Safety Data Sheet
Self-Polishing Spray E3
Safety Data Sheet dated 10/6/2002, version 1
1. IDENTIFICATION OF THE PRODUCT AND OF THE PRODUCER
Trade name: Self-Polishing Spray E3
Trade code: 015E3SPRAY-EN
Product type and use: Spray polisher and plastifier for the protection and polishing of
marble and granite edges.
Seller:
Bellinzoni s.r.l. - Via Don Gnocchi, 4 20016 Pero (MI)
Tel. +390233912133 Fax +390233915224
Emergency telephone number of the company and/or of an authorised advisory centre:
E.U.: Centro Antiveleni - Ospedale di Niguarda - Milano - Tel. +39 0266101029
U.S.A.: Chemtech +1.800.424.9300
International: +1.703.527.3887
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components within the meaning of EEC directive 67/548 and corresponding
classification:
20% - 25% 2-Butanone
CAS: 201-159-0
Xi Irritant
R36 Irritating to eyes.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
12.5% - 15% toluene
N.67/548/CEE: 601-021-00-3 CAS: 108-88-3 EINECS: 203-625-9
Xn Harmful
R20 Harmful by inhalation.
3. HAZARDS IDENTIFICATION
The product catches fire with extreme ease, even at temperatures below 0 掳C.
The product is harmful following acute exposure to it and poses a serious health threat if
inhaled.
If brought into contact with the eyes, the product causes considerable irritation which can last for
over 24 hours.
4. FIRST AID MEASURES
Contact with skin:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact
with the product must be rinsed immediately with plenty of running water and possibly
with soap.
Contact with eyes:
Wash immediately with water for at least 10 minutes.
Swallowing:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
IMMEDIATELY.
Give liquid paraffin to drink; do not give milk or animal or vegetable fats of any kind.
Inhalation:
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Ventilate the premises. The patient is to be removed immediately from the contaminated
premises to rest in a well ventilated area. OBTAIN MEDICAL ATTENTION.
5. FIRE-FIGHTING MEASURES
Recommended extinguishers:
CO2 or Dry chemical fire extinguishe.
Extinguishers not to be used:
None in particular.
Risks arising from combustion:
Avoid inhaling the fumes.
Protective equipment:
Use protection for the respiratory tract.
Cool the containers exposed to the fire with water.
6. ACCIDENTAL RELEASE MEASURES
Measures for personal safety:
Use gloves and protective clothing.
Environmental measures:
Limit leakages with earth or sand.
Eliminate all unguarded flames and possible sources of ignition. Do not smoke.
If the product has escaped into a water course, into the drainage system, or has
contaminated the ground or vegetation, notify the competent authorities.
Cleaning methods:
If the product is in a liquid form, stop it from entering the drainage system.
Recover the product for re-use if possible, or for elimination. The product might, where
appropriate, be absorbed by inert material.
After the product has been recovered, rinse the area and materials involved with water.
7. HANDLING AND STORAGE
Handling precautions:
Avoid contact and inhalation of the vapours. See, too, paragraph 8 below.
Do not eat or drink while working.
Do not smoke while working.
Incompatible materials:
None in particular.
Storage conditions:
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to
sunlight.
Instructions as regards storage premises:
Cool and adequately ventilated.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Precautionary measures:
Give adequate ventilation to the premises where the product is stored and/or handled.
Respiratory protection:
Use adequate protective respiratory equipment, e.g. CEN/FFP-2(S) or CEN/FFP-3(S).
Protection for hands:
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or
rubber.
Eye protection:
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Use close fitting safety goggles and/or visor conforming to BS 2092 GRADE 1).
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC
or viton.
Exposure limit(s) (ACGIH):
toluene
TLV TWA: 50 ppm, A4 - 188 mg/m3, A4 skin
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and colour: Can under pressure with base and liquified gas
Odour: Characteristic of solvent
Solid/gas flammability: <21掳C
Relative density: About 0,72
Solubility in water: Insoluble
Lipid solubility: Soluble
10. STABILITY AND REACTIVITY
Conditions to avoid:
Stable under normal conditions.
Substances to avoid:
Avoid contact with combustible materials. The product could catch fire.
Hazardous decomposition products:
None.
11. TOXICOLOGICAL INFORMATION
The concentration of each substance should be borne in mind in assessing the toxicological
effects deriving from the preparation.
Set out below is the toxicological information relating to the main substances in the preparation.
toluene
LD50 (RABBIT) SKIN: 14 G/KG (14000 MG/KG)
LD50 (RAT) YOUNG ADULTS ORAL: 5542 MG/KG BW
12. ECOLOGICAL INFORMATION
Adopt good working practices, so that the product is not released into the environment.
13. DISPOSAL CONSIDERATIONS
Recover, if possible. Send to authorised disposal plants or for incineration under controlled
conditions. In so doing, comply with the local and national regulations currently in force.
14. TRANSPORT INFORMATION
Road (ADR): Class 2,10掳 b2) liqufied gas mix with a liquid.
Rail (RID): Class 2,10掳 b2) liqufied gas mix with a liquid.
Air (ICAO/IATA): UN N掳1950
Sea (IMO): UN N掳1950 Classe 9 AEROSOLS Cod IMDG p 9022
UN number: 1950
15. REGULATORY INFORMATION
88/379/EEC (Classification and Labelling):
Symbols:
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Xn Harmful
F+ Extremely flammable
R Phrases:
R12 Extremely flammable.
R66 Repeated exposure may cause skin dryness or cracking.
R20 Harmful by inhalation.
R36 Irritating to eyes.
Notes:
PACK2 The packing must have tactive indications of danger for blind people.
Special Provisions:
Pressurized container. Protect from sunlight and do not expose to temperatures
exceeding 50 掳C. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of
ignition - No smoking. Keep out of reach of children.
Contents:
toluene
Where applicable, refer to the following regulatory provisions :
Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent
amendments.
16. OTHER INFORMATION
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research
Centre, Commission of the European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
Nostrand Reinold
ACGIH - Treshold Limit Values - 1993/94 edition
The information contained herein is based on our state of knowledge at the above-specified
date. It refers solely to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect
to the specific use intended.
This MSDS cancels and replaces any preceding release.
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