SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET PP 99
Threshold Limited Value
ALDON None established by (ACGIH 1992-93). Examples of TWA for some fractions: Gasoline (CAS # 8006-61-9)
1533 W.Henrietta Rd. 300 ppm or 900 mg/m3 ; STEL: 500 ppm, 1500 mg/m3 (AIR).
PP 99
Avon, New York 14414 MSDS No.
庐
CORPORATION December 31, 1996
Effective Date
(716) 226-6177 EYES: May cause severe irritation. SKIN: Causes skin irritation and rarely
Effects of Overexposure
skin photosensitization, dryness. INHALATION: Excessive inhalation
causes headache, dizziness and nausea. INGESTION: Specific data for
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE this product is not available. Ingestion of product may result in vomiting,
aspiration 鈥渂reathing" of vomitus into lungs must be avoided as even small
Product PETROLEUM CRUDE OIL CHEMTREC quantities may result in aspiration pneumonitis.
3 Health 1
800-424-9300
Chemical
Emergency and EYES: Flush thoroughly with water for at least 15 minutes, lifting lower and
1 0
Earth Oil, Seneca Oil
Synonyms 2
Fire
Day 716-226-6177 upper eyelids occasionally. Get immediate medical attention. SKIN: Flush
First Aid Procedures
Formula Mixture of Hydrocarbons with water, then wash with mild soap and water. Follow by applying skin
0
Reactivity
NFPA cream. INHALATION: Remove to fresh air. If not breathing, give artificial
HAZARD RATING HMIS *
Unit Size up to 4 Lt. respiration. If breathing is difficult, give oxygen. Get medical attention.
LEAST SLIGHT MODERATE HIGH EXTREME
INGESTION: Drink two glasses of water. Do NOT induce vomiting. Do not
0 1 2 3 4
C.A.S. No. 8002-05-9 give anything by mouth to an unconscious person. See a physician
SECTION II INGREDIENTS OF MIXTURES immediately.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
Petroleum Crude Oil 100% None established. Heat, sparks, open flame and fire.
Stable X
Incompatibility
Strong oxidizing materials.
(Materials to Avoid)
WARNING! FLAMMABLE LIQUID! HARMFUL OR FATAL IF SWALLOWED.
Hazardous
MAY CAUSE IRRITATION TO SKIN, EYES AND MUCOUS MEMBRANES. Smoke, acrid and toxic fumes, carbon dioxide and carbon monoxide.
Decomposition Products
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Variable (not determined). 0.780-0.970
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) Variable (wide range). Approx. 100%
by Volume (%) X
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Data not available. Ether Varies over wide range.
=1)
(
Steps to be taken in case
Vapor Density (Air=1) Data not available.
Recover for use if not contaminated. Absorb spill in vermiculite, sand,
material is released or spilled
earth, paper towel and place in a suitable container. Wash spill area
Solubility in Water Negligible.
with soap and water.
Appearance & Odor Thick, flammable liquid, dark yellow to brown or green-black.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dispose of in an approved incinerator equipped with an afterburner and
-7 to 32掳C (20-90掳F) N/A
% by Volume
(Method Used)
scrubber or contract with a licensed waste disposal system.
Extinguisher
SECTION VIII SPECIAL PROTECTION INFORMATION
Foam; carbon dioxide (CO ); dry chemical; water spray.
Media 2
Respiration Protection
In the laboratory work in ventilation hood or wear a NIOSH/MSHA-approved respirator.
(Specify Type)
SPECIAL FIREFIGHTING
Yes. No.
Local Exhaust Special
PROCEDURES Ventilation Explosion proof. Adequate to maintain below exposure limit.
Mechanical (General) Other
If involved in fire situation, wear a NIOSH/MSHA approved self-contained
breathing apparatus and full protective clothing.
Protective Gloves Eye Protection
Rubber. Chemical safety glasses.
Other Protective
Lab coat, apron, eye wash station, proper gloves, fire extinguisher.
Equipment
SECTION IX SPECIAL PRECAUTIONS
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 27)
Precautions to be Taken Store in a cool, dry area away from heat sparks and open flame. There is
UNUSUAL FIRE AND insufficient data in the published literature to recommend complete laboratory
in Handling & Storing
protective equipment for this product. Special precautions must be used in
EXPLOSION HAZARDS Keep container tightly closed when not in use.
storage, use and handling.
Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
Moderately dangerous when heated to decomposition, it emits toxic
fumes; it can react with oxidizing materials. Use with adequate ventilation. Avoid prolonged or repeated contact with skin.
Remove and wash contaminated clothing.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
Approved
Revision Date 12/31/96 Michael Raszeja MR
No. 3 Coordinator
D.O.T. Petroleum crude oil, 3, UN 1267, PG II The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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