MATERIAL SAFETY DATA SHEET
MONTEREY COPPER-ALL 5% Page 1 of 4 Issue Date: 01/06
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Chemical Product
MONTEREY COPPER-ALL 5%
Common Name: Liquid copper chelate fertilizer.
Chemical Description: Copper citrate/ethylenediaminetetraacetate (EDTA), aqueous solution.
TSCA/CAS No.: This product is a mixture 鈥? there is no specific CAS number.
Manufactured For
Monterey AgResources
P. O. Box 35000
Fresno, CA 93745-5000
Emergency Phone Numbers
Emergency Telephone: DAYS: (559) 499-2100 EVES: (559) 994-9144
CHEMTREC (24-Hour Emergency Number): (800) 424-9300
EPA National Response Center: (800) 424-8802
SECTION 2. HAZARDOUS INGREDIENTS
CHEMICAL CAS NO. % TLV OR PEL RQ (lbs)
Copper sulfate pentahydrate 7758-98-7 20.0 *N.A. 10 lbs.
* N.A. - Not available.
SECTION 3. EMERGENCY/HAZARDS OVERVIEW
Clear, blue liquid with no odor. Exposure to high temperatures or flames may result in the
formation of nitrogen oxides. May cause aesthetic pollution. Contain any liquid runoff. Not
D.O.T. regulated.
HEALTH: 1 REACTIVITY: 0 FLAMMABILITY: 0 ENVIRONMENT: 1
(0=Insignificant 1=Slight 2=Moderate 3=High 4=Extreme)
SECTION 4. FIRST AID
Eyes: Flush immediately with water for at least 15 minutes. Call a physician if eye
irritation persists.
Skin: Wash thoroughly with soap and water. Remove contaminated clothing and wash
before reuse. See a physician if skin becomes irritated.
Ingestion: If conscious and alert, drink water or milk to dilute, then induce vomiting. Call a
physician or Poison Control Center immediately.
Inhalation: Move to fresh air. If breathing becomes difficult, call a physician.
MONTEREY COPPER-ALL 5% Page 2 of 4 Issue Date: 01/06
SECTION 5. FIRE AND EXPLOSION HAZARDS
Flash Point: Not pertinent.
Test Method: Not pertinent.
LEL Flammable Limits: Not pertinent.
UEL Flammable Limits: Not pertinent.
Autoignition Temperature: Not pertinent.
Flammability Classification: None.
Known Hazardous Products of Combustion: None.
Properties that Initiate/Contribute to Intensity of Fire: None.
Potential For Dust Explosion: None.
Reactions that Release Flammable Gases or Vapors: None.
Potential For Release of Flammable Vapors: None.
Unusual Fire & Explosion Hazards: None.
Extinguishing Media: Not pertinent.
Special Firefighting Procedures: Wear positive pressure, self-contained
breathing apparatus and goggles.
Contain any liquid runoff.
SECTION 6. SPILLS AND LEAKS
Containment: Prevent product spillage from entering drinking water supplies or streams
Clean Up: Collect liquid or absorb onto absorbent material and package for disposal
Evacuation: Not necessary.
SECTION 7. STORAGE AND HANDLING
Storage: Store in plastic or stainless steel container in a cool, well-
ventilated, dry place at temperatures above 40掳F. Do not store in
contact with brass. Do not store near food or feeds. Do not stack
pallets more than two (2) high.
Transfer Equipment: Transfer product using chemical-resistant plastic or stainless steel
tanks, pumps, valves, etc.
Work/Hygienic Practices: Keep out of reach of children. Avoid contact with eyes, skin and
clothing. Avoid inhalation of spray mists. Wash thoroughly with
water after handling.
SECTION 8. PERSONAL PROTECTIVE EQUIPMENT
Eyes: Chemical dust/splash goggles or full-face shield to prevent eye contact. As a
general rule, do not wear contact lenses when handling.
Skin: Impervious gloves and clothes.
Respiratory: Not normally needed. If use generates an aerosol mist or respiratory irritation,
use NIOSH-approved dust/mist respirator (such as 3M #8710).
Ventilation: Recommended but no TLV established.
MONTEREY COPPER-ALL 5% Page 3 of 4 Issue Date: 01/06
SECTION 9. PHYSICAL AND CHEMICAL DATA
Appearance: Clear, blue liquid.
Odor: None.
pH: 1.7
Vapor Pressure: Not available.
Vapor Density (Air=1): <1.0
Boiling Point: 104掳C (220掳F)
Freezing Point: Not available.
Water Solubility: Soluble.
Density: 9.6 lbs./gal.
Evaporation Rate: Not available.
Viscosity: Not available.
% Volatile: Not available.
Octanol/Water Partition Coefficient: Not available.
Saturated Vapor Concentration: Not available.
SECTION 10. STABILITY AND REACTIVITY
Stability: Stable.
Conditions To Avoid: Contact with strong alkalies and/or reactive metals such
as aluminum and copper.
Incompatibility: Not available.
Hazardous Decomposition Products: High temperatures may result in formation of nitrogen
oxides.
Hazardous Polymerization: Will not occur.
SECTION 11. POTENTIAL HEALTH EFFECTS
Acute Effects:
Eyes: Moderate irritant. May cause redness and burning.
Skin: Moderate irritant, especially from prolonged exposure. May cause
redness.
Ingestion: May cause stomach cramps and/or nausea.
Inhalation: None expected but inhalation of aerosol mist may cause mild irritation of
nasal mucous membranes.
Subchronic Effects: None known.
Chronic Effects: None known.
SECTION 12. ECOLOGICAL INFORMATION
Algal/Lemna Growth Inhibition: Not known.
Toxicity to Fish and Invertebrates: Not known.
Toxicity to Plants: Not known.
Toxicity in Birds: Not known.
MONTEREY COPPER-ALL 5% Page 4 of 4 Issue Date: 01/06
SECTION 13. DISPOSAL
Do not contaminate lakes, streams, ponds, estuaries, oceans or other waters by discharge of
waste effluents or equipment washwaters. Dispose of waste effluents according to state and
local regulations. Also, chemical additions or other alterations of this product may invalidate
any disposal information in this MSDS. Therefore, consult local waste regulators for proper
disposal. Do not discharge.
SECTION 14. TRANSPORTATION
D.O.T. Information: Not D.O.T. Regulated.
Other Shipping Description: Fertilizing Compounds (Manufactured), Liquid.
NMFC Item 68140 Sub 6, LTL Class 70
SECTION 15. REGULATORY INFORMATION
CERCLA: Copper and its compounds are included as priority pollutants under the Clean Water
Act and, as such, fall under the CERCLA spill reporting requirements of 40 CFR 302.
SARA TITLE III, Section 313 Toxic Chemicals: Copper Compounds (20.0%).
PROPOSITION 65 (CA): WARNING: This product contains chemicals known to the State of
California to cause cancer and birth defects or other reproductive harm.
SECTION 16. OTHER
While the information contained herein is based on data considered accurate and was
compiled to comply with the Federal Hazard Communication Standard and the California
Hazardous Substances Information and Training Act, it is provided for guidance only.
Monterey AgResources does not guarantee its accuracy or completeness. Health and safety
precautions in this data sheet may not be adequate for all individuals and/or situations. It is
the user鈥檚 obligation to evaluate and use this product safely and to comply with all applicable
laws and regulations; in so doing, user assumes all risk in use of the material. The
information contained herein is not to be taken as a warranty or representation for which
Monterey AgResources assumes legal responsibility.
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