Conoco Rock Drill Oil
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: Conoco Rock Drill Oil
MSDS Code: 775697
Synonyms: Conoco Rock Drill Oil 32
Conoco Rock Drill Oil 46
Conoco Rock Drill Oil 68
Conoco Rock Drill Oil 100
Conoco Rock Drill Oil 150
Conoco Rock Drill Oil 220
Conoco Rock Drill Oil 320
Intended Use: Rock drill oil
Responsible Party: ConocoPhillips Lubricants
600 N. Dairy Ashford
Houston, Texas 77079-1175
Customer Service: 888-766-7676
Technical Information: 800-255-9556
MSDS Information: Internet: http://w3.conocophillips.com/NetMSDS/
Emergency Telephone Numbers: Chemtrec: 800-424-9300 (24 Hours)
California Poison Control System: 800-356-3219
2. HAZARDS IDENTIFICATION
NFPA
Emergency Overview
This material is not considered hazardous according to OSHA criteria.
Appearance: Clear and bright
Physical Form: Liquid
Odor: Characteristic petroleum
Potential Health Effects
Eye: Contact may cause mild eye irritation including stinging, watering, and redness.
Skin: Contact may cause mild skin irritation including redness and a burning sensation. Prolonged or repeated contact can defat the
skin, causing drying and cracking of the skin, and possibly dermatitis (inflammation).No harmful effects from skin absorption are
expected.
Inhalation (Breathing): Expected to have a low degree of toxicity by inhalation.
Ingestion (Swallowing): No harmful effects expected from ingestion.
Signs and Symptoms: Effects of overexposure may include irritation of the digestive tract nausea and diarrhea Inhalation of oil mist or
vapors at elevated temperatures may cause respiratory irritation.
Pre-Existing Medical Conditions: Conditions aggravated by exposure may include skin disorders
See Section 11 for additional Toxicity Information.
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Date of Issue: 26-Feb-2007 Status: Final
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Date of Issue: 26-Feb-2007 Status: Final
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3. COMPOSITION / INFORMATION ON INGREDIENTS
NON-HAZARDOUS COMPONENTS
Component CAS Concentration (wt %)
Lubricant Base Oil (Petroleum) VARIOUS >95
Additives PROPRIETARY <5
4. FIRST AID MEASURES
Eye: If irritation or redness develops from exposure, flush eyes with clean water. If symptoms persist, seek medical attention.
Skin: Remove contaminated shoes and clothing and cleanse affected area(s) thoroughly by washing with mild soap and water or a
waterless hand cleaner. If irritation or redness develops and persists, seek medical attention.
Inhalation (Breathing): First aid is not normally required. If breathing difficulties develop, move victim away from source of exposure
and into fresh air. Seek immediate medical attention.
Ingestion (Swallowing): First aid is not normally required; however, if swallowed and symptoms develop, seek medical attention.
Notes to Physician: Acute aspirations of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients
who aspirate these oils should be followed for the development of long-term sequelae. Inhalation exposure to oil mists below current
workplace exposure limits is unlikely to cause pulmonary abnormalities.
5. FIRE-FIGHTING MEASURES
NFPA 704 Hazard Class
Health: 1 Flammability: 1 Instability: 0 (0-Minimal, 1-Slight, 2-Moderate, 3-Serious, 4-Severe)
Unusual Fire & Explosion Hazards: This material may burn, but will not ignite readily. If container is not properly cooled, it can rupture
in the heat of a fire. Vapors are heavier than air and can accumulate in low areas.
Extinguishing Media: Dry chemical, carbon dioxide, foam, or water spray is recommended. Water or foam may cause frothing of
materials heated above 212掳F. Carbon dioxide can displace oxygen. Use caution when applying carbon dioxide in confined spaces.
Fire Fighting Instructions: For fires beyond the incipient stage, emergency responders in the immediate hazard area should wear
bunker gear. When the potential chemical hazard is unknown, in enclosed or confined spaces, or when explicitly required by DOT, a
self contained breathing apparatus should be worn. In addition, wear other appropriate protective equipment as conditions warrant (see
Section 8).
Isolate immediate hazard area, keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Move
undamaged containers from immediate hazard area if it can be done with minimal risk.
Water spray may be useful in minimizing or dispersing vapors and to protect personnel. Cool equipment exposed to fire with water, if it
can be done with minimal risk. Avoid spreading burning liquid with water used for cooling purposes.
See Section 9 for Flammable Properties including Flash Point and Flammable (Explosive) Limits
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: This material may burn, but will not ignite readily. Keep all sources of ignition away from spill/release.
Spill precautions: Stay upwind and away from spill/release. Notify persons down wind of the spill/release, isolate immediate hazard
area and keep unauthorized personnel out. Stop spill/release if it can be done with minimal risk. Wear appropriate protective equipment,
including respiratory protection, as conditions warrant (see Section 8).
Environmental precautions: Prevent spilled material from entering sewers, storm drains, other unauthorized drainage systems, and
natural waterways. Dike far ahead of spill for later recovery or disposal. Spilled material may be absorbed into an appropriate
absorbent material.
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Date of Issue: 26-Feb-2007 Status: Final
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Methods for cleaning up: Immediate cleanup of any spill is recommended. Notify fire authorities and appropriate federal, state, and
local agencies. If spill of any amount is made into or upon navigable waters, the contiguous zone, or adjoining shorelines, notify the
National Response Center (phone number 800-424-8802).
7. HANDLING AND STORAGE
Handling: Do not enter confined spaces such as tanks or pits without following proper entry procedures such as ASTM D-4276 and
29CFR 1910.146. The use of appropriate respiratory protection is advised when concentrations exceed any established exposure limits
(see Section 8).
Do not wear contaminated clothing or shoes. Use good personal hygiene practices.
"Empty" containers retain residue and may be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such
containers to heat, flame, sparks, or other sources of ignition. They may explode and cause injury or death. "Empty" drums should be
completely drained, properly bunged, and promptly shipped to the supplier or a drum reconditioner. All containers should be disposed
of in an environmentally safe manner and in accordance with governmental regulations.
Before working on or in tanks which contain or have contained this material, refer to OSHA regulations, ANSI Z49.1, and other
references pertaining to cleaning, repairing, welding, or other contemplated operations.
Storage: Keep container(s) tightly closed. Use and store this material in cool, dry, well-ventilated areas away from heat and all
sources of ignition. Store only in approved containers. Keep away from any incompatible material (see Section 10). Protect
container(s) against physical damage.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component ACGIH OSHA Other:
TWA: 5mg/m3 TWA: 5 mg/m3
Lubricant Base Oil (Petroleum) ---
STEL: 10 mg/m3 as Oil Mist, if Generated
as Oil Mist, if Generated
Note: State, local or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or
similar professional, or your local agencies, for further information.
Engineering controls: If current ventilation practices are not adequate to maintain airborne concentrations below the established
exposure limits additional engineering controls may be required.
Personal Protective Equipment (PPE):
Eye/Face: Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended. Depending
on conditions of use, a face shield may be necessary.
Skin: The use of gloves impervious to the specific material handled, such as nitrile, is advised to prevent skin contact and
possible irritation (see manufacturers literature for information on permeability).
Respiratory: A NIOSH certified air purifying respirator with a Type 95 (R or P) particulate filter may be used under conditions
where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited (see manufacturer's respirator selection guide). Use a NIOSH approved
self-contained breathing apparatus (SCBA) or equivalent operated in a pressure demand or other positive pressure mode if there
is potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators
may not provide adequate protection.
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed
whenever workplace conditions warrant a respirator's use.
Other Protective Equipment: A source of clean water should be available in the work area for flushing eyes and skin.
Impervious clothing should be worn as needed.
Suggestions for the use of specific protective materials are based on readily available published data. Users should check with
specific manufacturers to confirm the performance of their products.
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Date of Issue: 26-Feb-2007 Status: Final
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9. PHYSICAL AND CHEMICAL PROPERTIES
Note: Unless otherwise stated, values are determined at 20掳C (68掳F) and 760 mm Hg (1 atm).
Appearance: Clear and bright
Physical Form: Liquid
Odor: Characteristic petroleum
Odor Threshold: No data
pH: Not applicable
Vapor Pressure: <1
Vapor Density (air=1): >1
Boiling Point/Range: No data
Melting/Freezing Point: <5掳F / <-15掳C
Pour Point: <5掳F / <-15掳C
Solubility in Water: Insoluble
Partition Coefficient (n-octanol/water) (Kow): No data
Specific Gravity: 0.85 - 0.88 @ 60潞F (15.6潞C)
Bulk Density: 7.2 - 7.5 lbs/gal
Viscosity: 5.6 - 26 cSt @ 100掳C; 30 - 350 cSt @ 40掳C
Percent Volatile: Negligible
Evaporation Rate (nBuAc=1): <1
Flash Point: >320掳F / >160掳C
Test Method: Pensky-Martens Closed Cup (PMCC), ASTM D93, EPA 1010
LEL (vol % in air): No data
UEL (vol % in air): No data
Autoignition Temperature: No data
10. STABILITY AND REACTIVITY
Stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure.
Conditions to Avoid: Extended exposure to high temperatures can cause decomposition.
Materials to Avoid (Incompatible Materials): Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products: Combustion can yield carbon, nitrogen and sulfur oxides.
Hazardous Polymerization: Will not occur.
11. TOXICOLOGICAL INFORMATION
Chronic Data:
Lubricant Base Oil (Petroleum)
Carcinogenicity: The petroleum base oils contained in this product have been highly refined by a variety of processes
including solvent extraction, hydrotreating, and/or dewaxing to remove aromatics and improve performance characteristics.
They contain low concentrations of PAH's and none have been identified as a carcinogen by NTP, IARC or OSHA.
Acute Data:
Component Oral LD50 Dermal LD50 Inhalation LC50
Lubricant Base Oil (Petroleum) >5 g/kg >2 g/kg No Data
Oleic Acid 74 g/kg (rat) No data available. No data available.
12. ECOLOGICAL INFORMATION
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Date of Issue: 26-Feb-2007 Status: Final
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12. ECOLOGICAL INFORMATION
Lubricant oil basestocks are complex mixtures of hydrocarbons (primarily branched chain alkanes and cycloalkanes) ranging in carbon
number from C15 to C50. The aromatic hydrocarbon content of these mixtures varies with the severity of the refining process. White
oils have negligible levels of aromatic hydrocarbons, whereas significant proportions are found in unrefined basestocks. Olefins are
found only at very low concentrations. Volatilization is not significant after release of lubricating oil basestocks to the environment due to
the very low vapor pressure of the hydrocarbon constituents. In water, lubricating oil basestocks will float and will spread at a rate that
is viscosity dependent. Water solubilities are very low and dispersion occurs mainly from water movement with adsorption by sediment
being the major fate process. In soil, lubricating oil basestocks show little mobility and adsorption is the predominant physical process.
Both acute and chronic ecotoxicity studies have been conducted on lubricant base oils. Results indicate that the acute aquatic toxicities
to fish, Daphnia, Ceriodaphnia and algal species are above 1000 mg/l using either water accommodated fractions or oil in water
dispersions. Since lubricant base oils mainly contain hydrocarbons having carbon numbers in the range C15 to C50, it is predicted that
acute toxicity would not be observed with these substances due to low water solubility. Results from chronic toxicity tests show that the
no observed effect level (NOEL) usually exceeds 1000 mg/l for lubricant base oils with the overall weight of experimental evidence
leading to the conclusion that lubricant base oils do not cause chronic toxicity to fish and invertebrates.
Large volumes spills of lubricant base oils into water will produce a layer of undissolved oil on the water surface that will cause direct
physical fouling of organisms and may interfere with surface air exchange resulting in lower levels of dissolved oxygen. Petroleum
products have also been associated with causing taint in fish even when the latter are caught in lightly contaminated environments.
Highly refined base oils sprayed onto the surface of eggs will result in a failure to hatch.
Extensive experience from laboratory and field trials in a wide range of crops has confirmed that little or no damage is produced as a
result of either aerosol exposure or direct application of oil emulsion to the leaves of crop plants. Base oils incorporated into soil have
resulted in little or no adverse effects on seed germination and plant growth at contamination rates up to 4%.
13. DISPOSAL CONSIDERATIONS
The generator of a waste is always responsible for making proper hazardous waste determinations and needs to consider state and
local requirements in addition to federal regulations.
This material, if discarded as produced, would not be a federally regulated RCRA "listed" hazardous waste and is not believed to exhibit
characteristics of hazardous waste. See Sections 7 and 8 for information on handling, storage and personal protection and Section 9
for physical/chemical properties. It is possible that the material as produced contains constituents which are not required to be listed in
the MSDS but could affect the hazardous waste determination. Additionally, use which results in chemical or physical change of this
material could subject it to regulation as a hazardous waste.
This material under most intended uses would become "Used Oil" due to contamination by physical or chemical impurities. Whenever
possible, Recycle Used Oil in accordance with applicable federal and state or local regulations. Container contents should be
completely used and containers should be emptied prior to discard.
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation (DOT)
Shipping Description: Not regulated
Note: If shipped by land in a packaging having a capacity of 3,500 gallons or more, the provisions of
49 CFR, Part 130 apply. (Contains oil)
International Maritime Dangerous Goods (IMDG)
Shipping Description: Not regulated
Note: Additional Federal compliance requirements may apply. See 49 CFR 171.12.
International Civil Aviation Org. / International Air Transport Assoc. (ICAO/IATA)
UN/ID #: Not regulated
Note: Additional Federal compliance requirements may apply. See 49 CFR 171.11.
LTD. QTY Passenger Aircraft Cargo Aircraft Only
Packaging Instruction #: --- --- ---
Max. Net Qty. Per Package: --- --- ---
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Date of Issue: 26-Feb-2007 Status: Final
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15. REGULATORY INFORMATION
CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs (in pounds):
This material does not contain any chemicals subject to the reporting requirements of SARA 302 and 40 CFR 372.
CERCLA/SARA - Section 311/312 (Title III Hazard Categories)
Acute Health: No
Chronic Health: No
Fire Hazard: No
Pressure Hazard: No
Reactive Hazard: No
CERCLA/SARA - Section 313 and 40 CFR 372:
This material does not contain any chemicals subject to the reporting requirements of SARA 313 and 40 CFR 372.
EPA (CERCLA) Reportable Quantity (in pounds):
This material does not contain any chemicals with CERCLA Reportable Quantities.
California Proposition 65:
This material does not contain any chemicals which are known to the State of California to cause cancer, birth defects or other
reproductive harm.
Canadian Regulations:
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS
contains all the information required by the CPR.
WHMIS Hazard Class
None
National Chemical Inventories:
All components are either listed on the US TSCA Inventory, or are not regulated under TSCA.
All components are listed on the Canadian DSL.
U.S. Export Control Classification Number: EAR99
16. OTHER INFORMATION
Issue Date: 26-Feb-2007
Status: Final
Revised Sections or Basis for Revision: Periodic review and update
MSDS Code: 775697
MSDS Legend:
ACGIH = American Conference of Governmental Industrial Hygienists; CAS = Chemical Abstracts Service Registry; CEILING = Ceiling Limit (15
minutes); CERCLA = The Comprehensive Environmental Response, Compensation, and Liability Act; EPA = Environmental Protection Agency; IARC =
International Agency for Research on Cancer; LEL = Lower Explosive Limit; NE = Not Established; NFPA = National Fire Protection Association; NTP =
National Toxicology Program; OSHA = Occupational Safety and Health Administration; PEL = Permissible Exposure Limit (OSHA); SARA = Superfund
Amendments and Reauthorization Act; STEL = Short Term Exposure Limit (15 minutes); TLV = Threshold Limit Value (ACGIH); TWA = Time Weighted
Average (8 hours); UEL = Upper Explosive Limit; WHMIS = Worker Hazardous Materials Information System (Canada)
Disclaimer of Expressed and implied Warranties:
The information presented in this Material Safety Data Sheet is based on data believed to be accurate as of the date this Material
Safety Data Sheet was prepared. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR
PURPOSE, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OR
COMPLETENESS OF THE INFORMATION PROVIDED ABOVE, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS
INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. No
responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices.
The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own
determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use.
In addition, no authorization is given nor implied to practice any patented invention without a license.
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