Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ALIETTE 80 WG 11418 4X2.268KG GT 1/6
Version 3 / F Revision Date: 07.09.2004
102000001540 Print Date: 22.11.2004
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
Product information
Trade name ALIETTE 80 WG 11418 4X2.268KG GT
Product code (UVP) 05921058
Product code (EXP) 10369D
Specification 11418
Usage fungicide
Company Bayer CropScience SA
16, rue Jean-Marie Leclair
69009 Lyon
France
Emergency telephone number +33(0)4.72.85.25.25
Telefax +33(0)4.72.85.27.99
Num茅ro INRS +33(0)1.45.42.59.59
2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Water dispersible granules (WG)
Fosetyl-aluminium 80% WG
Hazardous components
Chemical Name CAS-No. / Symbol(s) R-phrase(s) Concentration [%]
EINECS-No.
Fosetyl Aluminium 39148-24-8 Xi R41 80,00
254-320-2
(Polyethylenethoxy)ethanol 10 68412-54-4 Xn, N R22, R41, >= 1,00 - <= 5,00
EO R51/53
Nonylphenol ethoxylate 40 68412-54-4 R52/53 >= 1,00 - <= 5,00
EO
Sodium hydroxide 1310-73-2 C R35 >= 1,00 - <= 5,00
215-185-5
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Irritating to eyes.
4. FIRST AID MEASURES
General advice
In the case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible).
Inhalation
Move the patient to fresh air and keep at rest. In the event of symptoms obtain medical
treatment.
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ALIETTE 80 WG 11418 4X2.268KG GT 2/6
Version 3 / F Revision Date: 07.09.2004
102000001540 Print Date: 22.11.2004
Skin contact
Take off all contaminated clothing immediately. Wash off with soap and water. If skin problems
persist, seek medical advice.
Eye contact
Rinse immediately with plenty of water for at least 15 minutes. An eye specialist must be
consulted immediately: Instillation of local anesthetic drops e.g. 1% Amethocaine Hydrochloride
eye drops. GiveAnalgesics as necessary.
Ingestion
Wash out mouth with water. Do not induce vomiting. Keep body calm, protect against loss of
heat. Seek medical advice immediately.
Notes to physician
Symptoms
The following symptoms may occur:, Eye and mucous membrane irritation, May cause skin and
eye irritation.
Treatment
There is no antidote.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
foam
dry powder
carbon dioxide (CO2)
Specific hazards during fire fighting
In the event of fire the following can be released:
carbon monoxide (CO)
nitrogen oxides (NOx)
phosphorus oxides (eg phosphorus pentoxide)
Special protective equipment for fire-fighters
Use breathing apparatus.
Further information
Contain the spread of the fire-fighting media.
6. ACCIDENTAL RELEASE MEASURES
Methods for cleaning up
Pick up and fill the product into a tightly closed container.
Use approved industrial vacuum cleaner for removal.
Additional advice
Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
7. HANDLING AND STORAGE
Handling
Advice on safe handling
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ALIETTE 80 WG 11418 4X2.268KG GT 3/6
Version 3 / F Revision Date: 07.09.2004
102000001540 Print Date: 22.11.2004
Smoking, eating and drinking should be prohibited in the application area.
Advice on protection against fire and explosion
Dust explosivity : very low sensitivity
Storage
Requirements for storage areas and containers
Keep out of the reach of children.
Advice on common storage
Keep away from food, drink and animal feedingstuffs.
Suitable materials
Rigid material with protection against moisture
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering measures
Provide appropriate exhaust ventilation at places where dust is formed.
Personal protective equipment
Respiratory protection Half mask with a particle filter P2 (EN 143).
Hand protection rubber gloves
Eye protection tightly fitting safety goggles
Skin and body protection dust impervious protective suit
Hygiene measures
Clean hands and face at work intervals and after work.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form water-dispersible granules
Colour grey to black
Safety data
pH 3-4
Determined as a 1% emulsion in distilled water.
Bulk density ca. 620 - 660 g/l
Water solubility dispersible
Partition coefficient (n- log Pow: -2,1
octanol/water) The value mentioned relates to the active ingredient fosetyl
aluminium.
10. STABILITY AND REACTIVITY
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ALIETTE 80 WG 11418 4X2.268KG GT 4/6
Version 3 / F Revision Date: 07.09.2004
102000001540 Print Date: 22.11.2004
Hazardous reactions No hazardous reactions when stored and handled according to
prescribed instructions.
Stable under normal conditions.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity LD50 (rat) 2.860 mg/kg
Acute inhalation toxicity LC50 (rat) > 5,02 mg/l
Exposure time: 4 h
Acute dermal toxicity LD50 (rat) > 2.000 mg/kg
Skin irritation slight irritant effect - does not require labelling (rabbit)
Eye irritation irritating (rabbit)
Sensitization Non-sensitizing
Further information
The toxicological data refer to a similar formulation.
12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability)
Biodegradability According to the results of tests on biodegradability this product is
considered as being readily biodegradable.
Ecotoxicity effects
Toxicity to fish LC50 (Rainbow trout (Oncorhynchus mykiss)) > 120 mg/l
Exposure time: 96 h
Test conducted with a similar formulation.
Toxicity to daphnia EC50 (Water flea (Daphnia magna)) 37 mg/l
Exposure time: 48 h
Test conducted with a similar formulation.
Toxicity to algae EC50 (Scenedesmus subspicatus) 8 mg/l
Exposure time: 72 h
Test conducted with a similar formulation.
Further information on ecology
Additional ecological information
Non-hazardous for Bees.
13. DISPOSAL CONSIDERATIONS
Product
Must be incinerated in a suitable incineration plant holding a permit delivered by the competent
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ALIETTE 80 WG 11418 4X2.268KG GT 5/6
Version 3 / F Revision Date: 07.09.2004
102000001540 Print Date: 22.11.2004
authorities.
Contaminated packaging
Empty remaining contents.
Must be incinerated in a suitable incineration plant holding a permit delivered by the competent
authorities.
Completely empty packaging may be treated as household waste
Waste key for the unused product
020108 agrochemical waste containing dangerous substances
14. TRANSPORT INFORMATION
Not dangerous goods
ADNR
Not dangerous goods
ADR
Not dangerous goods
GGVE
Not dangerous goods
GGVS
Not dangerous goods
IATA_C
Not dangerous goods
IATA_P
Not dangerous goods
IMDG
Not dangerous goods
RID
15. REGULATORY INFORMATION
Classification and labelling in accordance with the EC Directive on dangerous preparations
1999/45/EC as amended.
Hazardous components which must be listed on the label:
鈥? Fosetyl Aluminium
Symbol(s)
Xi Irritant
R-phrase(s)
R36 Irritating to eyes.
Classement FRANCE (d茅cision de la Commission des Toxiques)
Symbol(s)
Xi Irritant
R-phrase(s)
R36 Irritating to eyes.
S-phrase(s)
S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feedingstuffs.
S20/21 When using, do not eat, drink or smoke.
S25 Avoid contact with the eyes.
S46 If swallowed, seek medical advice immediately and show this container or
label.
Further information
WHO-classification: III (Slightly hazardous)
Bayer CropScience
SAFETY DATA SHEET according to EC Directive 2001/58/EC
ALIETTE 80 WG 11418 4X2.268KG GT 6/6
Version 3 / F Revision Date: 07.09.2004
102000001540 Print Date: 22.11.2004
Legislation on the control of L茅gislation des Installations Class茅es pour la Protection de
major-accident hazards l'Environnement (Loi du 19/07/76 modifi茅e et D茅cret du 21/09/77
involving dangerous modifi茅)- Rubrique(s) de la Nomenclature:, Rubrique n掳1155: D茅p么ts
substances de produits agropharmaceutiques.
Occupational health precautions
Not concerned
16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2:
R22 Harmful if swallowed.
R35 Causes severe burns.
R41 Risk of serious damage to eyes.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The advice on classification in section 15 of this Safety Data Sheet is based on European Directive
on Preparations (1999/45/EC and its subsequent adaptations). The legislation on pesticide
preparations should be applied by EU Member States not later than 30 July 2004.
The information provided in this safety data sheet has been provided according the requirements
from the French modified decree "arr锚t茅 du 5 janvier 1993". This sheet complements the technical
sheet but does not replace it. The information contained in this sheet is based on knowledge of the
product at the date of publication and is given in good faith. Users are further reminded of the
possible risks of using a product for purposes other than those for which it was intended. The user is
fully responsible for taking all the necessary precautions whilst using the product.The aim of the
statutory regulations indicated is to help the user to fulfil his obligations regarding the use of
hazardous products. This list should not be considered as exhaustive. It does not exonerate the user
from fulfilling other existing legal obligations in addition to those mentioned, relating to the use and
storage of the product. This remains solely the responsibility of the user.
Changes since the last version will be highlighted in the margin. This version replaces all previous
versions.
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