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MSDS Material Safety Data Sheet
CAS

814-94-8

File Name: palomar_edu---stannous_oxalate.asp
                      PRODUCT #: S3502        NAME: STANNOUS OXALATE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 18, 1903 1:16PM

Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850




SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: S3502
NAME: STANNOUS OXALATE
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 814-94-8
MF: C2O4SN
EC NO: 212-414-0
SYNONYMS
ETHANEDIOIC ACID, TIN(2+) SALT (1:1) (9CI) * OXALIC ACID, TIN(2+)
SALT (1:1) (8CI) * STANNOUS OXALATE * STAVELAN CINATY (CZECH) *
TIN(2+) OXALATE * TIN OXALATE *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
HARMFUL
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
RISK OF SERIOUS DAMAGE TO EYES.
TARGET ORGAN(S):
NERVES
KIDNEYS
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS AMOUNTS OF
WATER FOR AT LEAST 15 MINUTES.
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS
AMOUNTS OF WATER.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
WATER SPRAY.
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -
WEAR RESPIRATOR, CHEMICAL SAFETY GOGGLES, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL.
AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.

Page 1
PRODUCT #: S3502 NAME: STANNOUS OXALATE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 18, 1903 1:16PM

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
SAFETY SHOWER AND EYE BATH.
MECHANICAL EXHAUST REQUIRED.
DO NOT BREATHE DUST.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING.
HARMFUL SOLID.
SEVERE EYE IRRITANT.
KEEP CONTAINER CLOSED.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
WHITE POWDER
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
STRONG OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
TOXIC FUMES OF:
CARBON MONOXIDE, CARBON DIOXIDE
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN.
CAUSES SEVERE EYE IRRITATION.
CAUSES SKIN IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
TARGET ORGAN(S):
NERVES
KIDNEYS
G.I. SYSTEM
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
RTECS #: XQ3950000
TIN(II) OXALATE
TOXICITY DATA
ORL-RAT LD50:3620 MG/KG MARJV# 29MAR1977
TARGET ORGAN DATA
LUNGS, THORAX OR RESPIRATION (OTHER CHANGES)
KIDNEY, URETER, BLADDER (OTHER CHANGES)
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES
(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A
CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
HARMFUL
R 20/21/22

Page 2
PRODUCT #: S3502 NAME: STANNOUS OXALATE
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 18, 1903 1:16PM

HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
R 36/37/38
IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
R 41
RISK OF SERIOUS DAMAGE TO EYES.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 36
WEAR SUITABLE PROTECTIVE CLOTHING.
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
ACGIH TLV-TWA 2 MG(SN)/M3 DTLVS* TLV/BEI,1996
MSHA STANDARD-AIR:TWA 2 MG(SN)/M3
DTLVS* 3,257,1971
OSHA PEL (GEN INDU):8H TWA 2 MG(SN)/M3
CFRGBR 29,1910.1000,1994
OSHA PEL (CONSTRUC):8H TWA 2 MG(SN)/M3
CFRGBR 29,1926.55,1994
OSHA PEL (SHIPYARD):8H TWA 2 MG(SN)/M3
CFRGBR 29,1915.1000,1993
OSHA PEL (FED CONT):8H TWA 2 MG(SN)/M3
CFRGBR 41,50-204.50,1994
OEL-AUSTRALIA:TWA 2 MG(SN)/M3 JAN 1993
OEL-BELGIUM:TWA 2 MG(SN)/M3 JAN 1993
OEL-DENMARK:TWA 2 MG(SN)/M3 JAN 1993
OEL-FINLAND:TWA 2 MG(SN)/M3 JAN 1993
OEL-GERMANY:TWA 2 MG(SN)/M3 JAN 1993
OEL-HUNGARY:TWA 1 MG(SN)/M3;STEL 2 MG(SN)/M3;SKIN JAN 1993
OEL-THE NETHERLANDS:TWA 2 MG(SN)/M3 JAN 1993
OEL-THE PHILIPPINES:TWA 2 MG(SN)/M3 JAN 1993
OEL-SWITZERLAND:TWA 2 MG(SN)/M3;STEL 4 MG(SN)/M3 JAN 1993
OEL-THAILAND:TWA 2 MG(SN)/M3 JAN 1993
OEL-UNITED KINGDOM:TWA 5 MG(SN)/M3;STEL 10 MG(SN)/M3 JAN 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGIH TLV
NOHS 1974: HZD 83516; NIS 1; TNF 8; NOS 3; TNE 88
NOES 1983: HZD 83516; NIS 1; TNF 72; NOS 3; TNE 2953; TFE 504
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY




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