SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET PP 360
Threshold Limited Value None established. (ACGIH 1983-84). RTECS No. RO3600000
ALDON 1533 W.Henrietta Rd. Toxicity data: Orl-wmn TDLo 100 mg/kg, ivn-man TDLo 1071 mg/kg.
PP 360
Avon, New York 14414 MSDS No.
庐
CORPORATION May 24, 1996
Effective Date
(716) 226-6177
Effects of Overexposure INHALATION: Of dust may cause irritation of mucous membranes. SKIN
AND EYES: Strong irritant. Skin contact may have a corrosive action with
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE dermatitis and possible ulceration from prolonged contact. INGESTION:
Highly toxic. Symptoms of nausea, shock, convulsions and collapse occur
POTASSIUM BINOXALATE
Product CHEMTREC rapidly. POISON
3
Health
800-424-9300
Chemical
Emergency and
Potassium Acid Oxalate, Salt of Sorrel
Synonyms 0 INHALATION: Remove to fresh air. If symptoms of illness develop, get
Fire
Day 716-226-6177
First Aid Procedures medical attention. SKIN: Flush thoroughly with water, then wash with mild
KOOCCOOH鈥2 O
Formula 1
Reactivity
NFPA soap and water. EYES: Flush thoroughly with water for 15 minutes, lifting
HAZARD RATING HMIS * lower and upper eyelids occasionally. Get prompt medical attention.
Unit Size 100, 500 grams
LEAST SLIGHT MODERATE HIGH EXTREME INGESTION: If swallowed, if conscious, give large quantities of milk and
0 1 2 3 4 DO NOT induce vomiting. Follow with more milk. Call physician
C.A.S. No. 127-95-7 (Anhydrous)
immediately. Never give anything by mouth to an unconscious person.
SECTION II INGREDIENTS OF MIXTURES
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
Reducing agents, water, acids, powdered
Potassium Binoxalate 100% None established.
metals. Excessive temperature and heat.
Stable X
DANGER! POISON Incompatibility Silver compounds, strong oxidizing material, concentrated sulfuric acid, alkalies.
(Materials to Avoid) Reacts explosively with chlorites and hypochlorites.
MAY BE FATAL IF SWALLOWED.
Hazardous When heated to decomposition yields-carbon monoxide, carbon dioxide,
CAUSES SKIN AND EYE IRRITATION.
water and formic acid.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Decomposes at 460掳C (860掳F) 2.088 at 20掳C
Specific Gravity (H2O = 1)
Melting Point (掳F)
May Occur Will Not Occur Not applicable.
Percent Volatile
Decomposes. Non-volatile (NA).
Boiling Point (掳F) X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Negligible as solid. Non-volatile (NA).
=1)
(
Steps to be taken in case
Data not listed.
Vapor Density (Air=1) Recover if possible for reuse. Carefully sweep up without
material is released or spilled producing dust and place in a suitable container.
3 grams per 100 mL. water at 20掳C.
Solubility in Water
Wash spill area with soap and water.
White transparent crystals or white powder; no odor. Hygroscopic.
Appearance & Odor
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
% by Volume
Non-flammable (NA). NA -------- --------
(Method Used)
Dispose of in an approved incinerator or contract with a licensed waste disposal service.
Extinguisher Water spray; dry chemical (ABC); 鈥淎lcohol鈥? foam or carbon dioxide (CO2). SECTION VIII SPECIAL PROTECTION INFORMATION
Media
Respiration Protection None should be needed in normal laboratory handling. If dusty conditions prevail,
(Specify Type) work in ventilation hood or wear a NIOSH/MSHA-approved respirator.
SPECIAL FIREFIGHTING
Recommended. No.
Local Exhaust Special
PROCEDURES Ventilation Recommended. No.
Mechanical (General) Other
Foam or water on molten Potassium binoxalate may cause frothing. In fire
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
conditions, wear a NIOSH/MSHA-approved self-contained breathing
apparatus; wear goggles if eye protection is not provided. Other Protective
Goggles, smock, apron, eye wash station, proper gloves, ventilation hood.
Equipment
(1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5, GUIDE PAGE NO. 53)
SECTION IX SPECIAL PRECAUTIONS
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry place. Separate from oxidizable materials.
in Handling & Storing
Use with adequate ventilation. Wash thoroughly after handling.
EXPLOSION HAZARDS Dangerous, by chemical reaction; powerful oxidizing agent. When
Keep container tightly closed when not in use.
involved in fire, Potassium binoxalate emits highly toxic and irritating
Read label on container before using. Do not wear contact lenses when working with chemicals.
fumes. Decomposition products may include carbon monoxide and Other Precautions
formic acid. Explosion hazard: Moderate by chemical reaction with
water, acids, powdered metals. Disaster hazard: Dangerous; will
Avoid breathing dust. Avoid contact with skin, eyes and clothing. Remove and wash contaminated clothing.
react with water or steam to produce heat and toxic fumes; can react
vigorously with reducing materials.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date
No. 4 MR
05/24/96 Michael Raszeja Coordinator
Toxic solid, n.o.s., (Potassium binoxalate) 6.1, UN 3288, PG III
D.O.T. The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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