www.tra-con.com
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 12/15/2003
TRA-BOND 2113 Hardener
Revision Date: 11/11/2003
TRA-CON, INC.
Revision: D
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Diethylene triamine 000111-40-0 80 - 90 -- -- -- -- -- --
1 4.2 -- -- -- --
COMMENTS:
None.
Proprietary Epoxy polyamine adduct NJ 05995500- 5 - 15
(H1916U)
Non-hazardous ingredients -- <5
3. HAZARDS IDENTIFICATION
Effects of Overexposure Eye or skin contact: WARNING - causes severe eye irritation or burns. Material is a
strong sensitizer and respiratory tract irritant. Effects could be irreversible. No
delayed, subchronic or chronic test data are known.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing, destroy contaminated
leather.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; do NOT induce vomitting if swallowed; get
medical attention.
5. FIREFIGHTING MEASURES
Flashpoint > 200掳F
Flashpoint Method CC
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
QAF-1058 Rev B Date Printed: 12/15/2003 Page 1 of 9 2113 Hardener
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material, or scrape up, and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions, or use detergents.
7. HANDLING AND STORAGE
Handling and Storage For industrial use only. WARNING: May cause sensitization, irritation or other allergic
responses. Avoid eye and/or skin contact and prolonged inhalation of vapors.
Special Sensitivity Store in a cool place in closed containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Required
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Straw Yellow, ammoniacal odor.
Boiling Point (掳F) > 300
Solubility in Water negligible
Specific Gravity (H2O=1) 1.1
Evaporation Rate (BuAc=1) ND
Vapor Pressure (mm Hg.) <1
Vapor Density (air = 1) >2
Percent Volatile ND
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid high temperatures.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents, chlorinated compounds.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides, thermal products, ammonia.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) Chlorinated compounds; exotherms when used to cure epoxy resins.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 > 1080 mg/kg
Dermal, LD50 > 672 mg/kg
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
QAF-1058 Rev B Date Printed: 12/15/2003 Page 2 of 9 2113 Hardener
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
STATE LAWS:
FLORIDA TOXIC SUBSTANCE LIST
000111-40-0 Diethylene triamine 80 - 90
MASSACHUSETTS HAZARDOUS SUBSTANCE LIST
000111-40-0 Diethylene triamine 80 - 90
MINNESOTA HAZARDOUS SUBSTANCE LIST
000111-40-0 Diethylene triamine 80 - 90
WASHINGTON PEL FOR AIR CONTAMINANTS LIST TWA ppm TWA mg TWA ppm Ceil. mg
4 ---- ----
000111-40-0 Diethylene triamine 80 - 90 1
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
16. OTHER INFORMATION
H: 3 F: 1 R: 0
MSDS Date: 11/11/2003 Revision: D HMIS Coding:
QAF-1058 Rev B Date Printed: 12/15/2003 Page 3 of 9 2113 Hardener
www.tra-con.com
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 12/15/2003
TRA-BOND 2113 Pre-Mixed and Frozen
Revision Date: 11/11/2003
TRA-CON, INC.
Revision: D
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Phenol,4,4'-(1-methylethylidene)bis-, 025068-38-6 70 - 80
polymer with (chloromethyl) oxirane
Methyl alcohol 000067-56-1 <1 200 260 -- -- -- --
200 262 250 328 -- --
COMMENTS: SYN -
Methanol.
n-Butyl glycidyl ether 002426-08-6 5 - 15 50 270 -- -- -- --
25 133 -- -- -- --
COMMENTS: a. NIOSH - Value based on 15
minutes.
1,2-Ethanediamine, N-(2-aminoethyl)- 000111-40-0 5 - 15
3. HAZARDS IDENTIFICATION
Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation.
Eye May cause irritation
Skin Contact Frequent or prolonged contact can cause severe irritation. May cause skin
sensitization, a partial or whole-body dermatitis rash experienced after exposure,
however, minimal
Inhalation Hazards Inhalation of vapor can be harmful.
Ingestion Hazards Harmful if swallowed
4. FIRST AID MEASURES
Eyes Flush eyes with water for at least 15 minutes. Get prompt medical attention.
Skin Wash immediately with soap and water. If irritation persists, seek medical attention
immediately.
Inhalation Remove to fresh air. Get medical attention if irritation persists.
Ingestion No known antidote but give milk or water; do NOT induce vomitting if swallowed; get
medical attention.
QAF-1058 Rev B Date Printed: 12/15/2003 Page 4 of 9 2113 Pre-Mixed and Frozen
5. FIREFIGHTING MEASURES
Flashpoint > 164掳F
Flashpoint Method setaflash
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Wear self contained breathing apparatus and appropriate
personal protective equipment to avoid contact.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material, or scrape up and
transfer to disposal container. Wipe up remaining residue with solvents, observing
solvent flammability cautions, or use detergents.
7. HANDLING AND STORAGE
Handling and Storage As required to prevent all body contact; eye bath and/or safety shower.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Use with adequate ventilation. Local exhaust is recommended when appropriate to
control employee exposure.
Mechanical Exhaust Recommended
Eye Protection Requirements Wear safety glasses with side shields.
Glove Requirements Rubber or plastic disposable.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Colorless to pale yellow liquid; mild odor
Boiling Point (掳F) > 95
Solubility in Water negligible
Specific Gravity (H2O=1) 1.12
Evaporation Rate (BuAc=1) <1
Vapor Pressure (mm Hg.) <1
Vapor Density (air = 1) >1
Percent Volatile ND
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Incompatibility (Materials to Avoid) Carbon monoxide, carbon dioxide, aldehydes, phenol.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, nitrogen oxides, phenol.
Products
Hazardous Polymerization Will Not Occur
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation
QAF-1058 Rev B Date Printed: 12/15/2003 Page 5 of 9 2113 Pre-Mixed and Frozen
Oral, LD50 > 900 mg/kg
Dermal, LD50 > 200 mg/kg
Inhalation, LD50 > 3500 ppm
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
governmental agencies.
Empty Container Warnings Empty containers may contain product residue; follow MSDS and label warnings even
after they have been emptied.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
STATE LAWS:
FLORIDA TOXIC SUBSTANCE LIST
000067-56-1 Methyl alcohol <1
PENNSYLVANIA HAZARDOUS SUBSTANCE LIST
000111-40-0 1,2-Ethanediamine, N-(2-aminoethyl)- 5 - 15
MINNESOTA HAZARDOUS SUBSTANCE LIST
000067-56-1 Methyl alcohol <1
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
16. OTHER INFORMATION
MSDS Date: 11/11/2003 Revision: D
QAF-1058 Rev B Date Printed: 12/15/2003 Page 6 of 9 2113 Pre-Mixed and Frozen
www.tra-con.com
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Date Printed: 12/15/2003
TRA-BOND 2113 Resin
Revision Date: 11/11/2003
TRA-CON, INC.
Revision: D
45 Wiggins Avenue
Bedford, MA 01730
781-275-6363
1-800-872-2661
Emergency Telephone: 1-800-424-9300 (24 hours, CHEMTREC)
2. COMPOSITION/INFORMATION ON INGREDIENTS
TWA STEL Ceiling
Component CAS Number %
OSHA
ACGIH ppm mg/m3 ppm mg/m3 ppm mg/m3
Phenol,4,4'-(1-methylethylidene)bis-, 025068-38-6 80 - 90
polymer with (chloromethyl) oxirane
n-Butyl glycidyl ether 002426-08-6 5 - 15 50 270 -- -- -- --
25 133 -- -- -- --
COMMENTS: a. NIOSH - Value based on 15
minutes.
3. HAZARDS IDENTIFICATION
Effects of Overexposure Repeated contact or breathing of vapors may cause irritation; material is also a
strong sensitizer. Eye and skin contact may cause transient irritation, defatting and
drying of the skin. Chronic exposure may be mutagenic.
4. FIRST AID MEASURES
Eyes Flush with water, get medical attention.
Skin Wash with soap and water; remove contaminated clothing.
Inhalation Remove to fresh air.
Ingestion No known antidote but give milk or water; induce vomitting if large amount
swallowed.
5. FIREFIGHTING MEASURES
Flashpoint 164掳F
Flashpoint Method setaflash
Extinguishing Media Dry chemicals, chemical foam, carbon dioxide, water.
Special Firefighting Measures Avoid breathing smoke. Addition of water may reduce flame intensity.
Fire and Explosion Hazards Toxic gases may be liberated; handle as combustible; store in a cool place.
Flammable Limits N/AV
LEL N/A
UEL N/A
6.ACCIDENTAL RELEASE MEASURES
Spill and Leak Procedures Prevent skin and eye contact. Soak up in absorbent material or scrape up and
transfer to disposal container. Wipe up remaining residue with solvents, observing
QAF-1058 Rev B Date Printed: 12/15/2003 Page 7 of 9 2113 Resin
solvent flammability cautions or use detergents.
7. HANDLING AND STORAGE
Handling and Storage For industrial use only. WARNING: May cause sensitization, irritation or other allergic
responses. Avoid eye and/or skin contact and prolonged inhalation of vapors.
Special Sensitivity Store in a cool place in closed containers. Handle per Hazard Potential of Hardener.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Local Exhaust Recommended
Mechanical Exhaust Recommended
Eye Protection Requirements Safety glasses or goggles
Glove Requirements Rubber or plastic disposable.
Other Protection As required to prevent all body contact; eye bath and/or safety shower.
Respirator Requirements Air supplied or organic canister, mask in confined areas.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance and Odor Clear, low viscosity liquid, slight sweet odor.
Boiling Point (掳F) > 95
Solubility in Water negligible
Specific Gravity (H2O=1) 1.2
Evaporation Rate (BuAc=1) low
Vapor Pressure (mm Hg.) ND
Vapor Density (air = 1) >1
Percent Volatile ND
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid (Stability) Avoid uncontrolled excess heating over long periods; avoid uncontrolled amine reactions.
Incompatibility (Materials to Avoid) Strong acids and bases, strong oxidizing agents.
Hazardous Decomposition Carbon monoxide, carbon dioxide, aldehydes, phenol.
Products
Hazardous Polymerization Will Not Occur
Conditions to Avoid (Reactivity) High temperatures, strong acids; certain organics, metallic acids.
11. TOXICOLOGICAL INFORMATION
Primary Entry Route(s) Skin, eyes, inhalation.
Oral, LD50 > 900 mg/kg
Dermal, LD50 > 200 mg/kg
Inhalation, LD50 > 3500 ppm
Other Notes on Toxicity Considered Mutagenic
12. ECOLOGICAL INFORMATION
Not available
13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods Dispose of as hazardous waste according to local, state and federal regulations.
Disposal method can be land burial or chemical incineration as regulated by all
QAF-1058 Rev B Date Printed: 12/15/2003 Page 8 of 9 2113 Resin
governmental agencies.
14. TRANSPORTATION INFORMATION
Not Applicable
15. REGULATORY INFORMATION
TSCA: All components are on the TSCA inventory.
STATE LAWS:
The information given and the recommendations made herein apply to our product(s) alone and are not combined with other product(s). Such
are based on our research and on data from other reliable soruces and are believed to be accurate. no guaranty of accuracy is made. it is
the purchaser's responsibility before using any product to verify this data under their own operating conditions and to determine whether the
product is suitable for their purposes.
16. OTHER INFORMATION
H: 3 F: 2 R: 0
MSDS Date: 11/11/2003 Revision: D HMIS Coding:
QAF-1058 Rev B Date Printed: 12/15/2003 Page 9 of 9 2113 Resin
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