SECTION V HEALTH HAZARD DATA
MATERIAL SAFETY DATA SHEET MM 595
Threshold Limited Value Methanol TWA: SKIN 200 ppm; 262 mg/m ; Ethyl Acetate TWA: 400 ppm; 1440 mg/m3
3
ALDON 1533 W.Henrietta Rd. (AIR). a-Naphthol: TXDS: Oral-rabbit LD50: 880 mg/kg. IRDS: eye-rbt 1 mg SEV.
MM 595
Avon, New York 14414 MSDS No.
庐
CORPORATION December 16, 1996
Effective Date
(716) 226-6177
Effects of Overexposure INGESTION: Causes dizziness, drowsiness, decreased reaction, euphoria,
nausea, vomiting, staggering gait, and coma. SKIN ABSORPTION: No
evidence of adverse effects from available information. INHALATION: May
SECTION I NAME 24 HOUR EMERGENCY ASSISTANCE
cause dizziness, drowsiness, nausea and vomiting. SKIN CONTACT:
Product MOLISCH鈥橲 REAGENT Dehydration of skin. EYE CONTACT: May cause blindness.
CHEMTREC
3 Health 2
800-424-9300
Chemical
Emergency and
Molisch Test Solution 0 0 INGESTION: Do NOT give anything by mouth to a an unconscious or very
Synonyms 3
Fire
Day 716-226-6177 drowsy person. If conscious, have victim drink several glasses of water.
First Aid Procedures Call physician or Poison Control Center immediately. Induce vomiting if
Mixture. *
Formula 0
Reactivity
NFPA advised by physician or Poison Control Center. SKIN: Flush with water,
HAZARD RATING HMIS * then wash with mild soap and water. INHALATION: Remove to fresh air.
up to 4 Lt.
Unit Size
Give artificial respiration if not breathing. If breathing is difficult, give
LEAST SLIGHT MODERATE HIGH EXTREME
oxygen. Obtain medical attention. EYES: Flush thoroughly with water for
0 1 2 3 4
C.A.S. No. Mixture. See Section II.
at least 15 minutes, lifting upper and lower eyelids occasionally. Get
SECTION II INGREDIENTS OF MIXTURES medical attention.
SECTION VI REACTIVITY DATA
Principal Component(s) % TLV Units
Conditions to Avoid
Stability Unstable
Excessive temperature, heat, fire and
伪-Naphthol: (CAS No. 90-15-3) 5% None established. ignition source. Protect from light.
Stable X
TWA: 1000 ppm;1880 mg/m3
* Ethyl Alcohol: (CAS No. 64-17-5) 95% Incompatibility Darkens on exposure to light. Strong oxidizing materials. Strong bases,
halogenated materials, acid chlorides, acid anhydrides.
(Materials to Avoid)
DANGER! FLAMMABLE LIQUID! HARMFUL IF INHALED, SWALLOWED, OR ABSORBED
Hazardous Thermal decomposition or burning can produce carbon monoxide and/or
THROUGH SKIN. CAUSES IRRITATION TO SKIN, EYES AND MUCOUS MEMBRANES.
Decomposition Products carbon dioxide.
SECTION III PHYSICAL DATA
Conditions to Avoid
Hazardous Polymerization
Specific Gravity (H2O = 1)
Melting Point (掳F) Freezing point -80掳C (-112掳F) 0.795 @ 20/20掳C
May Occur Will Not Occur Not applicable.
Percent Volatile
Boiling Point (掳F) 75-80掳C (163-174掳F) 100% X
by Volume (%)
Evaporation Rate
SECTION VII SPILL OR LEAK PROCEDURES
Vapor Pressure (mm Hg) Ca 42 @ 68掳F n-Butyl Alc. =1) 4.1
(
Steps to be taken in case Remove all sources of ignition, provide adequate ventilation. For
Vapor Density (Air=1) Ca 1.6
material is released or spilled small spills, dilute with water and flush to sewer with copious amounts
Solubility in Water Complete. of water or absorb with an inert dry material and place in a suitable
container for disposal. Wash spill area with soap and water.
Appearance & Odor Clear, colorless, mobile liquid; mild characteristic odor.
Discharge, treatment, or disposal may be subject to Federal, State or Local laws.
Waste Disposal Method
SECTION IV FIRE AND EXPLOSION HAZARD DATA These disposal guidelines are intended for the disposal of catalog-size quantities only.
Lower
Flammable Limits in Air Upper
Flash Point
Dispose of in an approved incinerator or contract with a licensed waste
% by Volume
(Method Used) 47掳F (8.3掳C) TCC. 3.3 (Et. Alc.) 19.0 (Et. Alc.)
disposal agency.
Extinguisher
Water spray; carbon dioxide (CO ); dry chemical; alcohol-type, or universal-type foams. SECTION VIII SPECIAL PROTECTION INFORMATION
Media 2
None needed in normal laboratory handling. If misty conditions prevail,
Respiration Protection
work in ventilation hood or wear a NIOSH/MSHA respirator.
(Specify Type)
SPECIAL FIREFIGHTING
Recommended. No.
Local Exhaust Special
PROCEDURES Ventilation
In fire conditions, wear a NIOSH/MSHA-approved self-contained
Recommended. Adequate to maintain below exposure limit.
Mechanical (General) Other
breathing apparatus and full protective clothing.
Protective Gloves Eye Protection
* Denaturants: Rubber. Chemical safety glasses.
Ethyl Acetate: (CAS No. 141-78-6)
Other Protective
Methanol: (CAS No. 67-56-1) Smock, apron, eye wash station, goggles, fire extinguisher, proper gloves.
Equipment
Methyl Isobutyl Ketone: (CAS No. 108-10-1)
SECTION IX SPECIAL PRECAUTIONS
Rubber Hydrocarbon Solvent: (CAS No. 64742-89-8)
Precautions to be Taken
UNUSUAL FIRE AND Store in a cool, dry well-ventilated place away from oxidizing materials and
in Handling & Storing
Vapors formed from this product may travel or be moved by air
EXPLOSION HAZARDS fire hazards. Wash thoroughly after handling.
Keep container tightly closed when not in use.
currents and ignited by pilot lights, other flames, smoking, sparks,
heaters, electrical equipment, static discharge, or other ignition Read label on container before using. Do not wear contact lenses when working with chemicals.
Other Precautions
sources at location distant from handling point. CAUTION: Flame
Protect from light. Use with adequate ventilation. Avoid contact with skin,
may not be visible in daylight. Fire or excessive heat may produce
eyes and clothing. Do not take internally. Avoid inhalation. Remove and
hazardous decomposition products; can react vigorously with
wash contaminated clothing.
oxidizing materials.
For laboratory use only. Not for drug, food or household use. Keep out of reach of children.
Chemical Safety
(1993 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.6, GUIDE PAGE NO. 26) Approved
Revision Date Michael Raszeja MR
No. 5 12/16/96 Coordinator
D.O.T. DENATURED ALCOHOL, (SOLUTION), 3, NA 1987, PG II The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supplement to other information
gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these
Approved by U.S. Department of Labor "essentially similar" to form OSHA-20 materials and the safety and health of employees. * Hazardous Materials Industrial Standards. Printed on recycled paper.
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