December 2, 2002
Page 1 of 3
Material Safety Data Sheet
Product Name: Gordon's VEGEMEC Vegetation Killer
MSDS No.: 918-6 Version No.: 012 EPA Registration No.: 33955-454-2217
1. Basic Information:
PBI/Gordon Corporation
Manufacturer:
1217 West 12th Street
Address:
2 2
Kansas City, MO 64101-1407
City, State Zip:
2
Environmental, Health, & Safety Dept.
Information Contact:
2 0
(816)421-4070
Information Telephone Number:
0
Chemtrec
Emergency Contact:
B
(800)424-9300
Emergency Telephone Number:
12/2/2002
Last Update:
X
Chemical State: Liquid Gas Solid
X
Chemical Type: Pure Mixture
2. Ingredients:
(ND = Not Disclosed) SARA
Trade Secret EHS IARC
OSHA ACGIH Other
313
PEL TLV Limits
CAS No. Chemical Name % Range NTP SUB Z
95636 1,2,4-Trimethylbenzene 15.25% N N N N Y NI 25 ppm 25 ppm
1610180 2,4-bis(Isopropylamino)-6-methoxy-s-tria 3.60% N N N N N NI NI NI
zine
94757 2,4-Dichlorophenoxyacetic acid (2,4-D) 1.00% N N Y Y Y 10 mg/m3 10 mg/m3 10 mg/m3
8008206 Kerosene 28.60% N N N N N NI NI 100 ppm
64742956 Petroleum solvent 40.22% N N N Y N 500 ppm NI 50 ppm
126738 Tributyl phosphate <3.00% N N N Y N 5 mg/m3 2.2 mg/m3 2.5 mg/m
1330207 Xylene (mixed isomers) 1.43% N N N Y Y 100 ppm 100 ppm 100 ppm
3. Hazardous Identification: First Aid Measures (Continued)
and diarrhea.
Hazard Catagory:
X Acute X Chronic X Fire Pressure Reactive CHRONIC EFFECTS: Repeated or prolonged overexposure to solvents
may cause damage to liver and kidneys; and permanent brain and
Hazardous Identification Information: nervous system damage (sometimes referred to as solvent or painter's
The International Agency for Research on Cancer (IARC) lists syndrome). Overexposure may cause systemic toxicity, including
chlorophenoxy herbicides in its Group 2B (limited evidence for adverse effects to blood, CNS, eyes and fetus.
carcinogenicity in humans.) The US EPA has given the chlorophenoxy
herbicides 2,4-D, 2,4-DP, MCPP, and MCPA a Class D classification REPRODUCTIVE TOXICITY: Ths product contains a component(s)
(not classifiable as to human carcinogenicity.) More current 2,4-D which may cause adverse reproductive and/or developmental effects.
lifetime feeding studies in rats and mice did not show carcinogenic Pregnant women may be at an increased risk from exposure.
effects and a recent World Health Organization (WHO) review of 2,4-D Consumption of alcoholic beverages may enhance toxic effects.
toxicology has concluded that 2,4-D is not a carcinogen.
Signs and Symptoms:
Inhalation may cause burning in the chest, with coughing. Prolonged
4. First Aid Measures:
inhalation sometimes causes dizziness. Ingestion usually leads to
vomiting.
Route(s) of Entry:
Medical Conditions Generally Aggravated by Exposure:
Skin contact, Inhalation, Ingestion.
Individuals with chronic skin disease or known sensitivity to
Health Hazards (Acute and Chronic): chlorophenoxy compounds should either avoid using them or take strict
EYES: Corrosive. Causese severe irritation and burning. precautions to avoid contact. (respirator, gloves, etc.)
Emergency First Aid Procedure:
SKIN: Corrosive. Moderately to severely irritating to the skin; may be IN CASE OF EYE CONTACT: Wash with water for at least 15 minutes
absorbed through the skin. and seek medical attention.
INHALATION: Moderately irritating to the mucous membranes. IN CASE OF SKIN CONTACT: Wash with plenty of soap and water. Get
Inhalation of sprays may cause burning sensations in the respiratory medical attention if skin irritation persists.
tract, resulting in coughing. Overexposure by inhalation may cause
cardiac sensitization, including arrhythmias and death due to cardiac IF INGESTED: Do not induce vomiting. Drink milk, egg whites or gelatin;
arrest. if not available, drink plenty of water. Avoid alcohol.
INGESTION: May cause vomiting, with pain in the chest and abdomen,
Page 2 of 3 December 2, 2002
Material Safety Data Sheet
Product Name: Gordon's VEGEMEC Vegetation Killer
MSDS No.: 918-6 Version No.: 012 EPA Registration No.: 33955-454-2217
Exposure Controls/Personal Protection (Continued)
First Aid Measures (Continued)
IF INHALED: Remove victim to fresh air.
RESPIRATORY PROTECTION: If exposure limits may be exceeded,
wear a respirator with an organic-vapor removing cartridge with a prefilter
NOTE TO PHYSICIAN: There is not specific antidote; if ingested, do not
approved for pesticides (MSHA/NIOSH approval number prefix TC-23C),
induce emesis and take care to avoid aspiration of stomach contents
or a NIOSH approved respirator with any R, P or HE filter.
during gastric lavage. Give a saline laxative and supportive therapy.
Other Health Warnings:
9. Physical and Chemical Properties:
Note to physician: Contains petroleum solvents. If this product is
ingested, do not induce vomiting; avoid aspiration of stomach contents
Boiling Point: >240掳F Melting Point: NI
during gastric lavage.
Evaporation Rate (Butyl Acetate = 1) : <1
5. Fire Fighting Measures:
Vapor Pressure (mm Hg.): <10@25掳C
135掳F PM Closed Cup
Flash Point: F.P. Method:
Vapor Density (Air = 1): >1
NI
Lower Explosive Limit:
Specific Gravity (H20 = 1): 0.87470
NI
Upper Explosive Limit:
Solubility in Water: Emulsifiable.
Fire Extinguishing Media:
Appearance and Odor: Amber liquid; solvent odor.
Foam, CO2, and dry chemical.
Other Information:
Special Fire Fighting Procedures:
Density: 7.28 pounds/gallon
Wear positive-pressure breathing apparatus and full protective clothing.
Viscosity: 2-4 cp
Fight fire from maximum distance. Stay up wind and out of low areas.
10. Stability and Reactivity:
Unusual Fire and Explosion:
May be ignited by heat, sparks or flame. Burning may generate
poisonous gases. Run-off from fire control area or dilution water may Stability:
Stable.
cause pollution. If surface water is contaminated, contact local
authorities.
Incompatibility (Materials to Avoid):
6. Accidental Release Measures: None known.
Decomposition/By-Products:
Steps to be Taken in Case Material is Released or Spilled: May produce gases such as HCl when burning.
Do not touch spilled material. See Section 8 for Personal Protective
Equipment. Contain and absorb spilled material on Dri-Rite, sand or Hazardous Polymerization:
other inert absorbent. Collect into drums; cover and label for disposal. Will not occur.
Flush area with water if possible.
11. Toxicological Information:
7. Handling and Storage:
Acute dermal LD50: >2010 mg/kg (rabbit)
Precautions to be Taken:
STORAGE: Store in original container in a locked storage area Oral LD50: >2430 mg/kg (rats)
inaccessible to children and pets. Do not store near food or feedstuffs. To
12. Ecological Information:
prevent cross-contamination, do not store near fertilizers, insecticides,
fungicides, or near seeds. Do not contaminate feed or foodstuffs.
ENVIRONMENTAL HAZARDS:
Other Precautions:
This product is toxic to fish. Drift or runoff may adversely affect nontarget
Do not use or store near heat or open flame.
plants. Do not apply directly to water, or to areas where surface water is
present, or to intertidal areas below the mean high water mark. Do not
8. Exposure Controls/Personal Protection:
contaminate water when disposing of equipment washwater. Apply this
product only as specified on this label.
Ventilation Requirements:
13. Disposal Considerations:
Good local ventilation is recommended; mechanical ventilation may be
used if exposure limits may be exceeded.
PESTICIDE DISPOSAL: Securely wrap original container in several
Personal Protective Equipment:
layers of newspapers and discard in trash.
DANGER: Corrosive. Causes eye and skin irritation. Do not get in eyes,
on skin or clothing. May cause allergic skin reaction. When using this
CONTAINER DISPOSAL: Do not reuse container. Rinse thoroughly
product, wear long-sleeved shirt, long pants, socks, shoes, chemical
before discarding in trash.
resistant gloves and eye protection. It is recommended that safety glasses
include front, brow and temple protection. Wear goggles or face shield
14. Transport Information:
when handling. Harmful or fatal if swallowed. Do not breathe spray mist.
After using this product, rinse gloves before removing, remove clothing The following guidelines apply for domestic ground transport. If shipping
and launder separately before reuse, and promptly and thoroughly wash by air or ocean, please contact our Transportation Dept.
hands and exposed skin with soap and water. Remove saturated clothing
as soon as possible and shower. Freight Class: Herbicides, NOI - NMFC #50320
PROTECTIVE CLOTHING: Wear long sleeves and pants; In our current available sizes, this product does not qualify as a
chemical-resistant gloves and shoes with socks. Hazardous Material.
EYE PROTECTION: Safety glasses with side shields or safety goggles.
December 2, 2002
Page 3 of 3
Material Safety Data Sheet
Product Name: Gordon's VEGEMEC Vegetation Killer
MSDS No.: 918-6 Version No.: 012 EPA Registration No.: 33955-454-2217
15. Regulatory Information:
OSHA STATUS: This product is hazardous under the criteria of the
Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA STATUS: This product is exempt from TSCA Regulation under
FIFRA Section 3(2)(B)(ii) when used as a pesticide.
CERCLA REPORTABLE QUANTITY: 6993 pounds of the formulation
which contains 100 pounds of Xylene
SARA TITLE III:
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: None
SECTION 311/312 HAZARD CATEGORIES: Immediate Health
Hazard, Delayed Health Hazard, Fire Hazard
SECTION 313 TOXIC CHEMICALS: 2,4-D CAS# 94-75-7, Xylene
CAS# 1330-20-7
RCRA STATUS: When discarded in its purchased form, this product is a
listed RCRA hazardous waste and should be managed as a hazardous
waste. (40 CFR 261.20-24)
16. Other Information:
REASON FOR ISSUE: To revise Sections 2, 5, 9, 15.
NOTE: NI means not indicated.
The information and statements in this Material Safety Data Sheet are
believed to accurately reflect the scientific evidence used in making the
hazard determination, but is not to be construed as a warranty or
representation for which we assume legal responsibiltiy. Additional
information may be necessary or desirable depending on particular,
exceptional or variable conditions or circumstances of use or storage or
because of locally applicable laws or government regulations. Therefore,
you should use this information only as a supplement to other information
available to you and must make independent determinations of the
suitability of the information for your particular circumstances or
conditions and of the completeness of the information available from all
sources to assure both the proper use of the material described herein
and the safety and health of employees.
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