NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 1 of 10
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
NULON ANTI-WEAR ENGINE TREATMENT
SYNONYMS
"lubricant antiwear"
PRODUCT USE
Engine oil lubricant additive. Used according to manufacturer' s directions.
SUPPLIER
Company: Nulon Products Pty Ltd
Address:
1/4 Narabang Way
Belrose
NSW, 2085
AUS
Telephone: +61 2 9986 7800
Fax: +61 2 9450 2448
HAZARD RATINGS
Flammability
Toxicity
Body Contact
Reactivity
Chronic
SCALE: Min/Nil=0 Low=1 Moderate=2 High=3 Extreme=4
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK SAFETY
Inhalation may produce health damage*. Do not breathe gas/ fumes/ vapour/ spray.
Cumulative effects may result following Use only in well ventilated areas.
exposure*.
Limited evidence of a carcinogenic effect*. Keep container in a well ventilated place.
* (limited evidence). Keep container tightly closed.
Take off immediately all contaminated clothing.
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NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 2 of 10
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
mineral oil Not avail. 30-60
(solvent refined)
additives, unregulated 30-60
polytetrafluoroethylene 9002-84-0 1-10
performance additives 1-10
dye <1
NOTE: Manufacturer has supplied full ingredient
information to allow CHEMWATCH assessment.
Section 4 - FIRST AID MEASURES
SWALLOWED
For advice, contact a Poisons Information Centre or a doctor.
路 If swallowed do NOT induce vomiting.
路 If vomiting occurs, lean patient forward or place on left side (head-down position, if
possible) to maintain open airway and prevent aspiration.
路 Observe the patient carefully.
路 Never give liquid to a person showing signs of being sleepy or with reduced awareness;
i.e. becoming unconscious.
路 Give water to rinse out mouth, then provide liquid slowly and as much as casualty can
comfortably drink.
路 Seek medical advice.
EYE
If this product comes in contact with the eyes:
路 Wash out immediately with fresh running water.
路 Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and
moving the eyelids by occasionally lifting the upper and lower lids.
路 If pain persists or recurs seek medical attention.
路 Removal of contact lenses after an eye injury should only be undertaken by skilled
personnel.
SKIN
If skin contact occurs:
路 Immediately remove all contaminated clothing, including footwear.
路 Flush skin and hair with running water (and soap if available).
路 Seek medical attention in event of irritation.
INHALED
路 If fumes or combustion products are inhaled remove from contaminated area.
路 Lay patient down. Keep warm and rested.
路 Prostheses such as false teeth, which may block airway, should be removed, where
possible, prior to initiating first aid procedures.
路 Apply artificial respiration if not breathing, preferably with a demand valve
resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
路 Transport to hospital, or doctor.
NOTES TO PHYSICIAN
Treat symptomatically.
路 Heavy and persistent skin contamination over many years may lead to dysplastic changes.
Pre-existing skin disorders may be aggravated by exposure to this product.
路 In general, emesis induction is unnecessary with high viscosity, low volatility
products, i.e. most oils and greases.
路 High pressure accidental injection through the skin should be assessed for possible
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NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 3 of 10
Section 4 - FIRST AID MEASURES
incision, irrigation and/or debridement.
NOTE: Injuries may not seem serious at first, but within a few hours tissue may become
swollen, discoloured and extremely painful with extensive subcutaneous necrosis. Product
may be forced through considerable distances along tissue planes.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
路 Foam.
路 Dry chemical powder.
路 BCF (where regulations permit).
路 Carbon dioxide.
路 Water spray or fog - Large fires only.
FIRE FIGHTING
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Wear breathing apparatus plus protective gloves.
路 Prevent, by any means available, spillage from entering drains or water course.
路 Use water delivered as a fine spray to control fire and cool adjacent area.
路 Avoid spraying water onto liquid pools.
路 Do not approach containers suspected to be hot.
路 Cool fire exposed containers with water spray from a protected location.
路 If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
路 Combustible.
路 Slight fire hazard when exposed to heat or flame.
路 Heating may cause expansion or decomposition leading to violent rupture of containers.
路 On combustion, may emit toxic fumes of carbon monoxide (CO).
路 May emit acrid smoke.
路 Mists containing combustible materials may be explosive.
Other combustion products include:.
carbon dioxide (CO2). and hydrogen chloride.
FIRE INCOMPATIBILITY
Avoid contamination with strong oxidising agents as ignition may result.
HAZCHEM: None
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
路 Remove all ignition sources.
路 Clean up all spills immediately.
路 Avoid breathing vapours and contact with skin and eyes.
路 Control personal contact by using protective equipment.
路 Contain and absorb spill with sand, earth, inert material or vermiculite.
路 Wipe up.
路 Place in a suitable labelled container for waste disposal.
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NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 4 of 10
Section 6 - ACCIDENTAL RELEASE MEASURES
MAJOR SPILLS
Slippery when spilt.
Remove all ignition sources.
Minor hazard.
路 Clear area of personnel.
路 Alert Fire Brigade and tell them location and nature of hazard.
路 Control personal contact by using protective equipment as required.
路 Prevent spillage from entering drains or water ways.
路 Contain spill with sand, earth or vermiculite.
路 Collect recoverable product into labelled containers for recycling.
路 Absorb remaining product with sand, earth or vermiculite and place in appropriate
containers for disposal.
路 Wash area and prevent runoff into drains or waterways.
路 If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
Remove all ignition sources.
Avoid generating and breathing mist.
路 Limit all unnecessary personal contact.
路 Wear protective clothing when risk of exposure occurs.
路 Use in a well-ventilated area.
路 When handling DO NOT eat, drink or smoke.
路 Always wash hands with soap and water after handling.
路 Avoid physical damage to containers.
路 Use good occupational work practice.
路 Observe manufacturer's storing and handling recommendations.
SUITABLE CONTAINER
路 Metal can or drum
路 Packaging as recommended by manufacturer.
路 Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
Avoid storage with oxidisers.
_____________________________________________________
SAFE STORAGE WITH OTHER CLASSIFIED CHEMICALS
+ + + + + +
_____________________________________________________
+: May be stored together
O: May be stored together with specific preventions
X: Must not be stored together
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA mg/m鲁
_________ _________ _____
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NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 5 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
Australia Exposure Standards mineral oil (Oil mist, refined 5
mineral)
Australia Exposure Standards polytetrafluoroethylene 10
(Inspirable dust (Not
specified))
ODOUR SAFETY FACTOR (OSF)
OSF=0.001 (polytetrafluoroethylene)
Exposed individuals are NOT reasonably expected to be warned, by smell, that the Exposure
Standard is being exceeded.
Odour Safety Factor (OSF) is determined to fall into either Class C, D or E.
The Odour Safety Factor (OSF) is defined as:
OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm
Classification into classes follows:
Class OSF Description
A 550 Over 90% of exposed individuals
are aware by smell that the
Exposure Standard (TLV- TWA for
example) is being reached, even
when distracted by working
activities
B 26- 550 As " A" for 50- 90% of persons
being distracted
C 1- 26 As " A" for less than 50% of
persons being distracted
D 0.18- 1 10- 50% of persons aware of
being tested perceive by smell
that the Exposure Standard is
being reached
E <0.18 As " D" for less than 10% of
persons aware of being tested
.
MATERIAL DATA
Not available. Refer to individual constituents.
INGREDIENT DATA
MINERAL OIL:
Human exposure to oil mist alone has not been demonstrated to cause health effects
except at levels above 5 mg/m3 (this applies to particulates sampled by a method that
does not collect vapour). It is not advisable to apply this standard to oils containing
unknown concentrations and types of additive.
POLYTETRAFLUOROETHYLENE:
For thermal decomposition products, i.e.substances of variable composition
No TLV is recommended pending toxicity determination of decomposition
products, but their concentration in air should be minimal. [ACGIH]
PERSONAL PROTECTION
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NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 6 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EYE
路 Safety glasses with side shields; or as required,
路 Chemical goggles.
路 Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens or
restrictions on use, should be created for each workplace or task. This should include a
review of lens absorption and adsorption for the class of chemicals in use and an account
of injury experience. Medical and first-aid personnel should be trained in their removal
and suitable equipment should be readily available. In the event of chemical exposure,
begin eye irrigation immediately and remove contact lens as soon as practicable. Lens
should be removed at the first signs of eye redness or irritation - lens should be
removed in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
No special equipment needed when handling small quantities.
OTHERWISE: Wear chemical protective gloves, eg. PVC.
Safety footwear may be required.
OTHER
路 Overalls.
路 Eyewash unit.
The local concentration of material, quantity and conditions of use determine the type of
personal protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
Use in a well-ventilated area.
General exhaust is adequate under normal operating conditions. If risk of overexposure
exists, wear SAA approved respirator. Correct fit is essential to obtain adequate
protection. Provide adequate ventilation in warehouse or closed storage areas. Air
contaminants generated in the workplace possess varying "escape" velocities which, in
turn, determine the "capture velocities" of fresh circulating air required to effectively
remove the contaminant.
Type of Contaminant: Air Speed:
solvent, vapours, degreasing etc., evaporating 0.25- 0.5 m/s (50- 100 f/min)
from tank (in still air)
aerosols, fumes from pouring operations, 0.5- 1 m/s (100- 200 f/min.)
intermittent container filling, low speed
conveyer transfers, welding, spray drift,
plating acid fumes, pickling (released at low
velocity into zone of active generation)
direct spray, spray painting in shallow booths, 1- 2.5 m/s (200- 500 f/min)
drum filling, conveyer loading, crusher dusts,
gas discharge (active generation into zone of
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NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 7 of 10
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
rapid air motion)
grinding, abrasive blasting, tumbling, high 2.5- 10 m/s (500- 2000 f/min.)
speed wheel generated dusts (released at high
initial velocity into zone of very high rapid
air motion).
Within each range the appropriate value depends on:
Lower end of the range Upper end of the range
1: Room air currents minimal or favourable to 1: Disturbing room air currents
capture
2: Contaminants of low toxicity or of nuisance 2: Contaminants of high toxicity
value only
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood - local control only
Simple theory shows that air velocity falls rapidly with distance away from the opening
of a simple extraction pipe. Velocity generally decreases with the square of distance
from the extraction point (in simple cases). Therefore the air speed at the extraction
point should be adjusted, accordingly, after reference to distance from the contaminating
source. The air velocity at the extraction fan, for example, should be a minimum of 1-2
m/s (200-400 f/min.) for extraction of solvents generated in a tank 2 meters distant from
the extraction point. Other mechanical considerations, producing performance deficits
within the extraction apparatus, make it essential that theoretical air velocities are
multiplied by factors of 10 or more when extraction systems are installed or used.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Opaque viscous liquid; does not mix with water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Molecular Weight: Not applicable Boiling Range (掳 Not av ailable
C):
Melting Range (掳 Not available
C): Specific Gravity (water= 1): Not available
Solubility in water (g/L): Immiscible pH (as supplied): Not applicable
pH (1% solution): Not applicable Vapour Pressure (kPa): Not available
Volatile Component (%vol): Not available Evaporation Rate: Not available
Relative Vapour Density (air=1): Not available Flash Point (掳 Not available
C):
Lower Explosive Limit (%): Not available Upper Explosive Limit (%): Not available
Autoignition Temp (掳 Not available
C): Decomposition Temp ( 掳 Not available
C):
State: Liquid Viscosity: Not available
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
路 Presence of incompatible materials.
路 Product is considered stable.
路 Hazardous polymerisation will not occur.
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NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 8 of 10
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
The material is. slightly discomforting to the gastro-intestinal tract Ingestion may
result in nausea, abdominal irritation, pain and diarrhoea.
Considered an unlikely route of entry in commercial/industrial environments.
EYE
The material is. slightly discomforting to the eyes.
SKIN
The material is. slightly discomforting to the skin.
if exposure is prolonged. and is capable of causing skin reactions from repeated
exposures over long periods which may lead to dermatitis.
INHALED
Not normally a hazard due to non-volatile nature of product.
The vapour/mist is. moderately discomforting to the upper respiratory tract.
Inhalation hazard is increased at higher temperatures.
A vapour/mist containing chlorinated paraffins of more than 10 carbon atoms and a
chlorine content ranging between 40 and 70% may produce a sore throat, coughing and
shortness of breath.
CHRONIC HEALTH EFFECTS
Oil may contact the skin or be inhaled. Extended exposure can lead to eczema,
inflammation of hair follicles, pigmentation of the face and warts on the soles of the
feet. There are few systemic effects, but prolonged exposure may lead to a higher
incidence of lung scarring.
TOXICITY AND IRRITATION
None assigned. Refer to individual constituents.
MINERAL OIL:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
Toxicity and Irritation data for petroleum-based mineral oils are related to chemical
components and vary as does the composition and source of the original crude.
A small but definite risk of occupational skin cancer occurs in workers exposed to
persistent skin contamination by oils over a period of years. This risk has been
attributed to the presence of certain polycyclic aromatic hydrocarbons (PAH) (typified by
benz[a]pyrene).
Petroleum oils which are solvent refined/extracted or severely hydrotreated, contain very
low concentrations of both.
POLYTETRAFLUOROETHYLENE:
unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.
TOXICITY IRRITATION
Oral (rat) LD50: 1250 mg/kg * Nil Reported * [Manufacturer]
Oral (rat) LD50: 4230 mg/kg **
Oral (Mouse) LD50: 5000 mg/kg
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
MATERIAL CARCINOGEN REPROTOXIN SENSITISER SKIN
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NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 9 of 10
Section 11 - TOXICOLOGICAL INFORMATION
_______________ ____________ __________ __________ __________
polytetrafluoroeth IARC:3
ylene
CARCINOGEN
IARC: International Agency for Research on Cancer (IARC) Carcinogens:
polytetrafluoroethylene Category: 3
Section 12 - ECOLOGICAL INFORMATION
No data for Nulon Anti-Wear Engine Treatment.
Refer to data for ingredients, which follows:
MINERAL OIL:
DO NOT discharge into sewer or waterways.
POLYTETRAFLUOROETHYLENE:
DO NOT discharge into sewer or waterways.
Substances which are completely perfluorinated (that is, fluoride groups completely
substitute for hydrogen groups) or contain substantial proportions of perfluorinated
region, resist biodegradation in most natural environments.
Section 13 - DISPOSAL CONSIDERATIONS
路 Recycle wherever possible or consult manufacturer for recycling options.
路 Consult State Land Waste Authority for disposal.
路 Bury or incinerate residue at an approved site.
路 Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
HAZCHEM: None
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA,
IMDG
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
Nulon Anti-Wear Engine Treatment (CAS: None):
No regulations applicable
polytetrafluoroethylene (CAS: 9002-84-0) is found on the following regulatory lists;
Australia Exposure Standards
Australia Inventory of Chemical Substances (AICS)
International Agency for Research on Cancer (IARC) Carcinogens
No data available for mineral oil as CAS: Not avail.
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NULON ANTI-WEAR ENGINE TREATMENT
Chemwatch Material Safety Data Sheet
Issue Date: 14-May-2004 CHEMWATCH 5076-22
NC317TCP Version No:3
CD 2007/3 Page 10 of 10
Section 16 - OTHER INFORMATION
Classification of the preparation and its individual components has drawn on official and
authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written permission
from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 14-May-2004
Print Date: 8-Apr-2008
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