April 5, 2004
Page 1 of 3
Material Safety Data Sheet
Product Name: Gordon's TRIMEC Classic Brand Broadleaf Herbicide
MSDS No.: 881-6 Version No.: 021 EPA Registration No.: 2217-543
1. Basic Information:
PBI/Gordon Corporation
Manufacturer:
1217 West 12th Street
Address:
1 2
Kansas City, MO 64101-1407
City, State Zip:
1
Environmental, Health, & Safety Dept.
Information Contact:
2 0
(816)421-4070
Information Telephone Number:
0
Chemtrec
Emergency Contact:
B
(800)424-9300
Emergency Telephone Number:
9/27/2001
Last Update:
X
Chemical State: Liquid Gas Solid
X
Chemical Type: Pure Mixture
2. Ingredients:
(ND = Not Disclosed) SARA
Trade Secret EHS IARC
OSHA ACGIH Other
313
PEL TLV Limits
CAS No. Chemical Name % Range NTP SUB Z
2008391 Dimethylamine Salt of 25.93% N N Y N N NI NI NI
2,4-dichlorophenoxyacetic acid (2,4-D)
2300665 Dimethylamine Salt of 2.76% N N N N Y NI NI NI
3,6-dichloro-o-anisic acid (Dicamba)
66423094 Dimethylamine Salt of 6.93% N N Y N N NI NI NI
R(+)2-(2-Methyl-4-chlorophenoxy)
propionic acid (MCPP)
3. Hazardous Identification: First Aid Measures (Continued)
manifestations of severe poisoning, which may progress to
Hazard Catagory:
unconsciousness.
X Acute X Chronic Fire Pressure Reactive
Medical Conditions Generally Aggravated by Exposure:
Individuals with chronic skin disease or known sensitivity to
Hazardous Identification Information:
chlorophenoxy compounds should either avoid using them or take strict
The International Agency for Research on Cancer (IARC) lists precautions to avoid contact. (respirator, gloves, etc.)
chlorophenoxy herbicides in its Group 2B (limited evidence for
Emergency First Aid Procedure:
carcinogenicity in humans.) The US EPA has given the chlorophenoxy
IF IN EYES: Hold eyelids open and flush with a steady, gentle stream of
herbicides 2,4-D, 2,4-DP, MCPP, and MCPA a Class D classification
water for 15 minutes. Get medical attention.
(not classifiable as to human carcinogenicity.) More current 2,4-D
IF ON SKIN: Wash with plenty of soap and water. Get medical attention.
lifetime feeding studies in rats and mice did not show carcinogenic
IF SWALLOWED: Call a doctor or get medical attention. Do not induce
effects and a recent World Health Organization (WHO) review of 2,4-D
vomiting or give anything by mouth to an unconscious person. Drink
toxicology has concluded that 2,4-D is not a carcinogen.
promptly a large quantity of milk, eggwhites, gelatin solution, or if these
4. First Aid Measures: are not available, drink large quantities of water. Avoid alcohol.
IF INHALED: Remove victim to fresh air and apply respiration if
indicated.
Route(s) of Entry:
NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate
Skin contact, Inhalation, Ingestion. the use of gastric lavage.
Health Hazards (Acute and Chronic): Other Health Warnings:
EYES: Corrosive. Causes irreversible eye damage. NI
5. Fire Fighting Measures:
SKIN: Moderately irritating to the skin; may be absorbed through the skin.
INHALATION: Moderately irritating to the mucous membranes. 137掳F
Flash Point: F.P. Method:
Inhalation of sprays may cause burning sensations in the respiratory
NI
Lower Explosive Limit:
tract, resulting in coughing.
NI
Upper Explosive Limit:
INGESTION: May cause vomiting, with pain in the chest and abdomen,
Fire Extinguishing Media:
and diarrhea.
Foam, CO2, dry chemical, water. The low flash point of this product is
Signs and Symptoms: due to a minor component in the mixture. Based on independent
Inhalation may cause burning in the chest, with coughing. Prolonged laboratory testing of similar products, this product would not sustain
inhalation sometimes causes dizziness. Ingestion usually leads to combustion as specified in DOT Regulation 49 CFR 173 Appendix H,
vomiting. Pain in the chest and abdomen, and diarrhea may follow. and, therefore, would not be classified as a combustible liquid.
Headache, mental confusion, and bizarre behavior are early
Page 2 of 3 April 5, 2004
Material Safety Data Sheet
Product Name: Gordon's TRIMEC Classic Brand Broadleaf Herbicide
MSDS No.: 881-6 Version No.: 021 EPA Registration No.: 2217-543
9. Physical and Chemical Properties:
Fire Fighting Measures (Continued)
Special Fire Fighting Procedures:
Boiling Point: 212 掳F Melting Point: NI
Wear positive-pressure breathing apparatus and full protective clothing.
Fight fire from maximum distance. Stay up-wind and out of low areas. Evaporation Rate (Butyl Acetate = 1) : <1
Vapor Pressure (mm Hg.): <17 (20 C)
Unusual Fire and Explosion:
This product does not ignite readily, but may burn at a very high Vapor Density (Air = 1): >1
temperature. The fire may produce irritating or poisonous gases.
Specific Gravity (H20 = 1): 1.11700
Runoff from fire control area or dilution water may cause pollution. If
surface water is contaminated, contact local authorities. Solubility in Water: Infinite
Appearance and Odor: Brown liquid with an amine-type odo
6. Accidental Release Measures: Other Information:
pH = 7.5-8.5
Steps to be Taken in Case Material is Released or Spilled: Density = 9.30 pounds/gallon
See Section 8 for Personal Protective Equipment. Do not touch spilled Freezing point <35掳F
material. Contain and absorb spilled material on Dri-Rite, sand or other Percent volatile by volume 62%
non-combustible absorbent. Collect into drums; cover and label for
disposal. Flush area with water if possible.
10. Stability and Reactivity:
7. Handling and Storage: Stability:
Stable.
Precautions to be Taken:
Incompatibility (Materials to Avoid):
Do not contaminate water, food, or feed by storage or disposal.
Do not mix with acidic materials, as this will ruin the product.
STORAGE: Store in original container in a locked storage area. Keep
from freezing.
Decomposition/By-Products:
May produce gases such as HCl, organo chlorides, nitrogen oxides, and
Other Precautions:
Engineering Control Statements: carbon monoxide when burning.
Containers over 1 gallon and less than 5 gallons: Persons engaged in
Hazardous Polymerization:
open pouring of this product must also wear coveralls or a chemical
Will not occur.
resistant apron.
Containers of 5 gallons or more: Do not open-pour product from this
11. Toxicological Information:
container. A mechanical system (such as a probe and pump or spigot)
must be used for transferring the contents of this container. If the
Acute dermal LD50 >2010 mg/kg (rabbit)
contents of a non-refillable pesticide container are emptied, the probe
must be rinsed before removal.
Oral LD50 >2240 mg/kg (male rats) and >1550 mg/kg (female rats).
8. Exposure Controls/Personal Protection:
Ventilation Requirements:
12. Ecological Information:
Good local ventilation is recommended; mechanical ventilation may be
used if exposure limits may be exceeded.
Personal Protective Equipment: ENVIRONMENTAL HAZARDS:
Clothing Requirement Statement: This product is toxic to aquatic invertebrates. Drift or runoff may
When mixing, loading, or applying this product, wear long-sleeved shirt, adversely affect aquatic invertebrates and nontarget plants. For
long pants, socks, shoes, chemical-resistant gloves and eye protection. It terrestrial uses, do not apply directly to water, or to areas where surface
is recommended that safety glasses include front, brow, and temple water is present, or to intertidal areas below the mean high water mark.
protection. Do not contaminate water when disposing of equipment washwater. Do
not contaminate domestic or irrigation waters. Do not apply when
Personal Hygiene Statement: weather conditions favor drift from target area.
After using this product, rinse gloves before removing, remove clothing When cleaning equipment, do not pour the washwater on the ground;
and launder spray or drain over a large area away from wells and other water
separately before reuse, and promptly and thoroughly wash hands and sources.
exposed skin with soap and water. Remove saturated clothing as soon Most cases of groundwater contamination involving phenoxy herbicides
as possible and shower. such as 2,4-D and MCPP have been associated with mixing/loading and
disposal sites. Caution should be exercised when handling 2,4-D and
PROTECTIVE CLOTHING: Wear long sleeves and pants; MCPP pesticides at such sites to prevent contamination of groundwater
chemical-resistant gloves and shoes with socks. supplies. Use of closed systems for mixing or transferring this pesticide
will reduce the probability of spills. Placement of the mixing/loading
EYE PROTECTION: Safety glasses with side shields or safety goggles. equipment on an impervious pad to contain spills will help prevent
groundwater contamination.
RESPIRATORY PROTECTION: If exposure limits may be exceeded,
wear a dust/mist filtering respirator (MSHA/NIOSH approval number prefix
13. Disposal Considerations:
TC-21C), or a NIOSH approved respirator with any N, R, P or HE filter.
April 5, 2004
Page 3 of 3
Material Safety Data Sheet
Product Name: Gordon's TRIMEC Classic Brand Broadleaf Herbicide
MSDS No.: 881-6 Version No.: 021 EPA Registration No.: 2217-543
Disposal Considerations (Continued) Other Information (Continued)
hazard determination, but is not to be construed as a warranty or
PESTICIDE DISPOSAL: Pesticide wastes are acutely hazardous.
representation for which we assume legal responsibility. Additional
Improper disposal of excess pesticide, spray mixture, or rinsate is a
information may be necessary or desirable depending on particular,
violation of Federal law and may contaminate groundwater. If these
exceptional or variable conditions or circumstances of use or storage or
wastes cannot be disposed of by use according to label instructions,
because of locally applicable laws or government regulations. Therefore,
contact your State Pesticide or Environmental Control Agency, or the
you should use this information only as a supplement to other information
Hazardous Waste representative at the nearest EPA Regional Office for
available to you and must make independent determinations of the
guidance.
suitability of the information for your particular circumstances or
CONTAINER DISPOSAL: For Metal Containers - Triple rinse (or
conditions and of the completeness of the information available from all
equivalent). Then offer for recycling or reconditioning, or puncture and
sources to assure both the proper use of the material described herein
dispose of in a sanitary landfill or by other procedures approved by state
and the safety and health of employees.
and local authorities. For Plastic Containers - Triple rinse (or equivalent).
Then offer for recycling or reconditioning, or puncture and dispose of in a
sanitary landfill, or incineration, or if allowed by state and local authorities
by burning. If burned stay out of smoke.
14. Transport Information:
The following guidlines apply for domestic ground transport. If shipping
by air or ocean, please contact our Transportation Department.
Freight Class: Herbicides, NOI - NMFC Class #50320
Proper Shipping Name:
For package sizes less than 49.46 gallons: product is non-regulated.
For package sizes 49.46 gallons or greater: Environmentally
Hazardous Substances, Liquid, N.O.S., 9, UN3082, PGIII, RQ (2,4-D)
If shipped in bulk containers (greater than 119 gallons), this product is a
Marine Pollutant.
When shipped as a Hazardous Material, label required is Class 9
(Miscellaneous). Placards required on bulk shipments only.
15. Regulatory Information:
OSHA STATUS: This product is hazardous under the criteria of the
Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA STATUS: This product is exempt from TSCA Regulation under
FIFRA Section 3(2)(B)(ii) when used as a pesticide.
CERCLA REPORTABLE QUANTITY: 385 pounds of the formulation
which contains 100 pounds of Dimethylamine 2,4-D
SARA TITLE III:
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: None
SECTION 311/312 HAZARD CATEGORIES: Immediate Health
Hazard, Delayed Health Hazard
SECTION 313 TOXIC CHEMICALS: Dimethylamine dicamba CAS#
2300-66-5
RCRA STATUS: When discarded in its purchased form, this product is a
listed RCRA hazardous waste and should be managed as a hazardous
waste. (40 CFR 261.20-24)
16. Other Information:
REASON FOR ISSUE: To change from racemic MCPP to the plus
optical isomer.
Note: NI means not Indicated.
The information and statements in this Material Safety Data Sheet are
believed to accurately reflect the scientific evidence used in making the
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