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MSDS Material Safety Data Sheet
CAS

124-41-4
67-56-1

File Name: palomar_edu---sodium_methoxide.asp
               PRODUCT #: 403067       NAME: SODIUM METHOXIDE ACS REAGENT
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 18, 1903 11:10AM

Sigma Chemical Co. Aldrich Chemical Co., Inc. Fluka Chemical Corp.
P.O. Box 14508 1001 West St. Paul 1001 West St. Paul
St. Louis, MO 63178 Milwaukee, WI 53233 Milwaukee, WI 53233
Phone: 314-771-5765 Phone: 414-273-3850 Phone: 414-273-3850




SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -
CATALOG #: 403067
NAME: SODIUM METHOXIDE ACS REAGENT
SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -
CAS #: 124-41-4
MF: CH3NAO
EC NO: 204-699-5
ADDITIONAL INFORMATION
CONTAINS METHYL ALCOHOL, CHEMICAL ABSTRACTS REGISTRY NUMBER 67-56-1.
SYNONYMS
SODIUM METHOXIDE * SODIUM METHYLATE (UN1431) (DOT) * SODIUM METHYLATE
SOLUTIONS IN ALCOHOL (UN1289) (DOT) * UN1431 (DOT) * UN1289 (DOT) *
SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -
LABEL PRECAUTIONARY STATEMENTS
FLAMMABLE (USA)
HIGHLY FLAMMABLE (EU)
TOXIC
TOXIC BY INHALATION AND IF SWALLOWED.
IRRITATING TO EYES AND SKIN.
TARGET ORGAN(S):
EYES
KIDNEYS
KEEP CONTAINER TIGHTLY CLOSED.
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
AVOID CONTACT WITH SKIN.
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).
SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES.
ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS
WITH FINGERS.
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.
CALL A PHYSICIAN.
SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -
EXTINGUISHING MEDIA
CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
EXTREMELY FLAMMABLE.
VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND
FLASH BACK.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -

Page 1
PRODUCT #: 403067 NAME: SODIUM METHOXIDE ACS REAGENT
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 18, 1903 11:10AM

EVACUATE AREA.
SHUT OFF ALL SOURCES OF IGNITION.
WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
COVER WITH DRY-LIME, SAND, OR SODA ASH. PLACE IN COVERED CONTAINERS
USING NON-SPARKING TOOLS AND TRANSPORT OUTDOORS.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -
REFER TO SECTION 8.
SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT
GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.
MECHANICAL EXHAUST REQUIRED.
SAFETY SHOWER AND EYE BATH.
DO NOT BREATHE VAPOR.
AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID PROLONGED OR REPEATED EXPOSURE.
DO NOT USE IF SKIN IS CUT OR SCRATCHED. WASH THOROUGHLY AFTER
HANDLING.
TOXIC.
IRRITANT.
KEEP TIGHTLY CLOSED.
KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
STORE IN A COOL DRY PLACE.
SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -
APPEARANCE AND ODOR
CLEAR, COLORLESS LIQUID
SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -
INCOMPATIBILITIES
ACIDS
ACID CHLORIDES
ACID ANHYDRIDES
OXIDIZING AGENTS
REDUCING AGENTS
ALKALI METALS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
TOXIC FUMES OF:
CARBON MONOXIDE, CARBON DIOXIDE
SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -
ACUTE EFFECTS
HARMFUL IF INHALED.
HARMFUL IF SWALLOWED.
MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
CAUSES EYE AND SKIN IRRITATION.
MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT.
EXPOSURE CAN CAUSE:
GASTROINTESTINAL DISTURBANCES
MAY CAUSE CONVULSIONS.
TARGET ORGAN(S):
EYES
KIDNEYS
LIVER
HEART
RTECS #: PC3570000
METHANOL, SODIUM SALT
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES

Page 2
PRODUCT #: 403067 NAME: SODIUM METHOXIDE ACS REAGENT
MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98
Printed Tuesday, March 18, 1903 11:10AM

(RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR
COMPLETE INFORMATION.
SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -
DATA NOT YET AVAILABLE.
SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -
BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND
SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY
FLAMMABLE.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -
CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -
EUROPEAN INFORMATION
HIGHLY FLAMMABLE
TOXIC
R 23/25
TOXIC BY INHALATION AND IF SWALLOWED.
R 36/38
IRRITATING TO EYES AND SKIN.
HIGHLY FLAMMABLE
S7
KEEP CONTAINER TIGHTLY CLOSED.
S 16
KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.
S 24
AVOID CONTACT WITH SKIN.
S 45
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).
TLV AND SOURCE
FOR METHYL ALCOHOL - SKIN:
ACGIH TLV-TWA: 200 PPM (260 MG/M3); STEL: 250 PPM (310 MG/M3).
OSHA PEL: 8 H TWA 200 PPM (260 MG/M3); STEL: 250 PPM (310 MG/M3).
REVIEWS, STANDARDS, AND REGULATIONS
OEL=MAK
NOHS 1974: HZD 80549; NIS 6; TNF 185; NOS 14; TNE 3624
NOES 1983: HZD 80549; NIS 9; TNF 330; NOS 27; TNE 18230; TFE 4356
EPA TSCA SECTION 8(B) CHEMICAL INVENTORY
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997
U.S. INFORMATION
96.7% METHANOL 67-56-1
THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.
SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR
PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,
FLUKA CHEMIE AG
LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY




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