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MSDS Material Safety Data Sheet
CAS

64742-52-5
64742-01-4
7620-77-1
64742-53-6
68649-42-3

File Name: starbrite_com---26014-msds-6-18-05.asp
                                                          MATERIAL SAFETY DATA SHEET

Product No: 26014, 26016, 26003 Product Name: Star brite Wheel Bearing Grease
Manufacturer: Star brite DATE: June 18, 2005
4041 S.W. 47 Avenue
Ft. Lauderdale, FL 33314
Hazard Ranking
IMPORTANT: Read this MSDS before handling or disposing of this product HMIS NFPA
and pass this information on to employees, customers and users of this product. Health Hazard 1 0
Fire Hazard 1 1
EMERGENCY OVERVIEW Reactivity 0 0
Physical State Semi-solid to solid (Smooth texture) * = Chronic Health Hazard
Color Red Odor Mild petroleum odor Protective Equipment
Minimum Recommended
WARNING: See Section 8 for Details
Injection under the skin can cause severe injury. Most damage occurs in the first few hours. Initial symptoms may be minimal.
Hot grease will cause thermal burns upon contact. Spills may create a slipping hazard.
SECTION 1: PRODUCT IDENTIFICATION
Product Name: Star brite Wheel Bearing Grease Technical Contact: (800) 327-8583
Product Number: 26014, 26016, 26003 Emergency Number: (800) 424-9300 or (703) 527-3887 Chemtrec
CAS Number: Mixture
Product Family: Lubricating grease
SECTION 2: COMPOSITION
Component Name(s) CAS Registry No. Concentration (%)
1) Distillates, petroleum, hydrotreated heavy naphthenic 64742-52-5 60 - 80
2) Residual oils, petroleum, solvent-refined 64742-01-4 5 鈥? 20
3) Octadecanoic acid, 12-hydroxy, monolithium salt 7620-77-1 1 - 15
4) Lithium Carboxylate Proprietary <5
5) Distillates, Petroleum, hydrotreated light naphthenic 64742-53-6 <5
6) Proprietary Ingredients Proprietary Mixture <2
7) Zinc and Zinc Compounds 68649-42-3 <1
SECTION 3: HAZARDS IDENTIFICATION
Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS.

Major Route (s) of Entry Skin contact.

Signs and Symptoms of Acute Exposure

Inhalation No significant adverse health effects are expected to occur upon short-term exposure at ambient temperatures. At
elevated temperatures, product vapor may cause respiratory tract irritation. Repeated or prolonged overexposure to
product mists can result in respiratory tract inflammation and an increased risk of infection.

Eye Contact This material can cause mild eye irritation from contact with product or product mists.

Skin Contact This material can cause mild skin irritation from prolonged or repeated skin contact. Injection under the skin can
cause inflammation and swelling. Injection of pressurized hydrocarbons can cause severe, permanent tissue
damage. Initial symptoms may be minor. Injection of petroleum hydrocarbons requires immediate medical
attention. Skin contact with hot material may result in serve burns.

Ingestion This material can cause a laxative effect. If swallowed in large quantities, this material can obstruct the intestine.

Chronic Health This product contains a petroleum-base mineral oil. Prolonged or repeated skin contact can cause mild
Effects Summaryirritation inflammation characterized by drying, cracking, (dermatitis) or oil acne. Repeated or prolonged inhalation
of petroleum-based mineral oil mists at concentrations above applicable workplace exposure levels can cause
respiratory irritation or other pulmonary effects.

Conditions Disorders of the following organs or organ systems that may be aggravated by significant exposure to this material
or its components include: Skin
Aggravated by
Exposure

Target Organs May cause damage to the following organs: skin.
Product No: 26014,26016, 26003 Product Name: Star brite Wheel Bearing Grease
SECTION 3: HAZARDS IDENTIFICATION cont鈥檇
Carcinogenic This product is not known to contain any components at concentrations above 0.1% which are
Potential considered carcinogenic by OSHA, IARC or NTP.

OSHA Hazard Classification is indicated by an 鈥淴鈥? in the box adjacent to the hazard title. If no 鈥淴鈥? is present, the product does not exhibit the hazard as defined in the
OSHA Hazard Communication Standard (29 CFR 1910.1200).
OSHA Health Hazard Classification OSHA Physical Hazard Classification
Irritant Sensitizer Combustible Explosive Pyrophoric
Toxic Highly Toxic Flammable Oxidizer Water-reactive
Corrosive Carcinogenic Compressed Gas Organic Peroxide Unstable


SECTION 4: FIRST AID MEASURES
Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more
specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS.

Inhalation Vaporization is not expected at ambient temperatures. This material is not expected to cause inhalation-related
disorders under anticipated conditions of use. In case of overexposure, move the person to fresh air.

Eye Contact Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water while occasionally lifting and
lowering eyelids. Seek medical attention if excessive tearing, redness, or pain persists.

Skin Contact If burned by hot material, cool skin by quenching with large amounts of cool water. For contact with product at
ambient temperatures, remove contaminated shoes and clothing, Wipe off excess material. Wash exposed skin with
mild soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists. Thoroughly
clean contaminated clothing before reuse. Discard contaminated leather goods. If material is injected under the
skin, seek medical attention immediately.

Ingestion Do not induce vomiting unless directed to by a physician. Rinse out mouth with water. Never give anything by
mouth to a person who is not fully conscious. Allow small quantities to pass through the digestive system. If large
amounts are swallowed or irritation or discomfort occurs, seek medical attention immediately.

Notes to SKIN: In the event of injection in underlying tissue, immediate treatment should include
Physician extensive incision, debridement and saline irrigation. Inadequate treatment can result in ischemia and gangrene.
Early symptoms may be minimal..

SECTION 5: FIRE FIGHTING MEASURES
NFPA Flammability NFPA Class-IIIB combustible material.
Classification

Flash Point Open cup: 218掳 C (424掳 F) (Cleveland). (Minimum).

Lower Flammable Limit No data. Upper Flammable Limit No data.

Autoignition Not available.
Temperature

Hazardous Combustion Carbon dioxide, carbon monoxide, smoke, fumes, unburned
Products hydrocarbons and trace oxides of sulfur, phosphorus, zinc and/or nitrogen.

Special Properties Fight the fire from a safe distance in a protected location. Open any masses with a water stream to
prevent reignition due to smoldering. Cool surface with water fog. Molten material can form
flaming droplets if ignited. Water or foam can cause frothing. Use of water on product above
100掳C (212掳F) can cause product to expand with explosive force. Do not allow liquid runoff to
enter sewers or public waters.

Extinguishing Media Use dry chemical, foam Carbon Dioxide or water fog.

Protection of Fire Fighters Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained
breathing apparatus to protect against potential hazardous combustion or decomposition products
and oxygen deficiencies.
Product No: 26014,26016, 26003 Product Name: Star brite Wheel Bearing Grease
SECTION 6: ACCIDENTAL RELEASE MEASURES
Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific
information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection in Section 8 and
Disposal Considerations in Section 13 of this MSDS.
Do not touch damaged containers or spilled material unless wearing appropriate protective equipment. Slipping hazards; do
not walk through spilled material. Stop leak if you can do so without risk. For small spills, absorb or cover with dry earth,
sand or other inert non-combustible absorbent material and place into waste containers for later disposal. Contain large spills
to maximize product recovery or disposal. Prevent entry into waterways or sewers. In urban area, cleanup spill as soon as
possible. In natural environments, seek cleanup advice from specialists to minimize physical habitat damage. This material
will float on water. Absorbent pads and similar materials can be used. Comply with all laws and regulations.

SECTION 7: HANDLING AND STORAGE
Handling
If this product is stored or applied in high-pressure system such as grease guns or hydraulic lines, there is the
potential for accidental injection into the skin and underlying tissues. Hydrocarbons injected into skin or underlying
tissues are not readily removed by body fluids and can cause pain, swelling chemical irritation, infection and tissue
destruction. Early symptoms may be minimal. Workers must be aware of the significant hazards associated with a
hydrocarbon injection injury. In the event of an injection injury, workers should seek medical treatment
immediately. Avoid water contamination and elevated temperatures to minimize product degradation. Empty
containers may contain product residues that can ignite with explosive force. Do not pressurize, cut weld, braze
solder, drill, grind or expose containers to flames, sparks, heat or other potential ignition sources. Consult
appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of
empty containers and/or waste residues of this product.

Storage Keep container closed. Do not store with strong oxidizing agents. Do not store at elevated temperatures. Avoid
storing product in direct sunlight for extended periods of time. Consult appropriate federal, state and local
authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers or waste residues
of this product.

SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls Ventilation controls are not normally required under anticipated conditions of use. Provide exhaust
ventilation or other engineering controls if airborne mists or vapors concentrations exceed recommended
occupational exposure limits listed below. An eye wash station and safety shower should be located near
the work-station.

Personal Protective
Equipment Personal protective equipment should be selected based upon the conditions under which this material is
used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified
professional pursuant to OSHA regulations. The following pictograms represent the minimum
requirements for personal protective equipment. For certain operations, additional PPE may be required.

Eye Protection Safety glasses equipped with side shields are recommended as minimum protection in industrial settings.
Wear goggles and/or face shield if splashing or spraying is anticipated. Wear goggles and face shield if
material is heated above 125掳 F (51掳 C). Have suitable eye wash water available.

Hand Protection Use gloves constructed of chemical resistant materials such as neoprene or heavy nitrile rubber if frequent
or prolonged contact is expected. Use heat-protective gloves when handling product at elevated
temperatures.

Body Protection Use clean protective clothing (e.g., neoprene or Tyvek庐) if splashing or spraying conditions are present.
Protective clothing may include long-sleeve outer garment, apron, or lab coat. If significant contact occurs,
remove oil-contaminated clothing as soon as possible and promptly shower. Launder contaminated
clothing before reuse or discard. Wear heat protective boots and protective clothing when handling
material at elevated temperatures.
Product No: 26014,26016, 26003 Product Name: Star brite Wheel Bearing Grease
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION cont鈥檇
Respiratory Protection Vaporization is not expected at ambient temperatures. Therefore, the need for respiratory protection is not
anticipated under normal use conditions and with adequate ventilation. If elevated airborne concentration
above applicable workplace exposure levels are anticipated, a NIOSH- approved organic vapor respirator
equipped with a dust/mist prefilter should be used. Protection factors vary depending upon the type of
respirator used. Respirators should be used in accordance with OSHA requirements (29 CFR 1910.134).

General Comments Use good personal hygiene practices. Wash hands and other exposed skin areas with plenty of mild soap
and water before eating, drinking, smoking, use of toilet facilities, or leaving work. DO NOT use gasoline,
kerosene, solvents or harsh abrasives as skin cleaners. Since specific exposure standards/control limits
have not been established for this product, the 鈥淥il Mist, Mineral鈥? exposure limits shown below are
suggested as minimum control guidelines.

Occupational; Exposure Guidelines

Substance Applicable Workplace Exposure Levels
Oil Mist, Mineral ACGIH (United States).
TWA: 5mg/m3 8 hours(s).
STEL: 10mg/m3 15 minute(s).
OSHA (United States).
TWA: 5mg/m3 8 hour(s).
ACGIH TLV (United States).
TWA: 10 mg/m3 8 hour(s).


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (TYPICAL)

Physical State Semi-solid to solid Color Red. Odor Petroleum
(Smooth Texture)
Specific Gravity 0.93 (Water = 1) pH Not applicable Vapor >10 (Air =1)
Density
Boiling Range Not available. Melting/Freezing Not available.
Point
Vapor Pressure Not available. Volatility Negligible volatility.

Solubility in Water Insoluble in cold water. Viscosity 214
(cSt @ 40掳 C)
Additional Properties NLGI Grade = 2
Thickener = Lithium
Texture = Smooth

SECTION 10: STABILITY AND REACTIVITY

Chemical Stability Stable. Hazardous Polymerization Not expected to occur.

Conditions to Avoid Keep away from extreme heat, sparks, open flame, and strongly oxidizing
conditions.

Materials Incompatibility Strong oxidizers.

Hazardous No additional hazardous decomposition products were identified other than the combustion
Decomposition products identified in Section 5 of this MSDS.
Products

SECTION 11: TOXICOLOGICAL INFORMATION
For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification in Section 3
of this MSDS.
Toxicity Data Distillates, petroleum, hydrotreated heavy naphthenic
ORAL (LD50): Acute: >5000 mg/kg [Rat].
DERMAL (LD50): Acute: > 2000 mg/kg[Rabbit].
Product No: 26014,26016, 26003 Product Name: Star brite Wheel Bearing Grease
SECTION 11:TOXICOLOGICAL INFORMATION cont鈥檇
Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals.
Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above
applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid
pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or
near current work place exposure levels produced no significant toxicological effects.

Residual oils, petroleum, solvent 鈥搑efined:
ORAL (LD50): Acute: >5000 mg/kg [Rat].
DERMAL (LD50): Acute: > 2000 mg/kg[Rabbit].
Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals..
Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above
applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid
pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or
near current work place exposure levels produced no significant toxicological effects. In long term studies (up to
two years) no carcinogenic effects have been reported in any animal species tested.

Distillates, petroleum, hydrotreated light naphthenic
ORAL (LD50): Acute: >5000 mg/kg [Rat].
DERMAL (LD50): Acute: > 2000 mg/kg[Rabbit].

INHALATION (LC50) Acute: 9.6 mg/L (Female Rat).
INHALATION (LC50) Acute: 10.5 mg/L (Male Rat).
DRAIZE EYE Acute: Non-irritating (Rabbit).
DRAIZE DERMAL Acute: Mild skin irritant (Rabbit).
BUEHLER DERMAL Acute: Non-sensitizing (Guinea Pig).
28- Day DERMAL Sub-Chronic: Mild to moderate skin irritant (Rabbit & Rat).

A life-time dermal application of severely hydrotreated light naphthenic oils produced skin masses on mice which
correlated with the skin irritation response levels of the test animals. Additional studies attribute these masses to a
weak promotional activity. These studies indicate that light naphthenic oils are not mutagenic, tumor initiators nor
complete chemical carcinogens. These materials have not been determined to be carcinogenic by IARC, NTP or
OSHA.

Grease:
Injection of pressurized hydrocarbons under the skin, in muscle or into the blood stream can cause irritation,
inflammation, swelling, fever and mild central nervous system depression. Injection of pressurized hydrocarbons
can cause severe, permanent tissue damage.

SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity Ecotoxicity data are not available for this product.

Environmental Fate An environmental fate analysis is not available for this specific product. Plants and animals may experience
harmful or fatal effects when coated with petroleum-based products. Petroleum-based (mineral) lube oils
will normally float on water. In stagnant or slow-flowing waterways, an oil layer can cover a large surface
area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen transport into the water.
With time, if not removed, oxygen depletion in the water way can result in a loss or marine life or create an
anaerobic environment. This material contains phosphorus which is a controlled element for disposal in
effluent waters in most sections of North America. Phosphorus is known to enhance the formation of
algae. Severe algae growth can reduce oxygen content in the water possibly below levels necessary to
support marine life.
Product No: 26014,26016, 26003 Product Name: Star brite Wheel Bearing Grease
SECTION 13: DISPOSAL CONSIDERATIONS
Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the
responsibility of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent
materials and residues at the time of disposition.

Conditions of use may cause this material to become a 鈥渉azardous waste鈥?, as defined by federal or state regulations. It is the
responsibility of the user to determine if the material is a 鈥渉azardous waste鈥? at the time of disposal. Transportation,
treatment, storage and disposal of waste material must be conducted in accordance with RCRA regulations (See 40 CFR 260
through 40 CFR 271). State and/or local regulations may be more restrictive. Contact the RCRA/Superfund Hotline at (800)
424-9346 or your regional US EPA office for guidance concerning case specific disposal issues. Empty drums and pails
retain residue. DO NOT pressurize, cut, weld, braze, solder, drill, grind, or expose this product鈥檚 empty container to heat,
flame, or other ignition sources. DO NOT attempt to clean it. Empty drums and pails should be drained completely,
properly bunged or sealed, and promptly sent to a reconditioner.


SECTION 14: TRANSPORT INFORMATION
Call for information

SECTION 15: REGULATORY INFORMATION
TSCA Inventory This product and/or its components are listed on the Toxic Substance Control Act. (TSCA) Inventory.

SARA 302/304
Emergency Planning
And Notification The Superfund Amendments and Reauthorization Act of 1986. (SARA) Title III requires facilities subject
to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold
Planning Quantities (TPQs) and Reportable Quantities (RQs) for 鈥淓xtremely Hazardous Substances鈥? listed
in 40 CFR 302.4 and 40 CFR 355. No components were identified.

SARA 311/312 Hazard
Identification The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to
this subpart to submit aggregate information on chemicals by 鈥淗azard Category鈥? as defined in 40 CFR
370.2. This material would be classified under the following hazard categories:
No SARA 311/312 hazard categories identified.
SARA 313 Toxic
Chemical Notification
And Release Reporting This product contains the following components in concentration above de minimis levels that are listed as
toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA: No components
were identified.

CERCLA The comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA)
requires notification of the National Response Center concerning release of quantities of 鈥渉azardous
substances鈥? equal to or greater than the reportable quantities (RQ鈥檚) listed in 40 CFR 302.4. As defined by
CERCLA, the term 鈥渉azardous substance鈥? does not include petroleum, including crude oil or any fraction
thereof which is not otherwise specifically designated in 40 CFR 302.4. Chemical substances present in
this product or refinery stream that may be subject to this status are: Zinc and Zinc Compounds,
Concentration: <1%

Clean Water Act
(CWA) This material is classified as an oil under section 311 of the Clean Water Act (CWA) and the Oil Pollution
Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States,
their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA鈥檚 National
Response Center at (800) 424-8802.

California
Proposition 65 This material may contain the following components which are known to the State of California to cause
cancer, birth defects or other reproductive harm, and may be subject to the requirements of California
Proposition 65 (CA Health & Safety Code Section 25249.5): Ethylbenzene: 0.002%

New Jersey Petroleum Oil
Right-to-know Label

Additional Regulatory No additional regulatory remarks
Remarks
Product No: 26014,26016, 26003 Product Name: Star brite Wheel Bearing Grease

SECTIONS 16: OTHER INFORMATION
Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product.

AP: Approximately EQ: Equal >: Greater Than <: Less Than NA: Not Applicable ND: No data NE: Not Established

ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygiene Association
IARC: International Agency for Research on Cancer NTP: National Toxicology Program
NIOSH: National Institute of Occupational Safety and Health OSHA: Occupational Safety and Health Administration
NPCA: National Paint and Coating Manufacturers Association HMIS: Hazardous Material Information System
NFPA: National Fire Protection Association EPA: US Environmental Protection Agency

DISCLAIMER OF LIBILITY
THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE.
HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED
REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE
FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED
AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER
PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN
INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR
PARTICULAR PURPOSE.

THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE
BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS OTHER REASONS, WE DO NOT
ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE EXPENSE ARISING
OUT OF IN ANY WAY CONNECTED WITH HANDLING STORAGE, USE OR DISPOSAL OF THE PRODUCT.

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