MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS Standards and European EC Directives .This Material Safety Data Sheet is offered pursuant to OSHA’s
Hazard Communication Standard (29 CFR 1910.1200). Other government regulations must be reviewed for applicability to this product.
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
STAR BRITE AEROSOL MARINE GREASE GUN
TRADE NAME (AS LABELED):
PRODUCT #: 26005
CHEMICAL NAME/CLASS: Inert Gas Aerosol with Grease
SYNONYMS: Not Applicable
PRODUCT USE: Lubrication
SUPPLIER/MANUFACTURER'S NAME: STAR BRITE DISTRIBUTING
ADDRESS: 4041 S. W. 47 Avenue
Ft. Lauderdale, FL 33314
EMERGENCY PHONE: North America: 1-800-424-9300 (Chemtrec)
International: 1-703-527-3887 (Chemtrec)
BUSINESS PHONE: 954-587-6280
DATE OF PREPARATION: June 18, 2005
2. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This product consists of a grease mixture packaged in an aerosol gun with Nitrogen as the
propellant. The grease mixture is a dark, green semi-solid with a petroleum odor. The Nitrogen propellant gas is a
colorless, odorless gas. Health Hazards: The health hazards associated with overexposure are minimal, due to the small
size of the container and small volume of the contents. The Nitrogen propellant gas is inert and does not present a
health hazard. If a release of many containers of this product occurs at the same time, an oxygen-deficient
environment can occur, resulting in a hazard of asphyxiation. If the container is heated or punctured, rupture of the
container may occur, and may cause injury. Flammability Hazards: The grease mixture of this product can ignite if
highly heated. Persons responding to an emergency such as a fire that involves this product must take precautions to
avoid potential injury from containers that rupture. Reactivity Hazards: This product is not reactive. Environmental
Hazards: Release of the grease mixture may cause adverse effects to the environment, plants and animals. Emergency
Recommendations: Emergency responders must have personal protective equipment and fire protection appropriate
for the situation to which they are responding.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: Contact
with this product is not expected to cause significant adverse health effects, HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
due to the small size of container and limited amount of gas within the
container.
HEALTH HAZARD
INHALATION: Inhalation of this product is unlikely, as the grease product 1
(BLUE)
is not volatile and does not produce vapors. In event that rupture occurs of
a large quantity of containers, especially in a confined space, an oxygen-
deficient environment may be created due to the release of the Nitrogen
propellant gas. Individuals breathing such an atmosphere may experience FLAMMABILITY HAZARD 1
(RED)
symptoms which include headaches, ringing in ears, dizziness, drowsiness,
unconsciousness, nausea, vomiting, and depression of all the senses.
Under some circumstances of overexposure, death may occur. The effects
associated with various levels of oxygen are as follows: PHYSICAL HAZARD (YELLOW) 0
CONCENTRATION OF OXYGEN OBSERVED EFFECT
12-16% Oxygen: Breathing and pulse rate increase,
muscular coordination slightly disturbed.
PROTECTIVE EQUIPMENT
10-14% Oxygen: Emotional upset, abnormal fatigue,
disturbed respiration.
6-10% Oxygen: Nausea, vomiting, collapse, or loss of EYES HANDS BODY
RESPIRATORY
consciousness.
Below 6%: Convulsive movements, possible See See
respiratory collapse, and death. Section 8 Section 8
CONTACT WITH SKIN OR EYES: Contact of the grease mixture with the
For Routine Industrial Use and Handling Applications
skin is not expected to cause adverse effect if contact is brief and the
product is washed-off.
See Section 16 for Definition of Ratings
AEROSOL GREASE GUN EFFECTIVE DATE: OCTOBER, 2003
PAGE 1 OF 10
3. HAZARD IDENTIFICATION (Continued)
CONTACT WITH SKIN OR EYES (continued): Prolonged or repeated contact may cause defatting of the skin and result in
dermatitis with symptoms of dry, itchy, red skin. Serious injury can arise if oil-based products under high pressure, such as
this product, are accidentally discharged or injected into the flesh beneath the skin or into the eyes. Serious tissue
destruction can result, requiring immediate medical attention. Emergency surgery may be required to decompress the
injured area and to remove dead tissue and/or free-lying lubricant.
INGESTION: Not a likely route of exposure. If ingested, irritation of the gastric system and a laxative effect may occur with
symptoms of nausea, vomiting and diarrhea.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Over-exposure to this gas mixture
may cause the following health effects.
ACUTE: Acute exposure to the product is not expected to cause significant adverse health effects, unless rapid release of
the product results in injection of the grease mixture under the skin.
CHRONIC: Chronic skin contact may result in dermatitis.
TARGET ORGANS: ACUTE: Eyes, respiratory system, central nervous system. CHRONIC: Skin.
EC CLASSIFICATION: Xi: Irritating
RISK PHRASES: R 38: Irritating to skin.
SAFETY PHRASES: S 2: Keep out of reach of children. S 15: Keep away from heat. S 26: In case of contact with eyes,
rinse immediately with plenty of water and seek medical advice. S 45: In case of accident, or if you feel unwell, seek medical
advice immediately (show label where possible).
3. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # EINECS # % w/w
Grease Mixture Mixture 100
See below for composition
Lithium Hydroxide 1310-65-2 215-183-4 1-3
Methyl 12-Hydroxystearate Mixture 3-9
Hydrotreated Naphthenic Distillate 64741-95-3 265-096-0 20-45
Hydrotreated Heavy Paraffinic Distillate 64742-54-7 265-157-1 45-80
Nitrogen (propellant gas) 7727-37-9 231-783-9 0-> 99
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention, if adverse health effects occur. Rescuers should be taken
for medical attention, if necessary. Take copy of label and MSDS to health professional with victim.
SKIN EXPOSURE: If skin contact results in irritation or other adverse effect, seek the advice of a doctor.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gentle running water. Use sufficient force
to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek medical attention if adverse
health effects occur.
INHALATION: Not a likely route of exposure.
INGESTION: In the event that large quantities of this product are swallowed, CALL PHYSICIAN OR POISON CONTROL
CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING, unless directed by medical personnel. If
conscious, have victim rinse mouth with water. Never induce vomiting or give diluents (milk or water) to someone who is
unconscious, having convulsions, or unable to swallow.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing skin conditions may be aggravated by exposure to
this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. If injection of the grease mixture
has occurred, emergency surgery may be required to decompress the injured area and to remove dead tissue and/or
free-lying lubricant.
5. FIRE-FIGHTING MEASURES
FLASH POINT (Cleveland Open Cup): 251.67°C (485°F)
AUTOIGNITION TEMPERATURE: Not determined.
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable.
Upper (UEL): Not applicable.
AEROSOL GREASE GUN EFFECTIVE DATE: OCTOBER, 2003
PAGE 2 OF 10
5. FIRE-FIGHTING MEASURES (Continued)
FIRE EXTINGUISHING MATERIALS: Water fog, dry chemical, alcohol foam NFPA RATING
or carbon dioxide can be used on fire involving this product. Do not use a FLAMMABILITY
direct stream of water, which can spread burning material and spread fire.
SPECIFIC HAZARDS ARISING FROM THIS PRODUCT IN A FIRE
0
SITUATION: Containers of this product may explode in heat of fire.
Explosion Sensitivity to Mechanical Impact: Not sensitive. 1
3
HEALTH REACTIVITY
Explosion Sensitivity to Static Discharge: Not sensitive.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-
FIGHTERS: Incipient fire responders should wear eye protection. Structural
firefighters must wear Self-Contained Breathing Apparatus and full protective OTHER
equipment.
SPECIAL FIRE-FIGHTING PROCEDURES: Move containers from fire area if it can be done without risk to personnel.
Use water spray to keep fire-exposed containers cool. If possible, prevent
See Section 16 for
run-off water from entering storm drains, bodies of water, or other
Definition of Ratings
environmentally sensitive areas.
6. ACCIDENTAL RELEASE MEASURES
SPILL/LEAK RESPONSE: A release of a single container or several containers presents a minimal hazard. Allow
containers to vent and remove container for appropriate disposal. If a large quantity of containers of this product is involved,
evacuate immediate area. Uncontrolled releases should be responded to by trained personnel using pre-planned
procedures. Proper protective equipment should be used. If a large quantity of product is involved, the minimum Personal
Protective Equipment should be Level B: Self-Contained Breathing Apparatus. Allow the gas to dissipate. Monitor the
surrounding area for the level of Oxygen. The atmosphere must have at least 19.5 percent Oxygen before personnel can be
allowed in the area without Self-Contained Breathing Apparatus. Clean-up spilled grease mixture, using appropriate
absorbent material and dispose of in accordance with U.S. Federal, State, and local hazardous waste disposal regulations
and those of Canada and its Provinces and those of EC Member States (see Section 13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring
7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: Do not eat, smoke or drink while handling this material. Use ventilation
and other engineering controls to minimize potential exposure to the aerosol of this product.
STORAGE AND HANDLING PRACTICES: Store containers in a cool, dry location, away from direct sunlight, sources of
intense heat, or where freezing is possible. Store containers away from incompatible chemicals (see Section 10, Stability
and Reactivity). Do not incinerate empty or partially filled containers.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Not applicable.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
EXPOSURE LIMITS/GUIDELINES:
CHEMICAL NAME CAS # EINECS # % w/w EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL TWA STEL IDLH
ppm ppm ppm ppm ppm ppm
Grease Mixture Mixture 100 NE NE NE NE NE NE
See below for composition
Lithium Hydroxide 1310-65-2 215-183-9 1-3 NE NE NE NE NE NE
Methyl 12-Hydroxystearate Mixture 3-9 NE NE NE NE NE NE
Hydrotreated Naphthenic 64741-95-3 265-096-0 20-45 NE NE NE NE NE NE
Distillate
Hydrotreated Heavy 64742-54-7 265-157-1 45-80 NE NE NE NE NE NE
Paraffinic Distillate
Nitrogen 7727-37-9 231-783-9 0-> 99 There are no specific exposure limits for Nitrogen. Nitrogen is a simple
asphyxiant (SA). Oxygen levels should be maintained above 19.5%.
NE = Not Established. See Section 16 for Definitions of Terms Used.
AEROSOL GREASE GUN EFFECTIVE DATE: OCTOBER, 2003
PAGE 3 OF 10
8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
VENTILATION AND ENGINEERING CONTROLS: Not necessary under normal conditions of use.
RESPIRATORY PROTECTION: No respiratory protection is normally required when using this product. Maintain airborne
contaminant concentrations below guidelines listed in Section 2 (Composition and Information on Ingredients), if applicable. If
respiratory protection is needed, U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the
Canadian CSA Standard Z94.4-93 and applicable standards of Canadian Provinces. Respiratory Protection is
recommended to be worn during welding operations. Oxygen levels below 19.5% are considered IDLH by OSHA. In such
atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-
contained air supply is required under OSHA’s Respiratory Protection Standard (1910.134-1998).
EYE PROTECTION: None needed under normal use. If a hazard of flying debris may occur, wear safety glasses or
goggles. If necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian Standards. If necessary, refer to
U.S. OSHA 29 CFR 1910.138, or appropriate Standards of Canada.
HAND PROTECTION: None needed under normal conditions of use. If necessary, refer to U.S. OSHA 29 CFR 1910.138,
or appropriate Standards of Canada.
BODY PROTECTION: None needed for normal circumstances of use. If a hazard of injury to the feet exists due to falling
objects, rolling objects, where objects may pierce the soles of the feet or where employee’s feet may be exposed to electrical
hazards, use foot protection, as described in U.S. OSHA 29 CFR 1910.136.
9. PHYSICAL and CHEMICAL PROPERTIES
The following physical property values are for the grease mixture.
VAPOR DENSITY: Not applicable. EVAPORATION RATE (nBuAc = 1): Not applicable.
SPECIFIC GRAVITY (air = 1): Not available. MELTING POINT: 185°C (365°F)
SOLUBILITY IN WATER: Insoluble. BOILING POINT: -Not available.
EXPANSION RATIO: Not applicable pH: Not applicable.
ODOR THRESHOLD: Not available. VAPOR PRESSURE @ 20°C: Not available.
COEFFICIENT WATER/OIL DISTRIBUTION: Not available. FLASH POINT: 251.67°C (485°F)
APPEARANCE, ODOR and COLOR: This grease mixture is a dark, green semi-solid, with a mild petroleum odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The color and semi-solid state can be a warning property
in event of accidental release.
The following physical property values are for the propellant gas, Nitrogen
GAS DENSITY @ 0°C (32°F) and 1 atm: 0.072 lb./cu ft (1.153 kg/m3) SPECIFIC VOLUME (ft3/lb): 13.8
BOILING POINT: -195.8°C (-320.4°F) VAPOR PRESSURE: Not applicable.
FREEZING/MELTING POINT (@ 10 psig) -210°C (-345.8°F) ODOR THRESHOLD: Odorless.
SPECIFIC GRAVITY (air = 1) @ 21.1°C (70°F): 0.906 pH: Not applicable.
SOLUBILITY IN WATER vol/vol at 0°C (32°F) and 1 atm: 0.023 MOLECULAR WEIGHT: 28.01
EVAPORATION RATE (nBuAc = 1): Not applicable. EXPANSION RATIO: Not applicable.
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable. FLASH POINT: Not applicable.
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: If involved in a fire, this product will decompose to form carbon oxides, aldehydes,
ketones, lithium and other hydrocarbons.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: The Nitrogen propellant gas is inert and does not react with
any compound. Avoid contact of the grease mixture with strong oxidizers.
POSSIBILITY OF HAZARDOUS REACTIONS: Will not occur.
CONDITIONS TO AVOID: Extreme temperatures, incompatible materials.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: There are no toxicity data for the Nitrogen propellant gas. The following are toxicological data for the
components of the grease mixture.
HYDROTREATED HEAVY PARAFFINIC LITHIUM HYDROXIDE: LITHIUM HYDROXIDE (continued):
3
LD50 (Oral-Rat) 210 mg/kg: Behavioral: LC50 (Inhalation-Rat) 960 mg/m /4 hours:
DISTILLATE:
somnolence (general depressed activity), Lungs, Thorax, or Respiration: other
LD50 (Oral-Rat) > 15 gm/kg
convulsions or effect on seizure threshold; changes
LD50 (Skin-Rabbit) > 5 gm/kg
LD50 (Intratracheal-Rat) 8200 μg/kg: Lungs,
Nutritional and Gross Metabolic: weight loss
HYDROTREATED HEAVY PARAFFINIC
or decreased weight gain Thorax, or Respiration: other changes;
DISTILLATE:
Blood: hemorrhage
Currently, there are no data for this compound.
AEROSOL GREASE GUN EFFECTIVE DATE: OCTOBER, 2003
PAGE 4 OF 10
11. TOXICOLOGICAL INFORMATION (Continued)
TOXICITY DATA (continued):
LITHIUM HYDROXIDE (continued): LITHIUM HYDROXIDE (continued): LITHIUM HYDROXIDE (continued):
LD50 (Oral-Mouse) 363 mg/kg: Behavioral: TDLo (Oral-Mammal-species unspecified) 9100 LDLo (Subcutaneous-Mouse) 300 mg/kg
μg/kg/26 weeks-intermittent: Liver: liver
somnolence (general depressed activity), TCLo (Inhalation-Mammal-species unspecified)
3
convulsions or effect on seizure threshold; 8 mg/m /4 hours/30 days-intermittent:
function tests impaired; Blood: pigmented or
Nutritional and Gross Metabolic: weight loss Lungs, Thorax, or Respiration: other
nucleated red blood cells; Nutritional and
or decreased weight gain changes
Gross Metabolic: weight loss or decreased
weight gain
SUSPECTED CANCER AGENT: The components of this product are listed as follows:
Hydrotreated Heavy Naphthenic Distillate: IARC-3 (Unclassifiable as to Carcinogenicity in Humans)
The remaining components of this product are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and
CAL/OSHA, and therefore are not considered to be, nor suspected to be, cancer-causing agents by these agencies.
SENSITIZATION TO THE PRODUCT: No component of this product is known to be a skin or respiratory sensitizer.
TARGET ORGANS: Acute Exposure: Eyes, respiratory system, central nervous system. Chronic Exposure: Skin.
IRRITANCY OF PRODUCT: This product is not expected to be irritating to contaminated tissue. Prolonged skin exposure to
the grease mixture may cause dermatitis.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: The components of this product are not reported to cause mutagenic effects in humans. No firm
conclusions regarding the potential mutagenicity of related heavy paraffinic distillate materials can be drawn based on the
available animal evidence. Mineral oils that were previously not mutagenic to bacteria can become mutagenic, if exposed
to high temperatures during use. In one study, the polycyclic aromatic hydrocarbon (PAH) content of a used oil doubled.
Embryotoxicity: The components of this product are not reported to cause embryotoxic effects in human
Teratogenicity: The components of this product are not reported to cause teratogenic effects in humans.
Reproductive Toxicity: The components of this product are not reported to cause adverse reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight
weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which
causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is
any substance which interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE INDICES: Currently, there are no Biological Exposure Indices (BEIs) determined for the
components of this product.
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
PERSISTENCE/DEGRADABILITY: The Nitrogen propellant gas will dissipate. The grease mixture will not readily degrade.
BIOACCUMULATION/ACCUMULATION: There are no data on the product; the grease mixture is not expected to
bioaccumulate.
MOBILITY IN SOIL: As an oil mixture, the grease mixture may be mobile in the soil.
ECOTOXICITY: No data are available for this product.
OTHER ADVERSE EFFECTS: None known.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Product removed from the cylinder must be disposed of in accordance with
appropriate U.S. Federal, State, and local regulations, those of Canada and its Provinces and the EC and EC Member
States. .
U.S. EPA WASTE NUMBER: Not applicable to wastes consisting only of this product.
14. TRANSPORTATION INFORMATION
Call for information
AEROSOL GREASE GUN EFFECTIVE DATE: OCTOBER, 2003
PAGE 5 OF 10
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are not subject to the reporting requirements
of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act.
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for the components
of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs (4,540 kg)
therefore applies, per 40 CFR 370.20.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable.
OTHER FEDERAL REGULATIONS: The grease mixture is a considered an oil under 49 CFR, Part 130. Requirements
under this regulation may apply to quantities of 3500 gallons of the grease mixture.
U.S. STATE REGULATORY INFORMATION: The components of this product are covered under specific State regulations,
as denoted below:
Alaska - Designated Toxic and Hazardous Michigan - Critical Materials Register: None. Pennsylvania - Hazardous Substance List:
Nitrogen.
Substances: None. Minnesota - List of Hazardous Substances:
None. Rhode Island - Hazardous Substance List:
California - Permissible Exposure Limits for
Nitrogen.
Missouri - Employer Information/Toxic
Chemical Contaminants: Nitrogen.
Texas - Hazardous Substance List: None.
Substance List: Nitrogen.
Florida - Substance List: Nitrogen.
West Virginia - Hazardous Substance List:
New Jersey - Right to Know Hazardous
Illinois - Toxic Substance List: None.
None.
Substance List: Nitrogen.
Kansas - Section 302/313 List: None.
Wisconsin - Toxic and Hazardous
North Dakota - List of Hazardous Chemicals,
Massachusetts - Substance List: Nitrogen.
Substances:. None
Reportable Quantities: None.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): The components of this
product are not on the California Proposition 65 Lists.
ANSI LABELING (Z129.1) [Precautionary Statements]: CAUTION! KEEP AWAY FROM CHILDREN. SEMI-SOLID AND
GAS UNDER PRESSURE. IF RELEASED IN LARGE QUANTITY, REDUCES OXYGEN AVAILABLE FOR BREATHING.
Avoid breathing gas, vapor, or mists. Avoid contact with skin, clothing, and eyes. Use only with adequate ventilation. Wash
thoroughly in case of contact. Wear gloves, goggles, and appropriate body protection when handling. Do not puncture or
incinerate container. Dispose of in accordance with federal, state, and local requirements. FIRST-AID: In case of contact,
immediately flush skin or eyes for at least 15 minutes with water. Remove contaminated clothing and shoes. If inhaled,
move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention
immediately. IN CASE OF FIRE: Use fog, foam, dry chemical or carbon dioxide. Refer to Material Safety Data Sheet for
additional information on this product.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL Inventory.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No component of this
product is on the CEPA First Priorities Substance Lists.
CANADIAN WHMIS SYMBOLS: Class A: Compressed Gas
EUROPEAN COMMUNITY REGULATIONS:
EC LABELING AND CLASSIFICATION: The following is a self-classification, as defined by the European Community
Council Directives 67/548/EEC and 93/112/EEC.
EC CLASSIFICATION: [Xi]: IRRITANT
EC RISK PHRASES: [R: 38]: Irritating to skin.
EC SAFETY PHRASES: [S: 2]: Keep out of reach of children. (This safety phrase can be omitted from the label when the
substance or preparation is sold for industrial use only.) S 15: Keep away from heat. S 26: In case of contact with eyes,
rinse immediately with plenty of water and seek medical advice. S 45: In case of accident, or if you feel unwell, seek
medical advice immediately (show label where possible).
AEROSOL GREASE GUN EFFECTIVE DATE: OCTOBER, 2003
PAGE 6 OF 10
15. REGULATORY INFORMATION (Continued)
EUROPEAN COMMUNITY ANNEX II HAZARD SYMBOLS:
16. OTHER INFORMATION
DATE OF PRINTING: October 7, 2003
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these
data or the results to be obtained from the use thereof. Star brite Distributing assumes no responsibility for injury to the vendee or third persons
proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Star brite
Distributing, assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable
safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material.
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
identifies each constituent. RATINGS: This rating system was developed by the National Paint and
EXPOSURE LIMITS IN AIR: Coating Association and has been adopted by industry to identify the degree
of chemical hazards.
CEILING LEVEL: The concentration that shall not be exceeded during any
part of the working exposure. HEALTH HAZARD:
LOQ: Limit of Quantitation. 0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not
anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = �0�.
MAK: Federal Republic of Germany Maximum Concentration Values in the
Eye Irritation: Essentially non-irritating, or minimal effects which clear in < 24
workplace.
hours [e.g. mechanical irritation]. Draize = �0�. Oral Toxicity LD50 Rat: <
NE: Not Established. When no exposure guidelines are established, an
5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: < 2000 mg/kg. Inhalation
entry of NE is made for reference.
Toxicity 4-hrs LC50 Rat: < 20 mg/L.); 1 (Slight Hazard: Minor reversible Injury
NIC: Notice of Intended Change.
may occur; slightly or mildly irritating. Skin Irritation: Slightly or mildly
NIOSH CEILING: The exposure that shall not be exceeded during any part
irritating. Eye Irritation: Slightly or mildly irritating. Oral Toxicity LD50 Rat: >
of the workday. If instantaneous monitoring is not feasible, the ceiling shall
500-5000 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 1000-2000 mg/kg.
be assumed as a 15-minute TWA exposure (unless otherwise specified) that
Inhalation Toxicity LC50 4-hrs Rat: > 2-20 mg/L); 2 (Moderate Hazard:
shall not be exceeded at any time during a workday.
Temporary or transitory injury may occur. Skin Irritation: Moderately
NIOSH RELs: NIOSH’s Recommended Exposure Limits.
irritating; primary irritant; sensitizer. PII or Draize > 0, < 5. Eye Irritation:
PEL-Permissible Exposure Limit: OSHA’s Permissible Exposure Limits.
Moderately to severely irritating and/or corrosive; reversible corneal opacity;
This exposure value means exactly the same as a TLV, except that it is
corneal involvement or irritation clearing in 8-21 days. Draize > 0, < 25. Oral
enforceable by OSHA. The OSHA Permissible Exposure Limits are based
Toxicity LD50 Rat: > 50-500 mg/kg. Dermal Toxicity LD50Rat or Rabbit: >
in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal
200-1000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L.); 3
Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the
(Serious Hazard: Major injury likely unless prompt action is taken and
vacated PELs are indicated. The phrase, “Vacated 1989 PEL,� is placed
medical treatment is given; high level of toxicity; corrosive. Skin Irritation:
next to the PEL that was vacated by Court Order.
Severely irritating and/or corrosive; may destroy dermal tissue, cause skin
SKIN: Used when a there is a danger of cutaneous absorption.
burns, dermal necrosis. PII or Draize > 5-8 with destruction of tissue. Eye
STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a
Irritation: Corrosive, irreversible destruction of ocular tissue; corneal
15-minute time-weighted average (TWA) exposure that should not be
involvement or irritation persisting for more than 21 days. Draize > 80 with
exceeded at any time during a workday, even if the 8-hr TWA is within the
effects irreversible in 21 days. Oral Toxicity LD50 Rat: > 1-50 mg/kg. Dermal
TLV-TWA, PEL-TWA or REL-TWA.
Toxicity LD50Rat or Rabbit: > 20-200 mg/kg. Inhalation Toxicity LC50 4-hrs
TLV-Threshold Limit Value: An airborne concentration of a substance that
Rat: > 0.05-0.5 mg/L.); 4 (Severe Hazard: Life-threatening; major or
represents conditions under which it is generally believed that nearly all
permanent damage may result from single or repeated exposure. Skin
workers may be repeatedly exposed without adverse effect. The duration
Irritation: Not appropriate. Do not rate as a �4�, based on skin irritation alone.
must be considered, including the 8-hour.
Eye Irritation: Not appropriate. Do not rate as a �4�, based on eye irritation
TWA-Time Weighted Average: Time Weighted Average exposure
alone. Oral Toxicity LD50 Rat: < 1 mg/kg. Dermal Toxicity LD50Rat or
concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL)
Rabbit: < 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L).
workday and a 40-hr workweek.
IDLH-Immediately Dangerous to Life and Health: This level represents a
concentration from which one can escape within 30-minutes without
suffering escape-preventing or permanent injury.
AEROSOL GREASE GUN EFFECTIVE DATE: OCTOBER, 2003
PAGE 7 OF 10
DEFINITIONS OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARD
RATINGS (continued): RATINGS (continued):
FLAMMABILITY HAZARD: PHYSICAL HAZARD (continued):
0 (Minimal Hazard-Materials that will not burn in air when exposure to a 2 (continued): Explosives: Division 1.4 � Explosive substances where the
explosive effect are largely confined to the package and no projection of
temperature of 815.5°C [1500°F] for a period of 5 minutes.); 1 (Slight
fragments of appreciable size or range are expected. An external fire must
Hazard-Materials that must be pre-heated before ignition can occur.
not cause virtually instantaneous explosion of almost the entire contents of
Material require considerable pre-heating, under all ambient temperature
the package. Compressed Gases: Pressurized and meet OSHA definition
conditions before ignition and combustion can occur, Including: Materials
but < 514.7 psi absolute at 21.1°C (70°F) [500 psig]. Pyrophorics: No
that will burn in air when exposed to a temperature of 815.5°C (1500°F) for a
Rating. Oxidizers: Packing Group II Solids: any material that, either in
period of 5 minutes or less; Liquids, solids and semisolids having a flash
concentration tested, exhibits a mean burning time of less than or equal to
point at or above 93.3°C [200°F] (e.g. OSHA Class IIIB, or; Most ordinary
the mean burning time of a 2:3 potassium bromate/cellulose mixture and the
combustible materials [e.g. wood, paper, etc.]; 2 (Moderate Hazard-Materials
criteria for Packing Group I are not met. Liquids: any material that exhibits a
that must be moderately heated or exposed to relatively high ambient
mean pressure rise time less than or equal to the pressure rise of a 1:1
temperatures before ignition can occur. Materials in this degree would not,
aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria for
under normal conditions, form hazardous atmospheres in air, but under high
Packing Group I are not met. Unstable Reactives: Substances that may
ambient temperatures or moderate heating may release vapor in sufficient
polymerize, decompose, condense, or self-react at ambient temperature
quantities to produce hazardous atmospheres in air, Including: Liquids
and/or pressure, but have a low potential for significant heat generation or
having a flash-point at or above 37.8°C [100°F]; Solid materials in the form of
explosion. Substances that readily form peroxides upon exposure to air or
course dusts that may burn rapidly but that generally do not form explosive
oxygen at room temperature); 3 (Water Reactivity: Materials that may form
atmospheres; Solid materials in a fibrous or shredded form that may burn
explosive reactions with water. Organic Peroxides: Materials that are
rapidly and create flash fire hazards (e.g. cotton, sisal, hemp; Solids and
capable of detonation or explosive reaction, but require a strong initiating
semisolids that readily give off flammable vapors.); 3 (Serious Hazard-
source, or must be heated under confinement before initiation; or materials
Liquids and solids that can be ignited under almost all ambient temperature
that react explosively with water. Explosives: Division 1.2 � Explosive
conditions. Materials in this degree produce hazardous atmospheres with air
substances that have a fire hazard and either a minor blast hazard or a
under almost all ambient temperatures, or, unaffected by ambient
minor projection hazard or both, but do not have a mass explosion hazard.
temperature, are readily ignited under almost all conditions, including:
Compressed Gases: Pressure > 514.7 psi absolute at 21.1°C (70°F) [500
Liquids having a flash point below 22.8°C [73°F] and having a boiling point at
psig]. Pyrophorics: No Rating. Oxidizers: Packing Group I Solids: any
or above 38°C [100°F] and below 37.8°C [100°F] [e.g. OSHA Class IB and
material that, in either concentration tested, exhibits a mean burning time
IC]; Materials that on account of their physical form or environmental
less than the mean burning time of a 3.:2 potassium bromate/cellulose
conditions can form explosive mixtures with air and are readily dispersed in
mixture. Liquids: Any material that spontaneously ignites when mixed with
air [e.g., dusts of combustible solids, mists or droplets of flammable liquids];
cellulose in a 1:1 ratio, or which exhibits a mean pressure rise time less than
Materials that burn extremely rapidly, usually by reason of self-contained
the pressure rise time of a 1:1 perchloric acid (50%)/cellulose mixture.
oxygen [e.g. dry nitrocellulose and many organic peroxides]); 4 (Severe
Unstable Reactives: Substances that may polymerize, decompose,
Hazard-Materials that will rapidly or completely vaporize at atmospheric
condense or self-react at ambient temperature and/or pressure and have a
pressure and normal ambient temperature or that are readily dispersed in
moderate potential to cause significant heat generation or explosion.); 4
air, and which will burn readily, including: Flammable gases; Flammable
(Water Reactivity: Materials that react explosively with water without
cryogenic materials; Any liquid or gaseous material that is liquid while under
requiring heat or confinement. Organic Peroxides: Materials that are readily
pressure and has a flash point below 22.8°C [73°F] and a boiling point below
capable of detonation or explosive decomposition at normal temperature and
37.8°C [100°F] [e.g. OSHA Class IA; Material that ignite spontaneously
pressures. Explosives: Division 1.1 & 1.2-explosive substances that have a
when exposed to air at a temperature of 54.4°C [130°F] or below [e.g.
mass explosion hazard or have a projection hazard. A mass explosion is
pyrophoric]).
one that affects almost the entire load instantaneously. Compressed Gases:
PHYSICAL HAZARD:
No Rating. Pyrophorics: Add to the definition of Flammability �4�.
0 (Water Reactivity: Materials that do not react with water. Organic Oxidizers: No �4� rating. Unstable Reactives: Substances that may
Peroxides: Materials that are normally stable, even under fire conditions and polymerize, decompose, condense or self-react at ambient temperature
will not react with water. Explosives: Substances that are Non-Explosive. and/or pressure and have a high potential to cause significant heat
Unstable Compressed Gases: No Rating. Pyrophorics: No Rating. generation or explosion.).
Oxidizers: No �0� rating allowed. Unstable Reactives: Substances that will
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
not polymerize, decompose, condense or self-react.); 1 (Water Reactivity:
RATINGS:
Materials that change or decompose upon exposure to moisture. Organic
HEALTH HAZARD: 0 (material that on exposure under fire conditions would
Peroxides: Materials that are normally stable, but can become unstable at
offer no hazard beyond that of ordinary combustible materials); 1 (materials
high temperatures and pressures. These materials may react with water, but
that on exposure under fire conditions could cause irritation or minor residual
will not release energy. Explosives: Division 1.5 & 1.6 substances that are
injury); 2 (materials that on intense or continued exposure under fire
very insensitive explosives or that do not have a mass explosion hazard.
conditions could cause temporary incapacitation or possible residual injury);
Compressed Gases: Pressure below OSHA definition. Pyrophorics: No
3 (materials that can on short exposure could cause serious temporary or
Rating. Oxidizers: Packaging Group III; Solids: any material that in either
residual injury); 4 (materials that under very short exposure could cause
concentration tested, exhibits a mean burning time less than or equal to the
death or major residual injury).
mean burning time of a 3:7 potassium bromate/cellulose mixture and the
FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire
criteria for Packing Group I and II are not met. Liquids: any material that
conditions, including intrinsically noncombustible materials such as
exhibits a mean pressure rise time less than or equal to the pressure rise
concrete, stone, and sand. 1 Materials that must be preheated before
time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing
ignition can occur. Materials in this degree require considerable
Group I and II are not met. Unstable Reactives: Substances that may
preheating, under all ambient temperature conditions, before ignition and
decompose, condense or self-react, but only under conditions of high
combustion can occur 2 Materials that must be moderately heated or
temperature and/or pressure and have little or no potential to cause
exposed to relatively high ambient temperatures before ignition can occur.
significant heat generation or explosive hazard. Substances that readily
Materials in this degree would not under normal conditions form
undergo hazardous polymerization in the absence of inhibitors.);2 (Water
hazardous atmospheres with air, but under high ambient temperatures or
Reactivity: Materials that may react violently with water. Organic Peroxides:
under moderate heating could release vapor in sufficient quantities to
Materials that, in themselves, are normally unstable and will readily undergo
produce hazardous atmospheres with air.
violent chemical change, but will not detonate. These materials may also
react violently with water.
AEROSOL GREASE GUN EFFECTIVE DATE: OCTOBER, 2003
PAGE 8 OF 10
DEFINITIONS OF TERMS (Continued)
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD ECOLOGICAL INFORMATION:
EC is the effect concentration in water. BCF = Bioconcentration Factor,
RATINGS (continued):
which is used to determine if a substance will concentrate in lifeforms which
FLAMMABILITY HAZARD (continued): 3 Liquids and solids that can be
consume contaminated plant or animal matter. TLm = median threshold limit;
ignited under almost all ambient temperature conditions. Materials in this
Coefficient of Oil/Water Distribution is represented by log Kow or log Koc
degree produce hazardous atmospheres with air under almost all ambient
and is used to assess a substance’s behavior in the environment.
temperatures or, though unaffected by ambient temperatures, are readily
ignited under almost all conditions. 4 Materials that will rapidly or REGULATORY INFORMATION:
completely vaporize at atmospheric pressure and normal ambient U.S. and CANADA:
temperature or that are readily dispersed in air and will burn readily. ACGIH: American Conference of Governmental Industrial Hygienists, a
INSTABILITY HAZARD: 0 Materials that in themselves are normally professional association which establishes exposure limits.
stable, even under fire conditions. 1 Materials that in themselves are
This section explains the impact of various laws and regulations on the
normally stable, but that can become unstable at elevated temperatures
material. EPA is the U.S. Environmental Protection Agency. NIOSH is the
and pressures. 2 Materials that readily undergo violent chemical change
National Institute of Occupational Safety and Health, which is the research
at elevated temperatures and pressures. 3 Materials that in themselves
arm of the U.S. Occupational Safety and Health Administration (OSHA).
are capable of detonation or explosive decomposition or explosive
WHMIS is the Canadian Workplace Hazardous Materials Information
reaction, but that require a strong initiating source or that must be heated
System. DOT and TC are the U.S. Department of Transportation and the
under confinement before initiation. 4 Materials that in themselves are
Transport Canada, respectively. Superfund Amendments and
readily capable of detonation or explosive decomposition or explosive
Reauthorization Act (SARA); the Canadian Domestic/Non-Domestic
reaction at normal temperatures and pressures.
Substances List (DSL/NDSL); the U.S. Toxic Substance Control Act
FLAMMABILITY LIMITS IN AIR: Much of the information related to fire (TSCA); Marine Pollutant status according to the DOT; the Comprehensive
and explosion is derived from the National Fire Protection Association Environmental Response, Compensation, and Liability Act (CERCLA or
(NFPA). Flash Point - Minimum temperature at which a liquid gives off Superfund); and various state regulations. This section also includes
sufficient vapors to form an ignitable mixture with air. Autoignition information on the precautionary warnings which appear on the material’s
Temperature: The minimum temperature required to initiate combustion in package label. OSHA - U.S. Occupational Safety and Health Administration.
air with no other source of ignition. LEL - the lowest percent of vapor in air,
EC, European Economic Community).
by volume, that will explode or ignite in the presence of an ignition source.
EUROPE:
UEL - the highest percent of vapor in air, by volume, that will explode or
EINECS: This the European Inventory of Now-Existing Chemical
ignite in the presence of an ignition source.
Substances. The ARD is the European Agreement Concerning the
TOXICOLOGICAL INFORMATION:
International Carriage of Dangerous Goods by Road and the RID are the
Human and Animal Toxicology: Possible health hazards as derived from
International Regulations Concerning the Carriage of Dangerous Goods by
human data, animal studies, or from the results of studies with similar
Rail.
compounds are presented. Definitions of some terms used in this section
are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed
animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed
animals; ppm concentration expressed in parts of material per million parts
3
of air or water; mg/m concentration expressed in weight of substance per
volume of air; mg/kg quantity of material, by weight, administered to a test
subject, based on their body weight in kg. Other measures of toxicity include
TDLo, the lowest dose to cause a symptom and TCLo the lowest
concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo,
LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic
effects. Cancer Information: The sources are: IARC - the International
Agency for Research on Cancer; NTP - the National Toxicology Program,
RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and
CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing
potential to cause human cancer with rankings from 1 to 4. Subrankings
(2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological
Exposure Indices, represent the levels of determinants which are most likely
to be observed in specimens collected from a healthy worker who has been
exposed to chemicals to the same extent as a worker with inhalation
exposure to the TLV.
AEROSOL GREASE GUN EFFECTIVE DATE: OCTOBER, 2003
PAGE 9 OF 10
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