Specimen Label
PRO and MSDS
鈥? Algaecide also contact 1-800-858-7378 for emergency in a manner inconsistent with its labeling. For any
medical treatment information. requirements specific to your State or Tribe,
ACTIVE INGREDIENT: consult the agency responsible for pesticide
NOTE TO PHYSICIAN regulation. Do not apply this product in a way that
Sodium Carbonate Peroxyhydrate* . . . 85%
Probable mucosal damage may contraindicate the will contact workers or other persons, either
OTHER INGREDIENTS . . . . . . . . . . . . 15%
use of gastric lavage. directly or through drift. Only protected handlers
TOTAL . . . . . . . . . . . . . . . . . . . . . . . . . 100%
may be in the area during application.
* Contains 27.6% Hydrogen Dioxide by weight.
PRECAUTIONARY STATEMENTS:
Agricultural Use Requirements
HAZARDS TO HUMAN AND DOMESTIC
KEEP OUT OF REACH OF CHILDREN
Use this product only in accordance with its
ANIMALS 鈥? DANGER: Corrosive. Causes
DANGER 鈥? PELIGRO
labeling and with the Worker Protection
irreversible eye damage. Harmful if swallowed,
Si usted no entiende la etiqueta,
Standard, 40 CFR Part 170. This standard
inhaled or absorbed through skin. Do not get in
busque a alguien para que se la
contains requirements for the protection
eyes, on skin or on clothing. Wash thoroughly
explique a usted en detalle.
of agricultural workers on farms, forests,
with soap and water after handling.
(If you do not understand this label, nurseries and greenhouses, and handlers
find someone to explain it to you in detail.) of agricultural pesticides. It contains
PERSONAL PROTECTIVE EQUIPMENT (PPE):
requirements for training, decontamination,
When handling wear protective eyewear
notification, and emergency assistance.
(goggles or face shield) and chemical resistant
EPA Registration No.: 70299-6
It also contains specific instructions and
gloves. Applicators and handlers must wear
EPA Establishment No.: 68660-TX-001
exceptions pertaining to the statements
coveralls over longsleeved shirt, long pants, and
on this label about personal protective
chemical resistant footwear plus socks. Follow
FIRST AID
equipment (PPE), notification to workers,
manufacturer鈥檚 instructions for cleaning/main-
If in eyes
and restricted entry intervals (REI). The
taining PPE. If no such instructions exist for
鈥? Hold eye open and rinse slowly and gently
requirements in this box apply to uses of this
washables, use detergent and hot water. Keep
with water for 15 鈥? 20 minutes.
product that are covered by the Worker
and wash PPE separately from other laundry.
鈥? Remove contact lenses, if present, after the Protection Standard.
first 5 minutes, then continue rinsing eye. USER SAFETY RECOMMENDATIONS:
For enclosed environments:
Users should wash hands thoroughly with soap
鈥? Call a poison control center or doctor for There is a restricted entry of one (1) hour
and water before eating, drinking, chewing gum,
treatment advice. for this product when applied via spraying
using tobacco or using the toilet. Users should
or foaming on hard surfaces in enclosed
If on skin or clothing remove clothing immediately if pesticide gets
environments. PPE requirement for early entry
鈥? Take off contaminated clothing. inside. Then wash thoroughly and put on clean
to treated areas that is permitted under the
clothing. Remove PPE immediately after handling
鈥? Rinse skin immediately with plenty of water Worker Protection Standard and that involves
this product. Wash the outside of gloves before
for 15 鈥? 20 minutes. contact with anything that has been treated,
removing. As soon as possible, wash thoroughly
such as plants, soil or water, is coveralls,
鈥? Call a poison control center or doctor for
and change into clean clothing.
waterproof gloves and shoes plus socks.
treatment advice.
If swallowed ENVIRONMENTAL HAZARDS: There is a restricted entry of zero (0) hours
鈥? Call poison control center or doctor This pesticide is toxic to birds. Do not contam- for spreading, broadcasting, spot treatment,
immediately for treatment advice. inate water when cleaning equipment injection or other non-spraying or non-foaming
or disposing of equipment washwaters. Do not application methods when used in enclosed
鈥? Have person sip a glass of water if able
apply to treated, finished drinking water environments.
to swallow.
reservoirs or drinking water receptacles. This
鈥? Do not induce vomiting unless told to do For water treatment and applications in
product is highly toxic to bees and other
so by the poison control center or doctor. non-enclosed environments:
beneficial insects exposed to direct contact on
Keep unprotected persons out of treated areas
blooming crops or weeds. Do not apply this
鈥? Do not give anything by mouth to an
until sprays have dried or dusts have settled.
product or allow it to drift to blooming crops
unconscious person.
or weeds while bees are actively visiting the
If inhaled treatment area. Do not apply this product or Non-Agricultural Use Requirements
鈥? Move person to fresh air. allow it to drift to crops where beneficials are The requirements in this box apply to uses of
part of an integrated pest management strategy.
鈥? If person is not breathing, call 911 or an this product that are not within the scope of the
ambulance, then give artificial respiration, Worker Protection Standard for agricultural
PHYSICAL AND CHEMICAL HAZARDS:
preferably by mouth-to-mouth, if possible. pesticides (40 CFR Part 170). The WPS applies
Strong oxidizing agent. Corrosive. Do not bring when this product is used to produce agricul-
鈥? Call a poison control center or doctor in contact with other pesticides, cleaners or tural plants on farms, forests, nurseries or
for treatment advice. oxidative agents. greenhouses.
Have the product container or label with
Keep unprotected persons out of treated areas
you when calling a poison control center DIRECTIONS FOR USE:
until sprays have dried or dusts have settled.
or doctor, or going for treatment. You may It is a violation of Federal law to use this product
WATER APPLICATION RATES 1 lb = 2 Cups
Applications Rates Heavy Algae Growth Low Algae Growth/ Maintenance
Granular: 20-90 pounds of GreenClean Pro Granular 2-9 pounds of GreenClean Pro Granular
Large Volume Algaecide per acre-foot of water Algaecide per acre-foot of water
For example: Lakes, -or- -or-
Ponds, Lagoons. 50-250 pounds of GreenClean Pro Granular 5-25 pounds of GreenClean Pro Granular
Algaecide per million gallons of water. Algaecide per million gallons of water.
Granular: 2-10 Tablespoons of GreenClean Pro 1-3 teaspoons of GreenClean Pro Granular
Small Volume Granular Algaecide per 1000 gallons Algaecide per 1000 gallons of water.
For example: water of water.
gardens, fountains,
ornamental waterfalls.
Granular: 1-2 pounds of GreenClean Pro Granular 0.5-1 pounds of GreenClean Pro Granular
Ground/Surface: Algaecide per 1000 square feet of area. Algaecide per 1000 square feet of area.
For use on non-painted Make granular applications over a wet Make granular applications over a wet
surfaces to control algae, surface or activate with water immediately surface or activate with water immediately
moss, slime molds and following application. following application.
their spores.
Liquid Applications: Solution Preparation: Due to solubility limitations, use at least 1 gallon of water to fully
For Ground/Surface dissolve each 0.5 pounds of GreenClean Pro Granular Algaecide. Dissolution in cold
or Water applications. water takes approximately 5 minutes.
Treatment Rates: Use same rates at the granular application above.
Foam Applications: Solution Preparation: Follow the liquid solution preparation instructions above. Add 2.0 -
For Ground/Surface 5.0 fluid ounces of an alkaline-based foam, such as BioSafe Systems
applications. 鈥淏ioFoaming Agent庐鈥?, per gallon of finished solution.
Apply GreenClean Pro Granular Algaecide to any Standing Water, Bilge Water, Non-Potable Water (bubbling, bleaching/discoloration of algae).
listed non-food water or surface sites except Reservoirs, Waterways, Canals, Laterals, Waters treated with GreenClean Pro Granular
treated, finished drinking water reservoirs or Conveyance Ditches, Drainage Systems, Catch Algaecide are permissible to be used without
drinking water receptacles. Basins, Flooded Areas, Sewage Systems, Drain interruption.
Fields, Fire Ponds, Watering Tanks (Non-Potable
SURFACE TREATMENT
Application sites include: Water), Storage Tanks, Water Collectors and
Use GreenClean Pro Granular Algaecide on all
Sod Farms, Greenhouses, Nurseries, Golf Courses, Domestic/Commercial Non-Potable Waters.
listed non-painted surfaces, to prevent and control
Amusement Parks, Water Parks, Aquariums, Zoos,
algae, moss, slime molds and their spores, and the
Botanical Gardens, Parks, Recreational Areas, NON-PAINTED SURFACES
odors and conditions that these organisms cause
Non-Chlorinated Swimming Areas, Raceways, Floors, Walkways, Storage Areas, Patios, Decks,
(such as the breeding grounds for pests such as
Sports Facilities, Business Parks, Residential Railings, Roofs, Asphalt Shingles, Siding, Fiberglass,
shore flies and fungus gnats).
Developments, Indoor/Interiors, Malls, Hotels, Boats, Piers, Docks, Stairs, Ramps, Ground Cover
Kennels, Cemeteries, Carwashes, Marinas, Boats, Mats, Weed Control Mats, Concrete, Brick,
APPLICATION METHODS
Docks, Garden Centers, Power Washing, Water Tile, Slate, Granite, Outdoor Furniture,
鈥? SPREADING / BROADCASTING: Broadcast
Gardens, Landscapes, Municipalities, Waterways, Statues/Monuments, Tennis Courts (non-grass),
GreenClean Pro Granular Algaecide with a
Storm Waters, Drainage Systems, Impounded Nursery Yards, Shorelines, Gravel, Dirt Floors,
mechanical spreader or by hand, directly on
Waters, and Wastewater. Under Benches, and Other Non-Painted Surfaces.
the surface. A lawn spreader or any other
applicator that will ensure uniform coverage
Application surfaces include: WATER TREATMENT
is acceptable.
WATER SURFACES Use GreenClean Pro Granular Algaecide to treat,
Ponds, Lakes, Lagoons, Golf Course Ponds, control, and prevent a broad spectrum of algae. 鈥? SPOT TREATMENT: Apply GreenClean Pro
Impounded Waters, Industrial/Commercial Ponds, Effects of treatment are immediately apparent Granular Algaecide directly over the infested
area. Re-treatment is required when heavy to the water鈥檚 surface after treatment. Allowing area, away from direct sunlight. Do not allow
growth occurs. dead organics to sink and decay will provide product to become overheated in storage. This
a food source and additional nutrients that may cause increased degradation of the product,
鈥? LIQUID: Make a solution with GreenClean
stimulate algae re-growth and further blooms. which will decrease product effectiveness. In
Pro Granular Algaecide (refer to liquid
case of spill, flood area with large quantities of
application rates). Spray this solution on the 鈥? If using in conjunction with other water
water. Do not store in a manner where cross-con-
desired treatment surface. If using a slurry, additives (such as bacteria or enzymes), always
tamination with other pesticides or fertilizers
agitate constantly. apply GreenClean Granular first and wait
could occur.
several hours before adding other products.
鈥? FOAM: Make a solution with GreenClean Pro
PESTICIDE DISPOSAL:
Granular Algaecide (refer to foam applica- 鈥? Re-treat areas if re-growth begins to appear.
Wastes resulting from the use of this product
tion rates). Spray this solution on the desired Allow 48 hours between consecutive
may be disposed of on site or at an approved
treatment surface. Use a foamer, such as the treatments.
waste disposal facility. Open dumping is pro-
BioSafe BioFoamer庐, to apply.
鈥? Maintain with maintenance rates at a fre- hibited. If wastes cannot be disposed of
鈥? INJECTION: Make a solution with quency appropriate for your environmental according to label directions, contact your State
GreenClean Pro Granular Algaecide (refer to conditions. Pesticide or Environmental Control Agency, or
liquid application rates). Inject this solution the Hazardous Waste Representative at the
鈥? In regions where water freezes in the winter,
into the water via a piping system. nearest EPA Regional Office for guidance.
treatment with GreenClean Granular
鈥? SUBSURFACE: Place GreenClean Pro (including skimming) 6-8 weeks before
CONTAINER DISPOSAL: Triple rinse (or
Granular Algaecide in burlap bags and drag expected freeze will help prevent masses
equivalent). Then offer for recycling or dispose
through the water by means of a boat. Use of decaying algae under the ice cover.
of in a sanitary landfill, or incineration,
granular application rates. Begin treatment
鈥? After application, do not allow undiluted or if allowed by state and local authorities by
along the shoreline, and proceed outward. The
granules to remain in an area where humans burning. If burned, stay out of smoke.
path of the boat shall ensure an even distribu-
or animals are exposed.
tion. Continue dragging until all GreenClean
WARRANTY
Pro Granular Algaecide is dissolved. 鈥? Non-target plants will suffer contact burn if
This material conforms to the description on the
undiluted granules are accidentally spilled
label and is reasonably fit for the purposes
DETERMINING WATER VOLUME on them. Do not apply in such a way that the
referred to in the directions for use. Timing,
Measure length (L), width (W), and average depth concentrated product comes in contact with
unfavorable temperatures, water conditions,
(D) in feet (ft) or meters (m) and calculate volume grass, ornamentals and other foliage.
presence of other materials, method of
using one of the following formulas:
application, weather, watering practices, nature
鈥? Do not tank mix with aquatic herbicides or
1 acre-foot of water = of soil, disease problem, condition of crop,
algaecides containing copper or bromides.
208.7 ft long x 208.7 ft. wide x 1 ft. deep incompatibility with other chemicals,
43,560 ft.3 = 325,851 gal. = 2,780,000 lbs. pre-existing conditions and other conditions
EFFECTIVENESS FACTORS
influencing the use of this product are beyond
鈥? Effects of GreenClean Pro Granular Algaecide
Avg. L (ft) x Avg. W (ft) x Avg. D (ft) = acre-feet the control of the seller. Buyer assumes all risks
treatment are immediately apparent (bubbling,
of water
43,560 associated with the use, storage, or handling
bleaching/discoloration of algae).
of this material not in strict accordance with
鈥? GreenClean Pro Granular Algaecide directions given herewith. NO OTHER
treatments are successful when contact of
GENERAL TREATMENT NOTES EXPRESS OR IMPLIED WARRANTY OF
the pesticide is made with the algae.
鈥? Control is most easily achieved when algae are FITNESS OR MERCHANTIBILITY IS MADE.
not yet well established. Treat when growth 鈥? Liquid applications will not sink through
first begins to appear. the water column as readily as a granular
application.
鈥? GreenClean Granular is water activated.
鈥? When treating surface mats and blooms, it
鈥? When applying GreenClean Granular to soil,
is possible that GreenClean Pro Granular
gravel or other similar media, incorporate the
Algaecide will not penetrate the water col-
product into the first inch of substrate for
umn below the infested area, and a second
optimum effectiveness.
application is then required for treating any
鈥? Apply early in the day under calm, sunny bottom growing algae.
conditions, and when water temperatures are
鈥? Apply more frequently during the summer
warm. Sunlight and higher temperatures both
months when water consumption and
enhance GreenClean activity.
temperatures are high.
鈥? Apply in a manner that will ensure even
A Product of:
distribution of GreenClean Granular within the STORAGE AND DISPOSAL
treatment area. Do not contaminate water, food, or feed by L.L.C.
storage or disposal. Glastonbury, CT 06033
鈥? Break up any heavy algae before or during
888.273.3088
application. www.biosafesystems.com
PESTICIDE STORAGE:
鈥? Skim dead algae and organic matter that rises Store in original containers in a cool, well-vented
3000-7 6/2004
Material Safety
PRO Data Sheet
1. IDENTIFICATION: Specific Hazards: Reacts with strong 12. ECOLOGICAL INFORMATION:
reducing agents 鈥? decomposition may Toxic to simple cell organisms
Product Name: GreenCleanPRO
support combustion. Danger to the environment is limited - due
Granular Algaecide
to product properties.
Product Type: Algaecide
Manufacturer: BioSafe Systems L.L.C. 6. SPILL OR LEAK PROCEDURES: 鈥? No bioaccumulation
36 Commerce Street Cleanup: Collect the product with suitable 鈥? Soil degradation = 99% in 20 minutes
Glastonbury, CT 06033 means, shovel, and sweep, avoiding dust 鈥? Considerable abiotic and biotic degradability
US Patent Number: 5723406 formation. 鈥? Sediments = Non-significant adsorption
Office Telephone Number: (888) 273-3088 Waste Disposal: Do not return spilled or 鈥? Weak persistence of degradation products
Emergency: CHEMTREC: 800-424-9300 contaminated material to inventory. Clean the 鈥? Degradation products = sodium carbonate,
(24 HOURS EVERY DAY) area with large quantities of clean, cold water. carbon dioxide, bicarbonate carbonate,
Creation Date: 6/04 hydrogen dioxide.
NOTE: NOT VALID TWO YEARS AFTER 7. HANDLING AND STORAGE:
CREATION DATE. 鈥? Never return unused product to the 13. DISPOSAL CONSIDERATIONS:
original container Packing Treatment: Rinse empty containers
2. COMPONENTS: 鈥? Keep concentrate away from reactive with clean water. Clean and empty
Sodium Carbonate substances containers are to be recycled or disposed
Peroxhydrate: CAS 15630-89-4 鈥? Prevent contact with organic materials on accordance with local regulations.
鈥? Keep product in original container
3. HEALTH HAZARDS DATA: 鈥? Store in cool, dry area 14. TRANSPORT INFORMATION:
Inhalation: Slight nose and throat irritation 鈥? Keep out of direct sunlight and away D.O.T. Shipping Name: Oxidizing Solid
Eye contact: Severe eye irritation, risk from heat sources N.O.S.
of serious eye lesions UN Number: UN # 1479
Skin contact: Slight irritation 8. EXPOSURE CONTROLS / PERSONAL Hazard Class: 5.1
Ingestion: Severe irritation of the mouth, PROTECTION: Primary Hazard Label: Oxidizer
throat, esophagus and stomach Respiratory: For most conditions, no Subsidiary Risk Label: None
respiratory protection should be needed. Packing Group: III
4. FIRST AID: Eyes: Use dust proof chemical goggles WHMIS Classification: C 鈥? oxidizing
If inhaled: Immediately move a person to Hands: Protective gloves 鈥? chemical resistant material
fresh air. Consult with a physician in case of Skin: Body-covering clothing
respiratory symptoms. To the extent of our knowledge, the
Eyes: Immediately flush with plenty of cool 9. PHYSICAL AND CHEMICAL information herein is accurate as of the
running water. Remove contact lenses. PROPERTIES: date of this document. However, neither
Continue flushing for at least 15 minutes, Appearance: White, granular, solid BioSafe Systems nor any of its affiliates
holding eyelids apart to ensure rinsing of the Odor: None make any warranty, expressed or implied,
entire eye. Call a physician immediately. Bulk Density: 1.0 鈥? 1.2 g/cm3 or accept any liability in connection with
Skin: Remove contaminated shoes, socks, Solubility: 140 g/L @ 24潞 C (75潞 F) the information or its use. The information
and clothing. Wash the affected skin with pH: 1% solution: 10.4 鈥? 10.6 is for use by technically skilled persons at
running water. Wash clothing before reuse. their own discretion and risk. This is not
If swallowed: Consult a physician in all 10. STABILITY AND REACTIVITY: a license or a patent. The user alone
cases. If the subject is completely conscious, Stability: Stable under normal conditions must finally determine suitability of any
rinse mouth and administer fresh water. Do Avoid: Heat/Sources of Heat 鈥? information or material for any contem-
NOT induce vomiting. NEVER give anything Water/Moisture 鈥? Acids 鈥? Bases 鈥? plated use, the manner or use and whether
by mouth to an unconscious person. Reducing Agents 鈥? Organic Materials any patents are infringed.
5. FIRE AND EXPLOSION DATA: 11. TOXICOLOGICAL INFORMATION:
Special fire hazards: Oxidizing substance Acute Toxicity: A Product of:
that causes exothermic reactions with 鈥? Dermal = LD Lo rabbit > 2000 mg/kg
organic materials. L.L.C.
鈥? Inhalation = LC 0 1 hour, rat Glastonbury, CT 06033
Fire fighting methods: Product is not > 4580 mg /m 888.273.3088
flammable and can be quickly diluted with 鈥? Oral = LD 50 rat 1034 mg/kg www.biosafesystems.com
clean water.
3000-7 6/2004
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