MATERIAL SAFETY DATA SHEET
KALIGREEN Page 1 of 6
Please read the entire document. This Material Safety Data Sheet contains important environmental,
health and toxicology information for your employees, and anyone who will use, transport, store, dispose
of or handle this product. Please make sure this information is given to them. It also contains information
to help you meet community right-to-know/emergency response reporting requirements under SARA Title
III and many other laws. If you resell this product, this MSDS must be given to the buyer or the information
contained herein must be incorporated in your MSDS.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Kaligreen
PRODUCT NAME:
11581-2
EPA REGISTRATION NUMBER(S):
NA
SYNONYM(S):
COMPANY EMERGENCY TELEPHONE NUMBERS
Otsuka Chemical Co., Ltd. HEALTH EMERGENCY: SPILL EMERGENCY:
3-2-27, Ote-dori, Chuo-ku
1-866-303-6952, or 1-800-424-9300, or
Osaka 540-0021, Japan
1-651-632-8946 1-703-527-3887
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
Active Ingredient(s)/ CAS # Exposure Limits* % %
Hazardous Inert Ingredient(s) Weight Volume
Potassium hydrogencarbonate 298-14-6 82 NA
TWAa
b
(Potassium bicarbonate) OSHA PEL : NA
ACGIH TLVc: NA
NIOSH RELd: NA
Surfactants, others NA 18 NA
TWA
OSHA PEL: NA
ACGIH TLV: NA
NIOSH REL: NA
Only the identities of the active ingredient(s) and any hazardous inert ingredients are listed. Specific information on all
of this product鈥檚 ingredients can be obtained by the treating medical professional or spill emergency responder for the
management of exposures, spills, or safety assessments.
*Source: Guide to Occupational Exposure Values 2003, published by ACGIH
a
TWA: Time-weighted average exposure concentration for a conventional 8-hour (TLV, PEL) or up to a 10-hour (REL)
workday and a 40-hour workweek.
b
OSHA PEL: Occupational Safety and Health Administration Permissible Exposure Limits.
c
ACGIH TLV: American Conference of Governmental Industrial Hygienists, Inc., Threshold Limit Values.
d
NIOSH REL: National Institute for Occupational Safety and Health Recommended Exposure Limits.
EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00225 Issue Date: 05/22/06
NDA = No Data Available NA = Not Applicable
KALIGREEN Page 2 of 6
SECTION 3: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
CAUTION: - HARMFUL IF SWALLOWED, ABSORBED THROUGH SKIN, OR INHALED
- AVOID CONTACT WITH SKIN, EYES OR CLOTHING
- AVOID BREATHING DUST OR SPRAY MIST
- WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING
- KEEP OUT OF REACH OF CHILDREN
Acute Health Hazards
Eye: Mildly irritating.
Skin: Non-irritant.
Ingestion: NDA
Inhalation: NDA
Chronic Health Hazards (Including Cancer): NDA
Reproductive and Developmental Toxicity: NDA
SECTION 4: FIRST AID MEASURES
Eyes: Immediately flush with plenty of running water at least 15 minutes and get medical attention if
irritation persists.
Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call
a poison control center or doctor for treatment advice.
Inhalation: Move victim to fresh air. If person is not breathing, call 9-1-1 or an ambulance, then give
artificial respiration, preferably by mouth-to-mouth if possible. Call a poison control center or doctor for
treatment advice.
Ingestion: Call a poison control center or doctor for treatment advice. Have person sip a glass of water if
able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not
give anything by mouth to an unconscious person.
EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00225 Issue Date: 05/22/06
NDA = No Data Available NA = Not Applicable
KALIGREEN Page 3 of 6
SECTION 5: FIRE FIGHTING MEASURES
Flammable Limits in Air (% by volume):
NA
Upper:
NA
Lower:
Not combustible
Flash Point:
NA
Method Used:
None
Autoignition Temperature:
None
LEL/UEL:
NFPA Hazard Classification:
1
Health:
0
Flammability:
0
Reactivity:
0
Other:
Dry chemical, sand, water spray or regular foam
Extinguishing Media:
None
Special Fire Fighting Procedures:
None
Hazardous Combustion Products:
SECTION 6: ACCIDENTAL RELEASE MEASURES
EMERGENCY PHONE NUMBERS
Exposure Calls (PROSAR): 1-866-303-6952 or 1-651-632-8946 (International)
Spill Calls (CHEMTREC): 1-800-424-9300 or 1-703-527-3887
Pick up spills and place in suitable containers. Mop area with water after material has been picked up.
SECTION 7: HANDLING AND STORAGE
Store in a cool, dry place. Keep all foods in separate area away from product. Keep out of reach of
children. Follow label directions carefully. Do not eat or smoke while handling. Wash hands thoroughly
after handling.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Eye Protection: Wear safety goggles.
Skin Protection: Long-sleeved shirt, rubber gloves and boots.
Respiratory/Ventilation Requirements: Dust mask or chemical protection mask.
EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00225 Issue Date: 05/22/06
NDA = No Data Available NA = Not Applicable
KALIGREEN Page 4 of 6
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
White to pale yellow
Appearance:
NDA
Odor:
Powder
Physical State:
NDA
pH:
Does not boil
Boiling Point:
Does not melt
Melting Point:
NDA
Freezing Point
Does not vaporize
Vapor Pressure:
Does not vaporize
Vapor Density:
NDA
Bulk Density:
0.56 g/cm3 (20/20掳C)
Specific Gravity:
Does not vaporize
Evaporation Rate:
Soluble 600 g/liter (60掳C, 140掳F)
Solubility in Water:
NDA
Percent Solids by Weight:
0%
Percent Volatile:
NDA
Volatile Organic Compounds:
NDA
Molecular Weight:
NDA
Viscosity:
SECTION 10: STABILITY AND REACTIVITY
Stable
Chemical Stability:
Will not occur
Hazardous Polymerization:
Not combustible
Flash Point:
NA
Flammable Point:
None
Auto Ignition:
Do not mix with strong acidic compounds
Incompatibility With Other Materials:
KHCO3 鈫? K+ + H2O + CO2
Decomposition Products:
SECTION 11: TOXICOLOGICAL INFORMATION
Acute:
Oral Toxicity: LD50 (rat): 3,358 mg/kg
Dermal Toxicity: NDA
Inhalation Toxicity: NDA
Eye Irritation: NDA
Skin Irritation: NDA
Skin Sensitization: NDA
Subchronic: NDA
Chronic Toxicity: NDA
Carcinogenicity: NDA
Mutagenicity: NDA
EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00225 Issue Date: 05/22/06
NDA = No Data Available NA = Not Applicable
KALIGREEN Page 5 of 6
Developmental Toxicity: NDA
Reproduction: NDA
Neurotoxicity: NDA
SECTION 12: ECOLOGICAL INFORMATION
Aquatic Organism Toxicity: NDA
SECTION 13: DISPOSAL CONSIDERATIONS
Dispose of in accordance with local, state and federal regulations.
SECTION 14: TRANSPORT INFORMATION
Non-regulated
D.O.T. Shipping Name:
NDA
Technical Shipping Name:
NDA
Packing Group:
NDA
D.O.T. Hazard Class:
NDA
U.N/N.A. Number:
NDA
Product RQ (lbs):
NDA
D.O.T. Label:
NDA
D.O.T. Placard:
NDA
Marine Pollutant:
IMO :
NDA
IMO Label:
NDA
IMO Placard:
European Road/Rail:
NDA
Class:
SECTION 15: REGULATORY INFORMATION
U.S Federal Regulations
FIFRA (Federal Insecticide, Fungicide, and Rodenticide Act): All pesticides are governed
under FIFRA. Therefore, the regulations presented below are pertinent only when handled outside
of the normal use and applications of pesticides. This includes waste streams resulting from
manufacturing/formulation facilities, spills or misuse of products, and storage of large quantities of
products containing hazardous or extremely hazardous substances.
CERCLA (Comprehensive Response Compensation, and Liability Act): NA
EPCRA (Emergency Planning and Community Right-to-Know Act) Section 313: None
OSHA (Occupational Safety and Health Administration): This product is hazardous under the
criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200.
RCRA (Resource Conservation and Recovery Act): None
EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00225 Issue Date: 05/22/06
NDA = No Data Available NA = Not Applicable
KALIGREEN Page 6 of 6
SARA Title III (SUPERFUND Amendments and Reauthorization Act):
Section 302 (EHS) TPQ: None
Section 304 (EHS) RQ: None
Section 311/312 CATEGORIES 1. Immediate (Acute) Health Effects; YES
2. Delayed (Chronic) Health Effect; NO
3. Fire Hazard; NO
4. Sudden Release of Pressure Hazard; NO
5. Reactivity Hazard; NO
TSCA (Toxic Substance Control Act): This product is exempt from TSCA Regulation under
FIFRA Section 3 (2)(B)(ii) when used as a pesticide.
State Regulations: Each state may promulgate standards more stringent than the federal government.
This section cannot encompass an inclusive list of all state regulations. Therefore, the user should consult
state or local authorities.
International Regulations:
NDA
EEC Classification:
NDA
Risk Phrases:
NDA
Safety Phrases:
SECTION 16: OTHER INFORMATION
New MSDS for Otsuka Chemical
Reason for issue:
James J. Reilly, Jr.
Prepared by:
05/22/06
Issue date:
NA
Supersedes date:
00225
MSDS number:
The information in this MSDS is based on data available to us as of the issue date given herein, and
believed to be correct. Contact Arysta LifeScience North America Corporation at (919) 678-4900 to
determine if additional data and information have become available since the issue date.
Judgments as to the suitability of information herein for the individual鈥檚 own uses or purposes are
necessarily the individual鈥檚 own responsibility. Although reasonable care has been taken in the
preparation of such information, Arysta LifeScience North America Corporation extends no warranties,
makes no representations, and assumes no responsibility as to the accuracy or suitability of such
information for application to the individual's purposes or the consequences of its use.
EMERGENCY TELEPHONE #: 1-866-303-6952 or 1-651-632-8946
MSDS Number: 00225 Issue Date: 05/22/06
NDA = No Data Available NA = Not Applicable
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