Personalformulator.com
97 S. Red Willow Rd.
Evanston, WY 82930
US 1-800-426-2457 Ext. 1003
Material Safety Data Sheet
Ultrez 10
Last Revised: 7/20/06
1. Product Identification 6. Exposure Controls & Personal Protection
Product Name: Ultrez 10 Respiratory Protection: If respirable dust exposures exceed 0.05
INCI Name: Carbomer mg/m3 (8-hour TWA), wear a NIOSH-approved respirator equipped with
Chem. N.: Polymer/solids high efficiency particulate (HEPA) filters. Use respirator in accordance with
CAS Number(s): Proprietary manufacturer鈥檚 use limitations and OSHA standard 1910.134 (29 CFR).
Eye Protection: Eye protection (e.g. goggles) suitable for keeping dust
out of the eyes.
2. Physical and Chemical Properties
Protective Clothing: Wear protective gloves
Bulk Density: 0.19-0.24 g/ml Engineering Controls: Always provide effective general and, when
Vapor Density: Non-volatile necessary, local exhaust ventilation to draw dust away from workers to
% Volatile by Weight: < 3.0% prevent routine inhalation. Ventilation must be adequate to maintain the
Specific Gravity: ~ 1.4 ambient workplace atmosphere below the exposure limit(s).
pH Value: (@ 1% in H2O) ~ 2.5-3.0
Appearance & Odor: White fluffy powder, slight acidic odor 7. Hazards Identification
Acute Health Effects: Powder/dust eye irritation is a physical, not a
3. Stability and Reactivity
chemical effect. Solid particulates on the eye (powder/dust) may cause pain
Chemical Stability: This product is stable and be accompanied by irritation. Dust inhalation may cause coughing,
Incompatibility: Heat may generate if polymer comes in contact with mucous production and shortness of breath.
strong basic materials such as ammonia, sodium hydroxide, potassium Chronic Health Effects: Contact dermatitis may occur in individuals
hydroxide or strongly basic amines. Precautions beyond those described under extreme conditions of prolonged and repeated contact, high exposure
herein, such as chemical splash goggles or protective clothing, must be and temperature, and occlusion (held onto the skin) by clothing. No evidence
considered as the need exists. of adverse lung effects from polyacrylate dust exposure was observed in
Hazardous Decomposition: Carbon monoxide, carbon dioxide, studies of workers. Neither lower airway symptoms, chronic parenchylate
hydrocarbons, and irritating vapors disease, radiographic changes, nor clinically important effects on lung
Hazardous Polymerization: Will not occur function were found to result from polyacrylate exposure. Only a small
increase in upper respiratory symptoms appeared to be related to exposure.
However, various lung effects such as inflammation, hyperplasia (abnormal
4. Handling and Storage
increases in the number of cells composing a tissue or organ), scarring
(fibrosis), changes in the air sac (alveolar) ducts of the lung, and tumors were
Do not get in eyes. Do not ingest, taste or swallow. Avoid repeated or
prolonged skin contact. Avoid routine inhalation of dust of any kind. noted in laboratory studies with rodents inhaling concentrations of a water
absorbent sodium polyacrylate dust greater than 0.05 mg/m3 for the majority
Exercise care when emptying containers, sweeping, mixing or doing other
of their lives. Furthermore, some lung or lung cell effects were found in
tasks which can create dust. Bond, ground and properly vent conveyors, dust
control devices and other transfer equipment. Eliminate ignition sources (e.g. rodent laboratory studies of shorter duration.
Routes of Entry/Exposure: Skin contact, inhalation, ingestion and
sparks, static buildup, excessive heat) Although the risk of a dust explosion
is low, as a precaution, implement the following safety measures: Prohibit eye contact
Target Organs: Respiratory system and skin
flow of polymer, powder or dust through non-conductive ducts, vacuum
Medical Conditions Aggravated by Exposure: Pre-existing skin
hoses or pipes, etc; only use grounded, electrically conductive transfer lines
when pneumatically conveying product. Prevent accumulation of dust (e.g. problems may be aggravated by prolonged or repeated contact. Pre-existing
well-ventilated conditions, promptly vacuuming spills, cleaning overhead respiratory disease(s) may be aggravated by prolonged or repeated inhalation
horizontal surfaces, etc.) Wash thoroughly after handling this product. of airborne dust.
Signs and Symptoms of Exposure: Irritation
Always wash up before eating, smoking, or using the facilities. Use under
well-ventilated conditions. Keep container closed when not in use. Store in
dry area.
8. First Aid Measures
Eyes: Immediately flush eyes with plenty of one percent (1%)
5. Accidental Release Measures
physiological saline for five minutes while holding eyelids open; see a
Using care to avoid dust generation, vacuum or sweep into a closed physician. If no saline is easily available, flush eyes with plenty of clean
container for reuse or disposal. Do not sweep or flush spilled product into water for 15 minutes; see a physician. Water (moisture) swells this product
public sewer, streams or other water systems. If inhalation of dust cannot be into a gelatinous film and, when in contact with the eye, may be difficult
avoided, wear a particulate respirator approved by NIOSH/MSHA. Caution: Skin: Wash the affected area thoroughly with plenty of water and soap
Contact with water creates a slippery film. If this occurs, the film can be Inhalation: If any processing vapors, decomposition products or
cleaned up with detergent solution. particulates are inhaled, remove individual(s) to fresh air. Provide protection
before allowing reentry.
Ingestion: No ingestion effects known. Treat symptomatically.
Important Notice: The information presented herein is based on experimental data submitted by the manufacturers
of the raw materials and is considered scientifically correct; however, no warrant or representation, express or implied, is
made as to the accuracy or suitability of this information for application to the purchaser鈥檚 intended purpose or for
consequences of its use and we assume no responsibility for any loss, damage or expense, direct or consequential, arising
out of its use. Use these materials only as directed. If you have any questions regarding the proper interpretation of this
sheet or the meanings of any terms used, we strongly urge you to speak with your physician. For further information
concerning product safety and proper use, call the number listed on the front of the MSDS.
Personalformulator.com
97 S. Red Willow Rd.
Evanston, WY 82930
US 1-800-426-2457 Ext. 1003
Material Safety Data Sheet
Ultrez 10
Last Revised: 7/20/06
application to skin of 98 human panelists. The primary irritation/activation
9. Fire Fighting Measures
period consisted of twelve applications per panelist on four consecutive days
Fire and Explosive Properties: This product has a high volume of weeks 1,2 and 3. The patches were removed and the contact sites were
resistivity and a propensity to build up static electricity which may be examined 24 hours after each application. Following a one week rest period,
discharged as a spark. A spark can be an ignition source for solvent vapor/air a challenge period was conducted with four applications of the test material
mixtures. If you add this product to a solvent, ensure appropriate safe applied to the test site.
handling practices such as provision for inerting flammable vapors and 96 Hour static acute toxicity: Daphne Magna LC50 168-280 mg/L
measures such as those cited above. As with all organic dusts, fine particles Acrylic polymer
suspended in air in critical proportions and in the presence of an ignition 96 hour static acute toxicity: Bluegill, sunfish, LC50 580-2000 mg/L
source may ignite and/or explode. Dust may be sensitive to ignition by Skin: No evidence of irritation or sensitization during human patch
electrostatic discharge, electrical arcs, sparks, welding torches, cigarettes, testing.
open flame or other significant heat sources. As a precaution, implement Chronic oral toxicity: No significant effects in rats or dogs fed with resin
standard safety measures for handling finely divided organic powders. as 5% of diet for 6-1/2 months.
Typical results expected for this family of products:
Minimum explosive concentration: 0.080 oz/ft3 (80g/m3)
11. Disposal Considerations
Minimum ignition energy: 0.20 joules (dispersed dust cloud)
Deflagration index, Kst 275 bar m/sec For waste disposal purposes, this product is not known to be defined or
Maximum rate of pressure rise: 786 bar/s @ 500 g/m3 (11,400 psi/sec @ designated as hazardous by current provisions of the Federal (EPA) Resource
0.5 oz/ft3) Conservation and Recovery Act (RCRA, 40 CFR261). Incinerate or landfill
Maximum pressure of explosion: 6 bar @ 500 g/m3 (87 psi @ 0.5 oz/ft3) waste in a properly permitted facility in accordance with federal, state and
Volume resistivity: >3.68 x 10 + 15 ohm-cm local regulations. In appropriate dust/air ratio, dust cloud in air has explosion
Explosion severity: >5 (severe) potential. Therefore, land disposal must be in closed containers. If disposal is
National electrical code (NFPA 70): group G dust in bulk form, recognize that this polymer absorbs moisture resulting in a
Extinguishing Media: Use water spray, dry chemical or foam. Carbon gelatinous mass that is unable to support human weight.
dioxide may be ineffective on larger fires due to a lack of cooling capacity
which may result in reignition.
Fire Fighting Procedures: Avoid hose streams or any method which
will create dust clouds. Wear self-contained breathing apparatus (SCBA)
equipped with a full face piece and operated in a pressure-demand mode (or
other positive pressure mode) and approved protective clothing. Personnel
without suitable respiratory protection must leave the area to prevent
significant exposure to hazardous gases from combustion, burning or
decomposition. In an enclosed or poorly ventilated area, wear SCBA during
cleanup immediately after a fire as well as during the attack phase of
firefighting operations.
10. Toxicological Information
Acute Oral LD50: > 2500.00 mg/kg rat/adult
Skin LD50: > 3000.00 mg/kg rabbit/ adult
Note: Caution must be exercised through the prudent use of protective
equipment and handling procedures to minimize exposure. These results for
polyacrylic acid. Skin and eye irritation were evaluated using the product as-
supplied (i.e. powder) and as a 1% solution (neutralized to pH ~7.0) on
rabbits using international OECD guidelines: As a powder, very slight
erythema (redness of the skin) and edema (swelling) occurred with all
responses subsiding by the end of the seven day observation period. As a 1%
solution, very slight erythema was observed at four hours on one of the six
test animals. Slight irritant (rabbit) powder: Primary irritation index 0.9-1.5.
Non-irritant to very slight irritant (rabbit), 1% solution: Primary irritation
index 0.0-0.1. As a powder, slight to moderate corneal and conjunctival
irritation occurred with all responses clearing by the endof the secen day
observation period. As a 1% solution, very slight iridal conjunctival irritation
was noted with all irritation clear by 72 hours. Human repeated patch tests
produced no product-related irritation or sensitization during the primary
irritation/activation or challenged period. Surgical gauze pads were
impregnated with product and moistened with distilled water just prior to
Important Notice: The information presented herein is based on experimental data submitted by the manufacturers
of the raw materials and is considered scientifically correct; however, no warrant or representation, express or implied, is
made as to the accuracy or suitability of this information for application to the purchaser鈥檚 intended purpose or for
consequences of its use and we assume no responsibility for any loss, damage or expense, direct or consequential, arising
out of its use. Use these materials only as directed. If you have any questions regarding the proper interpretation of this
sheet or the meanings of any terms used, we strongly urge you to speak with your physician. For further information
concerning product safety and proper use, call the number listed on the front of the MSDS.
Personalformulator.com
97 S. Red Willow Rd.
Evanston, WY 82930
US 1-800-426-2457 Ext. 1003
Material Safety Data Sheet
Ultrez 10
Last Revised: 7/20/06
Important Notice: The information presented herein is based on experimental data submitted by the manufacturers
of the raw materials and is considered scientifically correct; however, no warrant or representation, express or implied, is
made as to the accuracy or suitability of this information for application to the purchaser鈥檚 intended purpose or for
consequences of its use and we assume no responsibility for any loss, damage or expense, direct or consequential, arising
out of its use. Use these materials only as directed. If you have any questions regarding the proper interpretation of this
sheet or the meanings of any terms used, we strongly urge you to speak with your physician. For further information
concerning product safety and proper use, call the number listed on the front of the MSDS.
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