www.tra-con.com
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 7/26/01
TRA-BOND 2111 Hardener
Revision Date: 9/5/97
TRA-CON, INC.
45 Wiggins Avenue Revision: B
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
1-propanamine,3,3'-(oxybis(2,1-- 004246-51-9 80 - 100
ethanediyloxy))bis-
3. HAZARDS IDENTIFICATION
Effects of Overexposure Contact may cause serious eye, mouth and/or skin irritation or burns; material is also
a strong sensitizer.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; do NOT induce vomitting if swallowed; get
medical attention.
5. FIREFIGHTING MEASURES
Flashpoint > 250掳F
Flashpoint Method PMCC
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material, or scrape up, and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions, or use detergents.
7. HANDLING AND STORAGE
Handling and Storage For industrial use only. WARNING: May cause sensitization, irritation or other allergic
responses. Avoid eye and/or skin contact and prolonged inhalation of vapors.
Special Sensitivity Store in a cool place in closed containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
QAF-1058 Rev B Date Printed: 7/26/01 Page 1 of 9 2111 Hardener
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Light amber liquid, slight amine odor.
Boiling Point (掳F) > 400
Solubility in Water high
Specific Gravity (H2O=1) 1.0
Evaporation Rate (BuAc=1) low
Vapor Pressure (mm Hg.) low
Vapor Density (air = 1) >2
Percent Volatile low
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid contact with metals corroded by liquid amines; avoid high temperatures.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, phenol.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) Chlorinated compounds; exotherms when used to cure epoxy resins.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 TLV not established.
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
STATE LAWS:
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such are
based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is the purchaser's
responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their
purposes.
QAF-1058 Rev B Date Printed: 7/26/01 Page 2 of 9 2111 Hardener
16. OTHER INFORMATION
HMIS Coding: H: 3 F: 1 R: 0
MSDS Date: 9/5/97 Revision: B
QAF-1058 Rev B Date Printed: 7/26/01 Page 3 of 9 2111 Hardener
www.tra-con.com
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 7/26/01
TRA-BOND 2111 Pre-Mixed and Frozen
Revision Date: 9/5/97
TRA-CON, INC.
45 Wiggins Avenue Revision: B
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Silica,amorphous,fumed, crystilline-free 112945-52-5 < 10
Glass, oxide, chemicals 065997-17-3 <5
n-Butyl glycidyl ether 002426-08-6 < 10 50 270 -- -- -- --
25 133 -- -- -- --
COMMENTS: a. NIOSH - Value based on 15
minutes.
Phenol,4,4'-(1-methylethylidene)bis-, 025068-38-6 50 - 70
polymer with (chloromethyl) oxirane
1-propanamine,3,3'-(oxybis(2,1-- 004246-51-9 15 - 35
ethanediyloxy))bis-
3. HAZARDS IDENTIFICATION
Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; induce vomitting if large amount
swallowed.
5. FIREFIGHTING MEASURES
Flashpoint 164掳F
Flashpoint Method setaflash
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Use self-contained breathing apparatus.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
QAF-1058 Rev B Date Printed: 7/26/01 Page 4 of 9 2111 Pre-Mixed and Frozen
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material or scrape up and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions or use detergents.
7. HANDLING AND STORAGE
Handling and Storage For industrial use only. WARNING: May cause sensitization, irritation or other allergic
responses. Avoid eye and/or skin contact and prolonged inhalation of vapors.
Special Sensitivity Store in freezer at minium -40掳F. Thaw cartridges in upright position, dispensing tip
up, to release air in tip cap, if any.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Translucent paste, slight ammoniacal odor.
Boiling Point (掳F) 295
Solubility in Water partial
Specific Gravity (H2O=1) 1.2
Evaporation Rate (BuAc=1) ND
Vapor Pressure (mm Hg.) <1
Vapor Density (air = 1) >3
Percent Volatile ND
10. STABILITY AND REACTIVITY
Stability Unstable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Will react at room temp. Keep frozen at all times.
Incompatibility (Materials to Avoid) Carbon monoxide, carbon dioxide, aldehydes, phenol.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides.
Products
Hazardous Polymerization May Occur
Conditions to Avoid (Reactivity) Moderate temperatures, strong acids; certain organics, metallic acids.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation
Oral, LD50 Ingestion LD50 900 mg/kg. Dermal LD50 > 20 ml/kg. Inhalation > 3500 ppm.
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
QAF-1058 Rev B Date Printed: 7/26/01 Page 5 of 9 2111 Pre-Mixed and Frozen
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
STATE LAWS:
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such are
based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is the purchaser's
responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their
purposes.
16. OTHER INFORMATION
HMIS Coding: H: 3 F: 2 R: 0
MSDS Date: 9/5/97 Revision: B
QAF-1058 Rev B Date Printed: 7/26/01 Page 6 of 9 2111 Pre-Mixed and Frozen
www.tra-con.com
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 7/26/01
TRA-BOND 2111 Resin
Revision Date: 9/5/97
TRA-CON, INC.
45 Wiggins Avenue Revision: B
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Phenol,4,4'-(1-methylethylidene)bis-, 025068-38-6 80 - 100
polymer with (chloromethyl) oxirane
n-Butyl glycidyl ether 002426-08-6 up to 20 50 270 -- -- -- --
25 133 -- -- -- --
COMMENTS: a. NIOSH - Value based on 15
minutes.
3. HAZARDS IDENTIFICATION
Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation, defatting and
drying of the skin. Chronic exposure may be mutagenic.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; induce vomitting if large amount
swallowed.
5. FIREFIGHTING MEASURES
Flashpoint 164掳F
Flashpoint Method setaflash
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material or scrape up and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions or use detergents.
7. HANDLING AND STORAGE
QAF-1058 Rev B Date Printed: 7/26/01 Page 7 of 9 2111 Resin
Handling and Storage For industrial use only. WARNING: May cause sensitization, irritation or other allergic
responses. Avoid eye and/or skin contact and prolonged inhalation of vapors.
Special Sensitivity Store in a cool place in closed containers. Handle per Hazard Potential of Hardener.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Clear, low viscosity liquid, slight sweet odor.
Boiling Point (掳F) > 350
Solubility in Water low
Specific Gravity (H2O=1) 1.2
Evaporation Rate (BuAc=1) low
Vapor Pressure (mm Hg.) <1
Vapor Density (air = 1) >1
Percent Volatile < 0.2
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, phenol.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) High temperatures, strong acids; certain organics, metallic acids.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 Ingestion LD50 (rats) 1200 mg/kg (CAS #2426-08-6); ACGIH TLV/TWA 25 ppm (CAS
#2426-08-6).
Other Notes on Toxicity Considered Mutagenic
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
QAF-1058 Rev B Date Printed: 7/26/01 Page 8 of 9 2111 Resin
TSCA: All components are on the TSCA inventory.
STATE LAWS:
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such are
based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is the purchaser's
responsibility before using any product to verify this data under their own operating conditions and to determine whether the product is suitable for their
purposes.
16. OTHER INFORMATION
HMIS Coding: H: 3 F: 2 R: 0
MSDS Date: 9/5/97 Revision: B
QAF-1058 Rev B Date Printed: 7/26/01 Page 9 of 9 2111 Resin
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