcinogens
CAS-No. Weight % Carcinogens Carcinogens
ETHYLBENZENE 1-5 Group A3 Confirmed
100-41-4 animal carcinogen with
unknown relevance to
humans.
If this section is blank, no information is available.
12. ECOLOGICAL DATA
Not available at this time.
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name: CONSUMER COMMODITY ORM-D
UN ID Number: CONCOM
Product ID: 069.000A902.076
Page 5 / 7
14. TRANSPORTATION INFORMATION
U.S. Highway & Rail Shipments
The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity,
Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult
49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions.
International Air Transport Association:
Proper Shipping Name: AEROSOLS, FLAMMABLE
Hazard Class: 2.1
UN ID Number: UN1950
International Maritime Organization:
Proper Shipping Name: AEROSOLS
Hazard Class: 2
Non-Bulk UN ID Number: UN1950
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
Common Name Approx. SARA 302 SARA 313 CERCLA RQ in lbs.
CAS-No. Weight %
DIMETHYL KETONE 30 - 35 5000
67-64-1
XYLENE (W/ ANTI-STATIC) 15 - 20 form R reporting required 100
1330-20-7 for 1.0% de minimis
concentration
MISCELLANEOUS PIGMENT 5 - 10 YES
66402-68-4
ETHYLBENZENE 1-5 form R reporting required 1000
100-41-4 for 1.0% de minimis
concentration
SARA 311/312 Hazard Class:
Acute: Yes
Chronic: Yes
Flammability: Yes
Reactivity: No
Sudden Pressure: Yes
U.S. STATE REGULATIONS:
Pennsylvania Right To Know:
PROPRIETARY INERT Trade Secret
XYLENE (W/ ANTI-STATIC) 1330-20-7
ETHYLBENZENE 100-41-4
BUTANE 106-97-8
MISCELLANEOUS PIGMENT 66402-68-4
DIMETHYL KETONE 67-64-1
PROPANE 74-98-6
Additional Non-Hazardous Materials
PROPRIETARY RESIN Trade Secret
California Proposition 65:
WARNING: This product contains a chemical known to the State of California to cause cancer.
Rule 66 status of product Photochemically reactive.
Product ID: 069.000A902.076
Page 6 / 7
INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory: This product does not comply with TSCA Inventory
Requirements.
Canada Domestic Substances List: Not all components in this product are listed on the Domestic
Substances List.
16. OTHER INFORMATION
HMIS Codes
Health: 2
Flammability: 4
Reactivity: 1
PPE: X - See Section 8 for Personal Protective Equipment (PPE).
Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH -
National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference
of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic
Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT -
Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ -
Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters,
MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed
cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term
exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance, this
information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information.
UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR
IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE
LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this
product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains
additional information required by the state of Pennsylvania.
Product ID: 069.000A902.076
Page 7 / 7
|