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MSDS Material Safety Data Sheet
CAS

124-41-4
67-56-1

File Name: palomar_edu---sodium_methoxide.asp
 
               PRODUCT #: 403067       NAME: SODIUM METHOXIDE ACS REAGENT

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Tuesday, March 18, 1903 11:10AM



Sigma Chemical Co.         Aldrich Chemical Co., Inc.     Fluka Chemical Corp.

P.O. Box 14508             1001 West St. Paul             1001 West St. Paul

St. Louis, MO 63178        Milwaukee, WI 53233            Milwaukee, WI 53233

Phone: 314-771-5765        Phone: 414-273-3850            Phone: 414-273-3850









SECTION 1. - - - - - - - - - CHEMICAL IDENTIFICATION- - - - - - - - - -

    CATALOG #:            403067

    NAME:                 SODIUM METHOXIDE ACS REAGENT

SECTION 2. - - - - - COMPOSITION/INFORMATION ON INGREDIENTS - - - - - -

    CAS #:   124-41-4

    MF: CH3NAO

    EC NO: 204-699-5

  ADDITIONAL INFORMATION

    CONTAINS METHYL ALCOHOL, CHEMICAL ABSTRACTS REGISTRY NUMBER 67-56-1.

  SYNONYMS

    SODIUM METHOXIDE * SODIUM METHYLATE (UN1431) (DOT) * SODIUM METHYLATE

    SOLUTIONS IN ALCOHOL (UN1289) (DOT) * UN1431 (DOT) * UN1289 (DOT) *

SECTION 3. - - - - - - - - - - HAZARDS IDENTIFICATION - - - - - - - - -

  LABEL PRECAUTIONARY STATEMENTS

    FLAMMABLE (USA)

    HIGHLY FLAMMABLE (EU)

    TOXIC

    TOXIC BY INHALATION AND IF SWALLOWED.

    IRRITATING TO EYES AND SKIN.

    TARGET ORGAN(S):

    EYES

    KIDNEYS

    KEEP CONTAINER TIGHTLY CLOSED.

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    AVOID CONTACT WITH SKIN.

    IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE

    IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).

SECTION 4. - - - - - - - - - - FIRST-AID MEASURES- - - - - - - - - - -

    IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS

    AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED

    CLOTHING AND SHOES.

    ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS

    WITH FINGERS.

    IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL

    RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.

    IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS.

    CALL A PHYSICIAN.

SECTION 5. - - - - - - - - - FIRE FIGHTING MEASURES - - - - - - - - - -

  EXTINGUISHING MEDIA

    CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE FOAM.

  SPECIAL FIREFIGHTING PROCEDURES

    WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO

    PREVENT CONTACT WITH SKIN AND EYES.

  UNUSUAL FIRE AND EXPLOSIONS HAZARDS

    EXTREMELY FLAMMABLE.

    VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND

    FLASH BACK.

    EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

SECTION 6. - - - - - - - - ACCIDENTAL RELEASE MEASURES- - - - - - - - -



                                          Page 1

               PRODUCT #: 403067       NAME: SODIUM METHOXIDE ACS REAGENT

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Tuesday, March 18, 1903 11:10AM



    EVACUATE AREA.

    SHUT OFF ALL SOURCES OF IGNITION.

    WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY

    RUBBER GLOVES.

    COVER WITH DRY-LIME, SAND, OR SODA ASH. PLACE IN COVERED CONTAINERS

    USING NON-SPARKING TOOLS AND TRANSPORT OUTDOORS.

    VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.

SECTION 7. - - - - - - - - - - HANDLING AND STORAGE- - - - - - - - - - -

    REFER TO SECTION 8.

SECTION 8. - - - - - - EXPOSURE CONTROLS/PERSONAL PROTECTION- - - - - -

    WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR, CHEMICAL-RESISTANT

    GLOVES, SAFETY GOGGLES, OTHER PROTECTIVE CLOTHING.

    MECHANICAL EXHAUST REQUIRED.

    SAFETY SHOWER AND EYE BATH.

    DO NOT BREATHE VAPOR.

    AVOID CONTACT WITH EYES, SKIN AND CLOTHING.

    AVOID PROLONGED OR REPEATED EXPOSURE.

    DO NOT USE IF SKIN IS CUT OR SCRATCHED. WASH THOROUGHLY AFTER

    HANDLING.

    TOXIC.

    IRRITANT.

    KEEP TIGHTLY CLOSED.

    KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.

    STORE IN A COOL DRY PLACE.

SECTION 9. - - - - - - - PHYSICAL AND CHEMICAL PROPERTIES - - - - - - -

  APPEARANCE AND ODOR

    CLEAR, COLORLESS LIQUID

SECTION 10. - - - - - - - - -STABILITY AND REACTIVITY - - - - - - - - -

  INCOMPATIBILITIES

    ACIDS

    ACID CHLORIDES

    ACID ANHYDRIDES

    OXIDIZING AGENTS

    REDUCING AGENTS

    ALKALI METALS

  HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS

    TOXIC FUMES OF:

    CARBON MONOXIDE, CARBON DIOXIDE

SECTION 11. - - - - - - - - - TOXICOLOGICAL INFORMATION - - - - - - - -

  ACUTE EFFECTS

    HARMFUL IF INHALED.

    HARMFUL IF SWALLOWED.

    MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.

    CAUSES EYE AND SKIN IRRITATION.

    MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER

    RESPIRATORY TRACT.

    EXPOSURE CAN CAUSE:

    GASTROINTESTINAL DISTURBANCES

    MAY CAUSE CONVULSIONS.

    TARGET ORGAN(S):

    EYES

    KIDNEYS

    LIVER

    HEART

  RTECS #: PC3570000

    METHANOL, SODIUM SALT

    ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES



                                          Page 2

               PRODUCT #: 403067       NAME: SODIUM METHOXIDE ACS REAGENT

                     MATERIAL SAFETY DATA SHEET, Valid 11/97 - 1/98

                         Printed Tuesday, March 18, 1903 11:10AM



    (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR

    COMPLETE INFORMATION.

SECTION 12. - - - - - - - - - ECOLOGICAL INFORMATION - - - - - - - - - -

    DATA NOT YET AVAILABLE.

SECTION 13. - - - - - - - - - DISPOSAL CONSIDERATIONS - - - - - - - - -

    BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND

    SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY

    FLAMMABLE.

    OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

SECTION 14. - - - - - - - - - - TRANSPORT INFORMATION - - - - - - - - -

    CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.

SECTION 15. - - - - - - - - - REGULATORY INFORMATION - - - - - - - - - -

  EUROPEAN INFORMATION

    HIGHLY FLAMMABLE

    TOXIC

    R 23/25

    TOXIC BY INHALATION AND IF SWALLOWED.

    R 36/38

    IRRITATING TO EYES AND SKIN.

    HIGHLY FLAMMABLE

    S7

    KEEP CONTAINER TIGHTLY CLOSED.

    S 16

    KEEP AWAY FROM SOURCES OF IGNITION - NO SMOKING.

    S 24

    AVOID CONTACT WITH SKIN.

    S 45

    IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE

    IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE).

  TLV AND SOURCE

    FOR METHYL ALCOHOL - SKIN:

    ACGIH TLV-TWA: 200 PPM (260 MG/M3); STEL: 250 PPM (310 MG/M3).

    OSHA PEL: 8 H TWA 200 PPM (260 MG/M3); STEL: 250 PPM (310 MG/M3).

  REVIEWS, STANDARDS, AND REGULATIONS

    OEL=MAK

    NOHS 1974: HZD 80549; NIS 6; TNF 185; NOS 14; TNE 3624

    NOES 1983: HZD 80549; NIS 9; TNF 330; NOS 27; TNE 18230; TFE 4356

    EPA TSCA SECTION 8(B) CHEMICAL INVENTORY

    EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, APRIL 1997

  U.S. INFORMATION

    96.7% METHANOL 67-56-1

    THIS PRODUCT IS SUBJECT TO SARA SECTION 313 REPORTING REQUIREMENTS.

SECTION 16. - - - - - - - - - - OTHER INFORMATION- - - - - - - - - - - -

    THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO

    BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,

    FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING

    OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR

    PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.

    COPYRIGHT 1997 SIGMA CHEMICAL CO., ALDRICH CHEMICAL CO., INC.,

    FLUKA CHEMIE AG

    LICENSE GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY









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