SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET MM 440
Threshold Limited Value
ALDON None established by (ACGIH 1983-84). TXDS: Methylene Blue Chloride
1533 W.Henrietta Rd. Oral-rat LD50: 1180 mg/kg. Oral-rabbit LDLo 1000 mg/kg.
MM 440
Avon, New York 14414 MSDS No.
庐
CORPORATION January 30, 1995
Effective Date
(716) 226-6177
Effects of Overexposure May be harmful by ingestion or skin absorption. May cause irritation. To
the best of our knowledge, the chemical, physical and toxicological
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE properties have not been thoroughly investigated. Specific data is not
available. Exercise appropriate procedures to minimize potential hazards.
Product METHYLENE BLUE CHLORIDE, AQ. SOL'N.
CHEMTREC
1
Health
800-424-9300
Chemical
Emergency and
Basic Blue 9, C.I. 52015
Synonyms INGESTION: If swallowed, if conscious, give one or two glasses of water to
0
Fire
Day 716-226-6177
First Aid Procedures drink, induce vomiting. Repeat until vomit fluid is clear. Call physician
C H N SCl/H O
Formula 0
Reactivity
16 18 3 2 immediately. Never give anything by mouth to an unconscious person.
NFPA
HAZARD RATING SKIN: Flush with water, then wash with mild soap and water. EYES: Flush
HMIS *
Unit Size up to 4 Lt.
LEAST SLIGHT MODERATE HIGH EXTREME thoroughly with water for at least 15 minutes, lifting lower and upper eyelids
0 1 2 3 4 occasionally. Get medical attention. INHALATION: If inhaled as dust or
C.A.S. No. Mixture. See Section II.
mist, remove to fresh air, treat symptomatically and get medical attention.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable Protect from light, excessive
Methylene Blue Chloride * 1% None established.
temperature and heat.
Stable X
Incompatibility
Strong oxidizing materials and reducing agents.
(Materials to Avoid)
WARNING! MAY BE HARMFUL IF SWALLOWED OR
Hazardous When heated to decomposition, emits toxic fumes of oxides of nitrogen
ABSORBED THROUGH SKIN. MAY CAUSE IRRITATION.
(NOx), sulfur (SO x) and hydrogen chloride.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Approx. 0掳C (32掳F) Approx. 1.0 at 20掳C
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) Approx. 100掳C (212掳F) 98.9% X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) 14 mm (water) Ether Greater than 1.
=1)
(
Steps to be taken in case
Vapor Density (Air=1) 0.7 (water)
material is released or spilled Absorb spill in vermiculite, sand, earth, paper towel and place in a
Solubility in Water Complete. suitable container. Wash spill area with soap and water.
Appearance & Odor Dark blue colored liquid; no odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dispose of in an approved incinerator equipped with an afterburner and
% by Volume
Non-flammable (NA). NA -------- --------
(Method Used)
scrubber or contract with a licensed waste disposal agency.
Extinguisher Use any media suitable for extinguishing supporting fire. SECTION VIII SPECIAL PROTECTION INFORMATION
Media
None should be needed in normal laboratory handling. If misty conditions prevail, work
Respiration Protection
(Specify Type) in ventilation hood or wear a NIOSH-approved respirator.
SPECIAL FIREFIGHTING In fire conditions, wear a NIOSH-approved self-contained breathing Not needed. No.
Local Exhaust Special
PROCEDURES Ventilation
apparatus and protective clothing to prevent contact with skin and
Not needed. No.
Mechanical (General) Other
eyes.
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
Other Protective
* Methylene Blue: (CAS No. 61-73-4) Lab coat, proper gloves, eye wash station, safety glasses.
Equipment
Sodium Benzoate, as preservative: (CAS No. 532-32-1)
SECTION IX SPECIAL PRECAUTIONS
Water: (CAS No. 7732-18-5)
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry place. Protect from light.
in Handling & Storing
EXPLOSION HAZARDS Wash thoroughly after handling.
Keep container tightly closed when not in use.
Fire or excessive heat may produce hazardous decomposition Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
products of oxides of nitrogen (NO x) and sulfur (SOx); and
hydrogen chloride. Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 4 1/30/95 Michael Raszeja MR
Coordinator
D.O.T. NON-REGULATED. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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