MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 1 of 23
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
SYNONYMS
"Manufacturer's Code: G140"
PROPER SHIPPING NAME
CORROSIVE LIQUID, N.O.S.
(contains phosphoric acid)
PRODUCT USE
Wheel cleaner.
SUPPLIER
Company: MotorActive
Address:
35 Slough Business Park
Holker St, Silverwater
NSW, 2128
AUS
Telephone: +61 2 9737 9422
Telephone: 1800 347 570
Fax: +61 2 9737 9414
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC,
and the ADG Code.
POISONS SCHEDULE
S6
RISK SAFETY
Harmful if swallowed. Keep locked up.
Causes severe burns. Do not breathe gas/fumes/vapour/spray.
Risk of serious damage to eyes. In case of insufficient ventilation wear
suitable respiratory equipment.
Harmful to aquatic organisms may cause Use only in well ventilated areas.
long- term adverse effects in the
aquatic environment.
May cause long- term adverse effects in Keep container in a well ventilated place.
the environment.
May impair fertility. Avoid exposure - obtain special instructions
before use.
May cause harm to the unborn child. To clean the floor and all objects contaminated
by this material use water.
Keep container tightly closed.
This material and its container must be disposed
of in a safe way.
Keep away from food drink and animal feeding
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 2 of 23
Section 2 - HAZARDS IDENTIFICATION
stuffs.
Take off immediately all contaminated clothing.
In case of accident or if you feel unwell
IMMEDIATELY contact Doctor or Poisons
Information Centre (show label if possible).
This material and its container must be disposed
of as hazardous waste.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
phosphoric acid 7664-38-2 10-15
polyethylene glycol mono- p- nonylphenyl ether, branched 127087-87-0 2-8
glycolic acid 79-14-1 1-5
N, N- dimethyldecylamine N- oxide 2605-79-0 1-5
propylene glycol monobutyl ether 5131-66-8 1-3
ammonium bifluoride 1341-49-7 1-3
conditioner proprietary 1-3
water 7732-18-5 55-70
Section 4 - FIRST AID MEASURES
SWALLOWED
路 For advice, contact a Poisons Information Centre or a doctor at once.
路 Urgent hospital treatment is likely to be needed.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Transport to hospital or doctor without delay.
EYE
If this product comes in contact with the eyes:
路 Immediately hold eyelids apart and flush the eye continuously with running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 Continue flushing until advised to stop by the Poisons Information Centre or a doctor,
or for at least 15 minutes.
路 Transport to hospital or doctor without delay.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If there is evidence of severe skin irritation or skin burns:
路 Avoid further contact. Immediately remove contaminated clothing, including footwear.
路 Flush skin under running water for 15 minutes.
路 Avoiding contamination of the hands, massage calcium gluconate gel into affected areas,
pay particular attention to creases in skin.
路 Contact the Poisons Information Centre.
路 Continue gel application for at least 15 minutes after burning sensation ceases.
路 If pain recurs, repeat application of calcium gluconate gel or apply every 20 minutes.
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 3 of 23
Section 4 - FIRST AID MEASURES
路 If no gel is available, continue washing for at least 15 minutes, using soap if
available. If patient is conscious, give six calcium gluconate or calcium carbonate
tablets in water by mouth.
路 Transport to hospital, or doctor, urgently.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 Transport to hospital, or doctor, without delay.
For massive exposures:
路 If dusts, vapours, aerosols, fumes or combustion products are inhaled, remove from
contaminated area.
路 Lay patient down.
路 Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 If victim is conscious, give six calcium gluconate or calcium carbonate tablets in
water by mouth.
路 Transport to hospital, or doctor, urgently.
NOTES TO PHYSICIAN
Treat symptomatically.
For acute or short term repeated exposures to strong acids:
路 Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100%
oxygen initially.
路 Respiratory distress may require cricothyroidotomy if endotracheal intubation is
contraindicated by excessive swelling
路 Intravenous lines should be established immediately in all cases where there is
evidence of circulatory compromise.
路 Strong acids produce a coagulation necrosis characterised by formation of a coagulum
(eschar) as a result of the dessicating action of the acid on proteins in specific
tissues.
INGESTION:
路 Immediate dilution (milk or water) within 30 minutes post ingestion is recommended.
路 DO NOT attempt to neutralise the acid since exothermic reaction may extend the
corrosive injury.
路 Be careful to avoid further vomit since re-exposure of the mucosa to the acid is
harmful. Limit fluids to one or two glasses in an adult.
路 Charcoal has no place in acid management.
路 Some authors suggest the use of lavage within 1 hour of ingestion.
SKIN:
路 Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns
with non-adherent gauze and wrapping.
路 Deep second-degree burns may benefit from topical silver sulfadiazine.
EYE:
路 Eye injuries require retraction of the eyelids to ensure thorough irrigation of the
conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes. DO NOT use
neutralising agents or any other additives. Several litres of saline are required.
路 Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer
term use) antibiotic drops, vasoconstrictive agents or artificial tears may be indicated
dependent on the severity of the injury.
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 4 of 23
Section 4 - FIRST AID MEASURES
路 Steroid eye drops should only be administered with the approval of a consulting
ophthalmologist).
[Ellenhorn and Barceloux: Medical Toxicology].
Following acute or short term repeated exposure to hydrofluoric acid:
路 Subcutaneous injections of Calcium Gluconate may be necessary around the burnt area.
Continued application of Calcium Gluconate Gel or subcutaneous Calcium Gluconate should
then continue for 3-4 days at a frequency of 4-6 times per day. If a "burning" sensation
recurs, apply more frequently.
路 Systemic effects of extensive hydrofluoric acid burns include renal damage,
hypocalcaemia and consequent cardiac arrhythmias. Monitor haematological, respiratory,
renal, cardiac and electrolyte status at least daily. Tests should include FBE, blood
gases, chest X-ray, creatinine and electrolytes, urine output, Ca ions, Mg ions and
phosphate ions. Continuous ECG monitoring may be required.
路 Where serum calcium is low, or clinical, or ECG signs of hypocalcaemia develop,
infusions of calcium gluconate, or if less serious, oral Sandocal, should be given.
Hydrocortisone 500 mg in a four to six hourly infusion may help.
路 Antibiotics should not be given as a routine, but only when indicated.
路 Eye contact pain may be excruciating and 2-3 drops of 0.05% pentocaine hydrochloride
may be instilled, followed by further irrigation
BIOLOGICAL EXPOSURE INDEX - BEI
These represent the determinants observed in specimens collected from a healthy worker
exposed at the Exposure Standard (ES or TLV):
Determinant Index Sampling Time Comments
1. Methaemoglobin in 1.5% of haemoglobin During or end of shift B, NS, SQ
blood
B: Background levels occur in specimens collected from subjects NOT exposed.
NS: Non-specific determinant; Also seen after exposure to other materials
SQ: Semi-quantitative determinant - Interpretation may be ambiguous; should be used as a
screening test or confirmatory test.
Hydrofluoric acid is produced by reaction in the product.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
The product contains a substantial proportion of water, therefore there are no
restrictions on the type of extinguishing media which may be used. Choice of
extinguishing media should take into account surrounding areas.
Though the material is non-combustible, evaporation of water from the mixture, caused by
the heat of nearby fire, may produce floating layers of combustible substances.
In such an event consider:
路 foam.
路 dry chemical powder.
路 carbon dioxide.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear full body protective clothing with breathing apparatus.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Use fire fighting procedures suitable for surrounding area.
路 Do not approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
路 Equipment should be thoroughly decontaminated after use.
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 5 of 23
Section 5 - FIRE FIGHTING MEASURES
FIRE/EXPLOSION HAZARD
The emulsion is not combustible under normal conditions. However, it will break down
under fire conditions and the hydrocarbon component will burn.
路 Non combustible.
路 Not considered to be a significant fire risk.
路 Acids may react with metals to produce hydrogen, a highly flammable and explosive gas.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 May emit corrosive, poisonous fumes. May emit acrid smoke., carbon dioxide (CO2),
phosphorus oxides (POx), other pyrolysis products typical of burning organic
material.
Decomposition may produce toxic fumes of:
FIRE INCOMPATIBILITY
None known.
HAZCHEM: 2X
Personal Protective Equipment
Gas tight chemical resistant suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Environmental hazard - contain spillage.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
路 Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Environmental hazard - contain spillage.
Chemical Class:acidic compounds, organic
For release onto land: recommended sorbents listed in order of priority.
SORBENT TYPE RANK APPLICATION COLLECTION LIMITATIONS
LAND SPILL - SMALL
wood fiber - 1 throw pitchfork R, P, DGC, RT
pillow
cross- linked 1 shovel shovel R, W, SS
polymer -
particulate
cross- linked 1 throw pitchfork R, DGC, RT
polymer - pillow
sorbent clay - 2 shovel shovel R, I, P
particulate
foamed glass - 2 throw pitchfork R, P, DGC, RT
pillow
wood fiber - 3 shovel shovel R, W, P, DGC
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 6 of 23
Section 6 - ACCIDENTAL RELEASE MEASURES
particulate
LAND SPILL - MEDIUM
cross- linked 1 blower skiploader R, W, SS
polymer -
particulate
polypropylene - 2 blower skiploader W, SS, DGC
particulate
sorbent clay - 2 blower skiploader R, I, P
particulate
cross- linked 3 throw skiploader R, DGC, RT
polymer - pillow
polypropylene - 3 throw skiploader W, SS, DGC
mat
expanded mineral 3 blower skiploader R, I, W, P, DGC
- particulate
Legend
DGC: Not effective where ground cover is dense
R; Not reusable
I: Not incinerable
P: Effectiveness reduced when rainy
RT:Not effective where terrain is rugged
SS: Not for use within environmentally sensitive sites
W: Effectiveness reduced when windy
Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control;
R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988.
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear full body protective clothing with breathing apparatus.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Consider evacuation (or protect in place).
路 Stop leak if safe to do so.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Neutralise/decontaminate residue.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 After clean up operations, decontaminate and launder all protective clothing and
equipment before storing and re-using.
路 If contamination of drains or waterways occurs, advise emergency services.
PROTECTIVE ACTIONS FOR SPILL
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 7 of 23
Section 6 - ACCIDENTAL RELEASE MEASURES
PROTECTIVE ACTION ZONE
half
evacuation
downwind
direction
distance
down wind distance
wind isolation
distance
direction
half
evacuation downwind
INITIAL direction distance
ISOLATION
ZONE
From IERG (Canada/Australia)
Isolation Distance 25 metres
Downwind Protection Distance 250 metres
IERG Number 37
FOOTNOTES
1 PROTECTIVE ACTION ZONE is defined as the area in which people are at risk of harmful exposure. This zone
assumes that random changes in wind direction confines the vapour plume to an area within 30 degrees on
either side of the predominant wind direction, resulting in a crosswind protective action distance equal
to the downwind protective action distance.
2 PROTECTIVE ACTIONS should be initiated to the extent possible, beginning with those closest to the spill
and working away from the site in the downwind direction. Within the protective action zone a level of
vapour concentration may exist resulting in nearly all unprotected persons becoming incapacitated and
unable to take protective action and/or incurring serious or irreversible health effects.
3 INITIAL ISOLATION ZONE is determined as an area, including upwind of the incident, within which a high
probability of localised wind reversal may expose nearly all persons without appropriate protection to
life-threatening concentrations of the material.
4 SMALL SPILLS involve a leaking package of 200 litres (55 US gallons) or less, such as a drum (jerrican or
box with inner containers). Larger packages leaking less than 200 litres and compressed gas leaking from
a small cylinder are also considered "small spills".
LARGE SPILLS involve many small leaking packages or a leaking package of greater than 200 litres, such as
a cargo tank, portable tank or a "one-tonne" compressed gas cylinder.
5 Guide 154 is taken from the US DOT emergency response guide book.
6 IERG information is derived from CANUTEC - Transport Canada.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 DO NOT allow clothing wet with material to stay in contact with skin.
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to
material.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 8 of 23
Section 7 - HANDLING AND STORAGE
路 Work clothes should be laundered separately. Launder contaminated clothing before re-
use.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to
ensure safe working conditions are maintained.
SUITABLE CONTAINER
路 DO NOT use aluminium or galvanised containers.
路 Check regularly for spills and leaks.
路 Lined metal can, lined metal pail/ can.
路 Plastic pail.
路 Polyliner drum.
路 Packing as recommended by manufacturer.
路 Check all containers are clearly labelled and free from leaks.
For low viscosity materials
路 Drums and jerricans must be of the non-removable head type.
路 Where a can is to be used as an inner package, the can must have a screwed enclosure.
For materials with a viscosity of at least 2680 cSt. (23 deg. C) and solids (between 15 C
deg. and 40 deg C.):
路 Removable head packaging;
路 Cans with friction closures and
路 low pressure tubes and cartridges
may be used.
-
Where combination packages are used, and the inner packages are of glass, porcelain or
stoneware, there must be sufficient inert cushioning material in contact with inner and
outer packages unless the outer packaging is a close fitting moulded plastic box and the
substances are not incompatible with the plastic.
STORAGE INCOMPATIBILITY
路 Reacts vigorously with alkalis.
路 Reacts with mild steel, galvanised steel / zinc producing hydrogen gas which may form
an explosive mixture with air.
路 Phosphates are incompatible with oxidising and reducing agents.
路 Phosphates are susceptible to formation of highly toxic and flammable phosphine gas in
the presence of strong reducing agents such as hydrides.
路 Partial oxidation of phosphates by oxidizing agents may result in the release of toxic
phosphorus oxides.
路 Avoid strong bases.
路 Segregate from alkalies, oxidising agents and chemicals readily decomposed by acids,
i.e. cyanides, sulfides, carbonates.
STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA mg/m鲁 STEL mg/m鲁
__________________ __________________ _______ _______
Australia Exposure Standards phosphoric acid (Phosphoric 1 3
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 9 of 23
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Source Material TWA mg/m鲁 STEL mg/m鲁
__________________ __________________ _______ _______
acid)
Australia Exposure Standards ammonium bifluoride (Fluorides 2.5
(as F))
The following materials had no OELs on our records
鈥? polyethylene glycol mono- p- nonylphenyl ether, CAS:127087- 87- 0
branched:
鈥? glycolic acid: CAS:79- 14- 1
鈥? N, N- dimethyldecylamine N- oxide: CAS:2605- 79- 0
鈥? propylene glycol monobutyl ether: CAS:5131- 66- 8 CAS:15821- 83- 7
鈥? water: CAS:7732- 18- 5
EMERGENCY EXPOSURE LIMITS
Material Original IDLH Value (mg/m3) Revised IDLH Value (mg/m3)
Revised IDLH Value (ppm) 10, 000
1, 000 ammonium bifluoride
500
MATERIAL DATA
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-
observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-
category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
INGREDIENT DATA
GLYCOLIC ACID:
N,N-DIMETHYLDECYLAMINE N-OXIDE:
POLYETHYLENE GLYCOL MONO-P-NONYLPHENYL ETHER, BRANCHED:
WATER:
No exposure limits set by NOHSC or ACGIH.
PHOSPHORIC ACID:
PROPYLENE GLYCOL MONOBUTYL ETHER:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 10 of 23
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-
observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-
category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
PHOSPHORIC ACID:
The saturated vapour concentration of phosphoric acid exceeds the TLV.
The TLV-TWA is based by analogy from comparable experience and data for
sulfuric acid. Exposure at or below this limit is thought to prevent
throat irritation amongst unacclimatised workers.
Fumes of phosphorus pentoxide at concentrations between 0.8 and 5.4 mg/m3
were reported to be noticeable but not uncomfortable whilst concentrations
between 3.6 and 11.3 mg/m3 produced coughing in unacclimatised workers but
were tolerable. Concentrations of 100 mg/m3 were unbearable except in
inured workers.
GLYCOLIC ACID:
CEL TWA: 10 mg/m3
AMMONIUM BIFLUORIDE:
Based on a study in which the threshold for minimum increase in bone density due to
fluoride exposure was 3.38 mg/m3 (as fluoride), the present TLV-TWA has been adopted to
prevent irritant effects and disabling bone changes. There is also support for the
proposition that occupational exposure below the TLV will have no adverse effect on
pregnant women or off-spring. IARC has classified fluorides in drinking water as Group 3
carcinogens; i.e. Not classifiable as to its carcinogenicity to humans. Equivocal
evidence of carcinogenic activity (osteosarcoma) has been found in male rats administered
sodium fluoride in drinking water. (0-175 ppm) Evidence was not found in female rats or
in male or female mice.
PERSONAL PROTECTION
EYE
路 Chemical goggles.
路 Full face shield may be required for supplementary but never for primary protection of
eyes
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 11 of 23
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
路 Elbow length PVC gloves.
路 When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid
spills entering boots.
Suitability and durability of glove type is dependent on usage. Factors such as:
路 frequency and duration of contact,
路 chemical resistance of glove material,
路 glove thickness and
路 dexterity,
are important in the selection of gloves.
OTHER
路 Overalls.
路 PVC Apron.
路 PVC protective suit may be required if exposure severe.
路 Eyewash unit.
路 Ensure there is ready access to a safety shower.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of breathing
zone contaminant and the chemical nature of the contaminant. Protection Factors (defined
as the ratio of contaminant outside and inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 AB- AUS P -
1000 50 - AB- AUS P
5000 50 Airline * -
5000 100 - AB- 2 P
10000 100 - AB- 3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear approved
respirator. Correct fit is essential to obtain adequate protection. Supplied-air type
respirator may be required in special circumstances. Correct fit is essential to ensure
adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some situations.
Provide adequate ventilation in warehouse or closed storage area. Air contaminants
generated in the workplace possess varying "escape" velocities which, in turn, determine
the "capture velocities" of fresh circulating air required to effectively remove the
contaminant.
Type of Contaminant: Air Speed:
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 12 of 23
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
solvent, vapours, degreasing etc., 0.25- 0.5 m/s (50- 100 f/min.)
evaporating from tank (in still air).
aerosols, fumes from pouring operations, 0.5- 1 m/s (100- 200 f/min.)
intermittent container filling, low speed
conveyer transfers, welding, spray drift,
plating acid fumes, pickling (released at
low velocity into zone of active generation)
direct spray, spray painting in shallow 1- 2.5 m/s (200- 500 f/min.)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air motion)
grinding, abrasive blasting, tumbling, high 2.5- 10 m/s (500- 2000 f/min.)
speed wheel generated dusts (released at
high initial velocity into zone of very high
rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or favourable 1: Disturbing room air currents
to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood- local control only
Simple theory shows that air velocity falls rapidly with distance away from the opening
of a simple extraction pipe. Velocity generally decreases with the square of distance
from the extraction point (in simple cases). Therefore the air speed at the extraction
point should be adjusted, accordingly, after reference to distance from the contaminating
source. The air velocity at the extraction fan, for example, should be a minimum of 1-2
m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from
the extraction point. Other mechanical considerations, producing performance deficits
within the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Clear acidic liquid with a pleasant odour; soluble in water.
PHYSICAL PROPERTIES
Mixes with water.
Corrosive.
Acid.
Molecular Weight: Not Applicable Boiling Range (掳C): 100
Melting Range (掳C): Not Available Specific Gravity (water=1): 1.08
Solubility in water (g/L): Miscible pH (as supplied): 2.5
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): 2 (VOC) Evaporation Rate: same as water
Relative Vapour Density (air=1): same as Flash Point (掳C): Not Applicable
water
Lower Explosive Limit (%): Not Applicable Upper Explosive Limit (%): Not Applicable
Autoignition Temp (掳C): Not Applicable Decomposition Temp (掳C): Not Available
State: LIQUID Viscosity: Not Available
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 13 of 23
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
Contact with alkaline material liberates heat.
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be harmful; animal experiments indicate that
ingestion of less than 150 gram may be fatal or may produce serious damage to the health
of the individual.
Ingestion of acidic corrosives may produce circumoral burns with a distinct
discolouration of the mucous membranes of the mouth, throat and oesophagus. Immediate
pain and difficulties in swallowing and speaking may also be evident. Oedema of the
epiglottis may produce respiratory distress and possibly, asphyxia. Nausea, vomiting,
diarrhoea and a pronounced thirst may occur. More severe exposures may produce a vomitus
containing fresh or dark blood and large shreds of mucosa. Shock, with marked hypotension,
weak and rapid pulse, shallow respiration and clammy skin may be symptomatic of the
exposure. Circulatory collapse may, if left untreated, result in renal failure. Severe
cases may show gastric and oesophageal perforation with peritonitis, fever and abdominal
rigidity. Stricture of the oesophageal, gastric and pyloric sphincter may occur as within
several weeks or may be delayed for years. Death may be rapid and often results from
asphyxia, circulatory collapse or aspiration of even minute amounts. Delayed deaths may
be due to peritonitis, severe nephritis or pneumonia. Coma and convulsions may be
terminal.
EYE
When applied to the eye(s) of animals, the material produces severe ocular lesions which
are present twenty-four hours or more after instillation.
Direct eye contact with acid corrosives may produce pain, lachrymation, photophobia and
burns. Mild burns of the epithelia generally recover rapidly and completely. Severe burns
produce long-lasting and possible irreversible damage. The appearance of the burn may not
be apparent for several weeks after the initial contact. The cornea may ultimately become
deeply vascularised and opaque resulting in blindness.
SKIN
Skin contact with acidic corrosives may result in pain and burns; these may be deep with
distinct edges and may heal slowly with the formation of scar tissue.
Skin contact is not thought to produce harmful health effects (as classified under EC
Directives using animal models). Systemic harm, however, has been identified following
exposure of animals by at least one other route and the material may still produce health
damage following entry through wounds, lesions or abrasions. Good hygiene practice
requires that exposure be kept to a minimum and that suitable gloves be used in an
occupational setting.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 14 of 23
Section 11 - TOXICOLOGICAL INFORMATION
INHALED
Evidence shows, or practical experience predicts, that the material produces irritation
of the respiratory system, in a substantial number of individuals, following inhalation.
In contrast to most organs, the lung is able to respond to a chemical insult by first
removing or neutralising the irritant and then repairing the damage. The repair process,
which initially evolved to protect mammalian lungs from foreign matter and antigens, may
however, produce further lung damage resulting in the impairment of gas exchange, the
primary function of the lungs. Respiratory tract irritation often results in an
inflammatory response involving the recruitment and activation of many cell types, mainly
derived from the vascular system.
Acidic corrosives produce respiratory tract irritation with coughing, choking and mucous
membrane damage. Symptoms of exposure may include dizziness, headache, nausea and
weakness. In more severe exposures, pulmonary oedema may be evident either immediately or
after a latent period of 5-72 hours. Symptoms of pulmonary oedema include a tightness in
the chest, dyspnoea, frothy sputum and cyanosis. Examination may reveal hypotension, a
weak and rapid pulse and moist rates. Death, due to anoxia, may occur several hours after
onset of the pulmonary oedema.
Inhalation of vapours or aerosols (mists, fumes), generated by the material during the
course of normal handling, may be damaging to the health of the individual.
CHRONIC HEALTH EFFECTS
Repeated or prolonged exposure to acids may result in the erosion of teeth, inflammatory
and ulcerative changes in the mouth and necrosis (rarely) of the jaw. Bronchial
irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Gastrointestinal disturbances may also occur. Chronic exposures may result in dermatitis
and/or conjunctivitis.
Long-term exposure to respiratory irritants may result in disease of the airways
involving difficult breathing and related systemic problems.
There is sufficient evidence to provide a strong presumption that human exposure to the
material may result in impaired fertility on the basis of: - clear evidence in animal
studies of impaired fertility in the absence of toxic effects, or evidence of impaired
fertility occurring at around the same dose levels as other toxic effects but which is
not a secondary non-specific consequence of other toxic effects.
There is sufficient evidence to provide a strong presumption that human exposure to the
material may result in developmental toxicity, generally on the basis of:
- clear results in appropriate animal studies where effects have been observed in the
absence of marked maternal toxicity, or at around the same dose levels as other toxic
effects but which are not secondary non-specific consequences of the other toxic effects.
Limited evidence suggests that repeated or long-term occupational exposure may produce
cumulative health effects involving organs or biochemical systems.
Limited evidence shows that inhalation of the material is capable of inducing a
sensitisation reaction in a significant number of individuals at a greater frequency than
would be expected from the response of a normal population.
Pulmonary sensitisation, resulting in hyperactive airway dysfunction and pulmonary
allergy may be accompanied by fatigue, malaise and aching. Significant symptoms of
exposure may persist for extended periods, even after exposure ceases. Symptoms can be
activated by a variety of nonspecific environmental stimuli such as automobile exhaust,
perfumes and passive smoking.
TOXICITY AND IRRITATION
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
Asthma-like symptoms may continue for months or even years after exposure to the material
ceases. This may be due to a non-allergenic condition known as reactive airways
dysfunction syndrome (RADS) which can occur following exposure to high levels of highly
irritating compound. Key criteria for the diagnosis of RADS include the absence of
preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 15 of 23
Section 11 - TOXICOLOGICAL INFORMATION
irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to
severe bronchial hyperreactivity on methacholine challenge testing and the lack of
minimal lymphocytic inflammation, without eosinophilia, have also been included in the
criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an
infrequent disorder with rates related to the concentration of and duration of exposure
to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that
occurs as result of exposure due to high concentrations of irritating substance (often
particulate in nature) and is completely reversible after exposure ceases. The disorder
is characterised by dyspnea, cough and mucus production.
PHOSPHORIC ACID:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
Unreported (human) LDLo: 220 mg/kg Skin (rabbit):595 mg/24h - SEVERE
Oral (rat) LD50: 1530 mg/kg Eye (rabbit): 119 mg - SEVERE
Oral (rat) LD50: 3500 mg/kg* [Monsanto]*
Dermal (rabbit) LD50: >1260 mg/kg*
The material may produce severe irritation to the eye causing pronounced inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may produce severe skin irritation after prolonged or repeated exposure, and
may produce a contact dermatitis (nonallergic). This form of dermatitis is often
characterised by skin redness (erythema) thickening of the epidermis.
Histologically there may be intercellular oedema of the spongy layer (spongiosis) and
intracellular oedema of the epidermis. Prolonged contact is unlikely, given the severity
of response, but repeated exposures may produce severe ulceration.
Asthma-like symptoms may continue for months or even years after exposure to the material
ceases. This may be due to a non-allergenic condition known as reactive airways
dysfunction syndrome (RADS) which can occur following exposure to high levels of highly
irritating compound. Key criteria for the diagnosis of RADS include the absence of
preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to
severe bronchial hyperreactivity on methacholine challenge testing and the lack of
minimal lymphocytic inflammation, without eosinophilia, have also been included in the
criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an
infrequent disorder with rates related to the concentration of and duration of exposure
to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that
occurs as result of exposure due to high concentrations of irritating substance (often
particulate in nature) and is completely reversible after exposure ceases. The disorder
is characterised by dyspnea, cough and mucus production.
phosphoric acid ( 85%)
POLYETHYLENE GLYCOL MONO-P-NONYLPHENYL ETHER, BRANCHED:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
for linear material:
Oral (rat) LD50: 1310 mg/kg Eye (rabbit): SEVERE
Intraperitoneal (mouse) LD50: 150 mg/kg Skin (rabbit): Mild
Maternal effects, effects on fertility recorded.
GLYCOLIC ACID:
Not available. Refer to individual constituents.
N,N-DIMETHYLDECYLAMINE N-OXIDE:
No significant acute toxicological data identified in literature search.
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 16 of 23
Section 11 - TOXICOLOGICAL INFORMATION
PROPYLENE GLYCOL MONOBUTYL ETHER:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
Dermal (rabbit) LD50: 3100 mg/kg Nil Reported
Oral (rat) LD50: 2830 uL/kg Skin (rabbit): 500 mg Open Mild
Inhalation (rat) LC50: >1000 ppm/8h Eye (rabbit): 15 mg SEVERE
Dermal (rat) LD50: 3560 uL/kg
as mixed isomers CAS RN 63716-40-5
AMMONIUM BIFLUORIDE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
as fluoride anion
Oral (human) LDLo: 50 mg/kg Eye (-): corrosive*
Oral (human) TDLo: 3 mg/kg Skin (-): corrosive*
Inhalation (rat) LC50: 1276 ppm/1hr*
Inhalation (mouse) LC50: 342 ppm/1hr* *[Bayer]
WATER:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
No significant acute toxicological data identified in literature search.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
_______________ ____________ __________ __________ __________
ammonium IARC:3
bifluoride
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: ammonium
bifluoride Category: The substance is classified by IARC as Group 3: NOT classifiable
as to its carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or
limited in animal testing.
Section 12 - ECOLOGICAL INFORMATION
On the basis of available evidence concerning either toxicity, persistence, potential to
accumulate and or observed environmental fate and behaviour, the material may present a
danger, immediate or long-term and /or delayed, to the structure and/ or functioning of
natural ecosystems.
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
Although small amounts of fluorides are conceded to have beneficial effects, two forms of
chronic toxic effect, dental fluorosis and skeletal fluorosis may be caused by excessive
intake over long periods. Fluorides are absorbed by humans following inhalation of
workplace and ambient air that has been contaminated, ingestion of drinking water and
foods and dermal contact.
Both hydrogen fluoride and particulate fluorides will be transported in the atmosphere
and deposited on land or water by wet and dry deposition. Non-volatile inorganic fluoride
particulates are removed from the atmosphere via condensation or nucleation processes.
Fluorides adsorbed on particulate matter in the atmosphere are generally stable and are
not readily hydrolysed, although they may be degraded by radiation if they persist in the
atmosphere. Fluorine and the silicon fluorides (fluosilicates, silicofluorides) are
hydrolysed in the atmosphere to form hydrogen fluoride. Hydrogen fluoride may combine
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 17 of 23
Section 12 - ECOLOGICAL INFORMATION
with water vapour to produce an aerosol or fog of aqueous hydrofluoric acid. Based upon
available data, inorganic fluoride compounds, with the exception of sulfur hexafluoride,
are not expected to remain in the troposphere for long periods or to migrate to the
stratosphere. Estimates of the residence time of sulfur hexafluoride in the atmosphere
range from 500 to several thousand years. Fluoride in aerosols can be transported over
large distances by wind or as a result of atmospheric turbulence. The distance travelled
is determined by the deposition velocity of both the gaseous hydrogen fluoride and the
fluorides in particulate form. Atmospheric fluorides may be transported to soils and
surface waters through both wet and dry deposition processes.
Fluorides undergo transformations in soil and water, forming complexes and binding
strongly to soil and sediment.
In water, the transport and transformation of inorganic fluorides are influenced by pH,
water hardness and the presence of ion-exchange materials such as clays. In natural water,
fluoride forms strong complexes with aluminum in water, and fluorine chemistry in water
is largely regulated by aluminum concentration and pH. Below pH 5, fluoride is almost
entirely complexed with aluminum and consequently, the concentration of free F- is low.
As the pH increases, Al-OH complexes dominate over Al-F complexes and the free F- levels
increase. Fluoride forms stable complexes with calcium and magnesium, which are present
in sea water. Calcium carbonate precipitation dominates the removal of dissolved fluoride
from sea water. The residence time for fluoride in ocean sediment is calculated to be 2鈥?3
million years. Fluorosilicic acid and hydrofluoric acid in high aquatic concentrations
such as may be found in industrial waste ponds may volatilise, releasing silicon
tetrafluoride and hydrogen fluoride into the atmosphere.
Solubilisation of inorganic fluorides from minerals may also be enhanced by the presence
of ion-exchange materials (e.g., bentonite clays and humic acid). Once dissolved,
inorganic fluorides remain in solution under conditions of low pH and hardness and in the
presence of ion-exchange material. Soluble inorganic fluorides may also form aerosols at
the air鈥搘ater interface or vaporise into the atmosphere whereas undissolved species
generally undergo sedimentation.
Factors that influence the mobility of inorganic fluorides in soil are pH and the
formation of aluminium and calcium complexes In more acidic soils, concentrations of
inorganic fluoride were considerably higher in the deeper horizons. The low affinity of
fluorides for organic material results in leaching from the more acidic surface horizon
and increased retention by clay minerals and silts in the more alkaline, deeper horizons.
The maximum adsorption of fluoride to soil was reported to occur at pH 5.5. In acidic
soils with pH below 6, most of the fluoride is in complexes with either aluminium or
iron. Fluoride in alkaline soils at pH 6.5 and above is almost completely fixed in soils
as calcium fluoride, if sufficient calcium carbonate is available. Fluoride is extremely
immobile in soil, as determined by lysimeter experiments.
Populations living in areas with high fluoride levels in groundwater may be exposed to
higher levels of fluorides in their drinking water or in beverages prepared with the
water. Among these populations, outdoor laborers, people living in hot climates, and
people with polydipsia will generally have the greatest daily intake of fluorides because
they consume greater amounts of water.
Foods characteristically high in fluoride content are certain types of fish and seafood
(1.9鈥?28.5 mg/kg), especially those types in which the bones are consumed, bone products
such as bone meal and gelatin, and tea, which contains approximately 0.52 mg fluoride/cup
Fluoride is mainly absorbed by the body in the form of hydrogen fluoride, which has a
pKa of 3.45. That is, when ionic fluoride enters the acidic environment of the
stomach lumen, it is largely converted into hydrogen fluoride. Most of the fluoride that
is not absorbed from the stomach will be rapidly absorbed from the small intestine.
Fluorides have been shown to accumulate in animals that consume fluoride-containing
foliage However, accumulation is primarily in skeletal tissue and therefore, it is
unlikely that fluoride will biomagnify up the food chain.
.
Octanol/water partition coefficients cannot easily be determined for surfactants because
one part of the molecule is hydrophilic and the other part is hydrophobic. Consequently
they tend to accumulate at the interface and are not extracted into one or other of the
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 18 of 23
Section 12 - ECOLOGICAL INFORMATION
liquid phases. As a result surfactants are expected to transfer slowly, for example, from
water into the flesh of fish. During this process, readily biodegradable surfactants are
expected to be metabolised rapidly during the process of bioaccumulation. This was
emphasised by the OECD Expert Group stating that chemicals are not to be considered to
show bioaccumulation potential if they are readily biodegradable.
Several anionic and nonionic surfactants have been investigated to evaluate their
potential to bioconcentrate in fish. BCF values (BCF - bioconcentration factor) ranging
from 1 to 350 were found. These are absolute maximum values, resulting from the
radiolabelling technique used. In all these studies, substantial oxidative metabolism was
found resulting in the highest radioactivity in the gall bladder. This indicates liver
transformation of the parent compound and biliary excretion of the metabolised compounds,
so that "real" bioconcentration is overstated. After correction it can be expected that
"real" parent BCF values are one order of magnitude less than those indicated above, i.e.
"real" BCF is <100. Therefore the usual data used for classification by EU directives to
determine whether a substance is "Dangerous to the "Environment" has little bearing on
whether the use of the surfactant is environmentally acceptable.
The principal problems of phosphate contamination of the environment relates to
eutrophication processes in lakes and ponds. Phosphorus is an essential plant nutrient
and is usually the limiting nutrient for blue-green algae. A lake undergoing
eutrophication shows a rapid growth of algae in surface waters. Planktonic algae cause
turbidity and flotation films. Shore algae cause ugly muddying, films and damage to
reeds. Decay of these algae causes oxygen depletion in the deep water and shallow water
near the shore. The process is self-perpetuating because anoxic conditions at the
sediment/water interface causes the release of more adsorbed phosphates from the
sediment. The growth of algae produces undesirable effects on the treatment of water for
drinking purposes, on fisheries, and on the use of lakes for recreational purposes.
Prevent, by any means available, spillage from entering drains or water
courses.
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
PHOSPHORIC ACID:
Fish LC50 (96hr.) (mg/l): 138
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
On the basis of available evidence concerning either toxicity, persistence, potential to
accumulate and or observed environmental fate and behaviour, the material may present a
danger, immediate or long-term and /or delayed, to the structure and/ or functioning of
natural ecosystems.
Prevent, by any means available, spillage from entering drains or water
courses.
The principal problems of phosphate contamination of the environment relates to
eutrophication processes in lakes and ponds. Phosphorus is an essential plant nutrient
and is usually the limiting nutrient for blue-green algae. A lake undergoing
eutrophication shows a rapid growth of algae in surface waters. Planktonic algae cause
turbidity and flotation films. Shore algae cause ugly muddying, films and damage to
reeds. Decay of these algae causes oxygen depletion in the deep water and shallow water
near the shore. The process is self-perpetuating because anoxic conditions at the
sediment/water interface causes the release of more adsorbed phosphates from the
sediment. The growth of algae produces undesirable effects on the treatment of water for
drinking purposes, on fisheries, and on the use of lakes for recreational purposes.
DO NOT discharge into sewer or waterways.
POLYETHYLENE GLYCOL MONO-P-NONYLPHENYL ETHER, BRANCHED:
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 19 of 23
Section 12 - ECOLOGICAL INFORMATION
Aquatic toxicity (Daphnia magna) 48hr LC50: 21.4 ppm
Aquatic toxicity (fathead minnow) 96hr LC50: 6.6 ppm [Calgon]
Alcohol (alkyl) ethoxylates (AEs) are generally biodegradable and do not persist for any
substantial period in the environment. They are not usually present a concentrations
which might produce problems. Contamination of natural waters, however, should be avoided.
The biodegradability of the alcohol ethoxylates (AE) is relatively unaffected by the
alkyl carbon chain length and the number of EO units. The linear AE are normally easily
degraded under aerobic conditions. Only small differences are seen in the time needed for
ultimate degradation of linear AE with different alkyl chain lengths. AE with a typical
alkyl chain (e.g., C12 to C15) will normally reach more than 60%
degradation in standardized tests for "ready" biodegradability. The rate of
biodegradation may however be determined by the length of the ethylene oxide (EO) chain..
Longer EO chains decrease the bioavailability of the AE (to microorganism) due to
increased hydrophilicity and molecular size, which limits the transport of the molecule
through the cell wall. The biodegradation of branched AE tends to be slower than
biodegradation of linear AE. The biodegradability of AE depends on degree and structure
of the branching. The general trend is that the biodegradation decreases considerably
with an increasing branching of the carbon chain. The biodegradability of alcohol
alkoxylates (AA), similarly, generally decreases with an increasing number of PO units.
AA containing 6 PO units did not pass the level required for ready biodegradability
whereas the same alcohol containing 2 PO units attained 83% ThOD in the closed bottle test
The mineralization observed in experiments with14C-labelled surfactants
suggests that almost complete degradation of linear AE may be expected in anaerobic
digesters.
Algae constitute the group of aquatic organisms which appears to be the most sensitive to
AE. The acute toxicity of linear and branched AE to algae is in the same range with EC50
values from 0.05 to 50 mg/l. For the linear AE, the toxicity increases with increasing
hydrophobe chain length of C13 ) and decreasing EO chain length. The toxicity
of AE to algae tends to decrease with increasing degree of branching
The acute toxicity of AE to invertebrates varies with EC50 values from 0.1 mg/l to more
than 100 mg/l for the linear types and from 0.5 mg/l to 50 mg/l for the branched types.
The toxicity is species specific and may vary between 0.29 mg/l to 270 mg/l for the same
linear AE The most commonly used invertebrates for testing are Daphnia magna and Daphnia
pulex, and they are also among the most sensitive invertebrates to AE. Apparently, the
toxicity of AE to invertebrates was not related to hydrophobicity as it is the case for
algae. Some AE are very toxic to invertebrates, i.e., linear AE of C12-15EO1-
8 and branched AE with a low degree of branching, i.e. < 10-25%. Branching of the alkyl
chain reduces the toxicity of AE to invertebrates as also observed for algae.
The acute toxicity of AE to fish varies with LC50 values from 0.4 mg/l to more than 100
mg/l for the linear types and from 0.25 mg/l to 40 mg/l for the branched AE. For linear
AE the toxicity increases with decreasing EO units . AE containing 7-11 EO groups are
considered to be very toxic to fish (EC/LC50 £ 1 mg/l).
Of special interest are the aryl alcohol ethoxylates.
A EU Risk Assessment Report (RAR) concluded that octyl- and nonyl- phenol ethoxylates are
not readily biodegradable but are inherently biodegradable
As a group, these materials are generally toxic to fish with LC50s ranging, typically,
between 1-6 mg/l.
Of special concern are the following families which are classified as "Environmentally
Hazardous Substances" (Dangerous Goods Class 9) by either or both the ADR (Accord
Europeen Relatif au Transport International des Merchandises Dangerous par Route) and the
IMDG Code (International Maritime Dangerous Goods Code).
alcohols C 6-17 (secondary) with 3-6 moles of ethoxylation.
alcohols C12-15 with 1-3 moles of ethoxylation (1-6 moles of ethoxylation IMDG)
alcohols C13-15 with 1-6 moles of ethoxylation.
New aquatic data suggests that
alcohols C 8-9 branched with 3-10 moles of ethoxylation
alcohols C 8-9 branched with > 10 moles of ethoxylation should also be classified as
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 20 of 23
Section 12 - ECOLOGICAL INFORMATION
'harmful to the environment"
These alcohols may also be found linked to aromatic structures (in nonylphenol
ethoxylates for example). The current consensus determines that such entities become
Environmental Toxins by association.
GLYCOLIC ACID:
log Pow (Verschueren 1983): - 1.11
Prevent, by any means available, spillage from entering drains or water
courses.
DO NOT discharge into sewer or waterways.
Readily biodegradable.
After 7 days 89.65 is biodegraded (closed bottle test).
log Kow: -1.11
BOD 5 if unstated: 0.175
Aquatic toxicity: Slight
Fish LC50 (96h): fathead minnow 164 mg/l, bluegill sunfish 93 mg/l
N,N-DIMETHYLDECYLAMINE N-OXIDE:
Octanol/water partition coefficients cannot easily be determined for surfactants because
one part of the molecule is hydrophilic and the other part is hydrophobic. Consequently
they tend to accumulate at the interface and are not extracted into one or other of the
liquid phases. As a result surfactants are expected to transfer slowly, for example, from
water into the flesh of fish. During this process, readily biodegradable surfactants are
expected to be metabolised rapidly during the process of bioaccumulation. This was
emphasised by the OECD Expert Group stating that chemicals are not to be considered to
show bioaccumulation potential if they are readily biodegradable.
Several anionic and nonionic surfactants have been investigated to evaluate their
potential to bioconcentrate in fish. BCF values (BCF - bioconcentration factor) ranging
from 1 to 350 were found. These are absolute maximum values, resulting from the
radiolabelling technique used. In all these studies, substantial oxidative metabolism was
found resulting in the highest radioactivity in the gall bladder. This indicates liver
transformation of the parent compound and biliary excretion of the metabolised compounds,
so that "real" bioconcentration is overstated. After correction it can be expected that
"real" parent BCF values are one order of magnitude less than those indicated above, i.e.
"real" BCF is <100. Therefore the usual data used for classification by EU directives to
determine whether a substance is "Dangerous to the "Environment" has little bearing on
whether the use of the surfactant is environmentally acceptable.
PROPYLENE GLYCOL MONOBUTYL ETHER:
DO NOT discharge into sewer or waterways.
AMMONIUM BIFLUORIDE:
Fish toxicity:
Acute (Brachydanio rerio) LC0: 237 mg/l/96h (F Flakes)*
Bacterial toxicity:
Acute (activated sludge micro-organism) EC50: 2394 mg/l (B Flakes)*
Acute (activated sludge micro-organism) EC50: 4184 mg/l (F Flakes)*
Water pollution class (WGK): 1 - slightly hazardous to water* *[Bayer]
WGK: Classification in accordance with German Water Resources Act.
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 21 of 23
Section 13 - DISPOSAL CONSIDERATIONS
路 Containers may still present a chemical hazard/ danger when empty.
路 Return to supplier for reuse/ recycling if possible.
Otherwise:
路 If container can not be cleaned sufficiently well to ensure that residuals do not
remain or if the container cannot be used to store the same product, then puncture
containers, to prevent re-use, and bury at an authorised landfill.
路 Where possible retain label warnings and MSDS and observe all notices pertaining to the
product.
Legislation addressing waste disposal requirements may differ by country, state and/ or
territory. Each user must refer to laws operating in their area. In some areas, certain
wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
路 Reduction,
路 Reuse
路 Recycling
路 Disposal (if all else fails)
This material may be recycled if unused, or if it has not been contaminated so as to make
it unsuitable for its intended use. If it has been contaminated, it may be possible to
reclaim the product by filtration, distillation or some other means. Shelf life
considerations should also be applied in making decisions of this type. Note that
properties of a material may change in use, and recycling or reuse may not always be
appropriate.
路 DO NOT allow wash water from cleaning or process equipment to enter drains.
路 It may be necessary to collect all wash water for treatment before disposal.
路 In all cases disposal to sewer may be subject to local laws and regulations and these
should be considered first.
路 Where in doubt contact the responsible authority.
路 Recycle wherever possible.
路 Consult manufacturer for recycling options or consult local or regional waste
management authority for disposal if no suitable treatment or disposal facility can be
identified.
路 Treat and neutralise at an approved treatment plant. Treatment should involve:
Neutralisation with soda-ash or soda-lime followed by: Burial in a licenced land-fill or
Incineration in a licenced apparatus (after admixture with suitable combustible material).
路 Decontaminate empty containers with 5% aqueous sodium hydroxide or soda ash, followed
by water. Observe all label safeguards until containers are cleaned and destroyed.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: CORROSIVE
HAZCHEM: 2X
UNDG:
Dangerous Goods 8 Subrisk: None
Class:
UN Number: 1760 Packing Group: II
Shipping Name:CORROSIVE LIQUID, N.O.S.
(contains phosphoric acid)
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 22 of 23
Section 14 - TRANSPORTATION INFORMATION
Air Transport IATA:
ICAO/IATA Class: 8 ICAO/IATA Subrisk: None
UN/ID Number: 1760 Packing Group: II
Special provisions: A3
Shipping Name: CORROSIVE LIQUID, N.O.S. *
Maritime Transport IMDG:
IMDG Class: 8 IMDG Subrisk: None
UN Number: 1760 Packing Group: II
EMS Number: F- A, S- B Special provisions: 274 944
Limited Quantities: 1L
Shipping Name: CORROSIVE LIQUID, N.O.S.
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: S6
REGULATIONS
Meguiar's G140 - Hot Rims Chrome Wheel Cleaner (CAS: None):
No regulations applicable
phosphoric acid (CAS: 7664-38-2) is found on the following regulatory lists;
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
IMO IBC Code Chapter 17: Summary of minimum requirements
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
polyethylene glycol mono-p-nonylphenyl ether, branched (CAS: 127087-87-0) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
glycolic acid (CAS: 79-14-1) is found on the following regulatory lists;
Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 2
Australia Hazardous Substances
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
IMO IBC Code Chapter 17: Summary of minimum requirements
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
propylene glycol monobutyl ether (CAS: 5131-66-8) is found on the following regulatory lists;
Australia Hazardous Substances
Australia Inventory of Chemical Substances (AICS)
International Air Transport Association (IATA) Dangerous Goods Regulations
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
propylene glycol monobutyl ether (CAS: 15821-83-7) is found on the following regulatory lists;
International Air Transport Association (IATA) Dangerous Goods Regulations
ammonium bifluoride (CAS: 1341-49-7) is found on the following regulatory lists;
Australia - Australian Capital Territory - Environment Protection Regulation: Pollutants entering waterways taken to cause environmental harm (IRRIG)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Agricultural uses (Stock)
Australia - Australian Capital Territory Environment Protection Regulation Pollutants entering waterways - Domestic water quality
Australia Dangerous Goods Code Draft 7th Edition - List of Common Pesticides with Corresponding UN Numbers
Australia Exposure Standards
Australia Hazardous Substances
Australia Inventory of Chemical Substances (AICS)
Australia National Pollutant Inventory
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix J (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 2
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 3
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 4
continued...
MEGUIAR'S G140 - HOT RIMS CHROME WHEEL CLEANER
Chemwatch Material Safety Data Sheet
Issue Date: 18-Apr-2008 CHEMWATCH 02-1957
NA317TC Version No:2.0
CD 2008/1 Page 23 of 23
Section 15 - REGULATORY INFORMATION
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 7
International Agency for Research on Cancer (IARC) Carcinogens
International Air Transport Association (IATA) Dangerous Goods Regulations
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
The Australia Group Export Control List: Chemical Weapons Precursors
WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking-water
water (CAS: 7732-18-5) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
IMO IBC Code Chapter 18: List of products to which the Code does not apply
OECD Representative List of High Production Volume (HPV) Chemicals
No data available for N,N-dimethyldecylamine N-oxide as CAS: 2605-79-0.
Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
propylene glycol monobutyl ether 5131- 66- 8, 15821- 83- 7
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components and
concentration:
Composite Exposure Standard for Mixture (TWA) :10 mg/m鲁.
Operations which produce a spray/mist or fume/dust, introduce particulates to the
breathing zone.
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc (%).
Component Breathing Zone Mixture Conc
(mg/m鲁) (%)
glycolic acid 10.0000 5.0
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk
Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Scale of use, frequency of use and current or available engineering controls must be
considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 18-Apr-2008
Print Date: 18-Apr-2008
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