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MATERIAL SAFETY DATA SHEET
Date-Issued: 02/20/2007
MSDS Ref. No: 007444A
Date-Revised: 02/20/2007
Revision No: New MSDS
PyGanic庐 Crop Protection EC 5.0 ii
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: PyGanic庐 Crop Protection EC 5.0 ii
PRODUCT DESCRIPTION: An Insecticide for Organic Crop Protection
PRODUCT CODE: 007444A, EPA REG. NO. : 1021-1772
MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS
McLaughlin Gormley King Company
CHEMTREC U.S. and CANADA:(800) 424-9300
8810 10th Avenue North
CHEMTREC All Other Areas:(703) 527-3887
Minneapolis, MN 55427
Emergency Phone:(888) 740-8712
Product Stewardship: (763) 544-0341
Customer Service: (800) 645-6466
COMMENTS: MGK庐 Hours of operation are 8:00 am to 4:30 pm CST, 14:00 to 22:30 GMT.
For information regarding MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day at 1-888-
740-8712.
2. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name Wt.% CAS# EINECS#
Pyrethrins 5 008003-34-7 232-319-8
COMMENTS: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications.
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
IMMEDIATE CONCERNS: WARNING. Causes skin irritation. May be harmful if swallowed due to skin irritation
effects. Avoid contact with skin, eyes, and clothing. Use of this product may cause skin reactions in rare cases
among certain sensitive individuals.
Applicators and other handlers must wear: Coveralls over a short-sleeved shirt and short pants. Chemical-
resistant gloves, such as, Barrier Laminate, Nitrile Rubber, Neoprene Rubber, or Viton. Chemical-resistant
footwear plus socks. Chemical-resistant headgear for overhead exposure. Chemical-resistant apron when
cleaning equipment, mixing, or loading.
POTENTIAL HEALTH EFFECTS
EYES: Causes temporary irritation, tearing, and blurred vision.
SKIN: Causes skin irritation. Can cause a burning or prickling sensation on more sensitive areas (face, eyes,
mouth).
Use of this product may cause skin reactions in rare cases among certain sensitive individuals.
SKIN ABSORPTION: May be harmful if absorbed through the skin.
INGESTION: May be harmful if swallowed due to skin irritation effects.
INHALATION: Excessive inhalation may be irritating to the respiratory tract.
CHRONIC: None known.
COMMENTS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR
1910.1200).
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PyGanic庐 Crop Protection EC 5.0 ii
4. FIRST AID MEASURES
EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment
advice.
SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a
poison control center or doctor for treatment advice.
INGESTION: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of
water if able to swallow. DO NOT induce vomiting unless told to do so by a poison control center or doctor. Do
not give anything by mouth to an unconscious person.
INHALATION: Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further
treatment advice.
NOTES TO PHYSICIAN: For skin effects, a highly efficient therapeutic agent for pyrethrin exposure is topical
application of tocopherol acetate (Vitamin E).
5. FIRE FIGHTING MEASURES
FLASHPOINT AND METHOD: > 93.3掳 (200掳
C F)TAG Closed Cup
FLAMMABLE CLASS: This product is NOT classified as flammable or combustible by OSHA.
EXTINGUISHING MEDIA: Foam, carbon dioxide or dry chemical.
HAZARDOUS COMBUSTION PRODUCTS: Under fire conditions this product may support combustion and may
decompose to give off toxic gases such as carbon monoxide, carbon dioxide, and nitrogen oxides.
FIRE FIGHTING PROCEDURES: Treat as an oil fire. Use a full-faced self-contained breathing apparatus along
with full protective gear. Keep nearby containers and equipment cool with a water stream.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: Stop release, if possible without risk. Dike or contain release, if possible, and if immediate
response can prevent further damage or danger. Isolate and control access to the release area. Take actions to
reduce vapors. Absorb with appropriate absorbent such as sand, or vermiculite. Clean spill area of residues and
absorbent.
LARGE SPILL: Stop release, if possible without risk. Dike or contain release, if possible, and if immediate
response can prevent further damage or danger. Isolate and control access to the release area. Take actions to
reduce vapors. Collect product into drums, storage tanks, etc., via drains, pumps, etc. Absorb with appropriate
absorbent such as sand or vermiculite. Clean spill area of residues and absorbent.
ENVIRONMENTAL PRECAUTIONS
WATER SPILL: Contains Pyrethrins, which are toxic to fish and other aquatic invertebrates. Contaminated
absorbent and wash water should be disposed of according to local, state, and federal regulations.
7. HANDLING AND STORAGE
HANDLING: Wear coveralls over a short-sleeved shirt and short pants. Wear chemical-resistant gloves, such as,
Barrier Laminate, Nitrile Rubber, Neoprene Rubber, or Viton. Wear chemical-resistant footwear plus socks.
Wear chemical-resistant headgear for overhead exposure. Wear a chemical-resistant apron when cleaning
equipment, mixing, or loading. Mechanical ventilation should be used when handling this product in enclosed
spaces. Do not contaminate water, feed, or food by storage, handling, or disposal. Read and observe all
precautions and instructions on the label.
STORAGE: Store in a cool, dry place. Keep container closed.
KEEP OUT OF REACH OF CHILDREN.
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PyGanic庐 Crop Protection EC 5.0 ii
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE GUIDELINES:
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)
EXPOSURE LIMITS
Chemical Name OSHA PEL ACGIH TLV Supplier OEL
ppm mg/m3 ppm mg/m3 ppm mg/m3
TWA
Pyrethrins 5 5
ENGINEERING CONTROLS: Mechanical ventilation should be used when handling this product in enclosed
spaces. Local exhaust ventilation may be necessary.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Take prudent precautions to avoid contact with eyes. Wear chemical-resistant headgear for
overhead exposure.
SKIN: Wear chemically impervious gloves such as Neoprene or Nitrile and protective clothing.
PROTECTIVE CLOTHING: Wear coveralls over a short-sleeved shirt and short pants. Wear chemical-resistant
footwear plus socks. Wear a chemical-resistant apron when cleaning equipment, mixing, or loading.
WORK HYGIENIC PRACTICES: DO NOT SMOKE, EAT, OR DRINK, OR APPLY COSMETICS IN WORK
AREA!
Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking,
or using the toilet.
OTHER USE PRECAUTIONS: AGRICULTURAL USE REQUIREMENTS:
Use this product only in accordance with its labeling and with the Woker Protection Standard, 40 CFR, Part 170.
This Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, and
greenhouses, and handlers of agricultural pesticides. It contains requirements for training, decontamination,
notification, and emergency assistance. It also contains specific instructions and exceptions pertaining to the
statements on the label about personal protective equipment (PPE), and restricted-entry interval. The
requirements listed below only apply to uses of this product that are covered by the Worker Protection Standard.
Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours.
PPE required for early entry to treated areas that is permitted under Worker Protection Standard and that
involves contact with anything that has been treated, such as plants, soil, or water, is:
Coveralls over a short-sleeved shirt and short pants;
Chemical-resistant gloves, such as Barrier Laminate, Nitrile Rubber, Neoprene Rubber, or Viton;
Chemical-resistant footwear plus socks; and Chemical-resistant headgear for overhead exposure.
COMMENTS: NON-AGRICULTURAL USE REQUIREMENTS:
The requirements in this section apply to uses of this product that are NOT within the scope of the Worker
Protection Standard for agricultural pesticides (40 CFR, Part 170). The WPS applies when this product is used
to treat agricultural plants on farms, forests, nurseries, or greenhouses.
Keep unprotected persons out of treated areas until sprays have dried.
Wear protective clothing when using or handling this product to help avoid exposure to eyes and skin. Eye
protection, gloves, a long-sleeved shirt and long-pants are recommended.
Allow spray to dry before allowing adults, children, or pets on treated areas.
For any requirements specific to your State or Tribe, consult the agency responsible for pesticide regulation.
9. PHYSICAL AND CHEMICAL PROPERTIES
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PyGanic庐 Crop Protection EC 5.0 ii
PHYSICAL STATE: Liquid
ODOR: Sweet surfactant odor.
APPEARANCE: Clear, amber-brown colored liquid.
pH: 5.9@ 5% in water.
VAPOR DENSITY: Heavier than air.
BOILING POINT: Not Available
FREEZING POINT: Not Available
SOLUBILITY IN WATER: Partially miscible in water.
SPECIFIC GRAVITY: 0.937 (Water = 1) at 20掳 (68掳
C F)
VISCOSITY: 34.8CPS at 24掳 (75.2掳 Brookfield
C F)
(VOC): <1.000 %
10. STABILITY AND REACTIVITY
STABLE: Yes
HAZARDOUS POLYMERIZATION: No
CONDITIONS TO AVOID: Not compatible with strong acids or bases. Not compatible with strong oxidizers.
11. TOXICOLOGICAL INFORMATION
ACUTE
DERMAL LD50: >2000 mg/kg
Albino rabbit.
ORAL LD50: >2000 mg/kg
Albino rat.
INHALATION LC50: The Acute Inhalation LC50 of this material places it in EPA Toxic Category IV.
EYE EFFECTS: Irritation clearing within 48 hours.
SKIN EFFECTS: Slight irritation at 72 hours. Primary Irritation Index = 1.3.
SENSITIZATION: Positive
COMMENTS: None of the components present in this material at concentrations equal to or greater than 0.1%
are listed by IARC, NTP, OSHA or ACGIH as being carcinogens.
Carcinogenicity/ Oncogenicity-Pyrethrum has been tested in chronic feeding studies in mice and rats. Slightly
elevated incidences of benign tumors of the thyroid and liver were seen in rats following high doses of
Pyrethrum. Further detailed scientific studies into the mechanism causing these responses indicate that these
effects in the animals only occur at doses greatly exceeding the likely human exposure levels. Thus, the effects
seen in animals are of little relevance to humans.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: Environmental data not available for this product.
ECOTOXICOLOGICAL INFORMATION: This pesticide is highly toxic to fish. For terrestrial uses, do not apply
directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water
mark. Do not contaminate water when disposing of equipment wash waters or rinsate. Drift and runoff may be
hazardous to aquatic organisms in water adjacent to treated areas. Do not discharge effluent containing this
product into lakes, streams, ponds, estuaries, oceans or other waters, unless in accordance with the
requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority
has been notified in writing prior to discharge. Do not discharge effluent containing this product into sewer
systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State
Water Board or Regional Office of the EPA.
13. DISPOSAL CONSIDERATIONS
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PyGanic庐 Crop Protection EC 5.0 ii
DISPOSAL METHOD: Wastes resulting from the use of this product must be disposed of on site or at an
approved waste disposal facility.
EMPTY CONTAINER: Triple rinse (or equivalent) and offer for recycling or reconditioning, or dispose of in a
sanitary landfill or by other procedures approved by State and Local authorities.
RCRA/EPA WASTE INFORMATION: This product contains the following RCRA/CERCLA Hazardous
wastes/substances:
Component, RCRA ID#, Cercla RQ
Pyrethrins, N/A, 1 Lb.
14. TRANSPORT INFORMATION
DOT (DEPARTMENT OF TRANSPORTATION)
PROPER SHIPPING NAME: Environmentally Hazardous Substance, Liquid, N.O.S. RQ(Pyrethrins)
PRIMARY HAZARD CLASS/DIVISION: 9
UN/NA NUMBER: UN3082
PACKING GROUP: III
REPORTABLE QUANTITY (RQ) UNDER CERCLA: 1 Lb.
OTHER SHIPPING INFORMATION: This material is not regulated as a hazardous material by the DOT in
quantities less than 20 Lbs.
Shipping name for quantities less than 20 Lbs. :
Insecticides, Insect or Animal Repellents, Liquid, N.O.S.
AIR (ICAO/IATA)
PROPER SHIPPING NAME: Environmentally Hazardous Substance, Liquid, N.O.S. RQ(Pyrethrins)
PRIMARY HAZARD CLASS/DIVISION: 9
UN/NA NUMBER: UN3082
PACKING GROUP: III
VESSEL (IMO/IMDG)
PROPER SHIPPING NAME: Not Available
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
311/312 HAZARD CATEGORIES:
FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes
313 REPORTABLE INGREDIENTS: This product contains no SARA Title III Section 313 chemicals that
exceed the reporting limits.
302/304 EMERGENCY PLANNING
EMERGENCY PLAN: There are no SARA Title III Section 302 extremely hazardous substances present in
this formulation (40 CFR 355).
See Section 13 of this MSDS for the components that are subject to emergency requirements under
CERCLA Section 103(a)(40 CFR 302.4).
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control
Act's inventory reporting requirements.
STATE REGULATIONS
VOLATILE ORGANIC COMPOUNDS (VOC):
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PyGanic庐 Crop Protection EC 5.0 ii
This product contains less than 1% VOC鈥檚.
16. OTHER INFORMATION
REVISION SUMMARY New MSDS
HMIS RATING
2
HEALTH:
1
FLAMMABILITY:
1
PHYSICAL HAZARD:
PERSONAL PROTECTION:
HMIS RATINGS NOTES: We assign HMIS ratings to this product based on the hazards of its ingredients(s).
Since the customer is most aware of the applications and conditions of use, he or she must ensure that the
proper Personal Protective Equipment is provided, consistent with the information contained in Section's 7 and 8
of this MSDS.
COMMENTS: The data contained herein are based on information currently available to McLaughlin Gormley King
Company and, to the best of our knowledge, are accurate and based on sound expert opinion. Our statements
herein, however, are not to be taken as a warranty or representation for which McLaughlin Gormley King
Company assumes legal responsibility.
MSDS Prepared by T. Azzivitto
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