MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 1 of 12
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MEGUIAR'S G103 - SCRATCHX
SYNONYMS
"Manufacturer's Code: G103"
PRODUCT USE
Polishing agent/burnishing compound.
SUPPLIER
Company: Meguiar' s Australia Pty Ltd
Address:
35 Slough Business Park
Holker St, Silverwater
NSW, 2128
AUS
Telephone: +61 2 9737 9422
Telephone: 1800 804 182
Fax: +61 2 9737 9414
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.
POISONS SCHEDULE
S5
RISK SAFETY
HARMFUL- May cause lung damage if swallowed. Do not breathe gas/fumes/vapour/spray.
Avoid contact with eyes.
Wear suitable protective clothing.
Use only in well ventilated areas.
Keep container in a well ventilated place.
To clean the floor and all objects contaminated
by this material, use water and detergent.
Keep container tightly closed.
Keep away from food, drink and animal feeding
stuffs.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty
of water and contact Doctor or Poisons
Information Centre.
If swallowed, IMMEDIATELY contact Doctor or
Poisons Information Centre. (show this container
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 2 of 12
Section 2 - HAZARDS IDENTIFICATION
or label).
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
naphtha petroleum, isoparaffin, hydrotreated 64742-48-9. 10-20
isoparaffins petroleum hydrotreated HFP 64742-47-8. 10-20
kaolin 1332-58-7 5-15
distillates, petroleum, middle, hydrotreated 64742-46-7. 1-10
conditoners proprietary 2-10
polydimethylsiloxane 63148-62-9 1-5
water 7732-18-5 45-65
Section 4 - FIRST AID MEASURES
SWALLOWED
For advice, contact a Poisons Information Centre or a doctor.
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious
- Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
- Seek medical advice.
EYE
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
- If pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
- Transport to hospital, or doctor.
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 3 of 12
Section 4 - FIRST AID MEASURES
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
- Water spray or fog.
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves for fire only.
- Prevent, by any means available, spillage from entering drains or water courses.
- Use fire fighting procedures suitable for surrounding area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
- The material is not readily combustible under normal conditions.
- However, it will break down under fire conditions and the organic component may burn.
- Not considered to be a significant fire risk.
- Heat may cause expansion or decomposition with violent rupture of containers.
- Decomposes on heating and may produce toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
Other combustion products include: carbon dioxide (CO2) and silicon dioxide (SiO2).
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result.
HAZCHEM: None
Personal Protective Equipment
Breathing apparatus.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labelled container for waste disposal.
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 4 of 12
Section 6 - ACCIDENTAL RELEASE MEASURES
MAJOR SPILLS
Slippery when spilt.
Minor hazard.
- Clear area of personnel.
- Alert Fire Brigade and tell them location and nature of hazard.
- Control personal contact by using protective equipment as required.
- Prevent spillage from entering drains or water ways.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labelled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite and place in appropriate
containers for disposal.
- Wash area and prevent runoff into drains or waterways.
- If contamination of drains or waterways occurs, advise emergency services.
EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly all individuals could be exposed
for up to one hour WITHOUT experiencing or developing
life-threatening health effects is:
naphtha petroleum, isoparaffin, hydrotreated 250 mg/m³
kaolin 500 mg/m³
distillates, petroleum, middle, hydrotreated 500 mg/m³
water 500 mg/m³
irreversible or other serious effects or symptoms which could impair an individual's ability to take
protective action is:
naphtha petroleum, isoparaffin, hydrotreated 50 mg/m³
kaolin 100 mg/m³
distillates, petroleum, middle, hydrotreated 400 mg/m³
water 500 mg/m³
other than mild, transient adverse effects without perceiving a clearly defined odour is:
naphtha petroleum, isoparaffin, hydrotreated 30 mg/m³
kaolin 6 mg/m³
distillates, petroleum, middle, hydrotreated 60 mg/m³
water 500 mg/m³
The threshold concentration below which most people will experience no appreciable risk of health effects:
naphtha petroleum, isoparaffin, hydrotreated 10 mg/m³
kaolin 5 mg/m³
distillates, petroleum, middle, hydrotreated 20 mg/m³
water 500 mg/m³
American Industrial Hygiene Association (AIHA)
Ingredients considered according to the following cutoffs
Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0%
R50 >= 0.25% Corrosive (C) >= 5.0%
R51 >= 2.5%
else >= 10%
where percentage is percentage of ingredient found in the mixture
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 5 of 12
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Limit all unnecessary personal contact.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- When handling DO NOT eat, drink or smoke.
- Always wash hands with soap and water after handling.
- Avoid physical damage to containers.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
SUITABLE CONTAINER
- Lined metal can, Lined metal pail/ can
- Plastic pail
- Polyliner drum
- Packing as recommended by manufacturer.
- Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers and acids.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA TWA STEL STEL Peak Peak TWA
ppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC
_________________ __________________ ______ ______ ______ ______ ______ ______ ______
Australia Exposure isoparaffins 5
Standards petroleum
hydrotreated HFP
(Oil mist, refined
mineral)
Australia Exposure kaolin (Kaolin 10
Standards (a))
Australia Exposure distillates, 5
Standards petroleum, middle,
hydrotreated (Oil
mist, refined
mineral)
The following materials had no OELs on our records
� naphtha petroleum, isoparaffin, hydrotreated: CAS:64742-48-9
� polydimethylsiloxane: CAS:63148-62-9
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 6 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA TWA STEL STEL Peak Peak TWA
ppm mg/m³ ppm mg/m³ ppm mg/m³ F/CC
_________________ __________________ ______ ______ ______ ______ ______ ______ ______
� water: CAS:7732-18-5
ODOUR SAFETY FACTOR (OSF)
OSF=0.042 (solvent naphtha, medium aliphatic)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by smell
that the Exposure Standard
(TLV- TWA for example) is
being reached, even when
distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
MATERIAL DATA
None assigned. Refer to individual constituents.
INGREDIENT DATA
NAPHTHA PETROLEUM, ISOPARAFFIN, HYDROTREATED:
POLYDIMETHYLSILOXANE:
WATER:
No exposure limits set by NOHSC or ACGIH.
ISOPARAFFINS PETROLEUM HYDROTREATED HFP:
NAPHTHA PETROLEUM, ISOPARAFFIN, HYDROTREATED:
for petroleum distillates:
CEL TWA: 500 ppm, 2000 mg/m3 (compare OSHA TWA).
NAPHTHA PETROLEUM, ISOPARAFFIN, HYDROTREATED:
REL TWA: 400 ppm [EXXON]
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 7 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ISOPARAFFINS PETROLEUM HYDROTREATED HFP:
REL TWA: 300 ppm [EXXON]
KAOLIN:
Kaolin dust appears to have fibrogenic potential even in the absence of
crystalline silica. Kaolinosis can exist as simple and complicated forms
with the latter often associated with respiratory symptoms. Crystalline
silica enhances the severity of the pneumoconiosis.
DISTILLATES, PETROLEUM, MIDDLE, HYDROTREATED:
Human exposure to oil mist alone has not been demonstrated to cause health effects
except at levels above 5 mg/m3 (this applies to particulates sampled by a method that
does not collect vapour). It is not advisable to apply this standard to oils containing
unknown concentrations and types of additive.
POLYDIMETHYLSILOXANE:
WATER:
PERSONAL PROTECTION
EYE
- Safety glasses with side shields; or as required,
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear protective gloves, eg. PVC.
OTHER
- Overalls.
- Eyewash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 A- AUS P -
1000 50 - A- AUS P
5000 50 Airline * -
5000 100 - A- 2 P
10000 100 - A- 3 P
100+ Airline**
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 8 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Use in a well-ventilated area.
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Off- white liquid with a pleasant odour; soluble in water.
PHYSICAL PROPERTIES
Liquid.
Molecular Weight: Not Applicable Boiling Range (°C): 177
Melting Range (°C): Not Available Specific Gravity (water=1): 0.955
Solubility in water (g/L): Not Available pH (as supplied): 8.00
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): <15 (VOC) Evaporation Rate: <1
Relative Vapour Density (air=1): >1 Flash Point (°C): 93 (PMCC)
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (°C): Not Available Decomposition Temp (°C): Not Available
State: Liquid Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments.
The liquid is discomforting to the gastro-intestinal tract and may be harmful if
swallowed in large quantity.
Ingestion may result in nausea, pain, vomiting. Vomit entering the lungs by aspiration
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 9 of 12
Section 11 - TOXICOLOGICAL INFORMATION
may cause potentially lethal chemical pneumonitis.
EYE
The liquid is discomforting to the eyes and is capable of causing a mild, temporary
redness of the conjunctiva (similar to wind-burn), temporary impairment of vision and/ or
other transient eye damage/ ulceration.
The material may produce moderate eye irritation leading to inflammation. Repeated or
prolonged exposure to irritants may produce conjunctivitis.
SKIN
The liquid is discomforting to the skin if exposure is prolonged and is capable of
causing skin reactions which may lead to dermatitis from repeated exposures over long
periods.
The material may accentuate any pre-existing skin condition.
INHALED
The vapour is discomforting to the upper respiratory tract.
Inhalation hazard is increased at higher temperatures.
Inhalation of vapour may aggravate a pre-existing respiratory condition.
If exposure to highly concentrated solvent atmosphere is prolonged this may lead to
narcosis, unconsciousness, even coma and possible death.
CHRONIC HEALTH EFFECTS
Principal routes of exposure are by accidental skin and eye contact and by inhalation of
vapours especially at higher temperatures.
Prolonged or continuous skin contact with the liquid may cause defatting with drying,
cracking, irritation and dermatitis following.
Chronic solvent inhalation exposures may result in nervous system impairment
and liver and blood changes. [PATTYS].
As with any chemical product, contact with unprotected bare skin; inhalation of vapour,
mist or dust in work place atmosphere; or ingestion in any form, should be avoided by
observing good occupational work practice.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
NAPHTHA PETROLEUM, ISOPARAFFIN, HYDROTREATED:
No significant acute toxicological data identified in literature search.
ISOPARAFFINS PETROLEUM HYDROTREATED HFP:
No significant acute toxicological data identified in literature search.
KAOLIN:
No significant acute toxicological data identified in literature search.
DISTILLATES, PETROLEUM, MIDDLE, HYDROTREATED:
TOXICITY IRRITATION
typical for isoparaffinic hydrocarbons:
Inhalation (rat) LC50: 3400 ppm/4H None reported
[EXXON]
Oral (rat) LD50
: >8000 mg/kg
[CCINFO-Shell]
POLYDIMETHYLSILOXANE:
TOXICITY IRRITATION
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 10 of 12
Section 11 - TOXICOLOGICAL INFORMATION
Inhalation (rat) LC50: >1100 mg/m³* Eye (rabbit): 100 mg/1h - Mild
Oral (rat) LD50: >35000 mg/kg*
Dermal (rabbit) LD50: >3000 mg/kg*
The material may be irritating to the eye, with prolonged contact causing inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
No toxic response noted during 90 day subchronic inhalation toxicity
studies
The no observable effect level is 450 mg/m³.
Non-irritating and non-sensitising in human patch test. [Xerox]*
WATER:
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
No data for Meguiar's G103 - ScratchX.
Refer to data for ingredients, which follows:
NAPHTHA PETROLEUM, ISOPARAFFIN, HYDROTREATED:
DO NOT discharge into sewer or waterways.
POLYDIMETHYLSILOXANE:
Fish LC50 (96hr.) (mg/l): 10000
Section 13 - DISPOSAL CONSIDERATIONS
- Consult manufacturer for recycling options and recycle where possible .
- Consult State Land Waste Management Authority for disposal.
- Incinerate residue at an approved site.
- Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: S5
REGULATIONS
naphtha petroleum, isoparaffin, hydrotreated (CAS: 64742-48-9) is found on the following
regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Poisons Schedule
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 11 of 12
Section 15 - REGULATORY INFORMATION
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
isoparaffins petroleum hydrotreated HFP (CAS: 64742-47-8) is found on the following
regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Poisons Schedule
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
kaolin (CAS: 1332-58-7) is found on the following regulatory lists;
Australia - Australia New Zealand Food Standards Code - Processing Aids - Generally
permitted
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
distillates, petroleum, middle, hydrotreated (CAS: 64742-46-7) is found on the following
regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Poisons Schedule
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
polydimethylsiloxane (CAS: 63148-62-9) is found on the following regulatory lists;
Australia - Australia New Zealand Food Standards Code - Food Additives - Schedule 2
Miscellaneous additives permitted in accordance with GMP in processed foods specified in
Schedule 1
Australia - Australia New Zealand Food Standards Code - Processing Aids - Permitted
antifoam agents
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule
4
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
OECD Representative List of High Production Volume (HPV) Chemicals
water (CAS: 7732-18-5) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule
6
OECD Representative List of High Production Volume (HPV) Chemicals
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
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MEGUIAR'S G103 - SCRATCHX
Chemwatch Material Safety Data Sheet
Issue Date: 15-Nov-2006 CHEMWATCH 4804-89
NA317EC CD 2006/4 Page 12 of 12
Section 16 - OTHER INFORMATION
Issue Date: 15-Nov-2006
Print Date: 11-Dec-2006
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