723 - (11/85)
Mineral King Minerals, Inc.
P. O. Box 2766 - Fresno, California 93745 - 559/582-9228 - FAX 559/486-3435
MATERIAL SAFETY DATA SHEET
IRON 6%
SECTION I. IDENTIFICATION
Chemical Family: Mixture
Chemical Name and Synonyms: N/A -- Mixture
Formula: Proprietary
Trade Name and Synonyms: IRON 6%
SECTION II. PRODUCT AND COMPONENT HAZARD DATA
A. Components: CAS. Reg. No: Approx. Percent: TLV:
Ferrous Sulfate 7720-78-7 24.5% 1 mg/m3 as Fe
SECTION III. PHYSICAL DATA
- Boiling Point: 212o F.
- Appearance and Odor: Brown; sweet, molasses-like odor
- Specific Gravity: 1.24 - Vapor Pressure: 30 mm (approximately)
- Percent Volatile by Volume: Proprietary - Vapor Density (Air = 1): > 1
- Evaporation Rate (Ethyl Ether = 1): < 1 - Solubility in Water: > 99%
SECTION IV. FIRE AND EXPLOSION HAZARD DATA
- Flash Point: N/A - Extinguishing Agent: N/A
- Flammable Limits: N/A - Special Fire-Fighting Procedures: N/A
- Unusual Fire and Explosion Hazards:
May evolve SO2 if involved in a fire.
SECTION V. REACTIVITY DATA
- Stability: Stable - Incompatibility: Oxidizers, strong acids
- Hazardous Polymerization: Will not occur - Hazardous Decomposition Products: Sulfur dioxide (SO2) may be
evolved over 300o C.
SECTION VI. TOXICITY AND HEALTH
A. EXPOSURE LIMITS
- OSHA Permissible Exposure Limit (PEL): None established
- Threshold Limit Value (TLV): 1 mg/m3 as Fe
B. EFFECTS OF OVEREXPOSURE
1. ACUTE
a. Inhalation: Irritation.
b. Eyes: Irritation. May cause ulceration.
c. Ingestion: Gastric disturbance, nausea, vomiting, hyperactivity.
d. Skin: Irritation.
2. CHRONIC Implicated in adverse changes in male reproductive system at very high exposure levels.
C. EMERGENCY FIRST AID PROCEDURES
- Inhalation: Remove from exposure area. If irritation exists from mists, or in the event of massive inhalation, seek
medical attention.
- Eyes: Rinse thoroughly with running water for 15 minutes. Seek medical attention.
- Ingestion: Drink at least 2 glasses of milk or water and induce vomiting. Consult a physician.
- Skin: Wash with soap and water. Rinse thoroughly. Seek medical attention if inflammation occurs.
D. ANIMAL TOXICITY DATA
LD 50 (oral-rat) 319 mg/Kg as Fe SO4
LD 20 (child) 390 mg/Kg as Fe SO4
LD 20 (woman) 200 mg/Kg as Fe SO4
LD 20 (woman) 60 mg/Kg as Fe SO4
SECTION VII. PERSONAL PROTECTION AND CONTROLS
A. RESPIRATORY PROTECTION
- As required by conditions. Use an OSHA or NIOSH approved respirator if required.
723 - (11/85)
IRON 6%
SECTION VII. PERSONAL PROTECTION AND CONTROLS (continued)
B. VENTILATION
- General: Not normally required. Use if needed for safe, comfortable working conditions.
- Local Exhaust: Not normally required.
C. SKIN AND EYE PROTECTION
- Safety glasses should be worn in any type of industrial operation. Protective gloves should be worn as good
hygiene dictates.
D. OTHER CONTROL MEASURES
- An eye bath and washing facilities should be available. Wash thoroughly after handling. Do not smoke when
handling chemicals.
SECTION VIII. SPECIAL STORAGE AND HANDLING PRECAUTIONS
Since emptied packages retain product residue follow label warning even after package is emptied. Dried residue can
constitute a fire hazard. Keep equipment and workplace clean.
SECTION IX. SPILL, LEAK, AND DISPOSAL PRACTICES
- Steps to be Taken in Case Material is Released or Spilled: Collect and contain for salvage or disposal. Absorb waste
on inert media and dispose of as solid waste.
- Waste Disposal Method: Landfill in compliance with all federal, state and local laws concerning health and
environment.
SECTION X. ENVIRONMENTAL EFFECTS DATA
SUMMARY
While this product has not been tested for environmental hazards, long experience with iron salts would indicate that no
adverse effects should be anticipated under normal conditions of use.
SECTION XI. TRANSPORTATION
- DOT Hazard Classification: ORM-E
SECTION XII. REFERENCES
1. The Merck Index: An Encyclopedia of Chemicals and Drugs, 1983 10th ed., Merck and Company, Rahway, N.J.
2. Dangerous Properties of Industrial Materials, 5th ed., 1979, Sax, N.I., Van Nostrand Reinhold & Co., N.Y., N.Y.
3. 29 C F R 1910 General Industry OSHA Safety and Health Standards., U.S. Department of Labor, Occupational
Safety and Health Administration. Rev. 1983, 1985.
4. Threshold Limit Values for Chemical Substances and Physical Agents in the Workroom Environment with Intended
Changes. American Conference of Governmental Industrial Hygenicists, Cincinnati, OH. 1985.
5. Handbook of Chemistry and Physics, Chemical Rubber Co., Cleveland, OH.
6. Water Quality Criteria, J.E. McKee and H.W. Wolf, Editors., Pub. No. 3-A (Revised). State of California, 1963.
7. Registry of Toxic Effects of Chemical substances: 1983 Supplement to the 1981-1982 Edition. National Institute of
Occupational Safety and Health, 1984.
IMPORTANT
The information and data herein are believed to be accurate and have been compiled from sources believed to
be reliable. It is offered for your consideration, investigation and verification. Buyer assumes all risk of use,
storage and handling of the product, in compliance with applicable federal, state and local laws and
regulations. Sustainable Farm Supply MAKES NO WARRANTIES EXPRESSED OR IMPLIED, CONCERNING THE
ACCURACY OR COMPLETENESS OF THE INFORMATION AND DATA HEREIN. THE IMPLIED WARRANTIES OF
MERCHANT ABILITY AND FITNESS FOR PARTICULAR PURPOSE ARE SPECIFICALLY EXCLUDED.
Sustainable Farm Supply will not be liable for claims relating to any party's use of or reliance on information
and data contained herein regardless of whether it is claimed that the information and data are inaccurate,
incomplete or otherwise misleading.
|