MEGUIAR'S G14922 - QUIK OUT
Chemwatch Material Safety Data Sheet
Issue Date: 5-Jul-2007 CHEMWATCH 6616-63
NA317EC Version No:1
CD 2007/2 Page 1 of 9
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MEGUIAR'S G14922 - QUIK OUT
SYNONYMS
"Manufacturer's Code: G14922"
PRODUCT USE
Cleaning agent.
SUPPLIER
Company: MotorActive
Address:
35 Slough Business Park
Holker St, Silverwater
NSW, 2128
AUS
Telephone: +61 2 9737 9422
Telephone: 1800 347 570
Fax: +61 2 9737 9414
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK SAFETY
None under normal operating conditions. None under normal operating conditions.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
propylene glycol monobutyl ether 5131-66-8 <2.1
hydrogen peroxide 7722-84-1 <2.1
Section 4 - FIRST AID MEASURES
SWALLOWED
- Immediately give a glass of water.
- First aid is not generally required. If in doubt, contact a Poisons Information Centre
or a doctor.
EYE
If this product comes in contact with eyes:
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Chemwatch Material Safety Data Sheet
Issue Date: 5-Jul-2007 CHEMWATCH 6616-63
NA317EC Version No:1
CD 2007/2 Page 2 of 9
Section 4 - FIRST AID MEASURES
- Wash out immediately with water.
- If irritation continues, seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin or hair contact occurs:
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
- There is no restriction on the type of extinguisher which may be used.
- Use extinguishing media suitable for surrounding area.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves for fire only.
- Prevent, by any means available, spillage from entering drains or water courses.
- Use fire fighting procedures suitable for surrounding area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
FIRE/EXPLOSION HAZARD
- Non combustible.
- Not considered to be a significant fire risk.
- Expansion or decomposition on heating may lead to violent rupture of containers.
- Decomposes on heating and may produce toxic/ irritating fumes.
- May emit acrid smoke.
May emit poisonous fumes.
FIRE INCOMPATIBILITY
None known.
HAZCHEM: None
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
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Chemwatch Material Safety Data Sheet
Issue Date: 5-Jul-2007 CHEMWATCH 6616-63
NA317EC Version No:1
CD 2007/2 Page 3 of 9
Section 6 - ACCIDENTAL RELEASE MEASURES
- Wipe up.
- Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Moderate hazard.
- Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labelled containers for recycling.
- Neutralise/decontaminate residue.
- Collect solid residues and seal in labelled drums for disposal.
- Wash area and prevent runoff into drains.
- After clean up operations, decontaminate and launder all protective clothing and
equipment before storing and re-using.
- If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- DO NOT allow material to contact humans, exposed food or food utensils.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately. Launder contaminated clothing before re
-use.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards to ensure
safe working conditions are maintained.
SUITABLE CONTAINER
- Polyethylene or polypropylene container.
- Packing as recommended by manufacturer.
- Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
None known.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
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Chemwatch Material Safety Data Sheet
Issue Date: 5-Jul-2007 CHEMWATCH 6616-63
NA317EC Version No:1
CD 2007/2 Page 4 of 9
Section 7 - HANDLING AND STORAGE
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁Peak ppm Peak mg/m鲁 TWA F/CC
_________ _________ _____ _____ _____ _____ _____ _____ _____
Australia hydrogen 1 1.4
Exposure peroxide
Standards (Hydrogen
peroxide)
The following materials had no OELs on our records
鈥? propylene glycol monobutyl ether: CAS:5131- 66- 8 CAS:15821- 83- 7
EMERGENCY EXPOSURE LIMITS
Material Revised IDLH Value (mg/m3) Revised IDLH Value (ppm)
hydrogen peroxide 75 [Unch]
MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
PROPYLENE GLYCOL MONOBUTYL ETHER:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no
-observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five
-category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
- cause inflammation
- cause increased susceptibility to other irritants and infectious agents
- lead to permanent injury or dysfunction
- permit greater absorption of hazardous substances and
- acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
HYDROGEN PEROXIDE:
NOTE: Detector tubes for hydrogen peroxide, measuring in excess of 0.1 ppm,
are available commercially.
Exposure at or below the TLV-TWA is thought to minimise irritation and
bleaching of hair.
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Chemwatch Material Safety Data Sheet
Issue Date: 5-Jul-2007 CHEMWATCH 6616-63
NA317EC Version No:1
CD 2007/2 Page 5 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTION
EYE
- Safety glasses with side shields
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Suitability and durability of glove type is dependent on usage. Factors such as:
- frequency and duration of contact,
- chemical resistance of glove material,
- glove thickness and
- dexterity,
are important in the selection of gloves.
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
OTHER
- Overalls.
- P.V.C. apron.
- Barrier cream.
- Skin cleansing cream.
- Eye wash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 AB- AUS P -
1000 50 - AB- AUS P
5000 50 Airline * -
5000 100 - AB- 2 P
10000 100 - AB- 3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas.
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Chemwatch Material Safety Data Sheet
Issue Date: 5-Jul-2007 CHEMWATCH 6616-63
NA317EC Version No:1
CD 2007/2 Page 6 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Cloudy liquid with a pleasant odour; soluble in water.
PHYSICAL PROPERTIES
Liquid.
Mixes with water.
Molecular Weight: Not Applicable Boiling Range (掳C): 100
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.0 +/- 0.2
Solubility in water (g/L): Miscible pH (as supplied): 7.1 to 7.7
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: same as water
Relative Vapour Density (air=1): Not Available Flash Point (掳C): Not Applicable
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: Liquid Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material has NOT been classified by EC Directives or other classification systems as
"harmful by ingestion". This is because of the lack of corroborating animal or human
evidence. The material may still be damaging to the health of the individual, following
ingestion, especially where pre-existing organ (e.g liver, kidney) damage is evident.
Present definitions of harmful or toxic substances are generally based on doses producing
mortality rather than those producing morbidity (disease, ill-health). Gastrointestinal
tract discomfort may produce nausea and vomiting. In an occupational setting however,
ingestion of insignificant quantities is not thought to be cause for concern.
EYE
Although the liquid is not thought to be an irritant (as classified by EC Directives),
direct contact with the eye may produce transient discomfort characterised by tearing or
conjunctival redness (as with windburn).
SKIN
The material is not thought to produce adverse health effects or skin irritation
following contact (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
gloves be used in an occupational setting.
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Chemwatch Material Safety Data Sheet
Issue Date: 5-Jul-2007 CHEMWATCH 6616-63
NA317EC Version No:1
CD 2007/2 Page 7 of 9
Section 11 - TOXICOLOGICAL INFORMATION
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
INHALED
The material is not thought to produce adverse health effects or irritation of the
respiratory tract (as classified by EC Directives using animal models). Nevertheless,
good hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
Not normally a hazard due to non-volatile nature of product.
CHRONIC HEALTH EFFECTS
Long-term exposure to the product is not thought to produce chronic effects adverse to
health (as classified by EC Directives using animal models); nevertheless exposure by all
routes should be minimised as a matter of course.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
PROPYLENE GLYCOL MONOBUTYL ETHER:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
TOXICITY IRRITATION.
TOXICITY IRRITATION
Dermal (rabbit) LD50: 3100 mg/kg Nil Reported
Oral (rat) LD50: 2830 uL/kg Skin (rabbit): 500 mg Open Mild
Inhalation (rat) LC50: >1000 ppm/8h Eye (rabbit): 15 mg SEVERE
Dermal (rat) LD50: 3560 uL/kg
as mixed isomers CAS RN 63716-40-5
HYDROGEN PEROXIDE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances
TOXICITY IRRITATION.
TOXICITY IRRITATION
Dermal (rabbit) LD50: 4060 mg/kg Nil Reported
Dermal (rabbit) LDLo: 500 mg/kg
Inhalation (mouse) LC50: 2000 mg/kg/4h
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
________________________ ____________________ ________________ ________________ ___________
hydrogen peroxide IARC:3
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: hydrogen peroxide
Category: 3
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
PROPYLENE GLYCOL MONOBUTYL ETHER:
DO NOT discharge into sewer or waterways.
HYDROGEN PEROXIDE:
log Kow: -1.36
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Chemwatch Material Safety Data Sheet
Issue Date: 5-Jul-2007 CHEMWATCH 6616-63
NA317EC Version No:1
CD 2007/2 Page 8 of 9
Section 12 - ECOLOGICAL INFORMATION
Fish LC50 (96 h): catfish 37.4 mg/l
Section 13 - DISPOSAL CONSIDERATIONS
Legislation addressing waste disposal requirements may differ by country, state and/ or
territory. Each user must refer to laws operating in their area. In some areas, certain
wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
- Reduction,
- Reuse
- Recycling
- Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make
it unsuitable for its intended use. If it has been contaminated, it may be possible to
reclaim the product by filtration, distillation or some other means. Shelf life
considerations should also be applied in making decisions of this type. Note that
properties of a material may change in use, and recycling or reuse may not always be
appropriate.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these
should be considered first. Where in doubt contact the responsible authority.
- Recycle wherever possible.
- Consult manufacturer for recycling options or consult local or regional waste
management authority for disposal if no suitable treatment or disposal facility can be
identified.
- Dispose of by: Burial in a licenced land-fill or incineration in a licenced apparatus
(after admixture with suitable combustible material).
- Decontaminate empty containers. Observe all label safeguards until containers are
cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
propylene glycol monobutyl ether (CAS: 5131-66-8) is found on the following regulatory
lists;
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
hydrogen peroxide (CAS: 7722-84-1) is found on the following regulatory lists;
Australia Dangerous Goods Code Draft 7th Edition - Goods too Dangerous to be Transported
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
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Chemwatch Material Safety Data Sheet
Issue Date: 5-Jul-2007 CHEMWATCH 6616-63
NA317EC Version No:1
CD 2007/2 Page 9 of 9
Section 15 - REGULATORY INFORMATION
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
Australia Therapeutic Goods Administration (TGA) Substances that may be used as active
ingredients in Listed medicines
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
International Air Transport Association (IATA) Dangerous Goods Regulations
OECD Representative List of High Production Volume (HPV) Chemicals
No data available for propylene glycol monobutyl ether as CAS: 15821-83-7.
Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
propylene glycol monobutyl ether 5131- 66- 8, 15821- 83- 7
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 5-Jul-2007
Print Date: 5-Jul-2007
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