NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 1 of 19
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
NULON LIFTER FREE AND TUNE UP
SYNONYMS
"Part Number: LFTU", "additive valve lifter degumming engine cleaner"
PRODUCT USE
Additive added to engine oil for removal of gum, carbon and varnish from internal parts
SUPPLIER
Company: Nulon Products Australia Pty Ltd
Address:
17 Yulong Close
Moorebank
NSW, 2170
AUS
Telephone: +61 2 9986 7800
Fax: +61 2 9601 4700
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.
COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.
POISONS SCHEDULE
None
RISK SAFETY
In use may form flammable/explosive vapour- Wear suitable protective clothing.
air mixture.
May form explosive peroxides. To clean the floor and all objects
contaminated by this material use water and
detergent.
Harmful by inhalation in contact with skin This material and its container must be
and if swallowed. disposed of in a safe way.
Irritating to eyes respiratory system and Keep away from food drink and animal
skin. feeding stuffs.
Toxic to aquatic organisms may cause long- If swallowed IMMEDIATELY contact Doctor or
term adverse effects in the aquatic Poisons Information Centre (show this
environment. container or label).
HARMFUL - May cause lung damage if Use appropriate container to avoid
swallowed. environment contamination.
Vapours may cause drowsiness and dizziness. Avoid release to the environment. Refer to
special instructions/ safety data sheets.
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 2 of 19
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
mineral oil Not avail. 10-30
ethylene glycol monobutyl ether 111-76-2 10-30
aromatic hydrocarbon solvent 64742-95-6. 10-30
isopropanol 67-63-0 1-5
nonylphenol, ethoxylated 9016-45-9 1-10
additives unregulated 1-10
Section 4 - FIRST AID MEASURES
SWALLOWED
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Seek medical advice.
Avoid giving milk or oils.
Avoid giving alcohol.
路 If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower
than their hips to help avoid possible aspiration of vomitus.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear.
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 Transport to hospital, or doctor, without delay.
NOTES TO PHYSICIAN
Any material aspirated during vomiting may produce lung injury. Therefore emesis should
not be induced mechanically or pharmacologically. Mechanical means should be used if it
is considered necessary to evacuate the stomach contents; these include gastric lavage
after endotracheal intubation. If spontaneous vomiting has occurred after ingestion, the
patient should be monitored for difficult breathing, as adverse effects of aspiration
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 3 of 19
Section 4 - FIRST AID MEASURES
into the lungs may be delayed up to 48 hours.
For acute or short term repeated exposures to petroleum distillates or related
hydrocarbons:
路 Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is
respiratory failure.
路 Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis,
tachypnoea, intercostal retraction, obtundation) and given oxygen. Patients with
inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be intubated.
路 Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and
electrocardiographic evidence of myocardial injury has been reported; intravenous lines
and cardiac monitors should be established in obviously symptomatic patients. The lungs
excrete inhaled solvents, so that hyperventilation improves clearance.
路 A chest x-ray should be taken immediately after stabilisation of breathing and
circulation to document aspiration and detect the presence of pneumothorax.
路 Epinephrine (adrenalin) is not recommended for treatment of bronchospasm because of
potential myocardial sensitisation to catecholamines. Inhaled cardioselective
bronchodilators (e.g. Alupent, Salbutamol) are the preferred agents, with aminophylline a
second choice.
路 Lavage is indicated in patients who require decontamination; ensure use of cuffed
endotracheal tube in adult patients. [Ellenhorn and Barceloux: Medical Toxicology].
Treat symptomatically.
Followed acute or short term repeated exposures to ethylene glycol monoalkyl ethers and
their acetates:
路 Hepatic metabolism produces ethylene glycol as a metabolite.
路 Clinical presentation, following severe intoxication, resembles that of ethylene glycol
exposures.
路 Monitoring the urinary excretion of the alkoxyacetic acid metabolites may be a useful
indication of exposure.
[Ellenhorn and Barceloux: Medical Toxicology].
For acute or short term repeated exposures to ethylene glycol:
路 Early treatment of ingestion is important. Ensure emesis is satisfactory.
路 Test and correct for metabolic acidosis and hypocalcaemia.
路 Apply sustained diuresis when possible with hypertonic mannitol.
路 Evaluate renal status and begin haemodialysis if indicated. [I.L.O]
路 Rapid absorption is an indication that emesis or lavage is effective only in the first
few hours. Cathartics and charcoal are generally not effective.
路 Correct acidosis, fluid/electrolyte balance and respiratory depression in the usual
manner. Systemic acidosis (below 7.2) can be treated with intravenous sodium bicarbonate
solution.
路 Ethanol therapy prolongs the half-life of ethylene glycol and reduces the formation of
toxic metabolites.
路 Pyridoxine and thiamine are cofactors for ethylene glycol metabolism and should be
given (50 to 100 mg respectively) intramuscularly, four times per day for 2 days.
路 Magnesium is also a cofactor and should be replenished. The status of 4-methylpyrazole,
in the treatment regime, is still uncertain. For clearance of the material and its
metabolites, haemodialysis is much superior to peritoneal dialysis.
[Ellenhorn and Barceloux: Medical Toxicology]
It has been suggested that there is a need for establishing a new biological exposure
limit before a workshift that is clearly below 100 mmol ethoxy-acetic acids per mole
creatinine in morning urine of people occupationally exposed to ethylene glycol ethers.
This arises from the finding that an increase in urinary stones may be associated with
such exposures.
Laitinen J., et al: Occupational & Environmental Medicine 1996; 53, 595-600.
路 Heavy and persistent skin contamination over many years may lead to dysplastic changes.
Pre-existing skin disorders may be aggravated by exposure to this product.
路 In general, emesis induction is unnecessary with high viscosity, low volatility
products, i.e. most oils and greases.
路 High pressure accidental injection through the skin should be assessed for possible
incision, irrigation and/or debridement.
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 4 of 19
Section 4 - FIRST AID MEASURES
NOTE: Injuries may not seem serious at first, but within a few hours tissue may become
swollen, discoloured and extremely painful with extensive subcutaneous necrosis. Product
may be forced through considerable distances along tissue planes.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
路 Water spray or fog - Large fires only.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear full body protective clothing with breathing apparatus.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 Avoid spraying water onto liquid pools.
路 DO NOT approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
WARNING: In use may form flammable/ explosive vapour-air mixtures.
路 Combustible.
路 Slight fire hazard when exposed to heat or flame.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
路 May emit acrid smoke.
路 Mists containing combustible materials may be explosive.
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of
burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.
FIRE INCOMPATIBILITY
路 Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine
bleaches, pool chlorine etc. as ignition may result.
HAZCHEM: None
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
路 Place in a suitable labelled container for waste disposal.
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 5 of 19
Section 6 - ACCIDENTAL RELEASE MEASURES
MAJOR SPILLS
Chemical Class: aliphatic hydrocarbons
For release onto land: recommended sorbents listed in order of priority.
SORBENT TYPE RANK APPLICATION COLLECTION LIMITATIONS
LAND SPILL - SMALL
cross- linked 1 shovel shovel R, W, SS
polymer -
particulate
cross- linked 1 throw pitchfork R, DGC, RT
polymer - pillow
wood fiber - 2 throw pitchfork R, P, DGC, RT
pillow
treated wood 2 throw pitchfork DGC, RT
fibre- pillow
sorbent clay - 3 shovel shovel R, I, P
particulate
foamed glass - 3 throw pitchfork R, P, DGC, RT
pillow
LAND SPILL - MEDIUM
cross- linked 1 blower skiploader R, W, SS
polymer -
particulate
cross- linked 2 throw skiploader R, DGC, RT
polymer - pillow
sorbent clay - 3 blower skiploader R, I, P
particulate
polypropylene - 3 blower skiploader W, SS, DGC
particulate
expanded mineral 4 blower skiploader R, I, W, P, DGC
- particulate
polypropylene - 4 throw skiploader DGC, RT
mat
Legend
DGC: Not effective where ground cover is dense
R; Not reusable
I: Not incinerable
P: Effectiveness reduced when rainy
RT:Not effective where terrain is rugged
SS: Not for use within environmentally sensitive sites
W: Effectiveness reduced when windy
Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control;
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 6 of 19
Section 6 - ACCIDENTAL RELEASE MEASURES
R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988.
Slippery when spilt.
Moderate hazard.
路 Clear area of personnel and move upwind.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 No smoking, naked lights or ignition sources.
路 Increase ventilation.
路 Stop leak if safe to do so.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite.
路 Collect solid residues and seal in labelled drums for disposal.
路 Wash area and prevent runoff into drains.
路 If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
路 Containers, even those that have been emptied, may contain explosive vapours.
路 Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
路 DO NOT allow clothing wet with material to stay in contact with skin.
The substance accumulates peroxides which may become hazardous only if it evaporates or
is distilled or otherwise treated to concentrate the peroxides. The substance may
concentrate around the container opening for example.
Purchases of peroxidisable chemicals should be restricted to ensure that the chemical is
used completely before it can become peroxidised.
路 A responsible person should maintain an inventory of peroxidisable chemicals or
annotate the general chemical inventory to indicate which chemicals are subject to
peroxidation. An expiration date should be determined. The chemical should either be
treated to remove peroxides or disposed of before this date.
路 The person or laboratory receiving the chemical should record a receipt date on the
bottle. The individual opening the container should add an opening date.
路 Unopened containers received from the supplier should be safe to store for 18 months.
路 Opened containers should not be stored for more than 12 months.
路 Electrostatic discharge may be generated during pumping - this may result in fire.
路 Ensure electrical continuity by bonding and grounding (earthing) all equipment.
路 Restrict line velocity during pumping in order to avoid generation of electrostatic
discharge (<=1 m/sec until fill pipe submerged to twice its diameter, then <= 7 m/sec).
路 Avoid splash filling.
路 Do NOT use compressed air for filling discharging or handling operations.
路 Avoid all personal contact, including inhalation.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 Prevent concentration in hollows and sumps.
路 DO NOT enter confined spaces until atmosphere has been checked.
路 Avoid smoking, naked lights or ignition sources.
路 Avoid contact with incompatible materials.
路 When handling, DO NOT eat, drink or smoke.
路 Keep containers securely sealed when not in use.
路 Avoid physical damage to containers.
路 Always wash hands with soap and water after handling.
路 Work clothes should be laundered separately.
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 7 of 19
Section 7 - HANDLING AND STORAGE
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
路 Atmosphere should be regularly checked against established exposure standards to
ensure safe working conditions.
SUITABLE CONTAINER
路 DO NOT use aluminium or galvanised containers.
路 Metal can or drum
路 Packaging as recommended by manufacturer.
路 Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
路 Glycol ethers may form peroxides under certain conditions.
路 In the presence of strong bases or the salts of strong bases, at elevated temperatures,
the potential exists for runaway reactions.
路 Contact with aluminium should be avoided. Release of hydrogen gas may result.
CARE: Water in contact with heated material may cause foaming or a steam explosion with
possible severe burns from wide scattering of hot material. Resultant overflow of
containers may result in fire.
路 Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
路 Store in original containers.
路 Keep containers securely sealed.
路 No smoking, naked lights or ignition sources.
路 Store in a cool, dry, well-ventilated area.
路 Store away from incompatible materials and foodstuff containers.
路 Protect containers against physical damage and check regularly for leaks.
路 Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA ppm TWA mg/m鲁 STEL ppm STEL mg/m鲁
__________________ __________________ _______ _______ _______ _______
Australia Exposure ethylene glycol 20 96.9 50 242
Standards monobutyl ether (2-
Butoxyethanol)
Australia Exposure isopropanol (Isopropyl 400 983 500 1230
Standards alcohol)
The following materials had no OELs on our records
鈥? aromatic hydrocarbon solvent: CAS:64742- 95- 6
鈥? nonylphenol, ethoxylated: CAS:9016- 45- 9 CAS:26027- 38- 3
EMERGENCY EXPOSURE LIMITS
Material Original IDLH Value (mg/m3) Revised IDLH Value (mg/m3)
Revised IDLH Value (ppm) 700
isopropanol 12, 000
2, 000 [LEL]
NOTES
Values marked LEL indicate that the IDLH was based on 10% of the lower explosive limit
for safety considerations even though the relevant toxicological data indicated that
irreversible health effects or impairment of escape existed only at higher concentrations.
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 8 of 19
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
MATERIAL DATA
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-
observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-
category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
INGREDIENT DATA
AROMATIC HYDROCARBON SOLVENT:
ISOPROPANOL:
Sensory irritants are chemicals that produce temporary and undesirable side-effects on
the eyes, nose or throat. Historically occupational exposure standards for these
irritants have been based on observation of workers' responses to various airborne
concentrations. Present day expectations require that nearly every individual should be
protected against even minor sensory irritation and exposure standards are established
using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no-
observable-effect-levels (NOEL) are used to determine these limits where human results
are unavailable. An additional approach, typically used by the TLV committee (USA) in
determining respiratory standards for this group of chemicals, has been to assign ceiling
values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV
STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints
combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five-
category system based on intensive odour, local irritation, and elimination half-life.
However this system is being replaced to be consistent with the European Union (EU)
Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely
allied to that of the USA.
OSHA (USA) concluded that exposure to sensory irritants can:
路 cause inflammation
路 cause increased susceptibility to other irritants and infectious agents
路 lead to permanent injury or dysfunction
路 permit greater absorption of hazardous substances and
路 acclimate the worker to the irritant warning properties of these substances thus
increasing the risk of overexposure.
MINERAL OIL:
ES TWA: 5 mg/m3 refined mineral oil mist
Human exposure to oil mist alone has not been demonstrated to cause health effects
except at levels above 5 mg/m3 (this applies to particulates sampled by a method that
does not collect vapour). It is not advisable to apply this standard to oils containing
unknown concentrations and types of additive.
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 9 of 19
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ETHYLENE GLYCOL MONOBUTYL ETHER:
Exposed individuals are reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class A or B.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed
individuals are aware by
smell that the Exposure
Standard (TLV- TWA for
example) is being reached,
even when distracted by
working activities
B 26- 550 As " A" for 50- 90% of
persons being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by
smell that the Exposure
Standard is being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
Odour Threshold Value: 0.10 ppm (detection), 0.35 ppm (recognition)
Although rats appear to be more susceptible than other animals anaemia is
not uncommon amongst humans following exposure. The TLV reflects the need
to maintain exposures below levels found to cause blood changes in
experimental animals. It is concluded that this limit will reduce the
significant risk of irritation, haematologic effects and other systemic
effects observed in humans and animals exposed to higher vapour
concentrations. The toxic effects typical of some other glycol ethers
(pancytopenia, testis atrophy and teratogenic effects) are not found with
this substance.
AROMATIC HYDROCARBON SOLVENT:
CEL TWA: 50 ppm, 250 mg/m3 as total hydrocarbons [Manufacturer]
ISOPROPANOL:
Odour Threshold Value: 3.3 ppm (detection), 7.6 ppm (recognition)
Exposure at or below the recommended isopropanol TLV-TWA and STEL is thought to
minimise the potential for inducing narcotic effects or significant irritation of the
eyes or upper respiratory tract. It is believed, in the absence of hard evidence, that
this limit also provides protection against the development of chronic health effects.
The limit is intermediate to that set for ethanol, which is less toxic, and n-propyl
alcohol, which is more toxic, than isopropanol.
NONYLPHENOL, ETHOXYLATED:
No exposure limits set by NOHSC or ACGIH.
PERSONAL PROTECTION
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 10 of 19
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EYE
路 Safety glasses with side shields.
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
路 Wear chemical protective gloves, eg. PVC.
路 Wear safety footwear or safety gumboots, eg. Rubber.
Suitability and durability of glove type is dependent on usage. Factors such as:
路 frequency and duration of contact,
路 chemical resistance of glove material,
路 glove thickness and
路 dexterity,
are important in the selection of gloves.
OTHER
路 Overalls.
路 P.V.C. apron.
路 Barrier cream.
路 Skin cleansing cream.
路 Eye wash unit.
RESPIRATOR
Respiratory protection may be required when ANY "Worst Case" vapour-phase concentration
is exceeded (see Computer Prediction in "Exposure Standards").
Protection Factor Half- Face Respirator Full- face Respirator
(Min)
10 x ES A- - AUS -
A- - PAPR- AUS -
20 x ES - A- - AUS
- A- - PAPR- AUS
100 x ES - A- - 2
- A- - PAPR- 2
^ - Full-face.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Local exhaust ventilation usually required. If risk of overexposure exists, wear approved
respirator. Correct fit is essential to obtain adequate protection. Supplied-air type
respirator may be required in special circumstances. Correct fit is essential to ensure
adequate protection.
An approved self contained breathing apparatus (SCBA) may be required in some situations.
Provide adequate ventilation in warehouse or closed storage area.
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 11 of 19
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Clear amber liquid, emulsifies in water. hydrocarbon solvent odour
PHYSICAL PROPERTIES
Liquid.
Molecular Weight: Not Applicable Boiling Range (掳 Not Av ailable
C):
Melting Range (掳 Not Available
C): Specific Gravity (water= 1): 0.96- 0.98
Solubility in water (g/L): Partly Miscible pH (as supplied): Not Applicable
pH (1% solution): Not Applicable Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Slow
Relative Vapour Density (air=1): >1 Flash Point (掳 >62
C):
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳 Not Available
C): Decomposition Temp ( 掳 Not Available
C):
State: Liquid Viscosity: Not Available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
There is some evidence to suggest that this material can cause, if swallowed once,
irreversible damage of organs.
Accidental ingestion of the material may be harmful; animal experiments indicate that
ingestion of less than 150 gram may be fatal or may produce serious damage to the health
of the individual.
Not a likely route of entry into the body in commercial or industrial environments. The
liquid may produce considerable gastrointestinal discomfort and be harmful or toxic if
swallowed. Ingestion may cause nausea, pain and vomiting. Vomit entering the lungs by
aspiration can cause inflammation of the lungs, which can lead to death.
Ingestion of petroleum hydrocarbons can irritate the pharynx, oesophagus, stomach and
small intestine, and cause swellings and ulcers of the mucous. Symptoms include a burning
mouth and throat; larger amounts can cause nausea and vomiting, narcosis, weakness,
dizziness, slow and shallow breathing, abdominal swelling, unconsciousness and
convulsions. Damage to the heart muscle can produce heart beat irregularities,
ventricular fibrillation (fatal) and ECG changes. The central nervous system can be
depressed. Light species can cause a sharp tingling of the tongue and cause loss of
sensation there. Aspiration can cause cough, gagging, pneumonia with swelling and
bleeding.
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NULON LIFTER FREE AND TUNE UP
Chemwatch Material Safety Data Sheet
Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 12 of 19
Section 11 - TOXICOLOGICAL INFORMATION
EYE
There is evidence that material may produce eye irritation in some persons and produce
eye damage 24 hours or more after instillation. Severe inflammation may be expected with
pain. There may be damage to the cornea. Unless treatment is prompt and adequate there
may be permanent loss of vision. Conjunctivitis can occur following repeated exposure.
The liquid produces a high level of eye discomfort and is capable of causing pain and
severe conjunctivitis. Corneal injury may develop, with possible permanent impairment of
vision, if not promptly and adequately treated.
Direct eye contact with petroleum hydrocarbons can be painful, and the corneal epithelium
may be temporarily damaged. Aromatic species can cause irritation and excessive tear
secretion.
SKIN
There is some evidence to suggest that this material, on a single contact with skin, can
cause irreversible damage of organs.
The material may accentuate any pre-existing dermatitis condition.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may
produce systemic injury with harmful effects. Examine the skin prior to the use of the
material and ensure that any external damage is suitably protected.
Skin contact with the material may be harmful; systemic effects may result following
absorption.
Aromatic hydrocarbons may produce sensitivity and redness of the skin. They are not
likely to be absorbed into the body through the skin but branched species are more likely
to.
INHALED
The material can cause respiratory irritation in some persons. The body's response to
such irritation can cause further lung damage.
There is some evidence to suggest that this material
can cause, if inhaled once, irreversible damage
of organs.
Inhalation hazard is increased at higher temperatures.
If exposure to highly concentrated solvent atmosphere is prolonged this may lead to
narcosis, unconsciousness, even coma and possible death.
Inhalation of aerosols (mists, fumes), generated by the material during the course of
normal handling, may be harmful.
Xylene is a central nervous system depressant.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern following
repeated or long-term occupational exposure.
There is some evidence from animal testing that exposure to this material may result in
toxic effects to the unborn baby.
Based on experience with similar materials, there is a possibility that exposure to the
material may reduce fertility in humans at levels which do not cause other toxic effects.
There has been concern that this material can cause cancer or mutations, but there is not
enough data to make an assessment.
Exposure to the material for prolonged periods may cause physical defects in the
developing embryo (teratogenesis).
Oil may contact the skin or be inhaled. Extended exposure can lead to eczema,
inflammation of hair follicles, pigmentation of the face and warts on the soles of the
feet. Exposure to oil mists can cause asthma, pneumonia and scarring of the lungs. Oils
have been linked to cancer of the skin and scrotum. Compounds that are less viscous and
with smaller molecular weights are more dangerous. There may be liver damage and the
lymph nodes may be affected; heart inflammation can also occur at high doses.
TOXICITY AND IRRITATION
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
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Section 11 - TOXICOLOGICAL INFORMATION
Asthma-like symptoms may continue for months or even years after exposure to the material
ceases. This may be due to a non-allergenic condition known as reactive airways
dysfunction syndrome (RADS) which can occur following exposure to high levels of highly
irritating compound. Key criteria for the diagnosis of RADS include the absence of
preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to
severe bronchial hyperreactivity on methacholine challenge testing and the lack of
minimal lymphocytic inflammation, without eosinophilia, have also been included in the
criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an
infrequent disorder with rates related to the concentration of and duration of exposure
to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that
occurs as result of exposure due to high concentrations of irritating substance (often
particulate in nature) and is completely reversible after exposure ceases. The disorder
is characterised by dyspnea, cough and mucus production.
The material may produce severe irritation to the eye causing pronounced inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.
MINERAL OIL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
Toxicity and Irritation data for petroleum-based mineral oils are related to chemical
components and vary as does the composition and source of the original crude.
A small but definite risk of occupational skin cancer occurs in workers exposed to
persistent skin contamination by oils over a period of years. This risk has been
attributed to the presence of certain polycyclic aromatic hydrocarbons (PAH) (typified by
benz[a]pyrene).
Petroleum oils which are solvent refined/extracted or severely hydrotreated, contain very
low concentrations of both.
ETHYLENE GLYCOL MONOBUTYL ETHER:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 470 mg/kg Skin (rabbit): 500 mg, open; Mild
Dermal (rabbit) LD50: 220 mg/kg Eye (rabbit): 100 mg/24h- Moderate
Inhalation (human) TCLo: 100 ppm Eye (rabbit): 100 mg SEVERE
Inhalation (human) TCLo: 195 ppm/8h *
[Union Carbide]
Inhalation (rat- male) LC50: 486 ppm *
Inhalation (rat- female) LC50: 450 ppm *
The material may produce severe irritation to the eye causing pronounced inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.
NOTE: Changes in kidney, liver, spleen and lungs are observed in animals
exposed to high concentrations of this substance by all routes.
AROMATIC HYDROCARBON SOLVENT:
The material may be irritating to the eye, with prolonged contact causing inflammation.
Repeated or prolonged exposure to irritants may produce conjunctivitis.
The material may cause skin irritation after prolonged or repeated exposure and may
produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.
Asthma-like symptoms may continue for months or even years after exposure to the material
continued...
NULON LIFTER FREE AND TUNE UP
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Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 14 of 19
Section 11 - TOXICOLOGICAL INFORMATION
ceases. This may be due to a non-allergenic condition known as reactive airways
dysfunction syndrome (RADS) which can occur following exposure to high levels of highly
irritating compound. Key criteria for the diagnosis of RADS include the absence of
preceding respiratory disease, in a non-atopic individual, with abrupt onset of
persistent asthma-like symptoms within minutes to hours of a documented exposure to the
irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to
severe bronchial hyperreactivity on methacholine challenge testing and the lack of
minimal lymphocytic inflammation, without eosinophilia, have also been included in the
criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an
infrequent disorder with rates related to the concentration of and duration of exposure
to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that
occurs as result of exposure due to high concentrations of irritating substance (often
particulate in nature) and is completely reversible after exposure ceases. The disorder
is characterised by dyspnea, cough and mucus production.
ISOPROPANOL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
Oral (human) LDLo: 3570 mg/kg Skin (rabbit): 500 mg - Mild
Oral (human) TDLo: 223 mg/kg Eye (rabbit): 10 mg - Moderate
Oral (man) TDLo: 14432 mg/kg Eye (rabbit): 100mg/24hr- Moderate
Oral (rat) LD50: 5045 mg/kg Eye (rabbit): 100 mg - SEVERE
Dermal (rabbit) LD50: 12800 mg/kg
The material may cause skin irritation after prolonged or repeated exposure and may
produce on contact skin redness, swelling, the production of vesicles, scaling and
thickening of the skin.
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
NONYLPHENOL, ETHOXYLATED:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of
Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: >2000 mg/kg Skin (human): 15 mg/3D Mild
Dermal (rabbit) LD50: 2830 ul/kg Skin (rabbit): 500 mg Mild
Eye (rabbit): 5 mg SEVERE
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
_______________ ____________ __________ __________ __________
ethylene glycol IARC:3
monobutyl ether
isopropanol IARC:3
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: ethylene glycol
monobutyl ether Category: The substance is classified by IARC as Group 3: NOT
classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be
inadequate or limited in animal testing.
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens: isopropanol
Category: The substance is classified by IARC as Group 3: NOT classifiable as to its
carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in
animal testing.
continued...
NULON LIFTER FREE AND TUNE UP
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Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
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Section 12 - ECOLOGICAL INFORMATION
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
DO NOT discharge into sewer or waterways.
Refer to data for ingredients, which follows:
MINERAL OIL:
DO NOT discharge into sewer or waterways.
ETHYLENE GLYCOL MONOBUTYL ETHER:
Fish LC50 (96hr.) (mg/l): 1490
BCF<100: 0.4
log Kow (Prager 1995): 0.83
log Kow (Sangster 1997): 0.8
Half- life Soil - High (hours): 672
Half- life Soil - Low (hours): 168
Half- life Air - High (hours): 32.8
Half- life Air - Low (hours): 3.28
Half- life Surface water - High (hours): 672
Half- life Surface water - Low (hours): 168
Half- life Ground water - High (hours): 1344
Half- life Ground water - Low (hours): 336
Aqueous biodegradation - Aerobic - High (hours): 672
Aqueous biodegradation - Aerobic - Low (hours): 168
Aqueous biodegradation - Anaerobic - High (hours): 2688
Aqueous biodegradation - Anaerobic - Low (hours): 672
Photooxidation half- life air - High (hours): 32.8
Photooxidation half- life air - Low (hours): 3.28
Fish LC50 (96hr.) (mg/l): 1250- 1650
Daphnia magna EC50 (48hr.) (mg/l): 600- 1000
DO NOT discharge into sewer or waterways.
log Kow: 0.76-0.83
Koc: 67
Half-life (hr) air: 17
Henry's atm m鲁 /mol: 2.08E-08
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Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
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Section 12 - ECOLOGICAL INFORMATION
BOD 5 if unstated: 0.71
COD: 2.2
Log BCF: 0.4
Fish toxicity:
(-) 24h LD50: 983-1650 mg/L
(Fathead minnow) 96h LC50: 1700 mg/L **
Invertebrate toxicity:
cell mult. inhib.91-900mg/L
(Daphnia) 48h LC50: >1000 mg/L **
Bioaccumulation: not sig
Effects on algae and plankton: cell mult. inhib.35-900mg/L
Degradation Biological: rapid
processes Abiotic: no hydrol&photol,RxnOH* ** [Union Carbide]
AROMATIC HYDROCARBON SOLVENT:
The lower molecular weight hydrocarbons are expected to form a "slick" on the surface of
waters after release in calm sea conditions. This is expected to evaporate and enter the
atmosphere where it will be degraded through reaction with hydroxy radicals.
Some of the material will become associated with benthic sediments, and it is likely to
be spread over a fairly wide area of sea floor. Marine sediments may be either aerobic or
anaerobic. The material, in probability, is biodegradable, under aerobic conditions
(isomerised olefins and alkenes show variable results). Evidence also suggests that the
hydrocarbons may be degradable under anaerobic conditions although such degradation in
benthic sediments may be a relatively slow process.
Under aerobic conditions the material will degrade to water and carbon dioxide, while
under anaerobic processes it will produce water, methane and carbon dioxide.
Based on test results, as well as theoretical considerations, the potential for
bioaccumulation may be high. Toxic effects are often observed in species such as blue
mussel, daphnia, freshwater green algae, marine copepods and amphipods.
Drinking Water Standards:
hydrocarbon total: 10 ug/l (UK max.).
Do NOT allow product to come in contact with surface waters or to intertidal areas below
the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste
sites.
DO NOT discharge into sewer or waterways.
ISOPROPANOL:
log Kow (Sangster 1997): 0.05
log Pow (Verschueren 1983): - 0.5714285
BOD5: 60%
BOD20: 78%
COD: 2.23
ThOD: 2.4
Half- life Soil - High (hours): 168
Half- life Soil - Low (hours): 24
Half- life Air - High (hours): 72
Half- life Air - Low (hours): 6.2
Half- life Surface water - High (hours): 168
Half- life Surface water - Low (hours): 24
Half- life Ground water - High (hours): 336
Half- life Ground water - Low (hours): 48
Aqueous biodegradation - Aerobic - High (hours): 168
Aqueous biodegradation - Aerobic - Low (hours): 24
Aqueous biodegradation - Anaerobic - High (hours): 672
continued...
NULON LIFTER FREE AND TUNE UP
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Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 17 of 19
Section 12 - ECOLOGICAL INFORMATION
Aqueous biodegradation - Anaerobic - Low (hours): 96
Photooxidation half- life water - High (hours): 1.90E+05
Photooxidation half- life water - Low (hours): 4728
Photooxidation half- life air - High (hours): 72
Photooxidation half- life air - Low (hours): 6.2
DO NOT discharge into sewer or waterways.
log Kow: -0.16- 0.28
Half-life (hr) air: 33-84
Half-life (hr) H2O surface water: 130
Henry's atm m鲁 /mol: 8.07E-06
BOD 5 if unstated: 1.19,60%
COD: 1.61-2.30,97%
ThOD: 2.4
Aquatic toxicity
(fish) 24-96h TLm: 42.5-240 mg/l
(fish) 96h LC50: 4200-9640 mg/l *
(daphnia) 48h EC50: 2285 mg/l *
BOD 20: >70% * * [Akzo Nobel]
NONYLPHENOL, ETHOXYLATED:
Fish LC50 (96hr.) (mg/l): 1.0- 11.2
Toxicity Fish: LC50(96)0.14-0.23mg/L
(Daphnia magna) 48hr EC50: 86 mg/L *
(rainbow trout) 96hr LC50: 18 mg/L *
Toxicity invertebrate: LC50(144)5mg/L
Bioaccumulation: not significant
Degradation Biological: some with acclim
* [Huntsman]
Section 13 - DISPOSAL CONSIDERATIONS
路 Containers may still present a chemical hazard/ danger when empty.
路 Return to supplier for reuse/ recycling if possible.
Otherwise:
路 If container can not be cleaned sufficiently well to ensure that residuals do not
remain or if the container cannot be used to store the same product, then puncture
containers, to prevent re-use, and bury at an authorised landfill.
路 Where possible retain label warnings and MSDS and observe all notices pertaining to the
product.
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Authority for disposal.
路 Bury or incinerate residue at an approved site.
路 Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.
continued...
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Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
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Section 14 - TRANSPORTATION INFORMATION
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
Nulon Lifter Free and Tune Up (CAS: None):
No regulations applicable
ethylene glycol monobutyl ether (CAS: 111-76-2) is found on the following regulatory lists;
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Agency for Research on Cancer (IARC) Carcinogens
OECD Representative List of High Production Volume (HPV) Chemicals
aromatic hydrocarbon solvent (CAS: 64742-95-6) is found on the following regulatory lists;
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
International Council of Chemical Associations (ICCA) - High Production Volume List
OECD Representative List of High Production Volume (HPV) Chemicals
isopropanol (CAS: 67-63-0) is found on the following regulatory lists;
Australia Exposure Standards
Australia Hazardous Substances
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
IMO IBC Code Chapter 18: List of products to which the Code does not apply
IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances
International Agency for Research on Cancer (IARC) Carcinogens
International Air Transport Association (IATA) Dangerous Goods Regulations
OECD Representative List of High Production Volume (HPV) Chemicals
nonylphenol, ethoxylated (CAS: 9016-45-9) is found on the following regulatory lists;
Australia High Volume Industrial Chemical List (HVICL)
Australia Inventory of Chemical Substances (AICS)
OECD Representative List of High Production Volume (HPV) Chemicals
OSPAR List of Substances of Possible Concern
nonylphenol, ethoxylated (CAS: 26027-38-3) is found on the following regulatory lists;
Australia Inventory of Chemical Substances (AICS)
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5
Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6
No data available for mineral oil as CAS: Not avail.
Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name CAS
nonylphenol, ethoxylated 9016- 45- 9, 26027- 38- 3
REPRODUCTIVE HEALTH GUIDELINES
Ingredient ORG UF Endpoi CR Adeq
nt TLV
ethylene glycol monobutyl 3.6 mg/m3 100 D
NA -
ether
These exposure guidelines have been derived from a screening level of risk assessment and
should not be construed as unequivocally safe limits. ORGS represent an 8-hour time-
continued...
NULON LIFTER FREE AND TUNE UP
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Issue Date: 15-Mar-2008 CHEMWATCH 4957-25
NC317ECP Version No:4
CD 2008/1 Page 19 of 19
Section 16 - OTHER INFORMATION
weighted average unless specified otherwise.
CR = Cancer Risk/10000; UF = Uncertainty factor:
TLV believed to be adequate to protect reproductive health:
LOD: Limit of detection
Toxic endpoints have also been identified as:
D = Developmental; R = Reproductive; TC = Transplacental carcinogen
Jankovic J., Drake F.: A Screening Method for Occupational Reproductive
American Industrial Hygiene Association Journal 57: 641-649 (1996).
EXPOSURE STANDARD FOR MIXTURES
"Worst Case" computer-aided prediction of vapour components/concentrations:
Composite Exposure Standard for Mixture (TWA) (mg/m3): 250 mg/m鲁
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
Component Breathing Zone ppm Breathing Zone mg/m3 Mixture Conc: (%).
Component Breathing zone Breathing Zone Mixture Conc
(ppm) (mg/m鲁) (%)
aromatic hydrocarbon solvent 50.00 250.0000 30.0
Operations which produce a spray/mist or fume/dust, introduce particulates to the
breathing zone.
If the breathing zone concentration of ANY of the components listed below is exceeded,
"Worst Case" considerations deem the individual to be overexposed.
At the "Composite Exposure Standard for Mixture" (TWA) (mg/m3): 250 mg/m鲁
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk
Assessment. Many factors determine whether the reported Hazards are Risks in the
workplace or other settings. Risks may be determined by reference to Exposures Scenarios.
Scale of use, frequency of use and current or available engineering controls must be
considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 15-Mar-2008
Print Date: 10-Apr-2008
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