Material Safety Data Sheet US Department of Labor
May be used to comply with Occupational Safety and Health Administration
OSHA's Hazard Communication Standard, (Non-Mandatory Form)
29 CFR 1910.1200. Standard must be consulted Form Approved
for specific requirements. OMB No. 1218-0072
IDENTITY (As Used on Label and List)
Bonide Turbo Spreader/Sticker
Date: October 8, 1998
Section I
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Bonide Products, Inc. (800) 424-9300
2 Wurz Ave. (315) 736-8231
Yorkville, NY 13495
Section II - Hazardous Ingredients/Identity
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Hazardous Components (Specific Chemical Identity: Common Name(s) OSHA PEL ACGIH TLV Other Limits % (Optional )
1.) Modified Phthalic/Glycerol Alkyl Resin 75-80
2.) 1,1,1-Trichloroethane CAS#71-55-6 20-25
Exposure Limit Information ROHM &HAAS ___OSHA___ ___ACGIH__
Component Units TWA STEL TWA STEL TLV STEL
1.) None None None None None None
2.) ppm 100 150 350 450 350 450
Section III - Hazard Information
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HEALTH EFFECTS FROM OVEREXPOSURE: PRIMARY ROUTES OF EXPOSURE: Inhalation, Skin contact,
and Eye Contact. INHALATION: Inhalation of vapor or mist can cause the following: Irritation of nose and
throat, drowsiness, slurred speech, headache, nausea, dizziness, stupor, and unconsciousness. EYE CONTACT:
Material can cause the following: Moderate irritation. SKIN CONTACT: Prolonged or repeated skin contact can
cause the following: Moderate skin irritation, splitting and cracking DELAYED EFFECTS: Repeated overexposure
to the solvents in this product can cause the following: Kidney damage, liver damage, and heart damage.
Section IV - First Aid Measures
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FIRST AID PROCEDURES: INHALATION: Move subject to fresh air. Give artificial respiration if breathing has
stopped. INGESTION: If swallowed, give 2 glasses of water to drink. Consult a physician. Never give anything
by mouth to an unconscious person. EYE AND SKIN CONTACT: Immediately flush eyes with a large amount of
water for at least 15 minutes. See a physician. Wash affected skin areas thoroughly with soap and water. Remove
and wash contaminated clothing thoroughly. NOTE TO PHYSICIAN: Because of the sensitizing effects of the
hydrocarbon compounds on the myocardium, sympathomimetic amines, like epinephrine, should be avoided.
Section V - Fire Fighting Measures
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UNUSUAL HAZARDS: Combustion generates toxic fumes of the following: Hydrogen Chloride.
EXTINGUISHING AGENTS: Use the following extinguishing media when fighting fires involving this material:
Carbon Dioxide, Water Spray, Dry Chemical. PERSONAL PROTECTIVE EQUIPMENT: Wear self-contained
breathing apparatus (pressure-demand MSHA/NIOSH approved equivalent) and full protective gear. SPECIAL
PROCEDURES: Use water spray to cool containers exposed to fire.
Section VI - Spill or Leak Handling Information
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PERSONAL PROTECTION: Appropriate protective equipment must be worn when handling a spill of this material.
See the Personal Protection Measures Section for recommendations. If exposed to material during clean-up
operations, see the First Aid Procedures Section for actions to follow.
PROCEDURES: Evacuate the spill area. Floor may be slippery; use care to avoid falling. Contain spills
immediately with inert materials (e.g. sand, earth). Transfer liquids and solid diking material to separate suitable
containers for recovery or disposal. CAUTION: Keep spills and cleaning runoff out of municipal sewers and open
bodies of water.
Section VII - Waste Disposal
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Incinerate liquid and contaminated solids in accordance with local, state and federal regulations.
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Section VIII - Personal Protection Measures
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RESPIRATORY PROTECTION: None required if airborne concentrations are maintained below the TWA/TLV's
listed in the Component Exposure Information Section. For airborne concentrations up to 10 times the TWA/TLV's
listed in the Component Exposure Information Section wear a MSHA/NIOSH approved (or equivalent) half-mask,
air-purifying respirator. Air-purifying respirators should be equipped with organic vapor cartridges and dust and
mist filters. EYE PROTECTION: Use chemical splash goggles (ANSI Z87.1 or approved equivalent). HAND
PROTECTION: Glove permeation data does not exist for this material. The following glove(s) should be used for
splash protection only: VITON (registered Trademark of E.I. Dupont). Polyvinyl Alcohol. Gloves should be
removed and replaced immediately if there is any indication of degradation or chemical breakthrough. Rinse and
remove gloves immediately after use. Wash hands with soap and water. OTHER PROTECTION: Use chemically
resistant apron or other impervious clothing to avoid prolonged or repeated skin contact.
Section IX - Fire and Explosive Properties
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FLASH POINT: 99掳C/210掳F. Set-a-flash Closed Cup. AUTO-IGNITION TEMPERATURE: 537掳C/999掳F. Solvent
LOWER EXPLOSIVE LIMIT: 8.0% Solvent UPPER EXPLOSIVE LIMIT: 10.5% Solvent
Section X - Reactivity Information
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INSTABILITY: This material is considered stable.
INCOMPATIBILITY: Contact with the following materials may cause a reaction generating heat or decomposition:
Aluminum and Magnesium.
HAZARDOUS POLYMERIZATION: Product will not undergo polymerization
HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition may yield the following: Phosgene,
Chlorine Gas and Hydrogen Chloride.
Section XI - Toxicity Information
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ACUTE DATA: ORAL LD50: rat: > 5000 mg/kg. EYE IRRITATION: rabbit: moderate irritation.
DERMAL LD50: rabbit: > 5000 mg/kg. SKIN IRRITATION: rabbit: moderate irritation.
Section XII - Regulatory Information
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WORKPLACE CLASSIFICATIONS: This product is considered hazardous under the OSHA Hazard
Communication Standard (29CFR 1910.1200). This product is exempt from the Canadian Workplace Hazardous
Materials Information System (WHMIS).
TRANSPORTATION CLASSIFICATIONS: US DOT Hazard Class.....NonRegulated EMERGENCY PLANNING
AND COMMUNITY RIGHT-TO-KNOW (SARA TITLE 3): SECTION 311/312 CATEGORIZATIONS (40CFR
370): This product is a hazardous chemical under 29cfr 1910.1200, and is categorized as an immediate health
hazard. SECTION 313 INFORMATION (40CFR 372): This product contains a chemical which is listed in Section
313 above de minimis concentrations. The following listed chemicals are present: (Quantity present is found
elsewhere on this MSDS.) 1,1,1-Trichloroethane (71-55-6)
CERCLA INFORMATION (40CFR 302.4): This material has a component or components with a reportable
quantity under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the
Superfund Amendments and Reauthorization Act (SARA) Title III Section 304. The components, CAS numbers,
and reportable quantities are listed below. Spills of a component in excess of its reportable quantity must be
reported to the National Response Center (1-800-424-8802) and to the appropriate state and local emergency
response organizations. 1,1,1-Trichloroethane (71-55-6) 1000lbs.
RCRA INFORMATION: When this product becomes a waste, it is classified as a non-hazardous waste under
criteria of the Resource Conservation and Recovery Act (40CFR 261).
CHEMICAL CONTROL LAW STATUS: All components of this product are listed or are excluded from listing on
the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Section XIII - Facility Control Measures
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VENTILATION: Use local exhaust ventilation with a minimum capture velocity of 100 ft./min. (30 m/min.) at the point
of vapor evolution. Refer to the current edition of Industrial Ventilation: A Manual of Recommended Practice published
by the American Conference of Governmental Industrial Hygienists for information of the design, installation, use, and
maintenance of exhaust systems.
OTHER PROTECTIVE EQUIPMENT: Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower.
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Section XIV - Storage Conditions
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Store in a well-ventilated area. Do not store this material near food, feed, or drinking water.
Section XV - Supplemental Information
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COLOR: Brown STATE: Liquid
ODOR CHARACTERISTIC: Solvent Odor VISCOSITY: 120 CPS @25掳C/77掳F.
SPECIFIC GRAVITY (Water=1): 1.095 VAPOR DENSITY (Air=1): > 1
VAPOR PRESSURE: 100 mm Hg @ 20掳C/ 68掳F. Solvent MELTING POINT: -12掳C/ 10掳F
BOILING POINT: 74掳C/ 165掳F. Solvent SOLUBILITY IN WATER: Dispersible
PERCENT VOLATILITY: 20-25% EVAPORATION RATE (BAc=1): > 1
HAZARD RATING SCALE
Toxicity 2 4=Extreme
Fire 1 3=High
Reactivity 0 2=Moderate
Special - 1=Slight
0=Insignificant
NOTICE: This information is believed to be accurate and reliable. However, no guarantee expressed or implied is
made with respect to the information contained herein.
KEEP OUT OF REACH OF CHILDREN
ABBREVIATION KEY
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N/A: NOT AVAILABLE OR APPLICABLE N/E: NOT ESTABLISHED ND: Not Determined
TLV: THRESHOLD LIMIT VALUE TWA: TIME WEIGHTED AVG./8 HOUR WORKDAY
STEL: SHORT TERM EXPOSURE LIMIT D.O.T.: DEPARTMENT OF TRANSPORTATION
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
Buyer assumes all risks of use, storage and handling of this material not in strict accordance with directions given herewith.
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