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MSDS Material Safety Data Sheet
CAS

63231-67-4

File Name: palomar_edu---silica_gel.asp
            PRODUCT #: H8269        NAME: HPLC SORBENT SILICA GEL SIZE 5 UM
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Thursday, March 13, 1903 4:15PM

Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850




SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: H8269
NAME: HPLC SORBENT SILICA GEL SIZE 5 UM
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 63231-67-4
SYNONYMS
A 4 * BIO-SIL RP 304 * CHROMAROD SII * CHROMOSORB LC 6 * DYNAGROUT SB
* DYNAGROUT SP * FK 310 * FRACTOSIL 500 * GASIL * GEMODEZ * GULSENIT-
STABIL * HI-SIL * KIESELGEL * KSK * KSM * KSMG * KSS 3 * KSS 4 * L
100 * LICHROPREP * LICHROSORB SI 60 * LICHROSPHERE SI 60 *
LICHROSPHERE SI 100 * LICHROSPHERE SI 500 * LICHROSPHERE SI 4000 *
LICHROSPHERE SI 1000 * MERCKOSORB SI 60 * MIZUKASIL P 801N * MSA 2500
* N 1030 * NDG 4L * NDG 5L * NEOBEAD SA * NIPSIL N 300A * NS 62 * NS
70 * PARTISIL * PLENAMIX 1013 * POLYPOR * PORASIL A * S 80 (VAN) * S
120 * SEPARON SI VSK * SEPARON SIX * SG-N 7 * SG-N 8 * SG-N 9 * SG 6 *
SILENE D * SILICA BS 280 * SILICA CM * SILICA CMS * META-SILICIC
ACID * SILLITIN * SILLITIN N 85 * SILLITIN PF 100 * SILOCHROME *
SILPEARL * SMD 1 * SMD 3 * SORBSIL * SPHERISORB * SPHEROSIL * ST 6 *
STABIFIX * STABIQUICK * SYLOBLANC * SYLOID * TSK-GEL SILICA 60 *
WAKOGEL 200 * WAKOGEL B 5 * WAKOGEL C 300 * WAKOGEL LC 10K * Y 333 *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
HARMFUL
HARMFUL BY INHALATION.
IRRITATING TO EYES AND RESPIRATORY SYSTEM.
TARGET ORGAN(S):
LUNGS
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING.
DO NOT BREATHE DUST.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF
WATER FOR AT LEAST 15 MINUTES.
ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS
WITH FINGERS.
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS
AMOUNTS OF WATER.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
NONCOMBUSTIBLE.
USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.

Page 1
PRODUCT #: H8269 NAME: HPLC SORBENT SILICA GEL SIZE 5 UM
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Thursday, March 13, 1903 4:15PM

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
CHEMICAL SAFETY GOGGLES.
COMPATIBLE CHEMICAL-RESISTANT GLOVES.
NIOSH/MSHA-APPROVED RESPIRATOR IN NONVENTILATED AREAS AND/OR FOR
EXPOSURE ABOVE THE ACGIH TLV.
SAFETY SHOWER AND EYE BATH.
MECHANICAL EXHAUST REQUIRED.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
WHITE TO BUFF TO PALE-GREY POWDER
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
STRONG ACIDS
HYDROGEN FLUORIDE
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
NATURE OF DECOMPOSITION PRODUCTS NOT KNOWN.
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF INHALED.
MAY BE HARMFUL IF SWALLOWED.
MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
CAUSES EYE IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
MAY CAUSE SKIN IRRITATION.
CHRONIC EFFECTS
TARGET ORGAN(S):
LUNGS
RTECS #: VV7340000
SILICA GEL
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
BURY IN A LANDFILL SITE APPROVED FOR THE DISPOSAL OF CHEMICAL
AND HAZARDOUS WASTES.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
CAUTION: SUBSTANCE NOT YET FULLY TESTED.
HARMFUL
R 20
HARMFUL BY INHALATION.
R 36/37
IRRITATING TO EYES AND RESPIRATORY SYSTEM.

Page 2
PRODUCT #: H8269 NAME: HPLC SORBENT SILICA GEL SIZE 5 UM
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Thursday, March 13, 1903 4:15PM

S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 36
WEAR SUITABLE PROTECTIVE CLOTHING.
S 22
DO NOT BREATHE DUST.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION
FEREAC 54,7740,1989
NOHS 1974: HZD M1532; NIS 68; TNF 6544; NOS 65; TNE 73973
NOES 1983: HZD M1532; NIS 68; TNF 8014; NOS 61; TNE 69100; TFE 7109
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY




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