MATERIAL SAFETY DATA SHEET
Date: June 18, 2005
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
COMPANY: Star brite EMERGENCY TELEPHONE NUMBER:
4041 N. W. 47th Avenue CHEMTREC: 1-800-424-9300 or 703-527-3887
Ft. Lauderdale, FL 33314 PRODUCT INFORMATION: 1-800-327-8583
PRODUCT NAME: Product Number: 19216, 19225, 19232, 19200
Star brite Super Premium 2-Cycle Engine Oil TC-W3
PRODUCT CATEGORY:
Petroleum Lubricating Oil
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
CAS NO. OF APPROXIMATE
COMPONENTS COMPONENTS CONCENTRATION
Distillates (petroleum), solvent- 64742-65-0 Approximately 46%
dewaxed heavy paraffinic
or or
Distillates (petroleum), hydrotreated 64742-54-7
heavy paraffinic
Proprietary additives Mixture Approximately 54%
SEE SECTION 8 FOR EXPOSURE LIMITS
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
OSHA REQUIRED LABEL INFORMATION
In compliance with hazard and right-to-know requirements, where applicable OSHA Hazard Warnings may be found
on the label, bill of lading or invoice accompanying this shipment.
Note: Product label may contain non-OSHA related information also.
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS)
Health Flammability Reactivity BASIS
1 1 0 Recommended by Star brite
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD IDENTIFICATION
Health Flammability Reactivity BASIS
1 1 0 Recommended by Star brite
VARIABILITY AMONG INDIVIDUALS
Health studies have shown that many petroleum hydrocarbons and synthetic lubricants pose potential human health
risks which may vary from person to person. As a precaution, exposure to liquids, vapors, mists or fumes should be
minimized.
EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure)
Inhalation of high vapor concentrations may have results ranging from dizziness, headache, and respiratory irritation
to unconsciousness and possibly death. Prolonged or repeated liquid contact with the skin will dry and defat the skin,
leading to possible irritation and dermatitis.
PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE
Petroleum Solvents/Petroleum Hydrocarbons - Skin contact may aggravate an existing dermatitis.
PRODUCT: Star brite Super Premium 2-Cycle Engine Oil TC-W3 Product Number: 19216, 19225, 19232, 19200
SECTION 4: FIRST AID MEASURES
EYE CONTACT
If splashed into the eyes, flush with clear water for 15 minutes or until irritation subsides. If irritation persists, call a
physician.
SKIN
In case of skin contact, remove any contaminated clothing and wash skin with soap and water. Launder or dry-clean
clothing before reuse. If product is injected into or under the skin, or into any part of the body, regardless of the
appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical
emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical
treatment within the first few hours may significantly reduce the ultimate extent of injury.
INHALATION
Vapor pressure is very low. Vapor inhalation under ambient conditions is normally not a problem. If overcome by
vapor from hot product, immediately remove from exposure and call a physician. If breathing is irregular or has
stopped, start resuscitation; administer oxygen, if available. If overexposed to oil mist, remove from further exposure
until excessive oil mist condition subsides.
INGESTION
If ingested, DO NOT induce vomiting; call a physician immediately.
SECTION 5: FIRE-FIGHTING MEASURES
FLASH POINT (MINIMUM) AUTOIGNITION TEMPERATURE
94.44掳C (202掳 F) Greater than 260掳C (500掳F)
ASTM D 93, Pensky Martens Closed Cup
FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR)
Estimated values: Lower Flammable Limit 0.9% Upper Flammable Limit 7 %
EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES
Foam, water spray (fog), dry chemical, carbon dioxide and vaporizing liquid type extinguishing agents may all be
suitable for extinguishing fires involving this type of product, depending on size or potential size of fire and
circumstances related to the situation. Plan fire protection and response strategy through consultation with local fire
protection authorities or appropriate specialists.
The following procedures for this type of product are based on the recommendations in the National Fire Protection
Association鈥檚 Fire Protection Guide on Hazardous Materials@, Tenth Edition (1991):
Use water spray, dry chemical, foam or carbon dioxide to extinguish the fire. Use water to keep fire-exposed
containers cool. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for
persons attempting to stop a leak. Water spray may be used to flush spills away from exposures. Minimize
breathing of gases, vapor, fumes or decomposition products. Use supplied-air breathing equipment for enclosed or
confined spaces or as otherwise needed.
DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS
Fumes, smoke, carbon monoxide, sulfur oxides, nitrogen oxides, aldehydes and other decomposition products, in the
case of incomplete combustion.
SECTION 6: ACCIDENTAL RELEASE MEASURES
CLEAN WATER ACT / OIL POLLUTION ACT
This product may be classified as an oil under Section 311 of the Clean Water Act, and under the Oil Pollution Act.
Discharges or spills into or leading to surface waters that cause a sheen must be reported to the National Response
Center (1-800-424-8802).
PRODUCT: Star brite Super Premium 2-Cycle Engine Oil TC-W3 Product Number: 19216, 19225, 19232, 19200
SECTION 6: ACCIDENTAL RELEASE MEASURES (cont鈥檇)
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Recover free product. Add sand, earth, or other suitable absorbent to spill area. Minimize skin contact. Keep product
out of sewers and watercourses by diking or impounding. Advise authorities if product has entered or may enter
sewers, watercourses, or extensive land areas.
Assure conformity with applicable governmental regulations.
SECTION 7: STORAGE AND HANDLING
HANDLING PRECAUTIONS
Use product with caution around heat, sparks, pilot lights, static electricity, and open flame.
鈥淓MPTY鈥? CONTAINER WARNING
鈥淓mpty鈥? containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT,
WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS,
STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY
OR DEATH.
Do not attempt to refill or clean containers since residue is difficult to remove. 鈥淓mpty鈥漝rums should be completely
drained, properly bunged and promptly returned to a drum reconditioner. All other containers should be disposed of
in an environmentally safe manner and in accordance with governmental regulations.
For work on tanks refer to Occupational Safety and Health Administration regulations, ANSI Z49.1, and other
governmental and industrial references pertaining to cleaning, repairing, welding, or other contemplated operations.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE LIMIT FOR TOTAL PRODUCT BASIS
5 mg/m3 for oil mist (aerosol) for OSHA Regulation 29 CFR 1910.1000 and recommended by the
an 8-hour workday American Conference of Governmental Industrial Hygienists
(ACGIH). ACGIH states that the air is to be sampled by a
method that does not collect vapor; in addition, it lists a
10 mg/m3 STEL.
VENTILATION
Use local exhaust to capture vapor, mists or fumes, if necessary. Provide ventilation sufficient to prevent exceeding
recommended exposure limit or buildup of explosive concentrations of vapor in air. No smoking, or use of flame or
other ignition sources.
RESPIRATORY PROTECTION
Use supplied-air respiratory protection in confined or enclosed spaces, if needed.
PROTECTIVE GLOVES
Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact.
EYE PROTECTION
Use splash goggles or face shield when eye contact may occur.
OTHER PROTECTIVE EQUIPMENT
Use chemical-resistant apron or other impervious clothing, if needed, to avoid contaminating regular clothing, which
could result in prolonged or repeated skin contact.
PRODUCT: Star brite Super Premium 2-Cycle Engine Oil TC-W3 Product Number: 19216, 19225, 19232, 19200
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (cont鈥檇)
WORK PRACTICES / ENGINEERING CONTROLS
To prevent Fire or explosion risk from static accumulation and discharge, effectively bond and/or ground product
transfer system in accordance with (THE) National Fire Protection Association PUBLICATIONS.
Keep containers closed when not in use. Do not store near heat, sparks, flame or strong oxidants.
In order to prevent fire or explosion hazards, use appropriate equipment.
Information on electrical equipment appropriate for use with this product may be found in the latest edition of the
National Electrical Code (NFPA-70). This document is available from the National Fire Protection Association,
Batterymarch Park, Quincy, Massachusetts 02269.
PERSONAL HYGIENE
Minimize breathing vapor, mist or fumes. Avoid prolonged or repeated contact with skin. Remove contaminated
clothing; launder or dry-clean before re-use. Remove contaminated shoes and thoroughly clean before re-use; discard
if oil-soaked. Cleanse skin thoroughly after contact, before breaks and meals, and at end of work period. Product is
readily removed form skin by waterless hand cleaners followed by washing thoroughly with soap and water.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
The following data are approximate or typical values and should not be used for precise design purposes.
BOILING RANGE VAPOR PRESSURE
IBP Approximately 193鈭扖 (380鈭扚) Less than 5 mm Hg @ 25鈭扖
SPECIFIC GRAVITY (15.6 Deg C/15.6 Deg C) VAPOR DENSITY (AIR = 1)
0.88 Greater than 5
MOLECULAR WEIGHT PERCENT VOLATILE BY VOLUME
Not determined Negligible from open container in 4 hours @ 38 Deg C (100
Deg F)
EVAPORATION RATE @ 1 ATM. & 25 Deg C
pH (77 Deg F) (n-BUTYL ACETATE = 1)
Essentially neutral Less than 0.01
SOLUBILITY IN WATER @ 1 ATM.
POUR, CONGEALING OR MELTING POINT AND 25 Deg C (77 Deg F)
-33 Deg C (-27 Deg F) Negligible; less than 0.1%
Pour Point by ASTM D 97
VISCOSITY
6.5 cSt @ 100 Deg C
PRODUCT APPEARANCE AND ODOR
Clear, blue-green liquid
Faint petroleum hydrocarbon odor
SECTION 10: STABILITY AND REACTIVITY
This product is stable and will not react violently with water. Hazardous polymerization will not occur. Avoid
contact with strong oxidants such as liquid chlorine, concentrated oxygen, sodium hypochlorite, calcium hypochlorite,
etc., as this presents a serious explosion hazard.
PRODUCT: Star brite Super Premium 2-Cycle Engine Oil TC-W3 Product Number: 19216, 19225, 19232,
19200
SECTION 11: TOXICOLOGICAL INFORMATION
NATURE OF HAZARD AND TOXICITY INFORMATION
Repeated and prolonged overexposure to oil mists may result in droplet deposition, oil granuloma formation,
inflammation and increased incidence of infection.
In accordance with the current OSHA Hazard Communication Standard criteria, this product does not require a cancer
hazard warning. This is because the product is formulated from base stocks which are severely hydrotreated, severely
solvent extracted, and/or processed by mild hydrotreatment and extraction. Alternatively, it may consist of
components not otherwise affected by IARC criteria, such as atmospheric distillates or synthetically derived materials,
and as such is not characterized by current IARC classification criteria.
Prolonged or repeated skin contact with this product tends to remove skin oils, possibly leading to irritation and
dermatitis; however, based on human experience and available toxicological data, this product is judged to be neither
a Acorrosive@ nor an Airritant@ by OSHA criteria.
Product contacting the eyes may cause eye irritation.
Product has a low order of acute oral and dermal toxicity, but minute amounts aspirated into the lungs during
ingestion or vomiting may cause mild to severe pulmonary injury and possible death.
This product is judged to have an acute oral LD50 (rat) greater than 5 g/kg of body weight, and an acute dermal LD50
(rabbit) greater than 3.16 g/kg of body weight.
SECTION 12: ECOLOGICAL INFORMATION
Do not discharge this product into public waters or waterways unless authorized by a National Pollution Discharge
Elimination System (NPDES) permit issued by the Environmental Protection Agency (EPA).
Environmental and Ecological data may be available for this product. Write or call Star brite to obtain further
information. Refer to Section 6 and Section 15 for Accidental Release information and Regulatory Reporting
information.
SECTION 13: DISPOSAL CONSIDERATION
Options for disposal of this product may depend on the conditions under which it was used. To determine the proper
method of disposal, refer to RCRA (40 CFR 261), as well as federal EPA and state and local regulations.
Please refer to Sections 5, 6 and 15 for additional information.
SECTION 14: TRANSPORTATION INFORMATION
Call for information
PRODUCT: Star brite Super Premium 2-Cycle Engine Oil TC-W3 Product Number: 19216, 19225, 19232, 19200
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
THE FOLLOWING INFORMATION MAY BE USEFUL IN COMPLYING WITH VARIOUS STATE AND FEDERAL
LAWS AND REGULATIONS UNDER VARIOUS ENVIRONMENTAL STATUTES:
THRESHOLD PLANNING QUANTITY (TPQ), EPA REGULATION 40 CFR 355
(SARA Sections 301-304)
No TPQ for product or any constituent greater than 1% or 0.1% (carcinogen).
TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA SECTION 313)
No toxic chemical is present greater than 1% or 0.1% (carcinogen).
HAZARDOUS CHEMICAL REPORTING, EPA REGULATION 40 CFR 370 (SARA SECTIONS 311-312)
EPA Hazard Classification Code: Not applicable
TOXIC SUBSTANCES CONTROL ACT (TSCA)
This product, as manufactured by Star brite, does not contain polychlorinated biphenyls (PCB鈥檚).
All components of this product are listed on the U.S. TSCA inventory.
SECTION 16: OTHER INFORMATION
The health and safety information presented herein must be used in conjunction with the pertinent standards for training,
work practices and facilities design established by OSHA, NIOSH, NFPA, API, NEC, NSC, UNDERWRITERS,
BUREAU OF MINES, and similar organizations.
The information and recommendations contained herein are, to the best of Star brite=s knowledge and belief, accurate and
reliable as of the date issued. Star brite does not warrant or guarantee their accuracy or reliability, and Star brite shall not
be liable for any loss or damage arising out of the use thereof.
The information and recommendations are offered for the user=s consideration and examination, and it is the user=s
responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product,
legal counsel should be consulted to insure proper health, safety and other necessary information is included on the
container.
The Environmental Information included under Section 15 hereof as well as the Hazardous Materials Identification
System (HMIS) and National Fire Protection Association (NFPA) ratings have been included by Star brite in order to
provide additional health and hazard classification information. The ratings recommended are based upon the criteria
supplied by the developers of these rating system, together with Star brite=s interpretation of the available data.
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