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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/12/2004 Reviewed on 05/12/2004
1 Identification of substance
路 Product details
路 Trade name: Darkener Super
路 Article number: 10940, 10941
路 Application of the substance / the
preparation Protective impregnation
路 Manufacturer/Supplier: AKEMI chemisch technische Spezialfabrik GmbH Tel. +49(0)911-642960
Lechstrasse 28 Fax. +49(0)911-644456
D 90451 N眉rnberg e-mail info@akemi.de
路 Information department: Laboratory
2 Composition/Data on components
路 Chemical characterization
路 Description: Mixture of the substances listed below with nonhazardous additions.
路 Dangerous components:
CAS: 64742-48-9 Naphtha (petroleum), hydrotreated heavy 50-100%
EINECS: 265-150-3
EU Number: 649-327-00-6
CAS: 67-56-1 methanol < 1%
EINECS: 200-659-6
EU Number: 603-001-00-X
CAS: 77-58-7 dibutyltin dilaurate < 1%
EINECS: 201-039-8
路 Additional information: For the wording of the listed risk phrases refer to section 16.
3 Hazards identification
路 Hazard description: Harmful
路 Information pertaining to particular
dangers for man and environment: The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid version.
Flammable.
Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking
路 Classification system: The classification was made according to the latest editions of international
substances lists, and expanded upon from company and literature data.
路 NFPA ratings (scale 0 - 4) Health = 2
Fire = 2
Reactivity = 0
路 HMIS-ratings (scale 0 - 4) Health = 2
Fire =2
Reactivity = 0
4 First aid measures
路 General information: Immediately remove any clothing soiled by the product.
路 After inhalation: Supply fresh air; consult doctor in case of complaints.
路 After skin contact: Immediately wash with water and soap and rinse thoroughly.
路 After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist,
consult a doctor.
路 After swallowing: Do not induce vomiting; immediately call for medical help.
(Contd. on page 2)
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Page 2/6
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/12/2004 Reviewed on 05/12/2004
Trade name: Darkener Super
(Contd. of page 1)
5 Fire fighting measures
路 Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or
alcohol resistant foam.
路 For safety reasons unsuitable
extinguishing agents: Water with full jet
路 Special hazards caused by the
material, its products of
combustion or resulting gases: Formation of toxic gases is possible during heating or in case of fire.
路 Protective equipment: Wear self-contained respiatory protective device.
6 Accidental release measures
路 Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
路 Measures for environmental
protection: Inform respective authorities in case of seepage into water course or sewage
system.
Do not allow to enter sewers/ surface or ground water.
路 Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal
binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
路 Handling:
路 Information for safe handling: Keep receptacles tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
路 Information about protection
against explosions and fires: Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
路 Storage:
路 Requirements to be met by
storerooms and receptacles: Store in a cool location.
路 Information about storage in one
common storage facility: Not required.
路 Further information about storage
conditions: Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls and personal protection
路 Additional information about
design of technical systems: No further data; see item 7.
路 Components with limit values that require monitoring at the workplace:
67-56-1 methanol
PEL 260 mg/m鲁, 200 ppm
REL Short-term value: 325 mg/m鲁, 250 ppm
Long-term value: 260 mg/m鲁, 200 ppm
Skin
TLV Short-term value: 328 mg/m鲁, 250 ppm
Long-term value: 262 mg/m鲁, 200 ppm
Skin; BEI
(Contd. on page 3)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/12/2004 Reviewed on 05/12/2004
Trade name: Darkener Super
(Contd. of page 2)
77-58-7 dibutyltin dilaurate
PEL 0.1 mg/m鲁
as Sn
REL 0.1 mg/m鲁
as Sn, Skin
TLV Short-term value: 0.2; A4 mg/m鲁
Long-term value: 0.1 mg/m鲁
as Sn; Skin
路 Additional information: The lists that were valid during the creation were used as basis.
路 Personal protective equipment:
路 General protective and hygienic
measures: Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Immediately remove all soiled and contaminated clothing.
Avoid contact with the eyes and skin.
路 Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation.
Filter AX
路 Protection of hands: Protective gloves
路 Material of gloves Fluorocarbon rubber (Viton)
The selection of the suitable gloves does not only depend on the material, but
also on further marks of quality and varies from manufacturer to manufacturer.
路 Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the
protective gloves and has to be observed.
路 Eye protection: Tightly sealed goggles
路 Body protection: Protective work clothing
9 Physical and chemical properties
路 General Information
Form: Fluid
Color: Colorless
Odor: Characteristic
路 Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 180掳C (356掳F)
路 Flash point: > 40掳C (> 104掳F)
路 Ignition temperature: 240掳C (464掳F)
路 Auto igniting: Product is not selfigniting.
路 Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are
possible.
路 Explosion limits:
Lower: 0.6 Vol %
Upper: 7.0 Vol %
路 Vapor pressure at 20掳C (68掳F): 1 hPa (1 mm Hg)
路 Density at 20掳C (68掳F): ~ 0.79 g/cm鲁
路 Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
10 Stability and reactivity
路 Thermal decomposition /
conditions to be avoided: No decomposition if used according to specifications.
路 Dangerous reactions Reacts with strong oxidizing agents.
Forms flammable gases / fumes.
(Contd. on page 4)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/12/2004 Reviewed on 05/12/2004
Trade name: Darkener Super
(Contd. of page 3)
路 Dangerous products of
decomposition: Carbon monoxide and carbon dioxide
11 Toxicological information
路 Acute toxicity:
路 LD/LC50 values that are relevant for classification:
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Oral LD50 >5000 mg/kg (rat)
Dermal LD50 >3000 mg/kg (rab)
路 Primary irritant effect:
路 on the skin: No irritant effect.
路 on the eye: No irritating effect.
路 Sensitization: No sensitizing effects known.
路 Additional toxicological
information: The product shows the following dangers according to internally approved
calculation methods for preparations:
12 Ecological information
路 Ecotoxical effects:
路 Remark: Harmful to fish
路 General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water,
water course or sewage system.
Harmful to aquatic organisms
13 Disposal considerations
路 Product:
路 Recommendation: Must not be disposed of together with household garbage. Do not allow product
to reach sewage system.
路 Uncleaned packagings:
路 Recommendation: Empty contaminated packagings thoroughly. They can be recycled after
thorough and proper cleaning.
14 Transport information
路 DOT regulations:
路 Hazard class: 3
路 Identification number: UN3295
路 Packing group: III
路 Proper shipping name (technical name): HYDROCARBONS, LIQUID, N.O.S.
路 Label 3
路 Land transport ADR/RID (cross-border):
路 ADR/RID class: 3 (F1) Flammable liquids
路 Danger code (Kemler): 30
路 UN-Number: 3295
路 Packaging group: III
路 Description of goods: 3295 HYDROCARBONS, LIQUID, N.O.S. (Naphtha (petroleum),
hydrotreated heavy)
路 Maritime transport IMDG:
路 IMDG Class: 3
路 UN Number: 3295
路 Label 3
路 Packaging group: III
路 EMS Number: F-E,S-D
路 Marine pollutant: No
(Contd. on page 5)
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Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/12/2004 Reviewed on 05/12/2004
Trade name: Darkener Super
(Contd. of page 4)
路 Propper shipping name: HYDROCARBONS, LIQUID, N.O.S.
路 Air transport ICAO-TI and IATA-DGR:
路 ICAO/IATA Class: 3
路 UN/ID Number: 3295
路 Label 3
路 Packaging group: III
路 Propper shipping name: HYDROCARBONS, LIQUID, N.O.S.
15 Regulations
路 Sara
路 Section 355 (extremely hazardous substances):
None of the ingredient is listed.
路 Section 313 (Specific toxic chemical listings):
67-56-1 methanol
路 TSCA (Toxic Substances Control Act):
All ingredients are listed.
路 Proposition 65
路 Chemicals known to cause cancer:
None of the ingredients is listed.
路 Chemicals known to cause reproductive toxicity:
None of the ingredients is listed.
路 Cancerogenity categories
路 EPA (Environmental Protection Agency)
None of the ingredients is listed.
路 IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
路 NTP (National Toxicology Program)
None of the ingredients is listed.
路 TLV (Threshold Limit Value established by ACGIH)
77-58-7 dibutyltin dilaurate A4
路 MAK (German Maximum Workplace Concentration)
None of the ingredients is listed.
路 NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
路 OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
路 Product related hazard
informations: The product has been classified and marked in accordance with directives on
hazardous materials.
路 Hazard symbols: Harmful
路 Hazard-determining components
of labelling: Naphtha (petroleum), hydrotreated heavy
路 Risk phrases: Flammable.
Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking
路 Safety phrases: Keep out of the reach of children.
Do not breathe fumes
Avoid contact with skin.
Do not empty into drains, dispose of this material and its container at hazardous
or special waste collection point
If swallowed, seek medical advice immediately and show this container or label.
Use only in well-ventilated areas.
(Contd. on page 6)
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Page 6/6
Material Safety Data Sheet
acc. to ISO/DIS 11014
Printing date 05/12/2004 Reviewed on 05/12/2004
Trade name: Darkener Super
(Contd. of page 5)
路 National regulations:
路 Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
路 Contact: Dieter Zimmermann USA
DR
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