3M MATERIAL SAFETY DATA SHEET 1370/1370L 3M(TM) ESPE(TM) FILTEK(TM) Z250 UNIVERSAL RESTORATIVE INTRO
KIT 05/10/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
PRODUCT NAME: 1370/1370L 3M(TM) ESPE(TM) FILTEK(TM) Z250 UNIVERSAL
RESTORATIVE INTRO KIT
MANUFACTURER: 3M
DIVISION: 3M ESPE Dental Products
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 05/10/2004
Supercedes Date: 01/22/2004
Document Group: 19-0145-3
ID Number(s):
70-2010-3710-1, 70-2010-3711-9, 70-2010-3712-7
This product is a kit or a multipart product which consists of multiple, independently packaged components. An MSDS for
each of these components is included. Please do not separate the component MSDSs from this cover page. The document
numbers of the MSDSs for components of this product are:
08-2286-6, 07-8720-0, 10-4782-8
Revision Changes:
Kit initial issue message was modified.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
_________________________________________________________________________________________________________
Page 1 of 2
3M MATERIAL SAFETY DATA SHEET 1370/1370L 3M(TM) ESPE(TM) FILTEK(TM) Z250 UNIVERSAL RESTORATIVE INTRO
KIT 05/10/2004
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
_________________________________________________________________________________________________________
Page 2 of 2
3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) SINGLE BOND ADHESIVE 06/02/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) ESPE(TM) SINGLE BOND ADHESIVE
MANUFACTURER: 3M
DIVISION: 3M ESPE Dental Products
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 06/02/2004
Supercedes Date: 01/07/2003
Document Group: 07-8720-0
Product Use:
Limitations on Use: For use only by dental professionals
Specific Use: Dental adhesive
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
ETHYL ALCOHOL 64-17-5 30 - 40
BISPHENOL A DIGLYCIDYL ETHER DIMETHACRYLATE 1565-94-2 15 - 25
2-HYDROXYETHYL METHACRYLATE 868-77-9 10 - 20
GLYCEROL 1,3 DIMETHACRYLATE 1830-78-0 5 - 15
COPOLYMER OF ACRYLIC & ITACONIC ACIDS 25948-33-8 5 - 15
DIURETHANE DIMETHACRYLATE 72869-86-4 2- 8
WATER 7732-18-5 2- 8
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Clear, slight acrylate odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Flammable liquid and vapor. Closed containers exposed to heat from
fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
May cause allergic skin reaction. May cause target organ effects.
_________________________________________________________________________________________________
Page 1 of 7
3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) SINGLE BOND ADHESIVE 06/02/2004
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Prolonged or repeated exposure may cause:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.
May be absorbed following ingestion and cause target organ effects.
NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of
ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an
expected effect during the foreseeable use of this product.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
_________________________________________________________________________________________________
Page 2 of 7
3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) SINGLE BOND ADHESIVE 06/02/2004
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
70 潞F [Test Method: Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Flammable liquid and vapor. Closed containers exposed to heat from fire may build
pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use
only non-sparking tools. Ventilate the area with fresh air. Cover with absorbent material. Remember, adding an absorbent material
does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Clean up residue.
Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities.
Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. A no-touch technique is recommended. If skin
contact occurs, wash skin with soap and water. Acrylates may penetrate commonly-used gloves. If product contacts glove, remove and
discard glove, wash hands immediately with soap and water and then re-glove. Avoid eye contact. Avoid skin contact.
7.2 STORAGE
Keep container tightly closed. Store away from heat. Store out of direct sunlight.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Not applicable.
_________________________________________________________________________________________________
Page 3 of 7
3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) SINGLE BOND ADHESIVE 06/02/2004
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid skin contact. See Sect. 7.1 for more information about skin protection.
8.2.3 Respiratory Protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
8.2.4 Prevention of Swallowing
Do not ingest.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ETHYL ALCOHOL ACGIH TWA 1000 ppm Table A4
ETHYL ALCOHOL OSHA TWA 1000 ppm Table Z-1
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Clear, slight acrylate odor
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
70 潞F [Test Method: Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
78 潞C
Boiling point
No Data Available
Density
No Data Available
Vapor Density
No Data Available
Vapor Pressure
1.003 [Ref Std: WATER=1]
Specific Gravity
5
pH
Not Applicable
Melting point
No Data Available
Solubility In Water
No Data Available
Evaporation rate
No Data Available
Volatile Organic Compounds
_________________________________________________________________________________________________
Page 4 of 7
3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) SINGLE BOND ADHESIVE 06/02/2004
No Data Available
Percent volatile
No Data Available
VOC Less H2O & Exempt Solvents
15 centistoke
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Sparks and/or flames; Heat
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product
in a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D001 (Ignitable)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
_________________________________________________________________________________________________
Page 5 of 7
3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) SINGLE BOND ADHESIVE 06/02/2004
ID Number(s):
LE-F100-0079-4, LE-F100-0085-8, 70-2010-1613-9, 70-2010-1616-2, 70-2010-1617-0, 70-2010-1618-8, 70-2010-1803-6
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the
FDA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 1 Flammability: 2 Reactivity: 0 Special Hazards: None
_________________________________________________________________________________________________
Page 6 of 7
3M MATERIAL SAFETY DATA SHEET 3M(TM) ESPE(TM) SINGLE BOND ADHESIVE 06/02/2004
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 16: NFPA hazard classification heading was modified.
Copyright was modified.
Section 8: Exposure guidelines data source legend was modified.
Section 3: Potential effects from inhalation information was modified.
Section 5: Fire fighting procedures information was modified.
Section 7: Handling information was modified.
Section 15: 311/312 hazard categories heading was modified.
Section 15: International regulations information was modified.
Section 15: State regulations information was modified.
Section 15: US federal regulations information was modified.
Section 10: Hazardous polymerization heading was modified.
Section 3: Carcinogenicity phrase was modified.
Section 2: Ingredient table was modified.
Section 14: ID Number(s) was modified.
Section 16: NFPA explanation was modified.
Section 15: Inventories information was modified.
Section 12: Ecotoxicological information heading was modified.
Section 12: Chemical fate information heading was modified.
Section 16: NFPA hazard classification for special hazards was modified.
Section 12: Ecotoxicological phrase was modified.
Section 12: Chemical Fate phrase was modified.
Section 2: Ingredient phrase was added.
Section 3: Other potential health effects heading was deleted.
Section 3: Other health effects information was deleted.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
_________________________________________________________________________________________________
Page 7 of 7
3M MATERIAL SAFETY DATA SHEET 3M FILTEK Z250 UNIVERSAL RESTORATIVE PASTE 06/02/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M FILTEK Z250 UNIVERSAL RESTORATIVE PASTE
MANUFACTURER: 3M
DIVISION: 3M ESPE Dental Products
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 06/02/2004
Supercedes Date: 02/12/2003
Document Group: 08-2286-6
Product Use:
Limitations on Use: For use only by dental professionals
Specific Use: Dental restorative
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
SILANE TREATED CERAMIC 444758-98-9 75 - 85
BISPHENOL A POLYETHYLENE GLYCOL DIETHER DIMETHACRYLATE 41637-38-1 5 - 10
DIURETHANE DIMETHACRYLATE 72869-86-4 5 - 10
BISPHENOL A DIGLYCIDYL ETHER DIMETHACRYLATE 1565-94-2 <5
TRIETHYLENE GLYCOL DIMETHACRYLATE 109-16-0 <5
WATER 7732-18-5 <2
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Paste
Odor, Color, Grade: Slight acrylate odor, various shades
General Physical Form: Solid
Immediate health, physical, and environmental hazards: May cause allergic skin reaction.
3.2 POTENTIAL HEALTH EFFECTS
_________________________________________________________________________________________________
Page 1 of 7
3M MATERIAL SAFETY DATA SHEET 3M FILTEK Z250 UNIVERSAL RESTORATIVE PASTE 06/02/2004
Eye Contact:
Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.
Skin Contact:
Prolonged or repeated exposure may cause:
Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Prolonged or repeated exposure may cause:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness,
and nose and throat pain.
Ingestion:
No health effects are expected.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: No need for first aid is anticipated.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
_________________________________________________________________________________________________
Page 2 of 7
3M MATERIAL SAFETY DATA SHEET 3M FILTEK Z250 UNIVERSAL RESTORATIVE PASTE 06/02/2004
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Non-flammable: ordinary combustible material.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Ventilate the area with fresh air. Collect as much of the spilled material as possible.
Clean up residue. Collect the resulting residue containing solution. Place in a closed container approved for transportation by
appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid eye contact. Avoid skin contact. A no-touch technique is recommended. If skin contact occurs, wash skin with soap and water.
Acrylates may penetrate commonly-used gloves. If product contacts glove, remove and discard glove, wash hands immediately with
soap and water and then re-glove.
7.2 STORAGE
Store in a cool place.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Not applicable.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid skin contact. See Sect. 7.1 for more information about skin protection.
8.2.3 Respiratory Protection
_________________________________________________________________________________________________
Page 3 of 7
3M MATERIAL SAFETY DATA SHEET 3M FILTEK Z250 UNIVERSAL RESTORATIVE PASTE 06/02/2004
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
8.2.4 Prevention of Swallowing
Do not ingest.
8.3 EXPOSURE GUIDELINES
None Established
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Paste
Specific Physical Form:
Slight acrylate odor, various shades
Odor, Color, Grade:
Solid
General Physical Form:
No Data Available
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
Not Applicable
Boiling point
No Data Available
Density
Not Applicable
Vapor Density
Not Applicable
Vapor Pressure
2.1 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
No Data Available
Melting point
Nil
Solubility in Water
Nil
Evaporation rate
No Data Available
Volatile Organic Compounds
No Data Available
Percent volatile
No Data Available
VOC Less H2O & Exempt Solvents
Approximately 300000 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: None known
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
_________________________________________________________________________________________________
Page 4 of 7
3M MATERIAL SAFETY DATA SHEET 3M FILTEK Z250 UNIVERSAL RESTORATIVE PASTE 06/02/2004
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal
alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
LE-F100-0078-3, 41-5300-6441-3, 70-2010-2225-1, 70-2010-2226-9, 70-2010-2227-7, 70-2010-2228-5, 70-2010-2229-3, 70-
2010-2230-1, 70-2010-2231-9, 70-2010-2232-7, 70-2010-2233-5, 70-2010-2234-3, 70-2010-2235-0, 70-2010-2236-8, 70-2010-
2237-6, 70-2010-2238-4, 70-2010-2241-8, 70-2010-2242-6, 70-2010-2243-4, 70-2010-2244-2, 70-2010-2245-9, 70-2010-2246-7,
70-2010-2247-5, 70-2010-2248-3, 70-2010-2249-1, 70-2010-2250-9, 70-2010-2251-7, 70-2010-2252-5, 70-2010-2253-3, 70-
2010-2254-1, 70-2010-2259-0, 70-2010-2260-8, 70-2010-2564-3, 70-2010-2565-0, 70-2010-2566-8, 70-2010-2567-6, 70-2010-
2568-4, 70-2010-2569-2, 70-2010-2570-0, 70-2010-2571-8, 70-2010-2572-6, 70-2010-2573-4, 70-2010-2574-2, 70-2010-2575-9,
70-2010-2576-7, 70-2010-2577-5, 70-2010-2578-3, 70-2010-2585-8, 70-2010-2586-6, 70-2010-2587-4, 70-2010-2588-2, 70-
2010-2589-0, 70-2010-2590-8, 70-2010-2591-6, 70-2010-2592-4, 70-2010-2593-2, 70-2010-2594-0, 70-2010-2595-7, 70-2010-
2596-5, 70-2010-2597-3, 70-2010-2598-1, 70-2010-2599-9, 70-2010-2700-3, 70-2010-2702-9, 70-2010-2703-7, 70-2010-2704-5,
70-2010-2707-8, 70-2010-2708-6, 70-2010-2709-4, 70-2010-2710-2, 70-2010-2711-0, 70-2010-2712-8, 70-2010-2713-6, 70-
2010-2714-4, 70-2010-2715-1, 70-2010-2716-9, 70-2010-2717-7, 70-2010-2718-5, 70-2010-2723-5, 70-2010-2724-3, 70-2010-
2725-0, 70-2010-2726-8, 70-2010-3118-7, 70-2010-3135-1, 70-2010-3177-3, 70-2010-3178-1, 70-2010-3195-5, 70-2010-3196-3,
70-2010-3197-1, 70-2010-3198-9, 70-2010-3200-3, 70-2010-3201-1, 70-2010-3202-9, 70-2010-3203-7, 70-2010-3232-6, 70-
2010-3278-9, 70-2010-3279-7
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
_________________________________________________________________________________________________
Page 5 of 7
3M MATERIAL SAFETY DATA SHEET 3M FILTEK Z250 UNIVERSAL RESTORATIVE PASTE 06/02/2004
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the
FDA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 16: NFPA hazard classification heading was modified.
Copyright was modified.
Section 5: Fire fighting procedures information was modified.
Section 15: 311/312 hazard categories heading was modified.
_________________________________________________________________________________________________
Page 6 of 7
3M MATERIAL SAFETY DATA SHEET 3M FILTEK Z250 UNIVERSAL RESTORATIVE PASTE 06/02/2004
Section 15: International regulations information was modified.
Section 15: State regulations information was modified.
Section 15: US federal regulations information was modified.
Section 10: Hazardous polymerization heading was modified.
Section 2: Ingredient table was modified.
Section 14: ID Number(s) was modified.
Section 16: NFPA explanation was modified.
Section 15: Inventories information was modified.
Section 12: Ecotoxicological information heading was modified.
Section 12: Chemical fate information heading was modified.
Section 16: NFPA hazard classification for special hazards was modified.
Section 8: Exposure guidelines information - none - was modified.
Section 12: Ecotoxicological phrase was modified.
Section 12: Chemical Fate phrase was modified.
Section 2: Ingredient phrase was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
_________________________________________________________________________________________________
Page 7 of 7
3M MATERIAL SAFETY DATA SHEET 7523 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHANT DELIVERY SYSTEM
06/03/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 7523 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHANT DELIVERY SYSTEM
MANUFACTURER: 3M
DIVISION: 3M ESPE Dental Products
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 06/03/2004
Supercedes Date: 01/16/2004
Document Group: 10-4782-8
Product Use:
Limitations on Use: For use only by dental professionals
Specific Use: Etching teeth
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
WATER 7732-18-5 55 - 65
PHOSPHORIC ACID 7664-38-2 30 - 40
SYNTHETIC AMORPHOUS SILICA 112945-52-5 5 - 10
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Gel
Odor, Color, Grade: Blue, slight characteristic odor
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause chemical skin burns.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
_________________________________________________________________________________________________
Page 1 of 7
3M MATERIAL SAFETY DATA SHEET 7523 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHANT DELIVERY SYSTEM
06/03/2004
Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.
Skin Contact:
Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and
tissue destruction.
Inhalation:
No health effects are expected.
Ingestion:
Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain, nausea, vomiting, and diarrhea;
blood in the feces and/or vomitus may also be seen.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15
minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: No need for first aid is anticipated.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Not Applicable
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Non-combustible. Choose material suitable for surrounding fire.
5.3 PROTECTION OF FIRE FIGHTERS
_________________________________________________________________________________________________
Page 2 of 7
3M MATERIAL SAFETY DATA SHEET 7523 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHANT DELIVERY SYSTEM
06/03/2004
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus
(SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards,
respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information
on handling and managing the spill. Ventilate the area with fresh air. Contain spill. Cover with absorbent material. Collect as much
of the spilled material as possible. Clean up residue. Collect the resulting residue containing solution. Place in a metal container
approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a
plastic drum liner made of polyethylene. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid eye contact. Avoid skin contact.
7.2 STORAGE
Not applicable.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Not applicable.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact.
The following eye protection(s) are recommended: Safety Glasses with side shields.
8.2.2 Skin Protection
Avoid skin contact.
8.2.3 Respiratory Protection
Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.
8.2.4 Prevention of Swallowing
Do not ingest.
_________________________________________________________________________________________________
Page 3 of 7
3M MATERIAL SAFETY DATA SHEET 7523 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHANT DELIVERY SYSTEM
06/03/2004
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
PHOSPHORIC ACID ACGIH TWA 1 mg/m3
PHOSPHORIC ACID ACGIH STEL 3 mg/m3
PHOSPHORIC ACID OSHA TWA 1 mg/m3 Table Z-1A
PHOSPHORIC ACID OSHA STEL 3 mg/m3 Table Z-1A
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Gel
Specific Physical Form:
Blue, slight characteristic odor
Odor, Color, Grade:
Liquid
General Physical Form:
Not Applicable
Autoignition temperature
Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
>= 212 潞F
Boiling point
No Data Available
Density
Not Applicable
Vapor Density
Not Applicable
Vapor Pressure
1.28
Specific Gravity
1
pH
Not Applicable
Melting point
Complete
Solubility in Water
No Data Available
Evaporation rate
No Data Available
Volatile Organic Compounds
Not Applicable
Percent volatile
No Data Available
VOC Less H2O & Exempt Solvents
100,000 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong bases
Hazardous Polymerization: Hazardous polymerization will not occur.
_________________________________________________________________________________________________
Page 4 of 7
3M MATERIAL SAFETY DATA SHEET 7523 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHANT DELIVERY SYSTEM
06/03/2004
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. As a
disposal alternative, dispose of waste product in a permitted hazardous waste facility.
EPA Hazardous Waste Number (RCRA): D002 (Corrosive)
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
LE-F100-0070-1, 70-2004-8041-9, 70-2010-0289-9, 70-2010-0349-1, 70-2010-0839-1, 70-2010-1442-3, 70-2010-1759-0, FH-
5000-3624-6, FH-5000-3625-3, FH-5000-4220-2
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
_________________________________________________________________________________________________
Page 5 of 7
3M MATERIAL SAFETY DATA SHEET 7523 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHANT DELIVERY SYSTEM
06/03/2004
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
STATE REGULATIONS
Contact 3M for more information.
CHEMICAL INVENTORIES
This material contains one or more substances not listed on the TSCA Inventory. Commercial use of this material is regulated by the
FDA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 0 Reactivity: 0 Special Hazards: None
Corrosive: Yes
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
Revision Changes:
Section 16: NFPA hazard classification heading was modified.
Section 8: Exposure guidelines data source legend was modified.
Section 15: 311/312 hazard categories heading was modified.
Section 15: International regulations information was modified.
Section 15: State regulations information was modified.
Section 15: US federal regulations information was modified.
Section 10: Hazardous polymerization heading was modified.
_________________________________________________________________________________________________
Page 6 of 7
3M MATERIAL SAFETY DATA SHEET 7523 3M(TM) ESPE(TM) SCOTCHBOND(TM) ETCHANT DELIVERY SYSTEM
06/03/2004
Section 2: Ingredient table was modified.
Section 16: NFPA explanation was modified.
Section 15: Inventories information was modified.
Section 12: Ecotoxicological information heading was modified.
Section 12: Chemical fate information heading was modified.
Section 16: NFPA hazard classification for special hazards was modified.
Section 12: Ecotoxicological phrase was modified.
Section 12: Chemical Fate phrase was modified.
Section 2: Ingredient phrase was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
_________________________________________________________________________________________________
Page 7 of 7
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