1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 1/10/00
TRA-BOND 2137 Hardener
Revision Date: 4/4/97
TRA-CON, INC.
Revision: B
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Fatty acids, c18-unsatd., dimers, reaction 068410-23-1 60 - 80
products with polyethylenepolyamines
Propane, 1,2,3-trichloro-,polymer with 1,1'- 068611-50-7 25 - 45
(methylenebis(oxy))bis(2-chloroethane) and
sodium sulfide reduced
3. HAZARDS IDENTIFICATION
Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; do NOT induce vomitting if swallowed; get
medical attention.
5. FIREFIGHTING MEASURES
Flashpoint 120掳F
Flashpoint Method CC
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material, or scrape up, and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions, or use detergents.
7. HANDLING AND STORAGE
Handling and Storage
Special Sensitivity Store in cool place in closed containers.
QAF-1058 Rev B Date Printed: 1/10/00 Page 6 of 11 2137 Hardener
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Clear amber liquid, mercaptan odor.
Boiling Point (掳F) 300
Solubility in Water partial
Specific Gravity (H2O=1) 1.2
Evaporation Rate (BuAc=1) <1
Vapor Pressure (mm Hg.) <5
Vapor Density (air = 1) 3.1
Percent Volatile low
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides, thermal products.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) High temperatures, strong acids; certain organics, metallic acids.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 Ingestion LD50 (rats) 2.6 grams/kg; Dermal LD50 > 10.2 g/kg.
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
STATE LAWS:
QAF-1058 Rev B Date Printed: 1/10/00 Page 7 of 11 2137 Hardener
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such are
based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is the purchaser's
responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their
purposes.
16. OTHER INFORMATION
HMIS Coding: H: 2 F: 1 R: 0
MSDS Date: 4/4/97 Revision: B
QAF-1058 Rev B Date Printed: 1/10/00 Page 8 of 11 2137 Hardener
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 1/10/00
TRA-BOND 2137 Resin
Revision Date: 4/4/97
TRA-CON, INC.
Revision: B
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Phenol,4,4'-(1-methylethylidene)bis-, 025068-38-6 55 - 75
polymer with (chloromethyl) oxirane
Oxirane, ((4-(1,1- 003101-60-8 up to 20
dimethylethyl)phenoxy)methyl)-
Oxirane, (((2-ethylhexyl)oxy)methyl)- 002461-15-6 up to 10
Silica,amorphous,fumed, crystilline-free 112945-52-5 up to 10
3. HAZARDS IDENTIFICATION
Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; induce vomitting if large amount
swallowed.
5. FIREFIGHTING MEASURES
Flashpoint > 200掳F
Flashpoint Method PMCC
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material or scrape up and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions or use detergents.
QAF-1058 Rev B Date Printed: 1/10/00 Page 9 of 11 2137 Resin
7. HANDLING AND STORAGE
Handling and Storage
Special Sensitivity Store in cool place in closed containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Translucent, medium viscosity liquid, slight sweet odor.
Boiling Point (掳F) 437
Solubility in Water partial
Specific Gravity (H2O=1) 1.2
Evaporation Rate (BuAc=1) ND
Vapor Pressure (mm Hg.) NA
Vapor Density (air = 1) high
Percent Volatile ND
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, phenol.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) High temperatures, strong acids; certain organics, metallic acids.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 LD50 (rats) >5000 mg/kg ; Dermal LD50 >4000 mg/kg.
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
QAF-1058 Rev B Date Printed: 1/10/00 Page 10 of 11 2137 Resin
STATE LAWS:
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such are
based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is the purchaser's
responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their
purposes.
16. OTHER INFORMATION
HMIS Coding: H: 2 F: 1 R: 0
MSDS Date: 4/4/97 Revision: B
QAF-1058 Rev B Date Printed: 1/10/00 Page 11 of 11 2137 Resin
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