Safety Data Sheet
Antique Finish & Enhancer Antik
Safety Data Sheet dated 22/12/2003, version 1
1. IDENTIFICATION OF THE PRODUCT AND OF THE PRODUCER
Trade name: Antique Finish & Enhancer Antik
Trade code: 065ANTIK-EN
Product type and use: Liquid antique finish & enhancer for marble and granite.
Seller:
Bellinzoni s.r.l. - Via Don Gnocchi, 4 20016 Pero (MI)
Tel. +390233912133 Fax +390233915224
Emergency telephone number of the company and/or of an authorised advisory centre:
E.U.: Centro Antiveleni - Ospedale di Niguarda - Milano - Tel. +39 0266101029
U.S.A.: Chemtech +1.800.424.9300
International: +1.703.527.3887
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components within the meaning of EEC directive 67/548 and corresponding
classification:
25% - 30% ethyl acetate
N.67/548/CEE: 607-022-00-5 CAS: 141-78-6 EINECS: 205-500-4
F Xi R11 R36 R66 R67
12.5% - 15% Alcani C9-12-ISO
CAS: 90622-57-4 EINECS: 292-459-0
Xn R53 R66 R55
1% - 3% toluene
N.67/548/CEE: 601-021-00-3 CAS: 108-88-3 EINECS: 203-625-9
F Xn R11 R20
0.1% - 0.25% methanol
N.67/548/CEE: 603-001-00-X CAS: 67-56-1 EINECS: 200-659-6
F T R11 R23/24/25 R39/23/24/25
3. HAZARDS IDENTIFICATION
The product easily catches fire if it is exposed to an ignition source.
If brought into contact with the eyes, the product causes considerable irritation which can last for
over 24 hours.
4. FIRST AID MEASURES
Contact with skin:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with
the product must be rinsed immediately with plenty of running water and possibly with soap.
Contact with eyes:
Do not use eyewash or ointment of any kind (before obtaining an examination or advice from
an eye specialist).
Wash immediately with water for at least 10 minutes.
Swallowing:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
IMMEDIATELY.
A suspension of activated charcoal in water, or liquid paraffin may be administered.
Inhalation:
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Ventilate the premises. The patient is to be removed immediately from the contaminated
premises and made to rest in a well ventilated area. Should the patient feel unwell, OBTAIN
MEDICAL ATTENTION.
5. FIRE-FIGHTING MEASURES
Recommended extinguishers:
CO2 or Dry chemical fire extinguishe.
Extinguishers not to be used:
None in particular.
Risks arising from combustion:
Avoid inhaling the fumes.
Protective equipment:
Use protection for the respiratory tract.
Cool the containers exposed to the fire with water.
6. ACCIDENTAL RELEASE MEASURES
Measures for personal safety:
Use a mask, gloves and protective clothing.
Environmental measures:
Limit leakages with earth or sand.
Eliminate all unguarded flames and possible sources of ignition. Do not smoke.
If the product has escaped into a water course, into the drainage system, or has
contaminated the ground or vegetation, notify the competent authorities.
Cleaning methods:
Rapidly recover the product. To do so, wear a mask and protective clothing.
If the product is in a liquid form, stop it from entering the drainage system.
Recover the product for re-use if possible, or for elimination. The product might, where
appropriate, be absorbed by inert material.
After the product has been recovered, rinse the area and materials involved with water.
7. HANDLING AND STORAGE
Handling precautions:
Avoid contact and inhalation of the vapours. See, too, paragraph 8 below.
Do not eat or drink while working.
Do not smoke while working.
Incompatible materials:
None in particular.
Storage conditions:
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to
sunlight.
Instructions as regards storage premises:
Cool and adequately ventilated.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Precautionary measures:
Give adequate ventilation to the premises where the product is stored and/or handled.
Respiratory protection:
Use adequate protective respiratory equipment, e.g. CEN/FFP-2(S) or CEN/FFP-3(S).
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or
rubber.
Eye protection:
Use close fitting safety goggles and/or visor conforming to BS 2092 GRADE 1).
Protection for skin:
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Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or
viton.
Exposure limit(s) (ACGIH):
ethyl acetate
TLV TWA: 400 ppm, A4 - 1440 mg/m3, A4
toluene
TLV TWA: 50 ppm, A4 - 188 mg/m3, A4 skin
methanol
TLV TWA: 200 ppm - 262 mg/m3 skin TLV STEL: 250 ppm - 328 skin mg/m3 skin
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and colour: Liquid transparent
Odour: Characteristic
pH: n.a.
Flash point: <21掳C
Relative density: 0,96
Solubility in water: Insoluble
10. STABILITY AND REACTIVITY
Conditions to avoid:
Stable under normal conditions.
Substances to avoid:
Avoid contact with combustible materials. The product could catch fire.
Hazardous decomposition products:
None.
11. TOXICOLOGICAL INFORMATION
The concentration of each substance should be borne in mind in assessing the toxicological effects
deriving from the preparation.
Set out below is the toxicological information relating to the main substances in the preparation.
ethyl acetate
LD50 (RABBIT) ORAL: 4935 MG/KG
toluene
LD50 (RABBIT) SKIN: 14 G/KG (14000 MG/KG)
LD50 (RAT) YOUNG ADULTS ORAL: 5542 MG/KG BW
methanol
LD50 (RAT) ORAL SINGLE DOSE: 5628 MG/KG
LD50 (RABBIT) SKIN SINGLE DOSE: 15800 MG/KG
12. ECOLOGICAL INFORMATION
Adopt good working practices, so that the product is not released into the environment.
List of substances dangerous for the environment and corresponding classification:
12.5% - 15% Alcani C9-12-ISO
CAS: 90622-57-4 EINECS: 292-459-0
R53 May cause long-term adverse effects in the aquatic environment.
R55 Toxic to fauna.
13. DISPOSAL CONSIDERATIONS
Recover, if possible. Send to authorised disposal plants or for incineration under controlled
conditions. In so doing, comply with the local and national regulations currently in force.
14. TRANSPORT INFORMATION
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UN number: 1263
Road (ADR): Class 3 II
Rail (RID): Class 3 II
Air (ICAO/IATA): Class 3
Sea (IMO): Class 3.2
15. REGULATORY INFORMATION
88/379/EEC, 1999/45/EEC (Classification and Labelling):
Symbols:
Xn Harmful
F Highly flammable
R Phrases:
R11 Highly flammable.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
R36 Irritating to eyes.
S Phrases:
S16 Keep away from sources of ignition - No smoking.
S2 Keep out of reach of children.
S23 Do not breathe vapour.
S29 Do not empty into drains.
S36/37 Wear suitable protective clothing and gloves.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this
container or label.
Where applicable, refer to the following regulatory provisions :
Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent
amendments.
16. OTHER INFORMATION
Text of R phrases referred to under heading 2:
R11 Highly flammable.
R36 Irritating to eyes.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
R53 May cause long-term adverse effects in the aquatic environment.
R55 Toxic to fauna.
R20 Harmful by inhalation.
R23/24/25 Toxic by inhalation,in contact with skin and if swallowed.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact
with skin and if swallowed.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
Nostrand Reinold
ACGIH - Treshold Limit Values - 1993/94 edition
The information contained herein is based on our state of knowledge at the above-specified date. It
refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to
the specific use intended.
This MSDS cancels and replaces any preceding release.
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