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MSDS Material Safety Data Sheet
CAS

000111-40-0

File Name: tra-con_com---2101.asp
         www.tra-con.com

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 6/28/2002
TRA-BOND 2101 Hardener
Revision Date: 6/11/2002
TRA-CON, INC.
Revision: C
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Diethylene triamine 000111-40-0 25 - 35 -- -- -- -- -- --

1 4.2 -- -- -- --


COMMENTS:
None.



Proprietary Epoxy polyamine adduct NJ 05995500- 55 - 65
(H1916U)

Non-hazardous ingredients -- 5 - 15



3. HAZARDS IDENTIFICATION

Effects of Overexposure Eye or mouth contact may cause serious burns; material is also a strong sensitizer.

4. FIRST AID MEASURES

Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; do NOT induce vomitting if swallowed; get
medical attention.

5. FIREFIGHTING MEASURES

Flashpoint > 200掳F
Flashpoint Method CC
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A

6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material, or scrape up, and

QAF-1058 Rev B Date Printed: 6/28/2002 Page 1 of 9 2101 Hardener
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions, or use detergents.

7. HANDLING AND STORAGE
Handling and Storage For industrial use only. WARNING: May cause sensitization, irritation or other allergic
responses. Avoid eye and/or skin contact and prolonged inhalation of vapors.
Special Sensitivity Store in a cool place in closed containers.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Required
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Straw Yellow, ammoniacal odor.
Boiling Point (掳F) > 300
Solubility in Water partial
Specific Gravity (H2O=1) 1.1
Evaporation Rate (BuAc=1) low
Vapor Pressure (mm Hg.) <1
Vapor Density (air = 1) >2
Percent Volatile <1

10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid contact with metals corroded by liquid amines; avoid high temperatures.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, phenol.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) Chlorinated compounds; exotherms when used to cure epoxy resin.

11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 > 1080 mg/kg
Dermal, LD50 > 1090 mg/kg

12. ECOLOGICAL INFORMATION

Not available

13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.

14. TRANSPORTATION INFORMATION
QAF-1058 Rev B Date Printed: 6/28/2002 Page 2 of 9 2101 Hardener
Not Applicable

15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.

STATE LAWS:

FLORIDA TOXIC SUBSTANCE LIST
000111-40-0 Diethylene 25 - 35
triamine




MASSACHUSETTS TOXIC SUBSTANCE LIST
000111-40-0 Diethylene triamine 25 - 35


The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
16. OTHER INFORMATION

H: 2 F: 1 R: 0
MSDS Date: 6/11/2002 Revision: C HMIS Coding:




QAF-1058 Rev B Date Printed: 6/28/2002 Page 3 of 9 2101 Hardener
www.tra-con.com

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 6/28/2002
TRA-BOND 2101 Pre-Mixed and Frozen
Revision Date: 6/11/2002
TRA-CON, INC.
Revision: C
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Silica,amorphous,fumed, crystilline-free 112945-52-5 <5


Poly(oxy(methyl-1,2-ethanediyl)),a- 026142-30-3 20 - 30
(oxiranylmethyl)-w-(oxiranylmethoxy)-

1,2-Ethanediamine, N-(2-aminoethyl)- 000111-40-0 1 - 10



Phenol,4,4'-(1-methylethylidene)bis-, 025036-25-3 50 - 60
polymer with 2,2'-((1-
methylethylidene)bis(4,1-
phenyleneoxymethylene))bis(oxira
Proprietary Epoxy polyamine adduct NJ 05995500- 5 - 15
(H1916U)

Non-hazardous ingredients -- <5



3. HAZARDS IDENTIFICATION

Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation.

4. FIRST AID MEASURES

Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; induce vomitting if large amount
swallowed.

5. FIREFIGHTING MEASURES
Flashpoint 310掳F
Flashpoint Method PMCC
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Use self-contained breathing apparatus.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A

QAF-1058 Rev B Date Printed: 6/28/2002 Page 4 of 9 2101 Pre-Mixed and Frozen
UEL N/A

6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material or scrape up and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions or use detergents.

7. HANDLING AND STORAGE
Handling and Storage For industrial use only. WARNING: May cause sensitization, irritation or other allergic
responses. Avoid eye and/or skin contact and prolonged inhalation of vapors.
Special Sensitivity Store in freezer at minium -40掳F. Thaw cartridges in upright position, dispensing tip
up, to release air in tip cap, if any.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Clear, light hazy , mild odor.
Boiling Point (掳F) >392
Solubility in Water none
Specific Gravity (H2O=1) 1.5
Evaporation Rate (BuAc=1) NA
Vapor Pressure (mm Hg.) 1.4
Vapor Density (air = 1) NA
Percent Volatile NA

10. STABILITY AND REACTIVITY

Stability Unstable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Will react at room temp. Keep frozen at all times.
Incompatibility (Materials to Avoid) Carbon monoxide, carbon dioxide, aldehydes, phenol.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides.
Products
Hazardous Polymerization May Occur
Conditions to Avoid (Reactivity) Moderate temperatures, strong acids; certain organics, metallic acids.

11. TOXICOLOGICAL INFORMATION

Primary Entry Route(s) Skin, eyes, inhalation
Oral, LD50 Ingestion > 4000 mg/kg.

12. ECOLOGICAL INFORMATION

Not available

13. DISPOSAL CONSIDERATIONS

QAF-1058 Rev B Date Printed: 6/28/2002 Page 5 of 9 2101 Pre-Mixed and Frozen
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.

14. TRANSPORTATION INFORMATION
Not Applicable

15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.

STATE LAWS:

PENNSYLVANIA TOXIC SUBSTANCE LIST
000111-40-0 1,2-Ethanediamine, N-(2-aminoethyl)- 1 - 10 --
-- Basic Hazard; E - Environmental Hazard; S - Special Hazard; * - Any compound of this substance is an environmental hazard

The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
16. OTHER INFORMATION

H: 2 F: 1 R: 0
MSDS Date: 6/11/2002 Revision: C HMIS Coding:




QAF-1058 Rev B Date Printed: 6/28/2002 Page 6 of 9 2101 Pre-Mixed and Frozen
www.tra-con.com

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 6/28/2002
TRA-BOND 2101 Resin
Revision Date: 6/11/2002
TRA-CON, INC.
Revision: C
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Phenol,4,4'-(1-methylethylidene)bis-, 025036-25-3 65 - 75
polymer with 2,2'-((1-
methylethylidene)bis(4,1-
phenyleneoxymethylene))bis(oxira
Poly(oxy(methyl-1,2-ethanediyl)),a- 026142-30-3 25 - 35
(oxiranylmethyl)-w-(oxiranylmethoxy)-

Silica,amorphous,fumed, crystilline-free 112945-52-5 <5



3. HAZARDS IDENTIFICATION

Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation.

4. FIRST AID MEASURES

Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; induce vomitting if large amount
swallowed.

5. FIREFIGHTING MEASURES

Flashpoint > 285掳F
Flashpoint Method PMCC
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A

6.ACCIDENTAL RELEASE MEASURES

Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material or scrape up and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions or use detergents.


QAF-1058 Rev B Date Printed: 6/28/2002 Page 7 of 9 2101 Resin
7. HANDLING AND STORAGE
Handling and Storage For industrial use only. WARNING: May cause sensitization, irritation or other allergic
responses. Avoid eye and/or skin contact and prolonged inhalation of vapors.
Special Sensitivity Store in a cool place in closed containers. Handle per Hazard Potential of Hardener.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Hazy, light straw colored liquid, mild odor.
Boiling Point (掳F) > 480
Solubility in Water low
Specific Gravity (H2O=1) 1.2
Evaporation Rate (BuAc=1) low
Vapor Pressure (mm Hg.) <1
Vapor Density (air = 1) >1
Percent Volatile < 0.5

10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) High temperatures, strong acids; certain organics, metallic acids.

11. TOXICOLOGICAL INFORMATION

Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 > 4000 mg/kg
Dermal, LD50 > 5000 mg/kg

12. ECOLOGICAL INFORMATION

Not available

13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.

14. TRANSPORTATION INFORMATION
Not Applicable


QAF-1058 Rev B Date Printed: 6/28/2002 Page 8 of 9 2101 Resin
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.

STATE LAWS:



The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
16. OTHER INFORMATION

H: 2 F: 1 R: 0
MSDS Date: 6/11/2002 Revision: C HMIS Coding:




QAF-1058 Rev B Date Printed: 6/28/2002 Page 9 of 9 2101 Resin

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