NULON PRO-STRENGTH OCTANE BOOSTER #2
Chemwatch Material Safety Data Sheet
Issue Date: 17-Apr-2008 CHEMWATCH 5099-38
C9317EC Version No:6
CD 2008/1 Page 1 of 6
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
NULON PRO-STRENGTH OCTANE BOOSTER #2
PROPER SHIPPING NAME
TOXIC LIQUID, ORGANIC, N.O.S.
(contains 2- methylcyclopentadienyl tricarbonyl)
PRODUCT USE
MSDS are intended for use in the workplace. For domestic- use products, refer to consumer labels. Fuel additive.
SUPPLIER
Company: Nulon Products Australia Pty Ltd
Address:
17 Yulong Close
Moorebank
NSW, 2170
AUS
Telephone: +61 2 9986 7800
Fax: +61 2 9601 4700
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code.
COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.
POISONS SCHEDULE
S6
RISK SAFETY
Harmful in contact with skin. Keep locked up.
Toxic by inhalation and if swallowed. Wear suitable protective clothing.
Limited evidence of a carcinogenic effect. In case of insufficient ventilation wear
suitable respiratory equipment.
Harmful: danger of serious damage to health To clean the floor and all objects
by prolonged exposure through inhalation. contaminated by this material use water and
detergent.
Harmful to aquatic organisms may cause long- This material and its container must be
term adverse effects in the aquatic disposed of in a safe way.
environment.
HARMFUL- May cause lung damage if swallowed. Keep away from food drink and animal feeding
stuffs.
Repeated exposure may cause skin dryness and This material and its container must be
cracking. disposed of as hazardous waste.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
kerosine, (petroleum), hydrodesulfurised 64742-81-0 >60
manganese 2- methylcyclopentadienyl tricarbonyl 12108-13-3 <11
naphthalene 91-20-3 <10
Section 4 - FIRST AID MEASURES
SWALLOWED
路 If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible
aspiration of vomitus.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
Avoid giving milk or oils.
Avoid giving alcohol. Seek medical advice.
continued...
NULON PRO-STRENGTH OCTANE BOOSTER #2
Chemwatch Material Safety Data Sheet
Issue Date: 17-Apr-2008 CHEMWATCH 5099-38
C9317EC Version No:6
CD 2008/1 Page 2 of 6
Section 4 - FIRST AID MEASURES
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting
the upper and lower lids.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear.
路 Flush skin and hair with running water (and soap if available).
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
NOTES TO PHYSICIAN
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or
pharmacologically.
For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction,
obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be
intubated.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 Foam.
路 Dry chemical powder.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear full body protective clothing with breathing apparatus.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 800 metres in all directions.
FIRE/EXPLOSION HAZARD
路 Combustible.
路 Slight fire hazard when exposed to heat or flame.
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc.
HAZCHEM: 2X
Personal Protective Equipment
Gas tight chemical resistant suit.
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
路 Remove all ignition sources.
路 Clean up all spills immediately.
MAJOR SPILLS
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
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NULON PRO-STRENGTH OCTANE BOOSTER #2
Chemwatch Material Safety Data Sheet
Issue Date: 17-Apr-2008 CHEMWATCH 5099-38
C9317EC Version No:6
CD 2008/1 Page 3 of 6
Section 7 - HANDLING AND STORAGE
SUITABLE CONTAINER
路 Lined metal can, lined metal pail/ can.
路 Plastic pail.
STORAGE INCOMPATIBILITY
路 Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁
__________________ __________________ _______ _______ _______ _______
Australia Exposure manganese 2- 0.2
Standards methylcyclopentadienyl
tricarbonyl
(Methylcyclopentadienyl
manganese tricarbonyl
(as Mn))
Australia Exposure manganese 2- 1 3
Standards methylcyclopentadienyl
tricarbonyl (Manganese,
fume (as Mn))
Australia Exposure manganese 2- 1
Standards methylcyclopentadienyl
tricarbonyl (Manganese,
dust & compounds (as
Mn))
Australia Exposure naphthalene 10 52 15 79
Standards (Naphthalene)
The following materials had no OELs on our records
鈥? kerosine, (petroleum), hydrodesulfurised: CAS:64742- 81- 0
PERSONAL PROTECTION
RESPIRATOR
Type A-P Filter of sufficient capacity
EYE
路 Safety glasses with side shields.
路 Chemical goggles.
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
OTHER
路 Overalls.
路 Eyewash unit.
ENGINEERING CONTROLS
For flammable liquids and flammable gases, local exhaust ventilation or a process enclosure ventilation system may be required.
Ventilation equipment should be explosion-resistant.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Dark amber liquid with paraffinic odour; does not mix with water.
PHYSICAL PROPERTIES
Does not mix with water.
Floats on water.
Toxic or noxious vapours/gas.
Molecular Weight: Not Available Boiling Range (掳 195 initial
C):
Melting Range (掳 Not Available
C): Specific Gravity (water=1): 0.862
Solubility in water (g/L): Immiscible pH (as supplied): Not Applicable
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
continued...
NULON PRO-STRENGTH OCTANE BOOSTER #2
Chemwatch Material Safety Data Sheet
Issue Date: 17-Apr-2008 CHEMWATCH 5099-38
C9317EC Version No:6
CD 2008/1 Page 4 of 6
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
Volatile Component (%vol): 100 Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (掳 63
C):
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳 Not Available
C): Decomposition Temp (掳 Not Available
C):
State: LIQUID Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS CHRONIC HEALTH EFFECTS
Harmful in contact with skin. Limited evidence of a carcinogenic effect.
HARMFUL- May cause lung damage if Harmful: danger of serious damage to health
swallowed.
Toxic by inhalation and if swallowed. by prolonged exposure through inhalation.
Vapours may cause dizziness or Repeated exposure may cause skin dryness and
suffocation. cracking.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
KEROSINE, (PETROLEUM), HYDRODESULFURISED:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: >5000 mg/kg Skin (rabbit): 500 mg/24h - Moderate
Inhalation (rat) LC50: >5000 mg/m鲁/4h
Dermal (rabbit) LD50 : >2000 mg/kg
MANGANESE 2-METHYLCYCLOPENTADIENYL TRICARBONYL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 50 mg/kg Skin (rabbit): 100 mg/24h - Mild
Oral (rat) LD50: 9 mg/kg *
Inhalation (rat) LC50: 76 mg/m鲁/4h
Inhalation (rat) LC50: 220 mg/m鲁/1h *
Dermal (rabbit) LD50: 140 mg/kg
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis.
NOAEL (inhalation) 6.2 mg/m鲁 (rats and mice)*
* Worksafe Australia
NAPHTHALENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (child) LDLo: 100 mg/kg Skin (rabbit):495 mg (open) - Mild
Unrep. (human) LDLo: 29 mg/kg Eye (rabbit): 100 mg - Mild
Unrep. (man) LDLo: 74 mg/kg
Oral (rat) LD50: 490 mg/kg
Dermal (rat) LD50: >2500 mg/kg
The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged exposure to
irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling epidermis.
WARNING: This substance has been classified by the IARC as Group 2B: Possibly Carcinogenic to Humans.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
_______________ ____________ __________ __________ __________
naphthalene IARC:2B NTPB
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: naphthalene Category: WARNING: This substance has been
classified by the IARC as Group 2B: Possibly Carcinogenic to Humans.
CARCINOGEN
NTPB: US National Toxicology Program (NTP) 11th Report Part B. Reasonably Anticipated to be a Human Carcinogen: naphthalene
Category:
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NULON PRO-STRENGTH OCTANE BOOSTER #2
Chemwatch Material Safety Data Sheet
Issue Date: 17-Apr-2008 CHEMWATCH 5099-38
C9317EC Version No:6
CD 2008/1 Page 5 of 6
Section 12 - ECOLOGICAL INFORMATION
Marine Pollutant:Not Determined
No data for Nulon Pro-Strength Octane Booster #2.
Refer to data for ingredients, which follows:
MANGANESE 2-METHYLCYCLOPENTADIENYL TRICARBONYL:
log Kow 3.4
MMT is subject to rapid photochemical degradation in the atmosphere with a reported atmospheric half-life of 8-18 seconds.
MMT can absorb to, and become immobilised by soils thereby reducing its potential for photodegradation.
Degradation of MMT in dark, anaerobic aqueous environment is slow.
Ecotoxicology
Fish LC50 (12 h): bluegill sunfish 0.2 mg/l; fathead minnow 0.23-0.36 mg/l
Daphnia EC50 (48 h): 0.83 mg/l
Daphnia EC50 (4 h): 0.87 mg/l
controlled ozone depleting gases: freeze by 1995 (C)
Toxicity invertebrate: cell mult. inhib.60-349mg/L
Effects on algae and plankton: cell mult. inhib. algae26-88mg/L
NAPHTHALENE:
log Kow: 3.01-3.59
Koc: 400-1000
log Kom: 2.93-3.29
Half-life (hr) air: 6.3-24
Half-life (hr) H2O surface water: 0.8-13200
Half-life (hr) H2O ground: 5256
Half-life (hr) soil: 8-150
Half-life (hr) sediment: 4.9->2112
Henry's Pa m鲁 /mol: 29.2-56
Henry's atm m鲁 /mol: (4.83-5.53)e-4
BOD 5 if unstated: nil
COD: 22%
ThOD: 2.99
BCF: 20-6000
Log BCF: 1.48-4.11
Toxicity Fish: LC50(96)2.1-20.8mg/L
Section 13 - DISPOSAL CONSIDERATIONS
路 Containers may still present a chemical hazard/ danger when empty.
路 Return to supplier for reuse/ recycling if possible.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: TOXIC
HAZCHEM: 2X
UNDG:
Dangerous Goods 6.1 Subrisk: None
Class:
UN Number: 2810 Packing Group: III
Shipping Name:TOXIC LIQUID, ORGANIC, N.O.S.
(contains 2-methylcyclopentadienyl tricarbonyl)
Air Transport IATA:
ICAO/IATA Class: 6.1 ICAO/IATA Subrisk: None
UN/ID Number: 2810 Packing Group: III
Special provisions: A3 A4 A137
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S. *
Maritime Transport IMDG:
IMDG Class: 6.1 IMDG Subrisk: None
UN Number: 2810 Packing Group: III
continued...
NULON PRO-STRENGTH OCTANE BOOSTER #2
Chemwatch Material Safety Data Sheet
Issue Date: 17-Apr-2008 CHEMWATCH 5099-38
C9317EC Version No:6
CD 2008/1 Page 6 of 6
Section 14 - TRANSPORTATION INFORMATION
EMS Number: F- A, S- A Special provisions: 223 274 944
Limited Quantities: 5L Marine Pollutant: Not Determined
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: S6
REGULATIONS
Nulon Pro-Strength Octane Booster #2 (CAS: None):
No regulations applicable
kerosine, (petroleum), hydrodesulfurised (CAS: 64742-81-0) is found on the following regulatory lists;
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
International Air Transport Association (IATA) Dangerous Goods Regulations
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
OSPAR List of Chemicals for Priority Action
manganese 2-methylcyclopentadienyl tricarbonyl (CAS: 12108-13-3) is found on the following regulatory lists;
Australia - Victoria Occupational Health and Safety Regulations - Schedule 9: Materials at Major Hazard Facilities (And Their Threshold Quantity) Table 2
Australia Exposure Standards
Australia Hazardous Substances
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 7
IMO IBC Code Chapter 17: Summary of minimum requirements
OECD Representative List of High Production Volume (HPV) Chemicals
naphthalene (CAS: 91-20-3) is found on the following regulatory lists;
Australia Exposure Standards
Australia Hazardous Substances
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix G
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
IMO IBC Code Chapter 17: Summary of minimum requirements
IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk
International Agency for Research on Cancer (IARC) Carcinogens
International Air Transport Association (IATA) Dangerous Goods Regulations
OECD Representative List of High Production Volume (HPV) Chemicals
Section 16 - OTHER INFORMATION
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as
independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the
reported Hazards are Risks in the workplace or other settings.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act,
no part may be reproduced by any process without written permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 17-Apr-2008
Print Date: 17-Apr-2008
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