NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 1 of 12
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
NULON HP DIESEL ENGINE TREATMENT
SYNONYMS
Part No: HP lubricant
PRODUCT USE
Lubricant.
SUPPLIER
Company: Nulon Products (Australia) Pty Ltd
Address:
1/4 Narabang Way
Belrose
NSW, 2085
AUSTRALIA
Telephone: +61 02 9450 1791
Fax: 02 9450 2448
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
According to the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
Harmful to aquatic organisms.
Dangerous for the ozone layer.
Inhalation, skin contact and/or ingestion may produce health damage*.
Cumulative effects may result following exposure*.
May produce discomfort of the eyes and skin*.
Limited evidence of a carcinogenic effect*.
* (limited evidence)
SAFETY
Do not breathe gas/fumes/vapour/spray.
Wear eye/face protection.
Use only in well ventilated areas.
Keep container in a well ventilated place.
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 2 of 12
Section 2 - HAZARDS IDENTIFICATION ...
To clean the floor and all objects contaminated by this material, use water and
detergent.
Keep container tightly closed.
This material and its container must be disposed of in a safe way.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
if possible).
Use appropriate container to avoid environment contamination.
Avoid release to the environment. Refer to special instructions/Safety data
sheets.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
mineral oil Not avail. 30-60
(solvent refined)
additives, unregulated 30-60
polytetrafluoroethylene 9002-84-0 1-10
performance additives 1-10
dye 1
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.
Section 4 - FIRST AID MEASURES
SWALLOWED
- IF SWALLOWED, REFER FOR MEDICAL ATTENTION, WHERE POSSIBLE, WITHOUT DELAY.
- For advice, contact a Poisons Information Centre or a doctor.
- Where Medical attention is not immediately available or where the patient is
more than 15 minutes from a hospital or unless instructed otherwise:
- For advice, contact a Poisons Information Centre or a doctor.
- Urgent hospital treatment is likely to be needed.
- If conscious, give water to drink.
- INDUCE vomiting with fingers down the back of the throat, ONLY IF CONSCIOUS.
Lean patient forward or place on left side (head-down position, if possible) to
maintain open airway and prevent aspiration.
NOTE: Wear a protective glove when inducing vomiting by mechanical means.
- In the mean time, qualified first-aid personnel should treat the patient
following observation and employing supportive measures as indicated by the
patient's condition.
- If the services of a medical officer or medical doctor are readily available,
the patient should be placed in his/her care and a copy of the MSDS should be
provided. Further action will be the responsibility of the medical specialist.
- If medical attention is not available on the worksite or surroundings send the
patient to a hospital together with a copy of the MSDS.
EYE
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 3 of 12
Section 4 - FIRST AID MEASURES ...
- Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
- If pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed,
where possible, prior to initiating first aid procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if
necessary.
- Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
- Heavy and persistent skin contamination over many years may lead to dysplastic
changes. Pre-existing skin disorders may be aggravated by exposure to this
product.
- In general, emesis induction is unnecessary with high viscosity, low
volatility products, i.e. most oils and greases.
- High pressure accidental injection through the skin should be assessed for
possible incision, irrigation and/or debridement.
NOTE: Injuries may not seem serious at first, but within a few hours tissue may
become swollen, discoloured and extremely painful with extensive subcutaneous
necrosis. Product may be forced through considerable distances along tissue
planes.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear full body protective clothing with breathing apparatus.
- Prevent, by any means available, spillage from entering drains or water
course.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- Avoid spraying water onto liquid pools.
- DO NOT approach containers suspected to be hot.
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 4 of 12
Section 5 - FIRE FIGHTING MEASURES ...
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
- Combustible.
- Slight fire hazard when exposed to heat or flame.
- Heating may cause expansion or decomposition leading to violent rupture of
containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
- Mists containing combustible materials may be explosive.
Combustion products include
carbon dioxide (CO2)
hydrogen chloride
phosgene
other pyrolysis products typical of burning organic material
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result
HAZCHEM
None
Personal Protective Equipment
Glasses:
Chemical goggles.
Gloves:
PVC chemical resistant type.
Respirator:
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
Environmental hazard - contain spillage.
- Remove all ignition sources.
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labelled container for waste disposal.
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 5 of 12
Section 6 - ACCIDENTAL RELEASE MEASURES ...
MAJOR SPILLS
Slippery when spilt.
Environmental hazard - contain spillage.
Moderate hazard.
- Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water
course.
- No smoking, naked lights or ignition sources.
- Increase ventilation.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labelled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite.
- Collect solid residues and seal in labelled drums for disposal.
- Wash area and prevent runoff into drains.
- If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- Avoid smoking, naked lights or ignition sources.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions.
DO NOT allow clothing wet with material to stay in contact with skin
SUITABLE CONTAINER
DO NOT use aluminium or galvanised containers
- Metal can or drum
- Packaging as recommended by manufacturer.
- Check all containers are clearly labelled and free from leaks.
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 6 of 12
Section 7 - HANDLING AND STORAGE ...
STORAGE INCOMPATIBILITY
For PTFE-containing materials:
Avoid storage with strong oxidising agents, tetrafluoroethylene,
hexafluoroethylene, perfluoroisobutylene, carbonyl fluoride and hydrogen
fluoride.
Avoid reaction with oxidising agents
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- No smoking, naked lights or ignition sources.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
ODOUR SAFETY FACTOR (OSF)
OSF=0.001 (polytetrafluoroethylene)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the
Exposure Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV-TWA for
example) is being
reached, even when
distracted by working
activities
B 26-550 As "A" for 50-90% of
persons being distracted
C 1-26 As "A" for less than 50%
of persons being
distracted
D 0.18-1 10-50% of persons aware
of being tested perceive
by smell that the
Exposure Standard is
being reached
E <0.18 As "D" for less than 10%
of persons aware of being
tested
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 7 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
EXPOSURE STANDARDS FOR MIXTURE
"Worst Case" computer-aided prediction of spray/ mist or fume/ dust components
and concentration:
Composite Exposure Standard for Mixture (TWA) :5.3846 mg/m鲁.
Operations which produce a spray/mist or fume/dust, introduce particulates to
the breathing zone.
If the breathing zone concentration of ANY of the components listed below is
exceeded, "Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m鲁 Mixture Conc (%)
Component Breathing Zone Mixture Conc
(mg/m鲁) (%)
mineral oil 4.6154 60.0
polytetrafluoroethylene 0.7692 10.0
INGREDIENT DATA
MINERAL OIL:
TLV TWA: 5 mg/m鲁 () [ACGIH]
TLV STEL: 10 mg/m鲁 [ACGIH]
PEL TWA: 5 mg/m鲁 [OSHA Z1]
oil mist, mineral
TLV TWA: 5 mg/m鲁; STEL: 10 mg/m鲁.
NOTICE OF INTENDED CHANGE.
TLV TWA 0.2 mg/m鲁 inhalable fraction highly refined A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing cancer in humans.
ES TWA: 5 mg/m鲁 (oil mist, refined mineral)
Human exposure to oil mist alone has not been demonstrated to cause health
effects except at levels above 5 mg/m鲁 (this applies to particulates sampled by
a method that does not collect vapour). It is not advisable to apply this
standard to oils containing unknown concentrations and types of additive.
POLYTETRAFLUOROETHYLENE:
TLV TWA: (Exposure by all routes should be carefully controlled to levels as low as possible) B1
[ACGIH]
Dusts not otherwise classified, as inspirable dust;
ES TWA: 10 mg/m鲁
For thermal decomposition products, i.e.substances of variable composition
No TLV is recommended pending toxicity determination of decomposition
products, but their concentration in air should be minimal. [ACGIH]
PERSONAL PROTECTION
EYE
- Safety glasses with side shields.
- Chemical goggles.
- Contact lenses pose a special hazard; soft lenses may absorb irritants and all
lenses concentrate them. DO NOT wear contact lenses.
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 8 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber
OTHER
- Overalls.
- P.V.C. apron.
- Barrier cream.
- Skin cleansing cream.
- Eye wash unit.
ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear
approved respirator. Correct fit is essential to obtain adequate protection.
Supplied-air type respirator may be required in special circumstances. Correct
fit is essential to ensure adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some
situations.
Provide adequate ventilation in warehouse or closed storage area. Air
contaminants generated in the workplace possess varying "escape" velocities
which, in turn, determine the "capture velocities" of fresh circulating air
required to effectively remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., 0.25-0.5 m/s (50-100 f/min.)
evaporating from tank (in still air).
aerosols, fumes from pouring 0.5-1 m/s (100-200 f/min.)
operations, intermittent container
filling, low speed conveyer transfers,
welding, spray drift, plating acid
fumes, pickling (released at low
velocity into zone of active
generation)
direct spray, spray painting in shallow 1-2.5 m/s (200-500 f/min.)
booths, drum filling, conveyer loading,
crusher dusts, gas discharge (active
generation into zone of rapid air
motion)
grinding, abrasive blasting, tumbling, 2.5-10 m/s (500-2000 f/min.)
high speed wheel generated dusts
(released at high initial velocity into
zone of very high rapid air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or 1: Disturbing room air currents
favourable to capture
2: Contaminants of low toxicity or of 2: Contaminants of high toxicity
nuisance value only.
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in 4: Small hood-local control only
motion
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 9 of 12
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION ...
Simple theory shows that air velocity falls rapidly with distance away from the
opening of a simple extraction pipe. Velocity generally decreases with the
square of distance from the extraction point (in simple cases). Therefore the
air speed at the extraction point should be adjusted, accordingly, after
reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for
extraction of solvents generated in a tank 2 meters distant from the extraction
point. Other mechanical considerations, producing performance deficits within
the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or
used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Opaque viscous liquid; does not mix with water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Molecular Weight: Not applicable Boiling Range (掳C): Not available
Melting Range (掳C): Not available Specific Gravity (water=1): Not available
Solubility in water (g/L): Immiscible pH (as supplied): Not applicable
pH (1% solution): Not applicable Vapour Pressure (kPa): Not available
Volatile Component (%vol): Not available Evaporation Rate: Not available
Relative Vapour Density (air=1): Not available Flash Point (掳C): Not available
Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available
Autoignition Temp (掳C): Not available Decomposition Temp (掳C): Not available
State: Liquid
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 10 of 12
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments
There is some evidence to suggest that this material can cause, if swallowed
once, irreversible damage of organs.
EYE
Limited evidence or practical experience suggests, that the material may cause
eye irritation in a substantial number of individuals. Prolonged eye contact may
cause inflammation characterised by a temporary redness of the conjunctiva
(similar to windburn).
SKIN
There is some evidence to suggest that this material, on a single contact with
skin, can cause irreversible damage of organs.
There is some evidence to suggest that the material may cause mild but
significant inflammation of the skin either following direct contact or after a
delay of some time. Repeated exposure can cause contact dermatitis which is
characterised by redness, swelling and blistering.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
There is some evidence to suggest that this material
can cause, if inhaled once, irreversible damage
of organs.
At temperatures of over 400 deg. C the polymer begins to decompose with the
reaction becoming faster as temperature rises.
Fumes from burning materials containing PTFE irritate the upper airway and may
be harmful if exposure is prolonged.
Overheated or burnt PTFE releases hydrogen fluoride (a highly irritating and
corrosive gas) and small amounts of carbonyl fluoride (highly toxic).
Inhalation of hydrogen fluoride gas causes hydrofluoric acid to form in the
mucous, causing choking, coughing, and severe irritation of the eye, nose and
throat. After a period of 1-2 days without symptoms, there may be a "polymer
fume fever" –a temporary flu-like illness with fever, chills and
sometimes, a cough and difficult breathing lasting for about 24 hours.
Inhalation or skin contact with carbonyl fluoride may cause irritation with
discomfort and rash. In addition, there may be eye corrosion with ulcers of the
cornea and conjunctiva, irritation of the nose and throat, or temporary lung
irritation producing cough, discomfort, difficult breathing and shortness of
breath. Those people with existing lung diseases may be more vulnerable to the
toxic effects of the above products.At temperatures of over 400 deg. C the
polymer begins to decompose with the reaction becoming faster as temperature
rises.
Fumes from burning materials containing PTFE irritate the upper airway and may
be harmful if exposure is prolonged.
Overheated or burnt PTFE releases hydrogen fluoride (a highly irritating and
corrosive gas) and small amounts of carbonyl fluoride (highly toxic).
Inhalation of hydrogen fluoride gas causes hydrofluoric acid to form in the
mucous, causing choking, coughing, and severe irritation of the eye, nose and
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 11 of 12
Section 11 - TOXICOLOGICAL INFORMATION ...
throat. After a period of 1-2 days without symptoms, there may be a "polymer
fume fever" – a temporary flu-like illness with fever, chills and
sometimes, a cough and difficult breathing lasting for about 24 hours.
Inhalation or skin contact with carbonyl fluoride may cause irritation with
discomfort and rash. In addition, there may be eye corrosion with ulcers of the
cornea and conjunctiva, irritation of the nose and throat, or temporary lung
irritation producing cough, discomfort, difficult breathing and shortness of
breath. Those people with existing lung diseases may be more vulnerable to the
toxic effects of the above products.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern
following repeated or long-term occupational exposure.
There has been some concern that this material can cause cancer or mutations but
there is not enough data to make an assessment.
Oil may contact the skin or be inhaled. Extended exposure can lead to eczema,
inflammation of hair follicles, pigmentation of the face and warts on the soles
of the feet. There are few systemic effects, but prolonged exposure may lead to
a higher incidence of lung scarring.
Nulon HP Diesel Engine Treatment
No data for Nulon HP Diesel Engine Treatment.
MINERAL OIL:
Toxicity and Irritation data is related to chemical components and
varies as does the composition and source of the original crude.
A small but definite risk of occupational skin cancer occurs in workers
exposed to persistent skin contamination by oils over a period of years.
This risk has been attributed to the presence of certain polycyclic
aromatic hydrocarbons (PAH) (typified by benz[a]pyrene).
Petroleum oils which are solvent refined/extracted or severely hydrotreated,
contain very low concentrations of both.
POLYTETRAFLUOROETHYLENE:
TOXICITY IRRITATION
Oral (rat) LD50: 1250 mg/kg * Nil reported
* [Manufacturer]
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
Section 12 - ECOLOGICAL INFORMATION
Harmful to aquatic organisms.
Dangerous for the ozone layer.
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
- Recycle wherever possible or consult manufacturer for recycling options.
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NULON HP DIESEL ENGINE TREATMENT
ChemWatch Material Safety Data Sheet CHEMWATCH 41786
Issue Date: Fri 14-May-2004 CD 2004/2 Page 12 of 12
Section 13 - DISPOSAL CONSIDERATIONS ...
- Consult State Land Waste Authority for disposal.
- Bury or incinerate residue at an approved site.
- Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Shipping Name:
None
Dangerous Goods Class: None
UN/NA Number: None
ADR Number:
Packing Group: None
Labels Required:
Additional Shipping Information:
International Transport Regulations:
IMO: None
HAZCHEM
None
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Fri 14-May-2004
Print Date: Mon 17-May-2004
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