MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 1 of 14
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
SYNONYMS
"Manufacturer's Code: G13508"
PRODUCT USE
Polishing agent/burnishing compound.
SUPPLIER
Company: MotorActive
Address:
35 Slough Business Park
Holker St, Silverwater
NSW, 2128
AUS
Telephone: +61 2 9737 9422
Telephone: 1800 347 570
Fax: +61 2 9737 9414
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.
COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.
POISONS SCHEDULE
None
RISK SAFETY
HARMFUL- May cause lung damage if Do not breathe gas/fumes/vapour/spray.
swallowed.
Repeated exposure may cause skin Avoid contact with eyes.
dryness and cracking.
Vapours may cause drowsiness and Wear suitable protective clothing.
dizziness.
Use only in well ventilated areas.
Keep container in a well ventilated place.
To clean the floor and all objects contaminated by
this material use water and detergent.
Keep container tightly closed.
Keep away from food drink and animal feeding stuffs.
Take off immediately all contaminated clothing.
In case of contact with eyes rinse with plenty of
water and contact Doctor or Poisons Information
Centre.
If swallowed IMMEDIATELY contact Doctor or Poisons
Information Centre. (show this container or label).
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 2 of 14
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
distillates, petroleum, light, acid- treated 64742-14-9. 10-20
kaolin 1332-58-7 2-5
distillates, petroleum, middle, hydrotreated 64742-46-7. 1-5
calcined flint clay 66402-68-4 5-10
aluminium oxide 1344-28-1. 10-15
Section 4 - FIRST AID MEASURES
SWALLOWED
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Seek medical advice.
Avoid giving milk or oils.
Avoid giving alcohol.
路 If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower
than their hips to help avoid possible aspiration of vomitus.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin or hair contact occurs:
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Any material aspirated during vomiting may produce lung injury. Therefore emesis should
not be induced mechanically or pharmacologically. Mechanical means should be used if it
is considered necessary to evacuate the stomach contents; these include gastric lavage
after endotracheal intubation. If spontaneous vomiting has occurred after ingestion, the
patient should be monitored for difficult breathing, as adverse effects of aspiration
into the lungs may be delayed up to 48 hours.
For acute or short term repeated exposures to petroleum distillates or related
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 3 of 14
Section 4 - FIRST AID MEASURES
hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is
respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis,
tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with
inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
路 Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported; intravenous lines
and cardiac monitors should be established in obviously symptomatic patients. The lungs
excrete inhaled solvents, so that hyperventilation improves clearance.
路 A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
路 Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of
potential myocardial sensitisation to catecholamines. Inhaled cardioselective
bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
路 Lavage is indicated in patients who require decontamination; ensure use of cuffed
endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
路 Water spray or fog - Large fires only.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear full body protective clothing with breathing apparatus.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 Avoid spraying water onto liquid pools.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
路 Combustible.
路 Slight fire hazard when exposed to heat or flame.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
路 May emit acrid smoke.
路 Mists containing combustible materials may be explosive.
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of
burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
路 Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
HAZCHEM: None
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 4 of 14
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
路 Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Chemical Class: aliphatic hydrocarbons
For release onto land: recommended sorbents listed in order of priority.
SORBENT TYPE RANK APPLICATION COLLECTION LIMITATIONS
LAND SPILL - SMALL
cross- linked 1 shovel shovel R, W, SS
polymer -
particulate
cross- linked 1 throw pitchfork R, DGC, RT
polymer - pillow
wood fiber - 2 throw pitchfork R, P, DGC, RT
pillow
treated wood 2 throw pitchfork DGC, RT
fibre- pillow
sorbent clay - 3 shovel shovel R, I, P
particulate
foamed glass - 3 throw pitchfork R, P, DGC, RT
pillow
LAND SPILL - MEDIUM
cross- linked 1 blower skiploader R, W, SS
polymer -
particulate
cross- linked 2 throw skiploader R, DGC, RT
polymer - pillow
sorbent clay - 3 blower skiploader R, I, P
particulate
polypropylene - 3 blower skiploader W, SS, DGC
particulate
expanded mineral 4 blower skiploader R, I, W, P, DGC
- particulate
polypropylene - 4 throw skiploader DGC, RT
mat
Legend
DGC: Not effective where ground cover is dense
R; Not reusable
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 5 of 14
Section 6 - ACCIDENTAL RELEASE MEASURES
I: Not incinerable
P: Effectiveness reduced when rainy
RT:Not effective where terrain is rugged
SS: Not for use within environmentally sensitive sites
W: Effectiveness reduced when windy
Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control;
R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988.
Moderate hazard.
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 Containers, even those that have been emptied, may contain explosive vapours.
路 Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
路 Electrostatic discharge may be generated during pumping - this may result in fire.
路 Ensure electrical continuity by bonding and grounding (earthing) all equipment.
路 Restrict line velocity during pumping in order to avoid generation of electrostatic
discharge (<=1 m/sec until fill pipe submerged to twice its diameter, then <= 7 m/sec).
路 Avoid splash filling.
路 Do NOT use compressed air for filling discharging or handling operations.
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to
ensure safe working conditions.
SUITABLE CONTAINER
路 Metal can or drum
路 Packaging as recommended by manufacturer.
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 6 of 14
Section 7 - HANDLING AND STORAGE
路 Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
路 Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 No smoking, naked lights or ignition sources.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA mg/m鲁
__________________ __________________ _______
Australia Exposure Standards kaolin (Kaolin (a)) 10
Australia Exposure Standards calcined flint clay (Inspirable dust 10
(not otherwise classified))
Australia Exposure Standards aluminium oxide (Aluminium oxide (a)) 10
The following materials had no OELs on our records
鈥? distillates, petroleum, light, acid- treated: CAS:64742- 14- 9
鈥? distillates, petroleum, middle, hydrotreated: CAS:64742- 46- 7
MATERIAL DATA
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-
observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-
category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
Because the margin of safety of the quartz TLV is not known with certainty and given the
associated link between silicosis and lung cancer it is recommended that quartz
concentrations be maintained as far below the TLV as prudent practices will allow.
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 7 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
INGREDIENT DATA
DISTILLATES, PETROLEUM, LIGHT, ACID-TREATED:
REL TWA: 300 ppm [Manufacturer]
KAOLIN:
Kaolin dust appears to have fibrogenic potential even in the absence of
crystalline silica. Kaolinosis can exist as simple and complicated forms
with the latter often associated with respiratory symptoms. Crystalline
silica enhances the severity of the pneumoconiosis.
DISTILLATES, PETROLEUM, MIDDLE, HYDROTREATED:
ES TWA: 5 mg/m3 refined mineral oil mist
Human exposure to oil mist alone has not been demonstrated to cause health effects
except at levels above 5 mg/m3 (this applies to particulates sampled by a method that
does not collect vapour). It is not advisable to apply this standard to oils containing
unknown concentrations and types of additive.
ALUMINIUM OXIDE:
The experimental and clinical data indicate that aluminium oxide acts as an
"inert" material when inhaled and seems to have little effect on the lungs
nor does it produce significant organic disease or toxic effects when
exposures are kept under reasonable control.
[Documentation of the Threshold Limit Values], ACGIH, Sixth Edition
PERSONAL PROTECTION
EYE
路 Safety glasses with side shields.
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Suitability and durability of glove type is dependent on usage. Factors such as:
路 frequency and duration of contact,
路 chemical resistance of glove material,
路 glove thickness and
路 dexterity,
are important in the selection of gloves.
路 Wear chemical protective gloves, eg. PVC.
路 Wear safety footwear or safety gumboots, eg. Rubber.
OTHER
路 Overalls.
路 P.V.C. apron.
路 Barrier cream.
路 Skin cleansing cream.
路 Eye wash unit.
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 8 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 A- AUS P -
1000 50 - A- AUS P
5000 50 Airline * -
5000 100 - A- 2 P
10000 100 - A- 3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear approved
respirator. Correct fit is essential to obtain adequate protection. Supplied-air type
respirator may be required in special circumstances. Correct fit is essential to ensure
adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some situations.
Provide adequate ventilation in warehouse or closed storage area. Air contaminants
generated in the workplace possess varying "escape" velocities which, in turn, determine
the "capture velocities" of fresh circulating air required to effectively remove the
contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25- 0.5 m/s (50- 100 f/min.)
evaporating from tank (in still air).
aerosols, fumes from pouring operations, 0.5- 1 m/s (100- 200 f/min.)
intermittent container filling, low speed
conveyer transfers, welding, spray drift,
plating acid fumes, pickling (released at
low velocity into zone of active generation)
direct spray, spray painting in shallow 1- 2.5 m/s (200- 500 f/min.)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air motion)
grinding, abrasive blasting, tumbling, high 2.5- 10 m/s (500- 2000 f/min.)
speed wheel generated dusts (released at
high initial velocity into zone of very high
rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or favourable 1: Disturbing room air currents
to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood- local control only
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 9 of 14
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Simple theory shows that air velocity falls rapidly with distance away from the opening
of a simple extraction pipe. Velocity generally decreases with the square of distance
from the extraction point (in simple cases). Therefore the air speed at the extraction
point should be adjusted, accordingly, after reference to distance from the contaminating
source. The air velocity at the extraction fan, for example, should be a minimum of 1-2
m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from
the extraction point. Other mechanical considerations, producing performance deficits
within the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Off-white liquid with a sweet odour; slightly soluble in water.
PHYSICAL PROPERTIES
Liquid.
Molecular Weight: Not Applicable Boiling Range (掳C): 193
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.04
Solubility in water (g/L): Partly Miscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Not Available
Volatile Component (%vol): 15 (VOC) Evaporation Rate: <1
Relative Vapour Density (air=1): >1 Flash Point (掳C): 93
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳C): Not Available Decomposition Temp (掳C): Not Available
State: Liquid Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Swallowing of the liquid may cause aspiration of vomit into the lungs with the risk of
haemorrhaging, pulmonary oedema, progressing to chemical pneumonitis; serious
consequences may result.
Signs and symptoms of chemical (aspiration) pneumonitis may include coughing, gasping,
choking, burning of the mouth, difficult breathing, and bluish coloured skin (cyanosis).
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion of petroleum hydrocarbons may produce irritation of the pharynx, oesophagus,
stomach and small intestine with oedema and mucosal ulceration resulting; symptoms
include a burning sensation in the mouth and throat. Large amounts may produce narcosis
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 10 of 14
Section 11 - TOXICOLOGICAL INFORMATION
with nausea and vomiting, weakness or dizziness, slow and shallow respiration, swelling
of the abdomen, unconsciousness and convulsions. Myocardial injury may produce
arrhythmias, ventricular fibrillation and electrocardiographic changes. Central nervous
system depression may also occur. Light aromatic hydrocarbons produce a warm, sharp,
tingling sensation on contact with taste buds and may anaesthetise the tongue. Aspiration
into the lungs may produce coughing, gagging and a chemical pneumonitis with pulmonary
oedema and haemorrhage.
EYE
Limited evidence exists, or practical experience suggests, that the material may cause
eye irritation in a substantial number of individuals and/or is expected to produce
significant ocular lesions which are present twenty-four hours or more after instillation
into the eye(s) of experimental animals. Repeated or prolonged eye contact may cause
inflammation characterised by temporary redness (similar to windburn) of the conjunctiva
(conjunctivitis); temporary impairment of vision and/or other transient eye
damage/ulceration may occur.
Petroleum hydrocarbons may produce pain after direct contact with the eyes. Slight, but
transient disturbances of the corneal epithelium may also result. The aromatic fraction
may produce irritation and lachrymation.
SKIN
The liquid may be miscible with fats or oils and may degrease the skin, producing a skin
reaction described as non-allergic contact dermatitis. The material is unlikely to
produce an irritant dermatitis as described in EC Directives .
Repeated exposure may cause skin cracking, flaking or drying following normal handling
and use.
The material may accentuate any pre-existing dermatitis condition.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
INHALED
Inhalation of vapours may cause drowsiness and dizziness. This may be accompanied by
narcosis, reduced alertness, loss of reflexes, lack of coordination and vertigo.
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the
course of normal handling, may be damaging to the health of the individual.
Limited evidence or practical experience suggests that the material may produce
irritation of the respiratory system, in a significant number of individuals, following
inhalation. In contrast to most organs, the lung is able to respond to a chemical insult
by first removing or neutralising the irritant and then repairing the damage. The repair
process, which initially evolved to protect mammalian lungs from foreign matter and
antigens, may however, produce further lung damage resulting in the impairment of gas
exchange, the primary function of the lungs. Respiratory tract irritation often results
in an inflammatory response involving the recruitment and activation of many cell types,
mainly derived from the vascular system.
High inhaled concentrations of mixed hydrocarbons may produce narcosis characterised by
nausea, vomiting and lightheadedness. Inhalation of aerosols may produce severe pulmonary
oedema, pneumonitis and pulmonary haemorrhage. Inhalation of petroleum hydrocarbons
consisting substantially of low molecular weight species (typically C2-C12) may produce
irritation of mucous membranes, incoordination, giddiness, nausea, vertigo, confusion,
headache, appetite loss, drowsiness, tremors and anaesthetic stupor. Massive exposures
may produce central nervous system depression with sudden collapse and deep coma;
fatalities have been recorded. Irritation of the brain and/or apnoeic anoxia may produce
convulsions. Although recovery following overexposure is generally complete, cerebral
micro-haemorrhage of focal post-inflammatory scarring may produce epileptiform seizures
some months after the exposure. Pulmonary episodes may include chemical pneumonitis with
oedema and haemorrhage. The lighter hydrocarbons may produce kidney and neurotoxic
effects. Pulmonary irritancy increases with carbon chain length for paraffins and
olefins. Alkenes produce pulmonary oedema at high concentrations. Liquid paraffins may
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 11 of 14
Section 11 - TOXICOLOGICAL INFORMATION
produce anaesthesia and depressant actions leading to weakness, dizziness, slow and
shallow respiration, unconsciousness, convulsions and death. C5-7 paraffins may also
produce polyneuropathy. Aromatic hydrocarbons accumulate in lipid rich tissues (typically
the brain, spinal cord and peripheral nerves) and may produce functional impairment
manifested by nonspecific symptoms such as nausea, weakness, fatigue and vertigo; severe
exposures may produce inebriation or unconsciousness. Many of the petroleum hydrocarbons
are cardiac sensitisers and may cause ventricular fibrillations.
Central nervous system (CNS) depression may include nonspecific discomfort, symptoms of
giddiness, headache, dizziness, nausea, anaesthetic effects, slowed reaction time,
slurred speech and may progress to unconsciousness. Serious poisonings may result in
respiratory depression and may be fatal.
Acute effects from inhalation of high concentrations of vapour are pulmonary irritation,
including coughing, with nausea; central nervous system depression - characterised by
headache and dizziness, increased reaction time, fatigue and loss of co-ordination.
CHRONIC HEALTH EFFECTS
Prolonged or repeated skin contact may cause drying with cracking, irritation and
possible dermatitis following.
Limited evidence suggests that repeated or long-term occupational exposure may produce
cumulative health effects involving organs or biochemical systems.
Repeated or prolonged exposure to mixed hydrocarbons may produce narcosis with dizziness,
weakness, irritability, concentration and/or memory loss, tremor in the fingers and
tongue, vertigo, olfactory disorders, constriction of visual field, paraesthesias of the
extremities, weight loss and anaemia and degenerative changes in the liver and kidney.
Chronic exposure by petroleum workers, to the lighter hydrocarbons, has been associated
with visual disturbances, damage to the central nervous system, peripheral neuropathies
(including numbness and paraesthesias), psychological and neurophysiological deficits,
bone marrow toxicities (including hypoplasia possibly due to benzene) and hepatic and
renal involvement. Chronic dermal exposure to petroleum hydrocarbons may result in
defatting which produces localised dermatoses. Surface cracking and erosion may also
increase susceptibility to infection by microorganisms. One epidemiological study of
petroleum refinery workers has reported elevations in standard mortality ratios for skin
cancer along with a dose-response relationship indicating an association between routine
workplace exposure to petroleum or one of its constituents and skin cancer, particularly
melanoma. Other studies have been unable to confirm this finding.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
DISTILLATES, PETROLEUM, LIGHT, ACID-TREATED:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
No data of toxicological significance identified in literature search.
KAOLIN:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
No significant acute toxicological data identified in literature search.
DISTILLATES, PETROLEUM, MIDDLE, HYDROTREATED:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
typical for isoparaffinic hydrocarbons:
Inhalation (rat) LC50: 3400 ppm/4H None reported [EXXON]
isoparaffinic hydrocarbon:
Oral (rat) LD50 : >8000 mg/kg
Dermal (rat) LD50: >4000 mg/kg
[CCINFO-Shell]
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 12 of 14
Section 11 - TOXICOLOGICAL INFORMATION
CALCINED FLINT CLAY:
~OTHER
No data of toxicological significance identified in literature search.
ALUMINIUM OXIDE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
No significant acute toxicological data identified in literature search.
Section 12 - ECOLOGICAL INFORMATION
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
Legislation addressing waste disposal requirements may differ by country, state and/ or
territory. Each user must refer to laws operating in their area. In some areas, certain
wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
路 Reduction,
路 Reuse
路 Recycling
路 Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make
it unsuitable for its intended use. If it has been contaminated, it may be possible to
reclaim the product by filtration, distillation or some other means. Shelf life
considerations should also be applied in making decisions of this type. Note that
properties of a material may change in use, and recycling or reuse may not always be
appropriate.
路 DO NOT allow wash water from cleaning or process equipment to enter drains.
路 It may be necessary to collect all wash water for treatment before disposal.
路 In all cases disposal to sewer may be subject to local laws and regulations and these
should be considered first.
路 Where in doubt contact the responsible authority.
路 Recycle wherever possible or consult manufacturer for recycling options.
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 13 of 14
Section 13 - DISPOSAL CONSIDERATIONS
路 Consult State Land Waste Authority for disposal.
路 Bury or incinerate residue at an approved site.
路 Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
Meguiar's G13508 - Hot Rims Mag & Aluminium Polish (CAS: None):
No regulations applicable
distillates, petroleum, light, acid-treated (CAS: 64742-14-9) is found on the following regulatory lists;
Australia Hazardous Substances
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
kaolin (CAS: 1332-58-7) is found on the following regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
IMO IBC Code Chapter 18: List of products to which the Code does not apply
OECD Representative List of High Production Volume (HPV) Chemicals
distillates, petroleum, middle, hydrotreated (CAS: 64742-46-7) is found on the following regulatory lists;
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
calcined flint clay (CAS: 66402-68-4) is found on the following regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 4
OECD Representative List of High Production Volume (HPV) Chemicals
aluminium oxide (CAS: 1344-28-1) is found on the following regulatory lists;
Australia Exposure Standards
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
IMO Provisioanl Categorization of Liquid Substances
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
continued...
MEGUIAR'S G13508 - HOT RIMS MAG & ALUMINIUM POLISH
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1958
NA317TC Version No:2.0
CD 2008/1 Page 14 of 14
Section 16 - OTHER INFORMATION
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk
Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Scale of use, frequency of use and current or available engineering controls must be
considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 18-Apr-2008
Print Date: 18-Apr-2008
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