Material Safety Data Sheet
Rating
NFPA HMIS (U.S.A.) Protective Clothing DOT (pictograms)
Health Hazard 0 Insignificant
1
Fire Hazard
1
1 Slight
Fire Hazard 1
1 0 Reactivity 2 Moderate
Health
Reactivity 0 3 High
Specific hazard
4 Extreme
Personal Protection B
Section I. Chemical Product and Company Identification
PSGREEN, 440-198-0
Product Name Code
PURESPRAY GREEN
See Section 15
DSL
Not available.
Synonym See Section 15
TSCA
In case of Petro-Canada: 403-296-3000
PETRO-CANADA
Manufacturer
Emergency Canutec Transportation:
P.O. Box 2844
613-996-6666
Calgary, Alberta
Poison Control Centre:
T2P 3E3
Consult local telephone
PureSpray Green is a Spray Oil that is registered as "Organic" with
Material Uses directory for emergency
USEPS and OMRI and used in Organic farming operations. number(s).
EPA registration number: 69526-9
Section II. Composition and Information on Ingredients
Exposure Limits (ACGIH)
Name CAS # % (V/V) TLV-TWA(8 h) STEL CEILING
8042-47-5 - 5 mg/m鲁 (oil 10 mg/m鲁 (oil Not
Mixture of severely hydrotreated and hydrocracked base
mist) mist) established
oil (petroleum).
Mixture - Not applicable Not applicable Not applicable
Other proprietary, non-hazardous additives.
Not applicable
Manufacturer
Recommendation
Consult local, state, provincial or territory authorities for acceptable exposure limits.
Other Exposure
Limits
Section III. Hazards Identification.
Prolonged or repeated contact may cause skin irritation, defatting, drying and dermatitis. Not expected to
Potential Health
cause more than slight skin or eye irritation. With its relatively low vapour pressure, this product is not
Effects
expected be inhaled in any appreciable quantity at ambient conditions. If heated to high temperatures or
subjected to mechanical actions which produce vapours or mists, inhalation may cause respiratory tract
irritation. Ingestion may produce a laxative effect. For more information refer to Section 11 of this MSDS.
Section IV. First Aid Measures
IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek medical
Eye Contact
attention.
Remove contaminated clothing - launder before reuse. Wash gently and thoroughly the contaminated skin
Skin Contact
with running water and non-abrasive soap. Seek medical attention.
Evacuate the victim to a safe area as soon as possible. If the victim is not breathing, perform artificial
Inhalation
respiration. Allow the victim to rest in a well ventilated area. Seek medical attention.
DO NOT induce vomiting because of danger of aspirating liquid into lungs. Seek medical attention.
Ingestion
Not available
Note to Physician
Section V. Fire-fighting Measures
May be combustible at high temperature. Flammable Limits Not available.
Flammability
OPEN CUP: 174掳C (345.2掳F) (Cleveland) Not available.
Auto-Ignition
Flash Points
Temperature
Low fire hazard. This material must be Explosion Hazards Do not cut, weld, heat, drill or pressurize
Fire Hazards in
heated before ignition will occur. empty container. Containers may explode
in Presence of
Presence of
Various Substances in heat of fire.
Various Substances
Carbon oxides (CO, CO2), smoke and irritating vapours as products of incomplete combustion.
Products of
Combustion
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PURESPRAY GREEN Page Number: 2
NAERG96, GUIDE 171, Substances (low to moderate hazard). If tank, rail car or tank truck is involved in a
Fire Fighting
fire, ISOLATE for 800 meters (0.5 mile) in all directions; also, consider initial evacuation for 800 meters (0.5
Media and
mile) in all directions. Shut off fuel to fire if it is possible to do so without hazard. If this is impossible,
Instructions
withdraw from area and let fire burn out under controlled conditions. Withdraw immediately in case of rising
sound from venting safety device or any discolouration of tank due to fire. Cool containing vessels with water
spray in order to prevent pressure build-up, autoignition or explosion. SMALL FIRE: use DRY chemicals,
foam, water spray or CO2. LARGE FIRE: use water spray, fog or foam. For small outdoor fires, portable fire
extinguishers may be used, and self contained breathing apparatus (SCBA) may not be required. For all
indoor fires and any significant outdoor fires, SCBA is required. Respiratory and eye protection are required
for fire fighting personnel.
Section VI. Accidental Release Measures
Consult current National Emergency Response Guide Book (NAERG) for appropriate spill measures if
Material Release
necessary. Extinguish all ignition sources. Stop leak if safe to do so. Dike spilled material. Use appropriate
or Spill
inert absorbent material to absorb spilled product. Collect used absorbent for later disposal. Avoid contact
with spilled material. Avoid contaminating sewers, streams, rivers and other water courses with spilled
material. Notify appropriate authorities immediately.
Section VII. Handling and Storage
Avoid contact with any sources of ignition, flames, heat, and sparks. Avoid eye contact. Avoid skin contact.
Handling
Avoid inhalation of product vapours or mists. Empty containers may contain product residue. Do not
pressurize, cut, heat, or weld empty containers. Do not reuse containers without commercial cleaning and/or
reconditioning. Personnel who handle this material should practice good personal hygiene during and after
handling to help prevent accidental ingestion of this product. Properly dispose of contaminated leather
articles including shoes that cannot be decontaminated.
Store away from incompatible and reactive materials (See section 5 and 10). Keep container tightly closed.
Storage
Store in dry, cool, well-ventilated area.
Section VIII. Exposure Controls/Personal Protection
For normal application, special ventilation is not necessary. If user's operations generate vapours or mist, use
Engineering
ventilation to keep exposure to airborne contaminants below the exposure limit. Make-up air should always be
Controls
supplied to balance air removed by exhaust ventilation. Ensure that eyewash station and safety shower are
close to work-station.
Personal Protection - The selection of personal protective equipment varies, depending upon conditions of use.
Eyes Eye protection (i.e., safety glasses, safety goggles and/or face shield) should be determined based on
conditions of use. If product is used in an application where splashing may occur, the use of safety goggles
and/or a face shield should be considered.
Body Wear appropriate clothing to prevent skin contact. As a minimum long sleeves and trousers should be worn.
Respiratory Where concentrations in air may exceed the occupational exposure limits given in Section 2 (and those
applicable to your area) and where engineering, work practices or other means of exposure reduction are not
adequate, NIOSH approved respirators may be necessary to prevent overexposure by inhalation.
Hands Wear appropriate chemically protective gloves. When handling hot product ensure gloves are heat resistant
and insulated.
Feet Wear appropriate footwear to prevent product from coming in contact with feet and skin.
Section IX. Physical and Chemical Properties
Viscous liquid. 13.6 cSt @ 40掳C (104掳F), 3.18 cSt @
Physical State and Viscosity
100掳C (212掳F)
Appearance
Colourless to light yellow. Not applicable.
Colour Pour Point
No odour or slight petroleum oil like. Not applicable.
Odour Softening Point
Not available. Not applicable.
Odour Threshold Dropping Point
Not available. Not available
Boiling Point Penetration
0.8550 kg/L @ 15掳C (59掳F) Oil / Water Dist. Coeff. Not available.
Density
Not available. Not available
Vapour Density Ionicity (in water)
Negligible at ambient temperature and Dispersion Properties Easily dispersed in water.
Vapour Pressure
pressure.
Non-volatile. Insoluble in water.
Volatility Solubility
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PURESPRAY GREEN Page Number: 3
Section X. Stability and Reactivity
Not available.
Corrosivity
The product is stable under normal Hazardous W ill not occur under normal working
Stability
handling and storage conditions. conditions.
Polymerization
Reactive with oxidizing agents. May release COx, organic compounds, smoke
Incompatible Decomposition
a n d i r r i t a t i n g v a p o u r s wh e n h e a t e d t o
Substances / Products
decomposition.
Conditions to Avoid
Section XI. Toxicological Information
Skin contact, eye contact, inhalation and ingestion.
Routes of Entry
Acute toxicity information is not available for the product as a whole, therefore, data for some of the
Acute Lethality
ingredients is provided below:
(Base oil CAS# 8042-47-5):
Acute Oral toxicity (LD50): >5000 mg/kg (rat)
Acute Dermal toxicity (LD50): >2000 mg/kg (rabbit)
Acute Inhalation toxicity (LC50): >2500 mg/m鲁/4h (rat)
Chronic or Other Toxic Effects
Prolonged or repeated contact may defat and dry skin, and cause dermatitis. Short-term exposure
Dermal Route:
is expected to cause only slight irritation, if any.
With its relatively low vapour pressure, this product is not expected be inhaled in any appreciable
Inhalation Route:
quantity at ambient conditions. If heated to high temperatures or subjected to mechanical actions
which produce vapours or mists, inhalation may cause respiratory tract irritation.
Ingestion of this product may lead to aspiration of the liquid, especially if vomiting occurs. This may
Oral Route:
result in chemical pneumonitis (inflammation of the lungs) and/or pulmonary edema (an
accumulation of fluid in the lungs). May produce a laxative effect.
Short-term exposure is expected to cause only slight irritation, if any.
Eye Irritation/Inflammation:
Not available.
Immunotoxicity:
Contact with this product is not expected to cause skin sensitization, based upon the available data
Skin Sensitization:
and the known hazards of the components.
Contact with this product is not expected to cause respiratory tract sensitization, based upon the
Respiratory Tract Sensitization:
available data and the known hazards of the components.
This product is not known to contain any components at >= 0.1% that have been shown to cause
Mutagenic:
mutagenicity. Therefore, based upon the available data and the known hazards of the
components, this product is not expected to be a mutagen.
This product is not known to contain any components at >= 0.1% that have been shown to cause
Reproductive Toxicity:
reproductive toxicity. Therefore, based upon the available data and the known hazards of the
components, this product is not expected to be a reproductive toxin.
This product is not known to contain any components at >= 0.1% that have been shown to cause
Teratogenicity/Embryotoxicity:
teratogenicity and/or embryotoxicity. Therefore, based upon the available data and the known
hazards of the components, this product is not expected to be a teratogen/embryotoxin.
This product is not known to contain any chemicals at reportable quantities that are listed as Group
Carcinogenicity (ACGIH):
A1 or A2 carcinogens by ACGIH.
This product is not known to contain any chemicals at reportable quantities that are listed as Group
Carcinogenicity (IARC):
1, 2A, or 2B carcinogens by IARC.
This product is not known to contain any chemicals at reportable quantities that are listed as
Carcinogenicity (NTP):
carcinogens by NTP.
This product is not known to contain any chemicals at reportable quantities that are listed as
Carcinogenicity (IRIS):
carcinogens by IRIS.
This product is not known to contain any chemicals at reportable quantities that are listed as
Carcinogenicity (OSHA):
carcinogens by OSHA.
No additional remark.
Other Considerations
Section XII. Ecological Information
Environmental Fate Not available Not available
Persistance/
Bioaccumulation
Potential
Not available. Not available.
Products of
BOD5 and COD
Biodegradation
Additional Remarks No additional remark.
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PURESPRAY GREEN Page Number: 4
Section XIII. Disposal Considerations
Spent/ used/ waste product may meet the requirements of a hazardous waste. Consult your local or regional
Waste Disposal
authorities. Ensure that waste management processes are in compliance with government requirements and
local disposal regulations.
Section XIV. Transport Information
DOT Classification Not a DOT controlled material (United Special Provisions Not applicable.
States). for Transport
Section XV. Regulatory Information
This product is acceptable for use under the provisions of WHMIS-CPR. All components of this formulation
Other
are listed on the CEPA-DSL (Domestic Substance List)
Regulations
All components of this formulation are listed on the US EPA-TSCA Inventory.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR.
Please contact Product Safety for more information.
Not evaluated. WHMIS (Canada) Not controlled
DSD/DPD (EEC)
ADR (Europe) TDG (Canada)
NOT EVALUATED FOR
EUROPEAN TRANSPORT
(Pictograms) (Pictograms)
NON 脡VALU脡 POUR LE
TRANSPORT EUROP脡EN.
Section XVI. Other Information
Available upon request.
References
* Marque de commerce de Petro-Canada - Trademark
Glossary
ACGIH - American Conference of Governmental Industrial IRIS - Integrated Risk Information System
Hygienists LD50/LC50 - Lethal Dose/Concentration kill 50%
ADR - Agreement on Dangerous goods by Road (Europe) LDLo/LCLo - Lowest Published Lethal Dose/Concentration
ASTM - American Society for Testing and Materials NAERG'96 - North American Emergency Response Guide Book (1996)
BOD5 - Biological Oxygen Demand in 5 days NFPA - National Fire Prevention Association
CAN/CGA B149.2 Propane Installation Code NIOSH - National Institute for Occupational Safety & Health
CAS - Chemical Abstract Services NPRI - National Pollutant Release Inventory
CEPA - Canadian Environmental Protection Act NSNR - New Substances Notification Regulations (Canada)
CERCLA - Comprehensive Environmental Response, NTP - National Toxicology Program
Compensation and Liability Act OSHA - Occupational Safety & Health Administration
CFR - Code of Federal Regulations PEL - Permissible Exposure Limit
CHIP - Chemicals Hazard Information and Packaging Approved RCRA - Resource Conservation and Recovery Act
Supply List SARA - Superfund Amendments and Reorganization Act
COD5 - Chemical Oxygen Demand in 5 days SD - Single Dose
CPR - Controlled Products Regulations STEL - Short Term Exposure Limit (15 minutes)
DOT - Department of Transport TDG - Transportation Dangerous Goods (Canada)
DSCL - Dangerous Substances Classification and Labeling TDLo/TCLo - Lowest Published Toxic Dose/Concentration
(Europe) TLm - Median Tolerance Limit
DSD/DPD - Dangerous Substances or Dangerous Preparations TLV-TWA - Threshold Limit Value-Time Weighted Average
Directives (Europe) TSCA - Toxic Substances Control Act
DSL - Domestic Substance List USEPA - United States Environmental Protection Agency
EEC/EU - European Economic Community/European Union USP - United States Pharmacopoeia
EINECS - European Inventory of Existing Commercial Chemical WHMIS - Workplace Hazardous Material Information System
Substances
EPCRA - Emergency Planning and Community Right to Know Act
FDA - Food and Drug Administration
FIFRA - Federal Insecticide, Fungicide and Rodenticide Act
HCS - Hazard Communication Standard
HMIS - Hazardous Material Information System
IARC - International Agency for Research on Cancer
For Copy of MSDS Prepared by Product Safety - TLM on
The Canadian Controlled Products Regulations (CPR) (Under the Hazardous 8/26/2004.
Products Act, part of the WHMIS legislation) only apply to WHMIS Controlled (i.e., Data entry by Product Safety - RS.
hazardous) products. Therefore, the CPR and the 3-year update rule specified
therein do not apply to WHMIS Non-Controlled products. Although this is true,
customarily Petro-Canada reviews and updates Non-Controlled product MSDS if a
customer requests such an update. These Non-Controlled product updates are given
a lower priority than Controlled products but are handled as soon as practicable. If
you would like to verify if the MSDS you have is the most current, or you require any
further information, please contact:
Continued on Next Page Internet: www.petro-canada.ca/msds Available in French
PURESPRAY GREEN Page Number: 5
Internet: www.petro-canada.ca/msds
Lubricants:
Western Canada, telephone: 1-800-661-1199; fax: (780) 464-9564
Ontario & Central Canada, telephone: 1-800-268-5850 and (905) 822-4222; fax:
1-800-201-6285
Quebec & Eastern Canada, telephone: 1-800-576-1686; fax: 800-201-6285
For Product Safety Information: (905) 804-4752
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its
subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should
be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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